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Joqysiou-so120u SOIWVYAD OL NOLLINGOXINI 0o Table 2.6. Coordination Simple Tonte Structures Grouped According to Anion Packing Number Sites ‘Anion Packing of M and 0 by Cations Structure Name Examples Cubie close-packed 6:6 MO All oct. Rock salt NaCI. KCl. LiF. KBr. MgO, CaO. SrO, BaO, C40, VO, MnO, FeO, CoO, NiO Cubic close-packed 4:4 MO U2 tet Zine blende ZnS, BeO, SIC Cubic close-packed 4:8 M0 Al tet. Antifluorite Li, Na.O, K,0, Rb.O, sulfides: Distorted cubic 6:3MOs 12 oct. Rutile TiOs, GeO», SnO:, PEO, VOs, NbOr close-packed TeOs, MnO, RUO:, 050, tO; Cubic close-packed 12:6:6 ABO, U4 oct. (B) ——_Perovskite CoTiOs, $FTIO,, SrSNOs, ZO, ‘StHfOs, BaTiO, Cubie close-packed 4:6:4 AB.O. 18 tet. (A) Spinel FeALO., ZnALO., MBALO. 12 oct. @) Cubic close-packed 4:6:4 B(AB)O, ‘1/8 tet. (B) Spinel FeMgFe0., MaTiMgO. U2 oct. (A,B) (inverse) Hexagonal close- 4:4MO 12 tet Wurtzite ZnS, Zn0, SiC packed Hexagonal close 6:6MO All oct Nickel arsenide NiAs, FeS, FeSe, CoSe packed Hexagonal close- 6:4 M05, 218 oct Corundum ALO, FesOs, COs, TOs, Vin, packed G205,Rh.Os Hexagonal close 6:6:4 ABOs 213 oct. (A,B) Iimenite FeTi0s, NiTiO,, COTIOS packed Hexagonal close 6:4:4 A:BO. 12 oct. (A) Olivine Mg.Si0., Fe:SiO. packed 18 tet. (B) Simple eubie 8:8MO All cubic scl CSCI, CsBr, Cst Simple cubic 84MO: 12 cubic Fluorite ‘ThO:, CeO}, PrOs, UOs, 210, HO, NpO,, PuOs, AmO: z a 5 (o'H wr suopys0d ua8ex0 pue“Oag os) HN9NA5 HZ) iSFig 2.2806). 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