Synozol Ultra Black DR (ENG)

SAFETY DATA SHEET
according to 1907/2006/EC, Article 31
Page 1/7
SYNOZOL ULTRA BLACK DR

Revision 6
Revision date 2019-01-11
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product name SYNOZOL ULTRA BLACK DR
1.2. Relevant identified uses of the substance or mixture and uses advised against
Description C.I. Reactive Unknown.

Textile dyestuffs.
1.3. Details of the supplier of the safety data sheet
Company Kyung-In Synthetic Corporation
Address 112-31, Yeomchang-dong,

Kangseo-gu,
Seoul,
Korea
Web www.kyungin.co.kr
Telephone 82-2-3660-7873
Fax 82-2-3660-7887
Email lifrog@kyungin.co.kr
Email address of the kisco@kyungin.co.kr

competent person
Local Supplier
Address 112-31 Yeomchang-dong

Kangseo-gu
Seoul
Korea
Web www.kyungin.co.kr
Telephone 82-2-3660-7873
Fax 82-2-3660-7887
Email lifrog@kyungin.co.kr
Email address of the kisco@kyungin.co.kr

competent person
1.4. Emergency telephone number
Emergency telephone number 82-2-3660-7873
24 Hours
E-Mail : lifrog@kyungin.co.kr
E-Mail(Comp.) : kisco@kyungin.co.kr
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
2.1.1. Classification - Xn; R42/43 Xi; R36/37/38

67/548/EEC Symbols: Xn: Harmful.
Copyright © 2016 ChemSoft Limited. All rights reserved. Print date 2019-01-18
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2.1. Classification of the substance or mixture
Main hazards Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin
contact.
2.1.2. Classification - EC Skin Irrit. 2: H315; Skin Sens. 1: H317; Eye Irrit. 2: H319; Resp. Sens. 1: H334; STOT SE 3: H335;
1272/2008
2.2. Label elements
Hazard pictograms
Signal Word Danger
Hazard Statement Skin Irrit. 2: H315 - Causes skin irritation.

Skin Sens. 1: H317 - May cause an allergic skin reaction.
Eye Irrit. 2: H319 - Causes serious eye irritation.
Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT SE 3: H335 - May cause respiratory irritation.
Precautionary Statement: P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

Prevention(예 방조치문구 P264 - Wash handling area thoroughly after handling.
예
방) P271 - Use only outdoors or in a well-ventilated area.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P285 - In case of inadequate ventilation wear respiratory protection.
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
Precautionary Statement: P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
Response(예 방조치문구 P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
응
대
P304+P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P321 - Specific treatment (see first aid on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P363 - Wash contaminated clothing before reuse.
P403+P233 - Store in a well-ventilated place. Keep container tightly closed.

P405 - Store locked up.
Precautionary Statement: P501 - Dispose of contents/container to an approved waste disposal plant
Storage(예 방조치문구
장
저
Precautionary Statement:
Disposal(예방조치문구 폐기
SECTION 3: Composition/information on ingredients

3.1. Substances
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3.1. Substances
67/548/EEC / 1999/45/EC
Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification
Number (%w/w)
Tetrasodium 17095-24-8 241-164-5 50 - 60% Xn; R42/43
4-amino-5-hydroxy-3,6-bis[[4-[[2-
(sulphonatooxy)ethyl]sulphonyl]ph
enyl]azo]naphthalene-2,7-disulpho
nate
ADDITIVES 7757-82-6 231-820-9 10 - 20%
disodium 12225-83-1 235-431-5 Xi; R36/37/38-43

6-acetamido-4-hydroxy-3-[[3-[[2-
enyl]azo]naphthalene-2-sulphonat
e
ANTIDUSTING AGENT 10024-47-2 233-022-6 0.5 - 1%
EC 1272/2008
Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification
Number (%w/w)
Tetrasodium 17095-24-8 241-164-5 50 - 60% Skin Sens. 1: H317; Resp.
4-amino-5-hydroxy-3,6-bis[[4-[[2- Sens. 1: H334;
enyl]azo]naphthalene-2,7-disulpho
nate
ADDITIVES 7757-82-6 231-820-9 10 - 20%
disodium 12225-83-1 235-431-5 Skin Irrit. 2: H315; Skin

6-acetamido-4-hydroxy-3-[[3-[[2- Sens. 1: H317; Eye Irrit. 2:
(sulphonatooxy)ethyl]sulphonyl]ph H319; STOT SE 3: H335;
enyl]azo]naphthalene-2-sulphonat
e
ANTIDUSTING AGENT 10024-47-2 233-022-6 0.5 - 1%
SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Move the exposed person to fresh air. Seek medical attention if irritation or symptoms persist.
Eye contact Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical
attention if irritation or symptoms persist.
Skin contact Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Wash off
immediately with plenty of soap and water.
Ingestion If swallowed, rinse mouth with water (only if the person is conscious).[삼 켰을 경우 물
로
입을 헹구어 내세요 (환자의 의식이 있는 경우에만 ).]. Drink 1 to 2
glasses of water. If you feel unwell, seek medical advice (show the label where possible).
General information
See section 16 for further information.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Use appropriate water spray, foam, powder, carbon dioxide(CO2).
5.3. Advice for firefighters
Wear suitable respiratory equipment when necessary.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear suitable protective clothing, gloves and eye/face protection.(적절한 보호의 , 장

