Professional Documents
Culture Documents
Gem Notes
Gem Notes
net/publication/276514092
Gem Notes
CITATIONS READS
0 16,140
1 author:
Brendan M. Laurs
Gem-A
134 PUBLICATIONS 702 CITATIONS
SEE PROFILE
Some of the authors of this publication are also working on these related projects:
All content following this page was uploaded by Brendan M. Laurs on 05 November 2015.
1 Editorial p. 57
COLUMNS
2 What’s New
Studies of tourmaline magnetism,
p. 50
HPHT-treated diamond and
CVD synthetic diamond |
Updated CIBJO Blue
Books | Gem laboratory
newsletters | New JVC
Essential Guides |MIM
Mineral Museum
ARTICLES
6 Practical Gemmology
Photomicrography using a Feature Articles
smartphone camera 24 Galileo as Gemmologist: The First Attempt in Europe at
6FLHQWLÀFDOO\7HVWLQJ*HPVWRQHV
8 Gem Notes
Colourless cat’s-eye apatite | By A. Mottana
Prismatic Ethiopian aqua-
32 Purple to Reddish Purple Chrysoberyl from Brazil
marine | Blue chrysocolla
By Karl Schmetzer, Jaroslav Hyršl, Heinz-Jürgen Bernhardt and
chalcedony | Painite specimen
Thomas Hainschwang
discovery | Tanzanite as a
stinkstone | Beaded cultured 42 ,GHQWLÀFDWLRQ&KDUDFWHULVWLFVRI 1DWXUDODQG,PLWDWLRQ
SHDUOPLVLGHQWLÀHGDVQDWXUDO_
Micro-focus X-radiography | Hornbill Ivory
Quahog pearl | Parcel of melee- By Jie Liang, Haibo Li, Taijin Lu, Jun Zhang, Meidong Shen
size yellow-brown diamonds and Jun Zhou
containing synthetics | Visit to
Mogok, Myanmar
Gemmological Brief
50 Detection of Ruby Crystals in Marble Host Rock by
20 Learning Opportunities X-ray Computed Tomography
Conferences, exhibits and other By Antonia Bouts
educational events
55 Excursions
Two trips to Mogok, Myanmar, in December 2013
ISSN: 1355-4565 i
Gemmology The Journal of
Editorial 1
What’s New
INSTRUMENTS AND TECHNIQUES
Identifying HPHT-treated Natural Type IIa Colourless exhibit a weak-to-moderate GR1 peak located in close
Diamonds and CVD Synthetic Diamonds proximity, at 741 nm. Cryogenic cooling of the sample is
Since November 2012, a series of Application Notes have recommended.
been posted on the M&A Gemological Instruments website Alberto Scarani and Mikko Åström
at www.gemmoraman.com/articles.aspx. These cover (info@gemmoraman.com)
various topics, including the use of a Raman spectrometer M&A Gemological Instruments
for separating heated from unheated spinel, identifying the Rome, Italy and Järvenpää, Finland
colour origin of cultured freshwater pearls, red coral and
conch pearls, and detecting resin-impregnated jadeite.
Most recently (in September 2013 and January 2014),
Application Notes were posted on two important diamond
topics. Tourmaline Magnetism
In December 2013, a study of the relationship
between magnetic susceptibility and coloration of gem
tourmaline was posted at www.gemstonemagnetism.
com/how_to_page_7.html. Quantitative magnetic
measurements were taken with a Hoover balance
of more than 150 samples, including a number of
3DUDtEDW\SHWRXUPDOLQHV$VSHFLÀFUDQJHRIPDJQHWLF
susceptibility was associated with each colour variety.
