Jul.

3, 2012 1/4
DKK-TOA CORPORATION
MSDS No.: E718-5
PRODUCT NAME: Potassium Chloride for Non-leak Silver Chloride Electrode Inner Solution

Created: July 2, 1998

Revised: Jul. 3, 2012
MATERIAL SAFETY DATA SHEET

1. PRODUCT AND MANUFACTURER

Product Name : Potassium Chloride for Non-leak Silver Chloride Electrode Inner Solution
Product Code : 143A253
Manufacturer : DKK-TOA CORPORATION
Address : 29-10, Takadanobaba 1-Chome, Shinjuku-ku, Tokyo 169-8648 Japan
Department : Sensor Technology Dept.
Phone : +81-4-2957-6154
Fax : +81-4-2957-6864

2. HAZARDS IDENTIFICATION
Critical Hazard Information
Hazardous Effect to
Human Health
Environmental Impact
Physical/Chemical Hazard
Specific Hazard Information
Hazard Class
(Japanese System)
: If a large amount of this product is digested, it may irritate digestive
organs causing vomiting, rise of blood pressure, damage to circulatory
organ system, etc.
: No data
: No risk is anticipated when used and stored under proper conditions.
: Not applicable

GHS Classification
Physical/Chemical Flammable liquids Not classified
Hazards: Self-reactive chemicals Not classified
Pyrophoric liquids Not classified
Self-heating chemicals Not classified
Water-reactive flammable chemicals Not classified
Oxidizing liquids Not classified
Organic peroxides Not classified
Corrosive to metals Not classifiable
Human Health Acute toxicity (Oral) Category 5
Hazards: Acute toxicity (Skin) Not classified
Acute toxicity (Inhalation: Gas) Not classifiable
Acute toxicity (Inhalation: Vapor) Not classifiable
Acute toxicity (Inhalation: Mist) Not classifiable
Skin corrosion/irritation Not classified
Serious eye damage/eye irritation Category 2B
Respiratory sensitization Not classifiable
Skin sensitization Not classified
Germ cell mutagenicity Not classifiable
Carcinogenicity Not classifiable
Reproductive toxicity Not classifiable
Specific target organ/general toxicity Not classifiable
(Single exposure)
Specific target organ/general toxicity Not classified
(Repetitive exposure)
Aspiration hazard Not classifiable
Environmental Hazards: Acute toxicity to the aquatic environment Not classified
Chronic toxicity to the aquatic environment Not classified

様式 QA3676 <0> TQS R-24

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DKK-TOA CORPORATION
MSDS No.: E718-5
PRODUCT NAME: Potassium Chloride for Non-leak Silver Chloride Electrode Inner Solution

GHS Label Elements

Signal Word:
Hazard Statements:
Precautionary Statements:
【Safety Measures】
【First Aid】
Warning
May be harmful if swallowed.
Causes eye irritation.
Wash hands thoroughly after handling.
If swallowed: Rinse mouth. If you feel unwell, get medical advice/attention.
If in eyes: Rinse cautiously with water for several minutes.
Get medical advice/attention.

3. COMPOSITION/INFORMATION ON INGREDIENTS
FORM: Single Substance
Chemical
Potassium Chloride
Name
Percent
≧99.0%
Range
Chemical
KCl
Formula
CAS No. 7447-40-7

4. FIRST AID
Inhalation : Let victim blow his/her nose and rinse mouth.
Skin Contact : Wash the contaminated or contacted spot of skin with water.
Eye Contact : Immediately, rinse eyes with running water for more than 15 minutes.
Ingestion : If swallowed a large amount, give plenty of water to induce vomiting.
Get medical treatment if necessary.

5. FIRE FIGHTING MEASURES

Extinguishing Media : This product is non-combustible.
Firefighting Instruction : In case of a fire in the vicinity, immediately remove containers to a safe
place. If containers can not be removed, spray water onto containers and the
surrounding area to cool down.

6. ACCIDENTAL RELEASE MEASURES

For Humans : This product irritates scratches or cuts on fingers or hands although it is not
toxic.
For Environment : Pay attention to stop spilled material from entering sewage and drainage
systems or bodies of water to protect the environment.
Clean-up : Recover the spilled and scattered material as much as possible into empty
containers. Then, thoroughly flush the spilled area with water.

7. HANDLING/STORAGE
Handling
Technical Measures
Precautions
Storage
Storage Conditions
Container Material
: Wear appropriate protective equipment such as eye protection, rubber
gloves, etc. if necessary.
: Pay extra attention to avoid the product from getting on skin or others.
: Keep containers tightly closed when not in use and store in a cool and
dark place.
: Glass, Polyethylene, Polypropylene, etc.