과
갑
눈 /안면 보호구를 착용하시오 .).
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6.2. Environmental precautions
No environmental requirements.
6.3. Methods and material for containment and cleaning up
For large spills:. Clean spillage area thoroughly with plenty of water.
For large spills:. Water jet. Avoid raising dust. Flush down the drain with plenty of water.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Occupational exposure controls.

Avoid contact with eyes and skin. Do not breathe dust.(먼지를 흡입하지 마시오.).
7.2. Conditions for safe storage, including any incompatibilities
Store in a cool, dry area. Keep containers tightly closed. Keep away from water.
SECTION 8: Exposure controls/personal protection
8.2. Exposure controls
8.2.2. Individual protection Wear suitable protective equipment.

measures
Respiratory protection Wear suitable respiratory equipment when necessary.
Occupational exposure Wear suitable protective equipment.

controls
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
State Powder
Colour Black
Odour Odourless
Vapour pressure Not applicable.
Relative density Not applicable.
pH 5-7
Melting point Not applicable.
Autoignition temperature Not applicable.
Freezing Point ( 녹는점 어는점 ) Not applicable.
Boiling point Not applicable.
Flash point Not applicable.
Explosive Not applicable.
Viscosity Not applicable.
Solubility Soluble in water
SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
10.3. Possibility of hazardous reactions(위험유해반응의 가능성
Avoid contact with: Reducing agents, Alkaline solution.
10.4. Conditions to avoid
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10.4. Conditions to avoid
None.
10.5. Incompatible materials
SECTION 11: Toxicological information
11.1. Information on toxicological effects(독성정보)
Sensitization May cause sensitisation by skin contact.
Respiratory or skin May cause sensitisation by skin contact.

sensitisation
Germ cell mutagenicity No mutagenic effects reported.
Repeated or prolonged See section 16 for further information.

exposure
11.1.4. Toxicological Information
SYNOZOL ULTRA BLACK DR Oral Rat LD50: > 5,000 mg/kg
SECTION 12: Ecological information

12.1. Toxicity
Ecotoxicity Aquatic toxicity against Bacteria, IC50/3hr 10 mg/l (OECD 209).

Algae EC50/72h = oECD 201, No Information.
Daphnia EC50/48h = oECD 202, No Information.
Fish LC50/96h = OECD 203, >10mg/l.
Further information
BOD5 246mg/g (tested by 0.01% Dye solution).
COD 600mg/g by Mn(KMnO4) method / 0.01% Dye solution test.
Metal content Metal content under the ETAD recommended limits.

Chromium (Cr) None.
Cobalt (Co) None.
Copper (Cu) None.
Phosphorus content < 0.1%.
Biodegradability . 70 % tested by OECD 302 B.
AOX < 1.0%.
SECTION 13: Disposal considerations

General information
Dispose of in compliance with all local and national regulations.
Disposal methods
Can be incinerated if in compliance with local and national regulations.

Can be sent to landfill if in compliance with local and national regulations.
Disposal of packaging
Can be incinerated if in compliance with local and national regulations.

Empty containers can be sent to landfill after cleaning, if in compliance with local and national
regulations.
SECTION 14: Transport information

ADR/RID
The product is not classified as dangerous for carriage.
IMDG
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IATA
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation by Occupation No data available.

Safety and Health Acts
Regulation by Toxic No data available.

Chemicals Control Act
Regulation by Safety Control No data is available on this product.

of Dangerous Substances Act
Regulation by Wastes Control No data is available on this product.

Act
Persistent Organic Pollutants No data available.

Control Act
American Management Not applicable.