Detecting HPHT Treatment of Natural
Type IIa Colorless Diamonds describes subtle
differences in the gemmological properties and
photoluminescence (PL) spectra between untreated
natural type IIa diamonds and their HPHT-treated
counterparts. The PL spectral acquisitions were carried
out with a GemmoRaman spectrometer utilizing 532
nm laser excitation. Spectra were collected at both
room temperature and with the samples cooled to
liquid nitrogen temperature to obtain sharper PL peaks
and reveal additional features not detectable at room
temperature. Although the results obtained at room Of the transparent samples tested, red and pink
temperature were surprisingly good, cryogenic testing is gems had some of the lowest values, while dark
UHFRPPHQGHGIRUFRQÀUPDWLRQRIWUHDWPHQWGHWHFWLRQ green and blue gems had some of the highest; yellow
in type IIa colourless diamonds. samples showed the greatest variations in magnetic
Detecting Synthetic CVD-Diamond with Gemmo- susceptibility. The study also showed that magnetic
Raman-532SG™ describes a testing procedure for responses to a handheld neodymium magnet can
identifying colourless to near-colourless CVD-grown be used to identify certain tourmaline varieties. For
synthetic diamonds. After initial screening for sim- example, a drag response from any blue tourmaline
ulants and establishment of type II diamond type, a was diagnostic of indicolite, while diamagnetic (repel)
FRPELQDWLRQ RI 89 ÁXRUHVFHQFH PLFURVFRS\ DQG 3/ behaviour from any blue tourmaline was indicative
spectroscopy is described for identifying CVD synthetics. of the Paraíba type. A diamagnetic response from
The authors note that the SiV– defect—which is typical of any green tourmaline was consistent with ‘chrome
CVD origin—can often be detected at room temperature tourmaline’ (coloured by chromium and/or vanadium).
as a somewhat broadened PL peak at about 738 Kirk Feral
nm. However, careful interpretation of the spectrum (kirk@gemstonemagnetism.com)
is important, as many natural type IIa diamonds San Diego, California, USA
PUBLICATIONS
3
DTXDPDULQH WKDW ZDV IUDFWXUHÀOOHG ZLWK HSR[\ UHVLQ
and an unpolished calcitic pearl with an ‘olive’ green
overgrowth. Announced is the availability of GGTL
photomicrographs for use in publications. Images can
be freely downloaded from www.ggtl-lab.org/pictures,
provided that the photos are credited to GGTL.
What’s New 3
What’s New
technique, and the exceptionally dark coloration ¶FRQÁLFW PLQHUDOV· WLQ WDQWDOXP WXQJVWHQ DQG JROG
UHVXOWHG IURP 7L GLIIXVLRQ LQWR ÀVVXUHV WKDW ZHUH The Essential Guide to the U.S. Trade in Materials
subsequently healed during high-temperature heat from Plant and Wildlife Products covers organic gem
treatment. PDWHULDOV WKDW KDYH EHHQ FODVVLÀHG DV SURWHFWHG E\
international, federal, and/or state laws.
ICGL Newsletter
The International Con- SSEF Facette and Lab Alert
sortium of Gem-Testing The Swiss Gemmological
Laboratories has released Institute SSEF has released
its latest newsletter (No. 1, the latest Facette Magazine
2014), available at http:// (No. 21, 2014), which is
icglabs.org. It describes a available at www.ssef.ch/
non-resin type synthetic research-publications/
RSDO E\ .\RFHUD SURÀOHV facette. It describes several
petalite as a collector’s exceptional items sold
gem and contains a review at auction by Christie’s
of the exhibition titled The and Sotheby’s in 2013,
Cheapside Hoard: London’s an expedition to Mogok
Lost Jewels, on display at the Museum of London until (Myanmar), a technique
27 April 2014. called ‘automated spectral diamond inspection’ for
DXWKHQWLFDWLQJPHOHHVL]HGLDPRQGV'1$ÀQJHUSULQWLQJ
of pearls, blue cobalt-bearing spinel from Vietnam, a
JVC Releases Two Essential Guides stability experiment on Ethiopian opal, colour-change
In 2013, the Jewelers Vigilance Committee published garnets from Tanzania showing the Usambara effect,
two additions to its Essential Guides series (see www. jadeite from Kazakhstan, an imitation amber carving,
jvclegal.org/index.php?categoryid=601). The Essential a brooch featuring a 110 ct non-nacreous natural
*XLGH WR &RQÁLFW 0LQHUDOV and the Dodd Frank Act pearl, rubies from Didy (Madagascar), spessartine from
explains legislation passed in 2010 that addresses 1LJHULDDQG0RJRN¶3LSL·SHDUOVIURPWKH3DFLÀF2FHDQ
vanadium-bearing chrysoberyl, a topaz pendant that
was evidently damaged in a barbeque, cultured pearls
from French Polynesia containing new bead materials
(organic nuclei and freshwater shell pieces) and a
report on the International Gemmological Conference
in Vietnam.
