SAFETY DATA SHEET

according to 1907/2006/EC, Article 31

Page 1/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name SYNOZOL YELLOW HF-4GL

1.2. Relevant identified uses of the substance or mixture and uses advised against

Description C.I. Reactive Yellow 186.

Ink & Dyestuff Industry.

1.3. Details of the supplier of the safety data sheet

Company Kyung-In Synthetic Corporation

Address 112-31, Yeomchang-dong,

Kangseo-gu,
Seoul,
Korea

Web www.kyungin.co.kr

Telephone 82-2-3660-7873

Fax 82-2-3660-7887

Email lifrog@kyungin.co.kr

Email address of the kisco@kyungin.co.kr

competent person

Local Supplier

Company Kyung-In Synthetic Corporation

Address 112-31 Yeomchang-dong

Kangseo-gu
Seoul
Korea

Web www.kyungin.co.kr

Telephone 82-2-3660-7873

Fax 82-2-3660-7887

Email lifrog@kyungin.co.kr

Email address of the kisco@kyungin.co.kr

competent person

1.4. Emergency telephone number

Emergency telephone number 82-2-3660-7873

Company Kyung-In Synthetic Corporation

24 Hours

E-Mail : ljfrog@kyungin.co.kr
E-Mail(Comp.) : kisco@kyungin.co.kr

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

2.1.1. Classification - Xi; R43

67/548/EEC Symbols: Xi: Irritant.

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by
 Page 2/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

2.1. Classification of the substance or mixture

Main hazards May cause sensitisation by skin contact.

2.2. Label elements

Precautionary Statement: P280 - Wear protective gloves/protective clothing/eye protection/face protection.

Prevention(에 방조치문구

예
방)Precautionary Statement:

Response(예 방조치문구
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
대응
lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor/physician.

P501 - Dispose of contents/container to an approved waste disposal plant

Precautionary Statement:
Disposal(예 방조치문구
기
폐

SECTION 3: Composition/information on ingredients

3.1. Substances

67/548/EEC / 1999/45/EC

Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification
Number (%w/w)
Benzenesulfonic acid, 2-[[5- 104256-92-0 40 - 50% Xi; R41
(aminocarbonyl)
-1-ethyl-1,6-dihydro-2-hydroxy-4-
methyl-6-oxo-3-pyridinyl]azo]-4-
[[4-chloro-6-[[4-[[2-
(sulfooxy)ethyl]sulfonyl]phenyl]ami
no]-1,3,5-triazin-2-yl]amino]-
Sulfuric acid sodium salt(1:2) 7757-82-6 231-820-9 40 - 50%

ANTIDUSTING AGENT 10024-47-2 233-022-6 0.5 - 1%

EC 1272/2008

Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification
Number (%w/w)
Benzenesulfonic acid, 2-[[5- 104256-92-0 40 - 50% Eye Dam. 1: H318;
(aminocarbonyl)
-1-ethyl-1,6-dihydro-2-hydroxy-4-
methyl-6-oxo-3-pyridinyl]azo]-4-
[[4-chloro-6-[[4-[[2-
(sulfooxy)ethyl]sulfonyl]phenyl]ami
no]-1,3,5-triazin-2-yl]amino]-
Sulfuric acid sodium salt(1:2) 7757-82-6 231-820-9 40 - 50%

ANTIDUSTING AGENT 10024-47-2 233-022-6 0.5 - 1%

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move the exposed person to fresh air. Seek medical attention if irritation or symptoms persist.

Eye contact Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical
attention if irritation or symptoms persist.

Skin contact Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Wash off
immediately with plenty of soap and water.

Ingestion If swallowed, rinse mouth with water (only if the person is conscious).[삼 켰을 경우 물
로
입을 헹구어 내세요 (환자의 의식이 있는 경우에만 ).]. Drink 1 to 2
glasses of water. If you feel unwell, seek medical advice (show the label where possible).

General information

See section 16 for further information.

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by
 Page 2/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

SECTION 5: Firefighting measures

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by
 Page 3/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

5.1. Extinguishing media

Use appropriate water spray, foam, powder, carbon dioxide(CO2).

