Corrosion is tendency deterioration reaction between
of the metal and environments in either of:
• Chemical attack • Electrochemical attack. The corrosion process always involves two simultaneous changes a metal attack or oxidize suffers (anodic change), and the corrosive agent is reduced (cathodic change). Deterioration of a material due to interaction with its environment (water or water vapor containing salt combine with oxygen). Two general classifications of corrosion: • Direct Chemical Attack Resulting from exposure of a bare surface to caustic liquid or gaseous agents • Spilled battery acid or fumes from batteries • Residual flux deposits inadequately cleaned, welded, etc • Entrapped caustic cleaning solutions Page 3 Mai 2011 Deterioration of a material due to interaction with its environment (water or water vapor containing salt combine with oxygen). Two general classifications of corrosion: • Electrochemical Attack • Likened chemically to the electrolytic reaction which takes place in electroplating, anodizing, or in a dry- cell battery • Requires a medium, usually water through which electrons may flow
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Page 5 Mai 2011 Page 7 Mai 2011 Elimination of any one of these conditions will stop corrosion.
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Chemical (Oxidation) With introduction of oxide film (sealed lead-acid, use nicad battery) to prevents the further corrosive. Remove residual flux from the metal surface immediately after the joining operation. Particular attention using a cleaning solutions should be directly toward their complete removal after use on aircraft. Electrochemical (Galvanic) The reaction in this corrosive attack requires a medium. Occur not only on the surface of metal, also within the granular structure of the metal. When a metal comes in contact with a corrosive agent and is also connected by a liquid or gaseous path through which electrons may flow, corrosion begins as the metal decays by oxidation. Form of Corrosion Surface Corrosion appears as a general roughening, etching, or pitting of the surface of a metal (powdery deposit of corrosion product) caused by Direct Chemical or Electrochemical attack. Corrosion will spread under the surface coating and cannot be recognized, closer inspection will reveal the paint or plating is lifted off the surface in small blisters which result from the pressure of the underlying accumulation of corrosion products. Form of Corrosion. Filiform Corrosion. Occurs beneath thin, with the paint or coating of bulging or blistering and very shallow. As a result, this type of corrosion (on bearing surfaces) has also been called false brinelling. Form of Corrosion. Galvanic (Dissimilar) Corrosion may result from contact between dissimilar metal parts in the presence of a conductor (electrochemical action of two dissimilar metals in the presence of an electrolyte and an electron conductive path) The contamination of a metal’s surface by mechanical means can also induce dissimilar metal corrosion. • Dissimilar Metal Corrosion Result from contact between dissimilar metal parts, electrochemical attack can be very serious.
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Form of Corrosion. Intergranular Corrosion (Inter crystalline) type of corrosion is an attack along the grain boundaries of an alloy results from a lack of uniformity caused by changes that occur in the alloy during heating and cooling. Inspected this corrosion can be detected by ultrasonic, eddy current or radiographic • Intergranular Corrosion Attack along the grain boundaries of an alloy. The lack of uniformity is caused by changes that occur in the alloy during heating and cooling.
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Form of Corrosion. Exfoliation Corrosion. Severe intergranular corrosion may sometimes cause the surface of a metal to “exfoliate”, a lifting or flaking of the metal at the surface due to delamination of the grain boundaries caused by the pressure of corrosion residual product buildup (just below the surface). Form of Corrosion. Stress Corrosion. As the result of the combined effect of sustained tensile stresses and a corrosive environment, is found in most metal. Usually occurs during manufacturing process (residual stress from). Form of Corrosion. Fretting Corrosion. Is a particularly damaging form of corrosive attack that occurs when two mating surfaces (rubbing), normally at rest with respect to one another, are subject to slight relative motion (occurs at the interface between contacting, highly loaded metal surfaces when subjected to slight vibratory motions). As a result, this type of corrosion (on bearing surfaces) has also been called false brinelling. Form of Corrosion. Pitting Corrosion. Occurs when the protective film breaks down localized corrosion and may also lead to intergranular corrosion. Local rough spots, contaminations and lack of homogeneity possible cause of pitting appears of white powder on the surface. Form of Corrosion. Microbiological Contamination. Caused by directly or indirectly (one or more ways), by micro-organism which able to produce corrosive, but also acts as catalysts in corrosion reactions (growth of micro-organisms in moisture traps). Microbial corrosion (also called microbiologically - influenced corrosion or MIC) is corrosion that is caused by the presence and activities of microbes. This corrosion can take many forms and can be controlled by biocides Factors Affecting Corrosion: Many factors affect the type, cause, speed attack and seriousness of metal corrosion • Climate Conditions under which an aircraft is maintained and operated greatly affect corrosion characteristics (marine environment). Temperature considerations are important because the speed of electrochemical attack is increased in a hot, moist climate. Factors Affecting Corrosion: Many factors affect the type, cause, speed attack and seriousness of metal corrosion • Foreign Material Factors which affect the onset and spread of corrosive attack • Soil and atmospheric dust. • Oil, grease, and engine exhaust residues. • Salt water and salt moisture condensation. • Spilled battery acids and caustic cleaning solutions. • Welding and brazing flux residues. Preventive Maintenance. It is important that aircraft be kept clean. How often and to what extent an aircraft should be cleaned depends on several factors, improvement the corrosion resistance • Improvement material • Surface treatment • Protective finishes Corrosion preventive maintenance includes • Adequate cleaning • Thorough periodic lubrication • Detailed inspection • Daily draining of fuel, keep drain holes free • Sealing aircraft against of water, proper ventilation • Use protective cover • Corrosion-Prone areas Lavatories and galleys, they are not kept clean, waste products may accumulate causes corrosive attack. Pay attention to bilge areas located under galleys and lavatories and to personnel relief and waste disposal vents or openings on the aircraft exteriors.
