Chemistry 20 Pilot

Final Review Answer Key

Unit 1: Chemical Bonding

Review Problems:
1.
2+ 2
a) iron (II) sulphide
FeS
Fe S

b) lithium chloride + 
LiCl Li Cl


c) nickel (III) bromide Br
NiBr3
3+

Ni Br


Br

d) calcium nitride
2+
Ca3N2 Ca 3
N
2+
Ca 3
N
2+
Ca

2. Electronegativity is a measure of the ability of an

atom to attract electrons when involved in a chemical bond. It is affected by the size of
the atoms and the amount of charge within the atoms.

3. London dispersion, dipole-dipole, hydrogen bonding.

4. Ionic bonds, covalent bonds, metallic bonds, network covalent bonds.
5. Network covalent, covalent, ionic (metallic has a wide range), HB, DD, LD
6. highest BP - C2H5OH, CH3Cl, C3H8 – lowest BP
C2H5OH has LD, DD, and HB; CH3Cl has LD and DD; C3H8 only has LD
The more forces there are between molecules, the higher the boiling point.

7. Complete the following chart:

Chemistry 20 Final Review 1 Jill Agnew

 1 2 3 4
Formula Lewis Dot Diagram Shape Code Shape Name Types of
Intermolecular
Forces
(LD, DD, HB)

1. CH4
H 4-0 tetrahedra LD
H C H l

H
2. OF2
2-2 bent LD, DD
F O
F

3. NCl3
3-1 pyramidal LD, DD
Cl N Cl
Cl

4. BI3
3-0 trigonal LD
I B I planar
I
5. CO2 H 2-0 linear LD
O C O

6. C2H4
3-0 trigonal LD
H H planar
C C
H H

7. H2O
H H
O 2-2 bent LD, DD, HB

Chemistry 20 Final Review 2 Jill Agnew

8. SiH4 H 4-0 tetrahedra LD
l
H Si H
H
2-2 bent LD, DD
9. SCl2 Cl S
Cl
10. C2H2
2-0 linear LD
H C C H

Unit 2: Forms of Matter: Gases

Review Problems:
1. 85.7 L

2. 112 L

3. 263 K or 10.3C

4. 302 kPa

5. 3.5  102 K or 74C

6. 1.67 L

7. 1.7  105 L

8. 149 kPa

9. 0.56 L

Unit 3: Matter as Solutions, Acids and Bases

Review Problems:
1. variables:
a) manipulated variable – amount of water
Chemistry 20 Final Review 3 Jill Agnew
 responding variable – growth of bean plant
controlled variable – all plants in same light, temperature conditions, same
amount of water etc
b) manipulated variable – amount of junk food
responding variable – weight
controlled variable – same person
c) manipulated variable – temperature
responding variable – solubility
controlled variable – amount, type of solute, pressure

2. 0.440 mol/L

3. 0.287 mol/L

4. 12.6 g

5. 0.0539 L

6. 1.26 mol/L

7. Ionic compounds and very polar molecular compounds form electrolytes, molecular
compounds form non-electrolytes.

8. Na2CO3(s) ⇌ 2 Na+(aq) + CO32(aq)

The arrows…saturated solutions use the equilibrium arrows (⇌) and unsaturated
solutions use regular arrow ()

9. a) LiOH(s)  Li+(aq) + OH(aq)

1.00 mol/L 1.00 mol/L
b) Al(NO3)3(s)  Al (aq) + 3 NO3(aq)
3+

0.335 mol/L 1.01 mol/L

3+ 2
c) Co2(SO4)3(s)  2 Co (aq) + 3 SO4 (aq)
1.13 mol/L 1.70 mol/L

10. 1.57  1010 mol/L

11. a) pH = 8.00 basic

b) pH = 3.184 acidic
c) pH = 12.00 basic
d) pH = 1.56 acidic

12. d, b, a, c

13. Monoprotic acids only give up one hydrogen while polyprotic acids give up more than
one. Monoprotic bases only take one hydrogen while polyprotic bases take more than
one hydrogen.

Chemistry 20 Final Review 4 Jill Agnew

 14. A strong acid dissociates 100% and a weak acid doesn’t.

15. HCl(aq), HNO3(aq), HI(aq), H2SO4(aq), HClO3(aq), HBr(aq).

16. Complete the following chart:

[H3O+(aq)] [OH(aq)] pH pOH Acid/Base/Neutral

1 x 10-7 mol/L 1  107 mol/L 7.0 7.0 neutral

6.3  107 mol/L 1.6  108 mol/L 6.20 7.80 acid

1.9  104 mol/L 5.2  1011 mol/L 3.72 10.28 acid

1.20 mol/L 8.34  1015 mol/L 0.079 14.079 acid

3  1014 mol/L 0.3 mol/L 13.5 0.5 base

1.7  106 mol/L 6.0  109 mol/L 5.78 8.22 acid

***Note: some answers may be off by a few decimal places depending on whether you used
rounded or unrounded values

Unit 4: Stoichiometry
Review Problems:
1. a) Ba2+(aq) + SO42(aq)  BaSO4(s)
b) Zn(s) + 2 Ag+(aq)  2 Ag(s) + Zn2+(aq)

2. A solubility test is when you add one reagent to both solutions and you only have a
precipitate forming with one of the solutions. Suitable reagents are: any SO42 solution,
any OH solution, any PO43 solution, any SO32 solution, any CO32 solution. Another
test is the flame test…calcium is red, potassium is violet.

3. 37.7 g

4. a) 213 g
b) % yield = 88.6% (unrounded) or 88.7% (rounded)
% error = 11.4% (unrounded) or 11.3% (rounded)

5. 0.624 g
6. 0.0458 L

7. 9.58 g

8.
Titration of 10.00 mL of oxalic acid with 0.0161 mol/L sodium hydroxide
Trial 1 2 3
Final Buret Volume (mL) 14.30 27.80 41.10
Initial Buret Volume (mL) 0.90 14.30 27.80
Chemistry 20 Final Review 5 Jill Agnew
 Volume of NaOH(aq) (mL) 13.40 13.50 13.30

concentration of oxalic acid = 0.0108 mol/L

9. Strong Base Titrated with Strong Acid

14

pH
7

endpoint pH

0
volume of titrant added (mL)

equivalence point
volume

Chemistry 20 Final Review 6 Jill Agnew