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MODEL QUARTERLY EXAMINATION 2022-2023

e e
Std 11
N t t e et t Max.Mark:70

lala i i .N
.Chemistry l a
l ai .iN
.N l a
l i
a .iN
.
assaa I.------------------------------------------------------------------------------------------------------------------
aa aa
Time: 3:00
dd a a s s a
d= 15as s
P P a a P P aXa1d
ww. . as the ..
Choose the correct answer 15
1. Molecular mass w w w
(a) mass of one w w compared with the mass of one molecule wwww
atom
iswdefined

et
(b) mass of one atom compared with the mass of one atom of hydrogen
(c) mass of one molecule of any substance compared with the mass of one atom of C-12
et
e t
(d) None of the above. eet t
lalai.iN
.N l a
l i
a .iN
.N
2. Bohr’s model is not able to account for which of the following.
l a
l i
a .iN
.
assaa ssaa ssaa

.N
(a) Stability of atom.
aa a
dda
(b) Spectrum of neutral Helium atom.
add
a aa
ww P
..P
(c) Energy of free electron at rest.
w
w P
.. P
wwww
(d) Calculation of radii of the stationary states.
wwww
3. Choose the correct codes for the following statements related to s-block elements. Here ‘T’
stands for true and F stands for false statement.

l
assaa
a
l i
a .iN
.Neet t lai
P aa a a aal a
l a .iN
.Ne
(iii) They are found in pure form in nature.
s s
et t
(i) They are all reactive metals with low ionization enthalpies.

P aa a
(iv) All the compounds of s-block elements are ionic in nature.
dd dd s
a aa
s l a
l i
a .iN
.
(ii) Their metallic character and reactivity increase as we go down the group.
i
(a) TTFF
.. P .. P
sa
w
w ww
wwww wwww
(b) TTFT
(c) TTTF
(d) TFFF
4. Splitting of spectral lines in an electric field is called
e t t
a) Zeeman effect
e eet t
i .iN
.N i .iN
.N i.iN
.
da

b) Shielding effect
l a
l a l a
l a l a
l a
assaa s aa s aa
c) Compton effect
d) Stark effect
ddaa s a
dd a s
P
.. Paa P
.. Paa
5. For a person travelling to the peak of the mountain which of the following statement(s)
w
w ww
wwww
is/are correct ?
(i) Oxygen level goes on decreasing. wwww
Pa

(ii) Gas law can be applied to this situation.

(a) Both (i) and (ii)
eet t
(b) Only (i) eet t
l a
l i
a .iN
.N
(c) Only (ii)
lalai.iN
.N l a
l i
a .iN
.
assaa (d) Neither (i) nor (ii)
aa a
ddassaa
aa a
dd s
a aa
s
6. Assertion : An exothermic process which is nonspontaneous at high temperature may
ww P
..P
become spontaneous at a low temperature.
w
w P
.. P
wwww wwww
Reason : There occurs a decrease in entropy factor as the temperature is decreased.
(a) Assertion is correct, reason is correct; reason is a correct explanation for assertion.

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(b) Assertion is correct, reason is correct; reason is not a correct explanation for assertion
(c) Assertion is correct, reason is incorrect
eet t e
(d) Assertion is incorrect, reason is correct.
et t
lalai .iN
.N l a
l i
a .iN
.N
7. Which of the following is not a thermodynamic function?
l a
l i
a .iN
.
assaa s aa
s s aa
s
a) internal energy
b) enthalpy
aa a
dd a aa a
dd a
c) entropy
w
w P
.. P ww P
..P
wwww
d) frictional energy
wwww
8. Solubility of carbon dioxide gas in cold water can be increased by

et
a) increase in pressure
b) decrease in pressure
et
e t eet t
lalai.iN
.N
c) increase in volume
d) none of these
l a
l i
a .iN
.N l a
l i
a .iN
.
assaa ssaa ssaa

