Welty - Ch29

BK dutta - Ch3

* 911112021 →
Makeup recording .

* 10/11/2021

☐

☐

Dalton's Law : -

Rauh's law → more applicable :

Pa
=

ya ✗ f- Ma = ✗
Pauap • non -

dilute sol.fr#~- 1)

✓ Ideal

fctemp)
*
systems .

gas
phase →YA_ Prtvap =

PA Pt
→

Cig phase
. .

}
Ranks law
'

Liquid

Tf DA : my
Gas & Henry 's law

CA : conc in
f- ( wa) in
fraction
Liquid .

or
Liquid

phase .

f- ( CA)
ya moi fraction
[ Liq Liq ]
:

in
gas phase
.
-

2 2

⑦ 420 → Not miscible
-

conch .
→
liquid

phase .

Henry 's law

0
..

if it is dilute solution

:-

pressures
Pai = HCAÑ

Gas [ eq .

relationship

phase
.

It is tranter from Gas → liquid .

* PAG > Pai Cai > CAL

↳ This doesn't
→
It's still
mean MT ocker
from ing

occurring From gas

Liquid togas

to liquid .

How would you check wether MT occurring

from [gas Liquid] or from [ Liquid to gas ] ?

→

[ Paa -

Pai] ✓ Not Pai and Cai

Kai -

CAL ]

PAG -
Pai > 0 ,
[Gas →
t.iq ]
.

Cai -
CAL > 0 [ Gas →
Liq]

CAL -
Cai 70 , [ Lig → Gas ]

[ MCQ ]

capital

previous topic

Avg MTC → for the

plate
↳ Avg over
.

the area .

Ka = Ka Individual MTC

sr ↳ only for
T

that particular

and local MTC

phase
particular point ( Ks)
-

dependent
KL Kc the phase

on
= .

[ NA gas =
NA Liquid ]

↳ because ,NA occurring through

the interface .

To Flux =

am%Fa.FI?Mty-=rmnI---kLCS Driving] force

=
Diffusion-1 Convection
if film

KL = Kc = Mls =
DgAB_=Theory ✓

is
applicable .
fluid
motion

a- Vmol =¥-V.moi .

What is
equation

of straight line .

g. Yi

←
⑧ Yz Yi -
=
Slope of

qy¥n . (Cal , Paa) the line

pom $292 = M

imposes
.

•
( Cai , Pai)
.

I 1

PAG - I

1 •
1- CAL

1 !
is

PAG Pai → slope

negative
-

=
.

TAL -
Cai ka

Kiska > 0

equilibrium line →
Yai = Hasani

imorhcial is
Pai)
☒
Measuring
core
very

Kai ,

difficult .

Gas : Ka sp =
Kabc =

Ky by

ftp.?-) -KaR- DyKyKc- KaRTLiguid:KLDc=Kabs

KGPT

¥ side
liquid

=
Kc G- Dc
mole fraction .

F-

= KLCT Dr

=
Knbr

gays axis

]→
side
,

gas µ axis
.

✗
-

⑨ CAL liquid
* →

PA = →

¥

Ccac Pa )
.

The point ,

Line
is also on
eg . .

liquid /

↳ mCA% PAG
side

→

eq relationships
.

toTake care of

to remember
&
.

PA
.
-
MEAL →

Pai mcai
/

-_

same slope

In which part
in all cases .

Question

in
if they are lineeirlyrelaled

Exam : 's law applicable ?
is
henry
-

line

eg .
.

Answer 8 Linear part .

'

×É÷¥

In which part

É is Raut 's law ?

*

non linear
-

part .


Fitment because z

Gas Liquid

→
Pat is that conc .

bj¥rt
'
side

Paa > Pa in the gas

> CAL which is
•

←
and CA in
equ
.

With bulk cone of

the
Liquid
→
Gas liquid side

Dviuingft
.

CAL > ( A-
•

PA
.
> PAG ⇐liquid
gas

Gas liquid .

1- I

1
EG
→ 1 DUK

Duk 1
dL
,

I -1

1 I

film

where is the resistance ? Gone .

[resistance anon film] varying

.

HowoH-his ?

¥ +1¥ Gas → liquid

NA =KG[ Paa Pa ]
'

Pai]

=§[ Paa -

(0cal .

=
KL [ Cai
-
CAL]

]
KL (
.
= CA -

CAL

1
PAG_-PA[ Paa Pai Pai Pa . 1

kg
=

ka[ PAG Pai]

-
= -

ka( Paa Pai) -

+
-

KGCPAG Pai) -
=

Fg
+
☐

eg relationships
CAL]
¥-1m

[ Cai
.
.

mcai
-

Pa;
.

=
=

KL [ Cai -
CAL ] pa•=m CAL

# IT
+

⇐
=

Done

☐ Tryth

(Chapter Welty )

29 -
.

Gas liquid

I 1

I 1

A
#

B l
l

UMD ←
stagnant I

or ,
moving

GEMTD

if MT UMD → K

if '
MT EMCD →
K

k=I
YBM

when we studied MT
only

in one phase

¥9M
"

liquid

phase controlled
MT
Gas phage controlled
MT
.

gas
.

of A in
"
•
Solubility of
Aingas is Now when

Stability
"

LOW Tranter from

⑨

Residence
gas
to
liquid
phase
liquid Then
lliquidlgasj
• in ,

is low .

gas

Interphase .

• Resistance in
liquid ¥ → is
High

DAB<<④ki<<Dn①

is high Ka low Mt controlled Ran controlled

.

is

is
high
liquid phase
•

, d

•
µ resistance is low Rtn
resistance
Gas
phase I ryg.mx
.

is low .

pve%°p That cods

be low
.
will

=0

if controlled

vapour phase .

KG = is low .

⇐ is high .

⇐ = 0