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Corrosion Removal In general, any complete corrosion treatment involves the following • Cleaning and stripping of the corroded area, • Removing of the corrosion products, • Neutralizing any residual materials, • Restoring protective surface films, and • Applying temporary or permanent coatings or paint finishes. Surface Protection Aircraft parts are almost given some of surface finish by the manufacturer to provide corrosion resistance, surface finishes may also be applied to increase wear resistance or to provide a suitable base for paint. Surface treatments usually include a cleaning treatment to remove all of dirt, oil, grease, oxides, and moisture (to provide an effective bond). Surface Protection The cleaning process may be either Mechanical (wire brush, steel wool, emery cloth, sandblasting) or Chemical (various chemical processes) depend on the material being cleaned and the type of foreign matter being removed. Surface Protection Treatment - the most common surface treatment of nonclad aluminum alloy surfaces is Anodizing, increases the thickness and density of the natural oxide film. When an anodized surface is cleaned including corrosion removal, should avoid unnecessary destruction of the oxide film. Surface Protection Alodizing is a simple chemical treatment for all aluminum alloys to increase their corrosion resistance and to improve their paint bonding qualities, consists of precleaning with an acidic or alkaline metal cleaner then rinsed with fresh water, after thorough rinsing applied Alodine®. Surface Protection Permanent treatment: • Electroplating • Sprayed • Cladding. Corrosion Preventive maintenance: • Adequate cleaning (remove dirt), • Periodic lubrication. • Treatment of corrosion of protective systems. • Drain holes free obstruction
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Painting and Finishing To protect the exposed surfaces from corrosion and deterioration, easier to clean and maintain because the exposed surfaces are more resistant to corrosion and dirt, provide the desired appearance. Term “paint” (includes primers, enamels, lacquers, and the various multipart finishing formulas) has three components: • Resin as coating material, • Pigment for color, and • Solvents to reduce the mix to a workable viscosity. Painting and Finishing Paint scheme a color ideas and color preferences should be silhouette drawing (easier to change a drawing than to remask). The primary objective of paint finish is to protect exposed surfaces against corrosion and other forms of deterioration. Painting and Finishing To protect from corrosion and deterioration, present a pleasing appearance (decorative finishing includes trim striping, logos and Emblems, decals, identification numbers, and letters). Painting and Finishing Paint touchup may be required on repair to the surface used to cover minor topcoat damage, such as scratches, abrasions of the trim colors. The paint system may consist of: • A primer (base coat that improves adhesion and inhibits corrosion), • A compatible topcoat (the finish coating material used over the primer), or • A combination of primer and compatible topcoat Surface Preparation Properly surface preparation will results are a long- lasting, corrosion-free finish. Remove all soils, lubricants, and preservatives from the surface (aluminium) scrubbed with Scotch-Brite® pads using an alkaline aviation cleaner. Kept wet and rinsed with clean water until the surface is water break free (no beads or breaks in the water surface). Surface Preparation Wash using a new sponge and covering a small area while keeping it wet, then rinsed with clean water without allowing the solution to dry on the surface. Continue this process until all the aluminum surfaces are washed and Rinsed. When the surfaces are completely dry, apply Alodine® or another type of an aluminum conversion coating, keep it wet then be thoroughly rinsed with clean water to remove all chemical salts. Surface Preparation When the surface is thoroughly dry, applied the primer (compatible with the topcoat finish) as soon as possible (recommended manufacturer). The primer should be one that is compatible with the topcoat finish. Two-part epoxy primers provide: • Excellent corrosion resistance and adhesion, Urethane surfaces, and • Polyurethane topcoats. Surface Preparation Epoxy sanding primers provide an excellent base over composites, finish sanded with 320 grit using a dual action orbital sander (compatible with two-part epoxy primers and polyurethane topcoats). Primer and Painting . Painting and Finishing . Painting and Finishing .