In September 2013, SSEF issued a lab alert on a
new, unstable treatment of conch pearls that results
in surface damage (see www.ssef.ch/research-
publications/press-releases).
MISCELLANEOUS
MIM Mineral Museum Opens in Beirut gem crystals selected for
Photo by Makhmout Douman
In October 2013, the MIM Mineral Museum opened at the their transparency, colour
Campus of Innovation and Sport, Saint-Joseph University, and morphology. There
Beirut, Lebanon (www.facebook.com/mim.museum). is also a large display of
The collection includes more than 1,400 minerals, and multi-coloured liddicoatite
of particular interest to gemmologists are world-class slices.
What’s New provides announcements of new instruments/technology, publications, online resources and more. Inclusion in What’s
New does not imply recommendation or endorsement by Gem-A. Entries are prepared by Brendan Laurs unless otherwise noted.
www.gubelingemlab.com /scholarship /
Dr. Eduard Gübelin Association for Research & Identification of Precious Stones
Maihofstrasse 102 6006 Lucerne Switzerland T: +41 41 429 17 17 info@gubelingemlab.com
What’s New 5
Practical Gemmology
Photomicrography Using a
Smartphone Camera
Edward Boehm
Edward Boehm GG CG
)LJXUH7KHDXWKRUGHPRQVWUDWHVWKHWHFKQLTXHIRUWDNLQJSKRWRPLFURJUDSKV
is principal of RareSource, PO
using a smartphone camera. Here the lens of the camera is positioned over the Box 4009, Chattanooga, Tennessee,
ULJKWRFXODUDQGWKHOHIWKDQGLVUHVWLQJRQWKHOHIWRFXODUIRUVWDELOLW\7KHFDPHUD USA 37405.
lens is held approximately 1 cm above the ocular. Photo by Carley Boehm. Email: edward@raresource.com
Gem-A Shop
Don't miss the SPECIAL OFFERS
on books and instruments from
the Gem-A Shop
Practical Gemmology 7
Gem Notes
COLOURED STONES
Colourless Cat’s-eye Apatite from Brazil
Intense blue apatite is known from Minas Gerais, )LJXUH7KHVH
Brazil, and cat’s-eye stones in yellow and green cat’s-eye apatites
DQGFW
have also been documented from this gem-rich
from Brazil are
country (O’Donoghue, 2006). In addition, a colourless, which is
small amount of colourless cat’s-eye apatite was highly unusual for
recently produced, and shown to this author at this material. Photo
the recent Tucson gem shows by David Epstein by B.M. Laurs.
(Precious Resources Ltda., Teófilo Otoni, Brazil).
He reported that the material was found in January
2013, and came from a parcel consisting mainly of Teófilo Otoni, but the origin of the unusual rough
greenish blue cat’s-eye apatite. Some of the rough material within Brazil is unknown.
was colour zoned, and the colourless portions Brendan M. Laurs
were polished into 40–50 pieces ranging from 1 to Reference
4 ct (e.g. Figure 1), for a total of approximately 100 O’Donoghue M. (Ed.), 2006. Gems, 6th edn., Butterworth-
carats. The material is known to have been cut in Heinemann, Oxford, 382–384.