.N
aa a
dda add
a aa
9. Consider the following reversible reaction at equilibrium, A + B ⇌ C, If the concentration

a) be doubled ww P
..P w
w P
of the reactants A and B are doubled, then the equilibrium constant will
.. P
wwww
b) become one fourth
c) be halved
wwww

l
assaa
a
l i
a
d) remain the same

.N
t t lai
a) 3 – Methyl –3–hexanone
b) 4–Methyl –3– hexanone
c) 3– Methyl –3– hexanol
P aa a
dd s
a aa
s l a
l i
a .N
t t
10.Which one of the following names does not fit a real name?
.iN ee .iN ee
P aa a
dd s
a aa
s l a
l i
a .iN
.
.. P
d) 2– Methyl cyclo hexanone.
.. P
sa
w
w ww
wwww wwww
11.In an organic compound, phosphorus is estimated as
a) Mg2P2O7
b) Mg3(PO4)2
c) H3PO4
ee
d) P2O5t t eet t
i .iN
.N i .iN
.N i.iN
.
da

l a
l a l a
l l a
12.How many cyclic and acyclic isomers are possible for the molecular formula C3H6O?
a l a
assaa ssaa s aa
s
a) 4 b) 5 c) 9 d) 10
add
a aa aa a
dd
13.Homolytic fission of covalent bond leads to the formation of a
(a) electrophile
w
w P
.. P ww P
.. P
(b) nucleophile
(c) Carbo cationwwww wwww
Pa

(d) free radical

eet
14.Decreasing order of nucleophilicity is
t eet t
l a
l i
a .iN
.N
(a) OH- > NH2- > -OCH3 > RNH2
(b) NH2- > OH- > -OCH3 > RNH2 lalai.iN
.N l a
l i
a .iN
.
assaa a
(c) NH2- > CH3O- > OH- > RNH2
aaddassaa
aa a
dd s
a aa
s
ww PP
(d) CH3O- > NH2- > OH- > RNH2
..
15.The geometrical shape of carbocation is w
w P
.. P
(a) Linear
(c) Planar
wwww wwww (b) tetrahedral
(d) Pyramidal
S.Prabakar M.Sc, M.Phil, B.Ed,PGDCA, PG ASST IN CHEMISTRY, HARUR - 9489182238
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II. Answer any six questions. But question no 22 is compulsory 6 X 2 = 12

e t t e t t
16.Calculate the empirical and molecular formula of a compound containing 76.6% carbon,
e e
lalai .iN
.N l a
l i
a .iN
.N
6.38 % hydrogen and rest oxygen its vapour density is 47 .
l a
l i
a .iN
.
assaa s aa s aa
17.What are isoelectronic ions? Give examples.
a
dd
18.Give the uses of heavy water.a s a
dd a s
P
.. Paa P
..Paa
19.A balloon filled with air at room temperature and cooled to a much lower temperature can
w
w ww
wwww
be used as a model for Charle’s law.
20.State the first law of thermodynamics. wwww

et
21.State Le-Chatelier principle.
22.Give the structure for the following compound.
et
e t eet t
lalai.iN
.N (i) tertiary butyl iodide
l a
l i
a .iN
.N l a
l i
a .iN
.
assaa aa aa
(ii) 1,3,5- Trimethyl cyclohex - 1 -ene
ss ss

.N
a
dda
(iii) 2,2-dimethyl-1-chloropropane
aa add
a aa
w P
..P
(iv) 3 - Chlorobutanal
w w
w P
.. P
wwww
23.Write short notes on Resonance
wwww
24.Mention the following represent a set of nuclephiles?

l a
l i
a
assaa 26.
.iN
25.
ee t
-
lai
-
(a) CN , RCH2 , ROH, H2O, NH2
t
N the Aufbau principle
.Describe
a
Explain the pauling method for the
P a a as s l a
l
-
i
a .iN
.Neet t
III. Answer any six questions. But question no33 is compulsory

aa of ionic radius.
dd into ortho hydrogen ?
determination
P
6 X 3 = 18

a addaa ss l
aa a
l i
a .iN
.
.. P
27.How do you convert parahydrogen
.. P
sa
ww w
w
wwww wwif the surrounding
28.State Gay Lusaac’ law.
29.If an automobile engine burns petrol at a temperature of 816 w
wand
C o

temperature is 21o C, calculate its maximum possible efficiency.

