Hydrocarbons 1

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of decarboslation

rate
Ques compare the

⑦ ⑦ -

13 R <R M 2004. R G

onn
-

C00N
-
-
-
-

oz No
(move stable

( I)-
2- I) greate
UCEC con.
az-m-won cn
c-con <
-

2)

↓ ⑦ ⑦

( c rC =
c
=

( H2
-

sp3 sp2 spo

Redp+
reduction
o
nI

⑧ by using
red p
* R-ON > R 4.-
20 Iz
+ +

nI


11
R
R > ( 4
-

* n
-
-
-

0
Red P
* R -
H -
R > R GR
-

nI
·

* R -
-
on -s R -

c37 10 12
+
prone

fromaldehydeatoutin

8 -

R-
x -
pi
quins,e > R cz R
- -

L-INNERRENT
A

7 0 >
)(y N4
=
+

(ii)
kon/p
③ MOINGO REGION

-=0
/
(03/ko);you

from
Gard reagent:

RMGB

onganometallic
pound)
CHC MGB CCE ->
R

cc+10 (yy 1.
-

-
prsionprpretes
#
(rowa mdar man
senfar
ener
of
molecule.

n-hescome

n-pentance
n-butane
>

of branching marchains
so
↓in case

⑥ ~ -
I
7 > X
*
n-

CHEMICAL PROPERTIES i -

1) OXIDATION (HALYTIC)
red notbe lute
2
CH+O2 cPtutes
3 cou
O
MOLOz 1

(n 02
+

238C, 100 atm H -c-v

[CsCOOK
Mn, CM-CEU2>n-100N.
Ch () M
+ -

high I
② PHOTOMALOGENATION:
(free
bra
radical methanisms

R-

4 +

X2 A
>R-X 4X.
+

X F,G,Br, I.
=

Momism
&n
chain initiation X -

X 2x
&2
17

propagation chon X0
+

-> 24 +

X
-

(
d
X8-X
+

- ( -
x x0
+

termination
i)
x+ x0
+
- >

y2

20 +

x cz
+
x
-

(0 10 Cz+ -
-

CH3.
uncontrollable reaction
highly exothermia &
FRNATION:
*

(zF Mzz CHFz + Cfu


mc 2fz -
+ +

best
NOTthe
possible way
to
prepare allye flourides.
* RINATION Imon reative & les selective

Ch
ae
>ayk
-
-

muz a)
monochlorinated

product.
yeeofry?
X
Calculate

->i:1:3:: 1:3.8: 5.
1) Roactivityratio
3y
27 no
of in, sn, ->

= 20
20
10
a
?
③,
#

& ·

I see

Eg
ydrogen
20

it=1. -

-
selective
#Bomination...
less reactive
a more

free
radical
*
major product formationis by stale
-

BVz +NBr
>
hp

product.B
BC
v

fz ⑬

CC-I -
weakbond isiodination
④ iodination
is reversible.
72 M
L

(
y( 3
yI o
-

> -

HI
+

removal.
h
- >

<

↓somone MIon
of
reaction withOA
agent.
HNOZ
->
.
-
③ iserisation
yo-cell
O BC cr.


pyrolysis or
cracking lower albone.
higher albanes -> -

⑤ aromatisation n -hescame G2Os/AlOs, #


500C

n-heptanc "! ·

Fltoutine

I
n-octane

o-lens
AKENES: -

method propation:
of loss of Mos
of
alcohols

from alcohols?(dehydration
**
-

1)

dB 1 1 20
20
- +
-
- =

I by -

I

dehydration
- >

by Alcos (no
formation)
eyer-on hop, in the

V.)
CHz-21-04 concyson 10 =
ch2 (85004y00,
>Mk
(C-intermediate possibilityof rearrangement
manism
pansion
i) az
-

z cy
-
- -
00

0 04

·2
-

Mz
-

M -

Go- -az
-

aut

E
3-ch e
RDS.

y( m( (<
-

B
- - -
=

6xH
·ov az u M3.
-
-

L
-

stable
priet
my more

SAYTIEF -

*

↳c cza M2. 12 2 M
- C
-
=
- -

224.
GOFFMANN
- I
las

formation of
is RAS so
stability
of formed.
it
First
decides the rate
of dehydration.
Rodon ↓
> 104.
mon

stable
~

10.
aide?

fromalty
a) by dehydro halogenation
al kon/A.
R X R -CH cz nX.
cy - >
=
- - -

t 'vz2 NONG.

Mechanism R M a

BC-H.-X.
- =
-

- >

base alo
kon, Nannz.
strong
A

EMSWat/Hon
formation other bases.

↓ noc

v v all Kon
BC C C-Ab. HC
C-C-c) Hoffman
=

k - -
->

C
(C-c uts.saytze
·

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