様式 QA3676 <0> TQS R-24

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DKK-TOA CORPORATION
MSDS No.: E718-5
PRODUCT NAME: Potassium Chloride for Non-leak Silver Chloride Electrode Inner Solution

8. EXPOSURE CONTROLS/PROTECTIVE EQUIPMENT

Equipment : In case generation of dust is anticipated, use enclosed equipment or device
if available to do so, or provide local ventilation equipment.
Control Concentration : Not established
Threshold Limit Value : Not established
Personal Protective Equipment
For respiratory organ : Wear appropriate protective equipment if necessary.
For hands : Wear appropriate protective equipment if necessary.
For eyes : Wear appropriate protective equipment if necessary.
For skin & body : Wear appropriate protective equipment if necessary.

9. PHYSICAL/CHEMICAL PROPERTIES
Appearance : Crystal, Powder Odor : None
Color : White pH : ―
Melting Point : 776℃
Boiling Point, Initial Boiling Point and Boiling Range : 1500℃
Flush Point : No data
Combustion/Explosion Upper Limit and Lower Limit : No data
Vapor Pressure : No data
Vapor Density (Air=1) : No data
Specific Gravity (Water=1) : 1.98
Solubility : Water : 20.4% (@20℃)
: Organic Solvent : No data
Spontaneous Ignition Temp. : No data
Decomposition Temp. : No data

10. STABILITY/REACTIVITY
Stability : Stable when used and stored under proper conditions.
Reactivity : No data
Incompatibility : No data

11. TOXICOLOGICAL INFORMATION

Acute Toxicity : Acute toxicity (Oral):May be harmful if swallowed. (Category 5)
Acute toxicity (Skin): Not classifiable due to insufficient data.
Inhalation (Vapor, Mist): Not classifiable due to insufficient data,
Oral Rat LD50=2020 mg/kg,
Skin Guinea pig LD50=2500 mg/kg
Skin Corrosion/Irritation : If in scratches or cuts on fingers or hands, this product causes severe
pain.
Serious Eye Damage/Eye : If in eyes, this product causes severe pain.
Irritation Causes eye irritation.(Category 2B)
Respiratory/Skin Sensitization : No data
Germ cell mutagenicity : No data
Carcinogenicity : No data
Reproductive Effect Data : No data
Specific Target Organ/General : No data
Toxicity (Single Exposure)
Specific Target Organ/General : No data
Toxicity (Repeated Exposure)
Aspiration hazard : No data

12. ECOLOGICAL INFORMATION

Ecological Information : No data,
Persistence/Decomposition : No data,
Accumulativeness : No data
Migration in Soil : No data

様式 QA3676 <0> TQS R-24

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DKK-TOA CORPORATION
MSDS No.: E718-5
PRODUCT NAME: Potassium Chloride for Non-leak Silver Chloride Electrode Inner Solution

13. DISPOSAL CONSIDERATIONS

Waste Chemicals : Dissolve and dilute with a large amount of water and dispose of in
accordance with your national and local regulations.
Empty Containers : Thoroughly remove contents and dispose of cleaned containers in
accordance with your national and local regulations.
14. TRANSPORT INFORMATION
UN Hazard Classification : Not applicable
Marine Pollution Material : Not applicable
National Regulations : Observe your national and local regulations.
Notes for Transport : Ensure that there is no leakage. Avoid dropping and damaging the bottle
of the material when the material is loaded onto a truck or the like. Be
sure to prevent collapse of cargo piles. Avoid direct sunlight.

15. REGULATORY INFORMATION

Be sure to handle this material in compliance with environmental, safety and health laws and regulations of
your national and local government.

16. OTHER INFORMATION

References
(1) Chemical Products Handbook (14504 no Kagaku Shouhin), The Chemical Daily Co., Ltd. (2004)
(2) Enciclopedia Chimica (Kagaku Dai-jiten), Kyoritsu Shuppan (2001)
(3) Chemical Substance Danger/Hazard Handbook (Kagaku-busshitu no Kiken Yugai-butu Binran),
Japan Industrial Safety and Health Association
(4) Handbook for Japan’s Specifications and Standards for Food Additives (Fifth Edition),
(Dai-5-han Shokuhin Tenkabutsu Koutei-sho Kaisetsu-sho), Hirokawa Shoten, Ltd. (1987)
Coverage
- The information contained herein is based on data collected from many technical documents and is
considered to be accurate, but is not necessarily inclusive. Due care should be exercised in handling
the material.
- All data herein are intended to provide information but not assured.
- All of the notes are for normal handling. In case of special handling, take safety measures suitable for
the use or application.

様式 QA3676 <0> TQS R-24