30.Derive the relation between KP and KC.
eet t eet t
31.Give a brief description of the principles of Fractional distillation.
i .iN
.N i .iN
.N i.iN
.
da

l a
l a l a
l a
32.What are electrophiles and nucleophiles? Give suitable examples for each. l a
l a
assaa ddaas aa
s a
dd s
a aa
s
33.0.30 g of a substance gives 0.88 g of carbon dioxide and 0.54 g of water calculate the
a a aa
..PP
percentage of carbon and hydrogen in it.
ww ww P
.. P
w w ww
IV. Answer all the question
ww ww 5 X 5 = 25
Pa

34.a. Explain briefly the time independent schrodinger wave equation?

OR
eet t eet t
b. (i) Explain the periodic trend of ionisation potential.
l a
l i
a .iN
.N lalai.iN
.N l a
l i
a .iN
.
(ii) Why the first ionisation enthalpy of sodium is lower that that of magnesium while its
assaa aa aassaa a
second ionisation enthalpy is higher than that of magnesium?
dd aadd s
a aa
s
P
..P
35.a. (i) Compare the structures of H2O and H2O2.
ww w
w P
.. P
wwww wwww
(ii) a Compound on analysis gave Na = 14.31% S = 9.97% H= 6.22% and O= 69.5%
calculate the molecular formula of the compound if all the hydrogen in the compound is

S.Prabakar M.Sc, M.Phil, B.Ed,PGDCA, PG ASST IN CHEMISTRY, HARUR - 9489182238

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present in combination with oxygen as water of crystallization. (molecular mass of the

compound is 322).
eet t e et t
lalai .iN
.N l a
l i
a .iN
OR
.N l a
l i
a .iN
.
assaa aa aa
b. Balance the following equation by using oxidation number & ion electron method.
a ass
KMnO4 + SnCl2+HCl → MnCl2 + SnCl4 + H2O + KCl
dd dd a s
a s
P P aa P
. . equation for a real gas. Explain the correction P aa
. . term for
ww w w ww
36.a. Write the Van
ww
pressure and
der
volume.
Waals
wwww

et
OR

N e t t
b. List the characteristics of internal energy.
e N eet t N
lalai i.N
.37. l a
l ai .
i . N l a
l i
a .
i .
assaa ssaa ssaa
a.State the various statements of second law of thermodynamics.

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a add aa OR
add
a aa
w w
b. Deduce the Vant Hoff PP
. . equation. w
w P
.. P
wwww wwww
38.a. Explain varions types of constitutional isomerism (structural isomerism) in organic

l
assaa
a
l i
a .iN
compounds

.Neet t

P
lai
aa a a
l a
l i
a .iN
.Neet t OR
b. i) Explain inductive effect with suitable example.
s aa
s
P aa a
dd s
a aa
s l a
l i
a .iN
ii) Give examples for the following types of β - elimination reactions
dd
.
.. P .. P
sa
w
w ww
PREPARE wwww
BY wwww
S.PRABAKAR M.Sc, B.Ed, M.Phil, PGDCA,
eet t PG Asst in Chemistry,
eet t
i .iN
.N i
Aspire Coaching Centre,
.iN
.N i.iN
.
da

l a
l a Makilvakam,
l a
l a l a
l a
assaa a ssaa
Achalvadi, Harur - 636903.
dd
Contact No : 94891-82238
aa a aa a
dd s
a aa
s
P
.. P
E.Mail:prabakar.che@gmail.com
w w ww P
.. P
wwww wwww
Pa

eet t eet t
l a
l i
a .iN
.N lalai.iN
.N l a
l i
a .iN
.
assaa aa a
ddassaa
aa a
dd s
a aa
s
ww P
..P w
w P
.. P
wwww wwww
S.Prabakar M.Sc, M.Phil, B.Ed,PGDCA, PG ASST IN CHEMISTRY, HARUR - 9489182238
t t t t
.NNee .NNee
Kindly send me your Questions & Keys to this email id - padasalai.net@gmail.com - Whatsapp No: 7358965593 .N