Gem Notes 9
Gem Notes
made by one of the authors (AH) in the Museum’s for new discoveries to be made within them. The
main systematic mineral collection. Within the distinctive look of the new painite specimens and
corundum collection was a specimen from Mogok our usual procedure of continually appraising the
labelled ‘Corundum (ruby) pitted crystals on collection—especially acquisitions of new pieces
crystals of brown tourmaline with limonite’. The and associated species—led us to visually identify
‘brown tourmaline’ was an immediate visual match this rather ordinary ‘brown tourmaline’ as a painite.
with material from the new painite discovery, Also, this example underlies the importance for
and in December 2007 an electron microprobe collections staff having the opportunity to be
analysis confirmed it was indeed painite. It is ‘out there’, knowing what is on the market and
a fine specimen in terms of its form, size and critically comparing new materials against existing
association with ruby crystals that are up to 8 mm collections. We have scoured the collection for
across (Figure 5). Astonishingly, the specimen had similar material, but have yet to find any more
been acquired in 1914, from Francis Powell & painite surprises. We urge other collections’
Co., London. It was registered into the collection custodians to take another look at their tourmaline
(BM 1914,1118) and remained misidentified for 93 drawers, as you never know what you might find.
years—and it also was present for 38 years before Alan Hart (a.hart@nhm.ac.uk) and Mike Rumsey
painite was formally discovered using the crystal Department of Earth Sciences
donated to the Museum by Pain. It is ironic that The Natural History Museum, London
this far superior specimen was sitting within the
collection just meters away from the 1952 specimen References
that was on display for so many years as the ‘best Claringbull G.F., Hey M.H. and Payne C.J., 1957. Painite,
of species’. It is also interesting to note that the a new mineral from Mogok, Burma. Mineralogical
mineral would not have been named painite if the Magazine, 31, 420–425.
McWhirter N., 1983. Guinness Book of World Records, 21st
‘tourmaline’ on the specimen acquired in 1914 had
edn. Bantam Books Inc., New York, 758 pages.
been recognized as a new species at that time. Rossman G.R., 2005. Gem News International: New
For us it raises some important points. discoveries of painite from Myanmar. Gems &
Although large mineral collections are known to Gemology, 41(4), 356.
play a role as long-term accessible repositories of Shigley J.E., 1986. New data on painite. Mineralogical
important specimens, there is always the potential Magazine, 50, 267–270.
Gem Notes 11
Gem Notes
Mercaptans? 2585
2572
CH4 (Ȟ)
References
Agricola G., 1546. De Natura Fossilium: Textbook of East and West Gondwana. 33rd International
Mineralogy. Translated from the First Latin Edition Gemmological Conference, Hanoi, Vietnam, 12–16
by M.C. Bandy and J.A. Bandy, Geological Society of October, 164–166.
America Special Paper No. 63, 1955, 240 pages. Taylor D., Rankin A.H. and Treloar P.J., 2013.
Dollish F.R, Fateley W.G. and Bentley F.F., 1974. Liquid hydrogen sulphide (H2S) fluid inclusions
Characteristic Raman Frequencies of Organic Compounds. in unheated tanzanites (zoisite) from Merelani,
Wiley, New York, USA, 443 pages. Tanzania: Part 1. Recognition, characterization and
Saul J.M., 2013. Gemstone occurrences, “organic” odors, gemmological importance. Journal of Gemmology,
and a circular structure in the collision zone between 33(5-6), 149–159.
PEARLS
Gem Notes 13
Gem Notes
round cultured pearl. Usually the culturing process to work with pearls. Simpler instrumentation
grows only a 1–2 mm thick layer of nacre around probably would not have detected this cultured
the nucleus. pearl’s unusual structure. Also, by highlighting
In Figure 9 the void adjacent to the bead also different depths, the internal structures became
became clearly perceptible. It corresponds with obvious and further testing with X-ray computed
the location where the graft was inserted during tomography (very time consuming) was not
the nucleation process. The line detected between necessary. This incident points out once again the
the nucleus and the surface can be interpreted as difficulty in some cases of establishing whether a
a regrowth pattern, which is commonly seen in pearl is natural or cultured.
