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Solutions DPP 2
Solutions DPP 2
3. The vapour pressures of pure A and B at 7. Two liquids A and B have PA0 : PB0 = 1 : 3
given temperature are 108 and 36 bar
at a certain temperature. If the mole fraction
respectively. What is the mole fraction of B
ratio of XA : XB = 1 : 3, the mole fraction of
in the vapour phase of the solution
A in vapour in equilibrium with the solution
containing equimolar mixture of A and B -
at a given temperature is
(A) 0.25 (B) 0.5
(A) 0.1 (B) 0.2
(C) 0.75 (D) 0.66
(C) 0.5 (D) 1.0
4. Mole fraction of the component A in vapour
8. Mixture of volatile components A and B has
phase is x1 and mole fraction of component
total vapour pressure (in torr) p = 254 – 119
A in liquid mixture is x2 ( PA0 = vapour XA where XA is mole fraction of A in
pressure of pure A; PB0 = vapour pressure of mixture. The values of PA and PB (in torr)
pure B), then total vapour pressure of the are
liquid mixture is - (A) 254, 119 (B) 119, 254
(C) 135, 254 (D) 154, 119
PA x 2 PA x1
(A) (B)
x1 x2
PB x1 PB x 2
(C) (D)
x2 x1
2
9. Two liquids A and B from ideal solutions. 10. Two liquids A and B have vapour pressure
At 300 K, the vapour pressure of solution in the ratio PA : PB 1: 3 at a certain
containing 1 mole of A and 3 mole of B is
temperature. Assume A and B form an ideal
550 mm Hg. At the same temperature, if one
solution and the ratio of mole fractions of A
more mole of B is added to this solution, the
to B in the vapour phase is 4:3. Then the
vapour pressure of the solution increases by
mole fraction of B in the solution at the same
10 mm Hg. Determine the vapour pressure
temperature is
of A and B in their pure states (in mm Hg):
(A) 400, 600 1 2
(A) (B)
(B) 500, 500 5 3
(C) 600, 400 4 1
(C) (D)
(D) None of these 5 4
3
ANSWER KEY
1. (D)
2. (C)
3. (A)
4. (A)
5. (A)
6. (A)
7. (A)
8. (C)
9. (A)
10. (A)