1.

Which of the following is a primary haiide) 9 The UPAC narne of the compound
(a) iso-propyliodide (h)secButyl iodide
() tert-Butyl bromidc
(d) neo-Hexylchloride.
2. Classify the following compounds as primary,
secondary and tertiary halides. (a) 1fMuoro-4 methyl 2 nitrobenzene
() 1-Bromobut -2-ene (b) 4-fluoro 1-methyl-3-nitrobenzene
(ii)4-Bromopent-2-ene (c) 4- methyl-1-fluro-2-nitrobenzene
(iii) 2- Bromo-2-methylpropane (d) 2-fluro-5-methyl-1-nitrobenzene
(a) (i)-secondary, (ii) -tertiary, (iii)-primary 9. Which of the following halides is not correct
(b) (i)-secondary. (ii)-primary. (ii)-tertiary according to the name and classification?
(a) CH;CH,C(CH;);CH,I
(c)()-primary, (ii)-tertiary. (ii)-secondary 1-lodo-2,2-dimethybutane, Primary haloalkane
(d) (i)-primary, (ii)-secondary. (iii) tertiary
3. Which of the following is not an allylic halide? (b) (CH;)2CHCH(CI)CH,
2-Chloro-3-methylbutane, Secondary halcalkane
(a) 4-Bromopent-2-ene
(b)3-Bromo-2-methylbut-1-ene (c) CH;C(CI)(C,H:)CH,CH;
2-Chloro-2-ethylbutane, secondary haloaikane
(c) 1-Bromobut-2-ene
CH3 CI
(d) 4-Bromobut-1-ene
4. Haloakanes contain halogen atom (s) attached to
(d) CH- CH,-CH-CH-CH-CH;
the sp³ hybridised carbon atom of an alkyl group. 3-Chloro-4-methylhexane, Secondary haloalkane
ldentify haloalkane from the following compounds their
() 2-Bromopentane (ii) Vinylchloride 10. Match the isomer given in column Iwith
(ii) 2-Chloroacetophenone names given in column II and mark the appropriate
(b) (i)and (iv) only choice.
(a) Only (i) Column I
(c) () and (iv) only (d) (). (1) and (iii) only Column I
(i) 2-Bromo 3-nethylbutane
5. Match the column Iwith column II and mark the (A) Br
appropriate choice.
Column I Column II B) (D2-Bromopentane
(A)CH,CHCl, () vinyl hallide
(B) CH,CICH,CI (i) Alkylidenehalide Br (ii)]1-Bromo 3-methylbutane
() CHCI =CH; (ii)Alkylene dihalide
(iv) Allyl halide Br (iv)1-Bromo-2-nethybatane
(D) CICH-CH =CH, (D)
(a) (A)’), (B) ’(i), (C) ’(v), (D)+(ii)
’(iv)
(b) (A) -’ (ii), (B) ’(i), (C) -’(), (D)
(a) (A) -’(ii), (B)’(), (C)’(iv), (D)-(1)
(c) (A) ->(ii), (B) ’(iv), (C) ’(ii), (D) ’(ii)
’(i) (b) (A) ’(iv). (B) ’(i), (C)’(i1), (D)’()
(d) (A) ’iv). (B) -+(), (C) ’(ii), (D)
chloride its (c) (A)’1), (B) ’(ii), (C) ’(i), (D) ’(v)
6. The IUPAC name of tertiary butyl
(a) 2-chloro-2-methypropane (d) (A) ’(ii). (B) ’(ii), (C) ’(iv). (D) ’()matched
correctly
(b) 3-chlorobutane 11. Which of the following is not
with its IUPACname?
(c) 4-chlorobutane CHF;CBrCIF:1-Bromo-1-chloro-1,2,2
(d) 1,2-chloro-3-methylpropane (a)
CH3Br is trifluroethane
7. The IUPAC name of (CH3)2CH-CH2- (CCl):CCi:2-(Trichloromethyl)-1,1,1,2,3,3,3
(a) 1-bromopentane (b)
(b)1-bromo-3-methylbutane heptachloropropane
() CH;C(p-CiCçH.),CH(Br)CH3:
(c) 2-methyl-4-bromobutane 2-Bromo-3,3-bis(4-chloropheney)butane
(d) 2-methyl-3-bromopropane