Information (OSHA
Regulations)

Information (CERCLA
Regulations)

Information (EPCRA 302
Regulations)

Information (EPCRA 304
Regulations)

Information (Material by
Montreal Protocol)

Information (Material by
Rotterdam Convention)
SECTION 16: Other information
Other information
Data sources The Chemical Database, The Department of Chemistry at the University of
Akron(http://ull.chemistry.uakron.edu/erd) (Description(state))
The Chemical Database, The Department of Chemistry at the University of
Akron(http://ull.chemistry.uakron.edu/erd) (Colour)
Akron(http://ull.chemistry.uakron.edu/erd) (Odour)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Melting
Point/Freezing Point)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Initial Boiling
Point & Boiling Point Range)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Flash Point)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Upper / Lower
Flammability or Explosive Limits)
National Institute of Technology and Evaluation(NITE)
(http://www.safe.nite.go.jp/ghs/h18_bunrui.html) (Vapor Pressure)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Solubility)
Intermational Programme on Chemical Safety(IPCS INCHEM)(http://www.inchem.org/) (Vapor
Density)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Specific
Gravity)
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Other information
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (n-octanol /

water partition coefficient)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (.Autoignition
Temperature)
Akron(http://ull.chemistry.uakron.edu/erd) (Molecular Weight)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Oral)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Dermal)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Skin Corrosion or
Irritation)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Serious Eye Damage
or Irritation)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Skin Sensitization)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Skin
Sensitization)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Mutagenicity)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Germ Cell
Mutagenicity)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Reproductive Toxicity)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Reproductive
Toxicity)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Specific Target Organ
Toxicity (Single Exposure))
Target Organ Toxicity (Single Exposure))
Target Organ Toxicity (Repeated Exposure))
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Specific Target Organ
Toxicity (Repeated Exposure))
SIDS (Fish)
SIDS (Shellfish)
SIDS (Algae)
International Uniform ChemicaL Information Database(IUCLID)(http://ecb.jrc.it/esis) (Persistence)
OECD Screening Information Data Set(http://cs3-hq.oecd.org/scripts/hpv/) (Biodegradability).
Text of risk phrases in Section R36/37/38 - Irritating to eyes, respiratory system and skin.
3 R42/43 - May cause sensitisation by inhalation and skin contact.
R43 - May cause sensitisation by skin contact.
Text of Hazard Statements in Skin Sens. 1: H317 - May cause an allergic skin reaction.
Section 3 Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Skin Irrit. 2: H315 - Causes skin irritation.
Eye Irrit. 2: H319 - Causes serious eye irritation.
STOT SE 3: H335 - May cause respiratory irritation.
Further information
The information supplied in this Safety Data Sheet is designed only as guidance for the safe use,
storage and handling of the product. This information is correct to the best of our knowledge and
belief at the date of publication however no guarantee is made to its accuracy. This information
relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any other process.
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SAFETY DATA SHEET

according to 1907/2006/EC, Article 31

SYNOZOL ULTRA BLACK DR

Revision date 2019-01-11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product name SYNOZOL ULTRA BLACK DR

Description C.I. Reactive Unknown.

1.3. Details of the supplier of the safety data sheet

Company Kyung-In Synthetic Corporation

Address 112-31, Yeomchang-dong,

Email address of the kisco@kyungin.co.kr

Company Kyung-In Synthetic Corporation

Address 112-31 Yeomchang-dong

Email address of the kisco@kyungin.co.kr

1.4. Emergency telephone number

Emergency telephone number 82-2-3660-7873

Company Kyung-In Synthetic Corporation

SECTION 2: Hazards identification

2.1.1. Classification - Xn; R42/43 Xi; R36/37/38

SYNOZOL ULTRA BLACK DR

Revision date 2019-01-11

2.1. Classification of the substance or mixture

2.2. Label elements

Signal Word Danger

Hazard Statement Skin Irrit. 2: H315 - Causes skin irritation.

Precautionary Statement: P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.

P403+P233 - Store in a well-ventilated place. Keep container tightly closed.

Precautionary Statement: P501 - Dispose of contents/container to an approved waste disposal plant

SECTION 3: Composition/information on ingredients

SYNOZOL ULTRA BLACK DR

Revision date 2019-01-11

disodium 12225-83-1 235-431-5 Xi; R36/37/38-43

disodium 12225-83-1 235-431-5 Skin Irrit. 2: H315; Skin

SECTION 4: First aid measures

See section 16 for further information.

SECTION 5: Firefighting measures

Use appropriate water spray, foam, powder, carbon dioxide(CO2).

5.3. Advice for firefighters

Wear suitable respiratory equipment when necessary.

SECTION 6: Accidental release measures

Wear suitable protective clothing, gloves and eye/face protection.(적절한 보호의 , 장

SYNOZOL ULTRA BLACK DR

Revision date 2019-01-11

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

SECTION 7: Handling and storage

Occupational exposure controls.

7.2. Conditions for safe storage, including any incompatibilities

SECTION 8: Exposure controls/personal protection

8.2. Exposure controls

8.2.2. Individual protection Wear suitable protective equipment.

Respiratory protection Wear suitable respiratory equipment when necessary.

Occupational exposure Wear suitable protective equipment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Vapour pressure Not applicable.

Relative density Not applicable.

Melting point Not applicable.

Autoignition temperature Not applicable.

Freezing Point ( 녹는점 어는점 ) Not applicable.

Boiling point Not applicable.

Flash point Not applicable.