5.3. Advice for firefighters

Wear suitable respiratory equipment when necessary.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Wear suitable protective clothing, gloves and eye/face protection.(적절한 보호의 , 장

과
갑
눈 /안면 보호구를 착용하시오 .).

6.2. Environmental precautions

No environmental requirements.

6.3. Methods and material for containment and cleaning up

For large spills:. Clean spillage area thoroughly with plenty of water.
For large spills:. Water jet. Avoid raising dust. Flush down the drain with plenty of water.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Occupational exposure controls.

Avoid contact with eyes and skin. Do not breathe dust.(먼지를 흡입하지 마시오.).

7.2. Conditions for safe storage, including any incompatibilities

Store in a cool, dry area. Keep containers tightly closed. Keep away from water.

SECTION 8: Exposure controls/personal protection

8.2. Exposure controls

8.2.2. Individual protection Wear suitable protective equipment.

measures

Respiratory protection Wear suitable respiratory equipment when necessary.

Occupational exposure Wear suitable protective equipment.

controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State Powder

Colour Yellow

Odour Odourless

pH 6-7

Melting point Not applicable.

Freezing Point ( 녹는점 어는점 ) Not applicable.

Boiling point Not applicable.

SECTION 10: Stability and reactivity

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions(위험유해반응의 가능성

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by
 Page 4/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

10.3. Possibility of hazardous reactions(위험유해반응의 가능성

Avoid contact with: Reducing agents, Alkaline solution.

10.4. Conditions to avoid

None.
Stable under normal conditions.

10.5. Incompatible materials

Stable under normal conditions.

SECTION 11: Toxicological information

11.1. Information on toxicological effects(독성정보)

Irritancy Skin OECD 404.

Irritancy Eye Negative by OECD 405.

Senstization Skin Negative by OECD 406.

Sensitization May cause sensitisation by skin contact.

Respiratory or skin May cause sensitisation by skin contact.

sensitisation

Germ cell mutagenicity No mutagenic effects reported.

Repeated or prolonged See section 16 for further information.

exposure

11.1.4. Toxicological Information

SYNOZOL YELLOW HF-4GL Oral Mouse LD50: OECD 401,

>2000mg/kg

SECTION 12: Ecological information

12.1. Toxicity

Ecotoxicity Aquatic toxicity against Bacteria, IC50/3hr 10 mg/l (OECD 209).

Algae EC50/72h = oECD 201, No Information.
Daphnia EC50/48h = oECD 202, No Information.
Fish LC50/96h = OECD 203, >10mg/l.

Further information

BOD5 9 mg/g.

COD 243mg/g by Mn(KMnO4) method / 0.01% Dye solution test.

Metal content Metal content under the ETAD recommended limits.

Chromium (Cr) None.
Cobalt (Co) None.
Copper (Cu) None.

Phosphorus content <0.2%.

Biodegradability . 70 % tested by OECD 302 B.

AOX 5.4%.

SECTION 13: Disposal considerations

General information

Dispose of in compliance with all local and national regulations.

Disposal methods

Can be incinerated if in compliance with local and national regulations.

Can be sent to landfill if in compliance with local and national regulations.

Disposal of packaging

Can be incinerated if in compliance with local and national regulations.

Empty containers can be sent to landfill after cleaning, if in compliance with local and national
regulations.

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by
 Page 5/5

SYNOZOL YELLOW HF-4GL

Revision 2

Revision date 2019-01-12

SECTION 14: Transport information

ADR/RID

The product is not classified as dangerous for carriage.

IMDG

The product is not classified as dangerous for carriage.

IATA

The product is not classified as dangerous for carriage.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations(법적규제 Local and national regulations.

SECTION 16: Other information

Other information

Revision This document differs from the previous version in the following areas:.
2 - 2.1.2. Classification - EC 1272/2008.
2 - Hazard pictograms.
2 - Signal Word.

Text of risk phrases in Section R41 - Risk of serious damage to eyes.

3

Text of Hazard Statements in Eye Dam. 1: H318 - Causes serious eye damage.
Section 3

Copyright © 2014 ChemSoft Limited. All rights reserved. Print date 2019-01-20
Powered by