SHARJAH INDIAN SCHOOL, PREPARATORY EXAMINATION ~ 2022-2093) Class: X1(G.W) ‘Time Allotteds ty; hrs Subject: CHEMISTRY Max, Marks: 35, Day & Date: Wednesday, 18/01/2023. General Instructions: Read the following instructions carefully, 8) There are questions in this question paper with internal choice. b) SECTION A consists of multiple-choice questions carrying 1 mark ech ©) SECTION B consists of very short answer questions carrying 2 marks each 4) SECTION C consists of short answer questions carrying 3 marks cach, ©) SECTION D consists of case-based questions carrying 4 marks, 1) SECTION Econsiss of long answer questions carying $ marks. £8) All questions are compulsory. 'h) Use of log tables and calculators isnot allowed. see ee SECTION 4 ‘The following questions are multiple-choice questions with one correct answer- Each question carries 1 mark. 1. The shape and bond angle of BFs molecle () Linear, 180° ‘@JTrigonal planar, 120° (©) Tetrahedral, 109.5° (@) Trigonal pyramidal, 107° 2. The number of sigma (0) and pi (n)bonds present in CH\COOH (b) 6 6 and one x bond we (©) 6 cand2 x bonds we (@) Tc and 2.x bonds - 3. AP" is isoelectronic with GH O)CH Na (Gz Page 1 of 44. Bay! propanat is (@) H.CO0-ch.cry o Ci-CH-Coo-cH-Ch ©) CHs-COO-Cal (@) CHs-Coo.cHt-ctl-CH 5. Which of the following isa false statement?” (2) Addition of atomic orbitals result in molecular orbitals. (©) Atomie orbitals of nearly same energy combine to form molecular orbitals. (€) Each molecular orbital accomodate maximum number of two electrons ; (@) Bonding molecular orbital occupy higher energy than anti bonding molecular orbital In the following questions (Q.6 and Q. 7) a statement of assertion followed by a statement of reason is given, Choose the correct answer out ofthe following choices: (@) Assertion and reason both are correct statements and reason is correct explanation for assertion . (©) Assertion and reason both are correct statements but reason is not correct explanation for assertion. (©) Assertion is correct statement but reason is wrong statement. dla Assertion is wrong statement but reason is correct statement. 6. Assertion: Ionic radius of Na” is smaller than N; Reason; Effective nuclear charge of Na" is highe? than Na: 7. Assertion: Beryllium has a smaller first ionization enthalpy than Boron. Reason : The penetration of 2s electron of Berylliun is more and the 2p electron of boron is more shielded by the inner core of electrons. SECTION B 8. (9 Write the bond line structure of S-methylheptan-3-one \dentify the compound oy 9. Wiite any two differences between o and bond. 10, Arrange the following in the increasing order of property indicated, @) Mg, Al, Si, Na ( Ionisation enthalpy) 7 8.1. Cy onic si) Page? of 4\LL. (Explain metamerism, (Gi)Consider structures A to D and identify the pair of compounds Which ae metamers. (CHs-O-CHa-CHo-CHs CH-CH:-CHp-CHy-OH — CHs-CH2-O-CH2-CHs CHs.CHy-CH-CHs | OH (a) (B) © @) (ee first (AH) and the second (A.Hs) ionization enthalpies (in kJ mol) andthe (AcgH) lectron gain enthalpy (in kJ mol") ofa few elements are given below. Elements, ath als aa | 2P 419 3051 -48 $Q. 1681 3374 2328 oR 738 1451 -40 = eS 272 5251 +48; Which of the above elements is likely to be (i) Most reactive non metal (ii) Most reactive metal (iii) Least reactive element (iv) Metal forming binary halide SECTION C 13. (i)Write the TUPAC name of the following compounds. (a) (CHs-CO-CH-CH-Cl Ee. CHs (b) CH»-CHO os (CH2-CHO; (ji) Write the condensed formula of 3-methylbut-1-yne, ee c eas 14. Account for the following. mm (j) The axial bonds in PCls are longer as compared to the equatorial bonds- (ii) Halogens have very high negative electron gain enthalpy. ox ii) H20 is a liquid while HS is a gas roa 02 Noo 15, (i) Define hybridization (Gi) Explain the hybridization shown by CH, kage sue4 ms and carries it Carerons acct questions that ange 4 C12) marks each, Read theggy taal AB Cr cc the arrangement of leg I Used (oe and symmetric mot o: especially 5h ich is bonded to two "Y as an at leetron pairs around central lecules. A central atom is, ‘OF more other atoms, oF tipie bond is tested a8 a single bonding group. The scctoye it multiple bongs Se ae assumed to lie onthe surieec ofa ee junceetal afOm and tend to occupy positions that minimize their mutvat distance between then The number of electron pairs (or groups), therefore, overall geometry that they will adopt. Answer the folowing questions: (i) Arrange the bond pair electron and lone repulsive interaction among them, pair electron in the decreasing order of the (Gi) Watermotecule has bent structure. Why’? (Gi) Draw thebond dipoles of NFs and NH. Which will have more dipole moment and why? yooh SECTIONE wrt 17. (0) Write the molecular orbital configuration of O2 and Os". i) Compare the stabilities of these species. (ii) Indica their magnetic properties. | eo} lentfy the type of hydrogen bonding in the following structures A and B. Br HEN 8+ HY OSH. RO F | & & | (a) ®) | (Whats resonance? Draw the resonating structures of ozone molecule. | Jeera nnn Rieti fei Page 4 of 4 | ee oe