SURPRISE TEST

BHUBANESWAR CENTRE
ST# 01 [OC] DATE : 20/05/2023
1. Choose the incorrect option?

O O
C–OH O C–OH
N
(1) O > [Acidic strength]

N
O O



(2) CH CH3 > CH3 CH3
3

CH3 CH3 CH3 CH3

[Stability of cation]

O O
N 1
CH3 CH3
(3) Bond length  1 >  2

2
N
O O

(4) None of these

2.
Br2
(A) DryNa
ether (B)
h

Product B is :-

(1) (2) (3) (4)

3. Following carbocation rearrange to :-

(1) (2) (3) (4) No rearrangement

|
4. –C=C–C–H which H is abstracted easily :-
| | | 
H H
 

(1)  (2)  (3)  (4) with equal case

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5. How many of following are meta directing ?
–CH3, –CCl 3, –NO2, –SO3H, –NH2, –OH, –COOH
(1) 3 (2) 4 (3) 2 (4) 7

6. Tautomerism is possible in :-

CH3
(1) H–C=O (2) CH3–C–CHO (3) Ph–CHO (4) CH3–CH2–C–CH2–CH3
H CH3 O
7. The order of stability of the following carbocations :
+ 
(I) CH 2=CH–CH2 (II) CH3 – CH 2 – C H 2

+
CH2

(III)

(1) III > I > II (2) III > II >I (3) II > III > I (4) I > II > III
8. Which of the following is the most stable free radical ?
(1) (CH3)3C (2) CH3CH 2 (3) (CH3)2CH (4) CH 2=CH–CH2
9. CH3CH 2Cl undergoes homolytic fission, produces :
+ + +
(1) CH3CH 2 and Cl (2) CH3CH2 and Cl– (3) CH3CH 2 and Cl (4) CH3CH2 and Cl–
10. Correct match is :-

CH2
CH2

(1) < Carbocation stability


O
(2) CH3–C–O > O Stability

O

– O – H (Bond length  > )
(3) CH 3 – C 

(4) All
11. Among the following the weakest base is –
(1) C 6H 5CH 2NH 2 (2) C6H5CH2NHCH3 (3) NO2CH2NH2 (4) CH3NHCHO
12. Which of the following is maximum basic?
(1) (CH3)4NOH (2) (CH3)3N (3) (CH3)2NH (4) CH3NH2
13. Which of the following statements are correct :
O
(1) CH2 is more stable than CH3–C–CH 2

(2) Boiling point of o-nitrophenol is more than p-nitrophenol

(3) pyroll is more basic than pyridine
(4) 2-Butene is more stable than 2-pentene

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14. We have some boxes on the basis of effect of their groups in it. But one naugnty student mixed all the
groups in one box
Groups:-

, , ,

, , ,

Now we have task to put again this groups in their corresponding boxes. 'SKC' has give this work to
his students of phase 'MEJ' then choose the correctly matched boxes :-
+I –I +M –M

–CH3,–O, –NO2–NH3,–OH, –OH, –O –NO3, –PH,

(1) –Et –N=O,–Ph –NH3 –N=O

–CH3,–Et –NO2, –NH3 , –OH, –O –Ph, –NO2

(2) –Ph, –O –OH, –N=O –N=O,–Ph –NH3

–CH3,–Et –NO2, –NH3, –OH, –O –Ph, –NO2

(3) –O –OH, –N=O, –Ph –NH3–Ph –N=O

–CH3,–Et –Ph, –NO2, –NH 3, –OH, –O –NO2, –N=O

(4) –O –N=O,–OH –N=O,–Ph –Ph

15. Which of the following is not aromatic?

(1) (2) (3) (4)

N
16. Which one of the following ion is aromatic?

 H
(1) (2) (3) (4)
  H 

17. Which of the following is aromatic?



(1) (2) (3) (4)
O
18. Which of the following compound is Anti-Aromatic?

H H H
N N N
(1) (2) (3) (4)
N N
H
19. Choose the correct statement?
(1) Resonance involve delocalisation of –electron.
(2) Tautomeric structres are hypothetical as resonating.
(3) Resonating hybrid is hypothetical
(4) CH3–CHO and CH2 = CH – OH are tautomer's of each other.

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20. Which of the following has + R – effect?
(1) – CN (2) – CHO (3) – NH2 (4) – NO2
21. Stability order of following resonating structure is :-
– + – +
CH2=CH–OH CH2–CH=OH CH2–CH–OH
I II III
(1) I > II > III (2) II > I > III (3) I > III > II (4) III > I > II
22. Which of the following can show conjugation?

(1) CH2=CH–NH 3 (2) CH2=CH–CH2–NH2 (3) CH 2=CH–BH2 (4) CH2=CH–CH3
23. Which can show +M effect?
(1) –NO2 (2) –OH (3) –CH=O (4) – C–CH3
O
24. Which is most basic?

(1) CH3– NH2 (2) CH3–C–NH2 (3) –NH2 (4) NH3

O
25. Resonance is not obsorved in :-

(1) NH3 (2) CH2=CH–CH=NH (3) CH2=C=C=CH2 (4) Cl

26. Incorrect statement for stereoisomer is :-

(1) Different structural formula (2) Same molecular formula
(3) Different stereochemical formula (4) All

27. Select the correct options :

I Cl
F Cl
Cl F C
(I) (II) C=C (III) C
I Br
Br I F Br

(1) I and II are identical compound (2) II and III are position isomers
(3) I and III are geometrical isomers (4) II and III are geometrical isomers

28. Which of the following statement is correct for optical isomerism?

(1) Chirality in molecule is necessary and sufficient condition for optical isomerism.
(2) Achirality in molecule is necessary and sufficient condition for optical isomerism.
(3) Achiral molecule always show optical isomerism
(4) Meso-compound have ability to rotate plane polarise light.

29. Which of the following shows geometrical as well as optical isomerism?

CH3 Cl

(1) CH3–CH=CH–CH–CH3 (2) CH3–C=CH–CH3 (3) CH3–CH=CH–CH3 (4) CH3–CH–CH2–CH3

Cl
30. Which is optically active?
COOH
HO H
HO CH3 H OH
(1) H3C CH3
(2) (3) (4)
Cl H OH

COOH

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