natural pearls or cultured pearls with a thick nacre Olivier Segura (o.segura@bjop.fr)
layer. Laboratoire Français de Gemmologie, Paris, France
This is a good example of the value of
X-radiography technology designed specifically Emmanuel Fritsch
Pearls are routinely tested for natural or such as concentrically arranged lines, arcs and inner
cultured origin using imaging techniques such as cores of organic substance. However, the centre
X-radiography (Schloßmacher, 1969; Strack, 2006). pearl (7.8 mm diameter) revealed only a single
Such identifications require clear visualization irregular growth line that was suggestive of a natural
of internal structures. This brief report explores pearl (Figure 11a) but not conclusive. Examination
how a recent advance in technology, the micro- of the drill hole with a gemmological microscope
focus technique, can enhance the capabilities of revealed an inner core with a slightly more creamy
traditional X-radiography. colour than the pearl’s body colour (Figure 12).
A pearl necklace was submitted to author ES for Consequently, the necklace was subjected to
identification (Figure 10). Initial testing comprised further testing with a Y.Cougar micro-focus X-ray
taking a series of radiographs of various pearls in system at YXLON company. The inspection was
the necklace with a Kodak 2200 digital X-ray system performed using 80–100 kV, depending on pearl
(60–70 kV, 49 W). The radiographs showed various size, and 3 W of power for the X-ray tube. A small
growth characteristics indicative of natural pearls, focal spot of 1 μm, in conjunction with a digital flat-
)LJXUH7KLVQHFNODFHFRQWDLQV
QDWXUDOSHDUOVRI²PPLQ
diameter, and has a total weight of
J&RXUWHV\RI)+DXVHU
photo by E. Strack.
panel detector, allowed for high magnification with accompanied by additional arcs and rings.
a resolution of ~1 μm. Radiographs were taken of In cases where higher resolution is desired than
several individual pearls (including the centre one), can be achieved with traditional X-radiography,
as well as the entire necklace. The radiograph of the Y.Cougar instrument provides a viable option,
the centre pearl (Figure 11b) shows several growth in addition to X-ray computed tomography (e.g.
lines in a generally circular arrangement. This Krzemnicki et al., 2010, and references therein).
pattern positively identifies the pearl as natural. Elisabeth Strack (info@strack-gih.de)
The differently coloured inner core seen through Gemmologisches Institut Hamburg, Germany
the drill hole with the gemmological microscope is
therefore interpreted as being an internal layer of Friedhelm W. Maur (friedhelm.maur@hbg.yxlon.com)
the natural pearl. YXLON, Hamburg, Germany
The high-resolution capability of the Y.Cougar References
instrument further allowed us to visualize a record Krzemnicki M.S., Friess S.D., Chalus P., Hänni
of the growth processes in some of these natural H.A., Karampelas S., 2010. X-ray computed
pearls. The radiograph of pearl no. 51 (Figure 13a) microtomography: Distinguishing natural pearls from
shows an inner core with a prismatic-concentric beaded and non-beaded cultured pearls. Gems &
structure, surrounded by rings in a circular Gemology, 46(2), 128–134.
Schloßmacher K., 1969. Edelsteine und Perlen. E.
arrangement within the nacre layers. A much Schweizerbart’sche Verlagsbuchhandlung, Stuttgart,
different pattern is shown by pearl no. 68 (Figure Germany, 306–309.
13b), which has an inner core composed of less- Strack E., 2006. Pearls. Rühle-Diebener-Verlag, Stuttgart,
dense material (probably an organic substance), Germany, 642–645.
)LJXUH0LFURIRFXV;UDGLRJUDSK\
may record details of the growth history
RISHDUOVD3HDUOQRVKRZVDQ
inner core with a prismatic-
concentric structure, surrounded by
rings in a circular arrangement.
E3HDUOQRVKRZVDQLQQHURUJDQLF
rich core with an irregular round shape,
surrounded by arcs and rings in a
circular arrangement.
Gem Notes 15
Gem Notes
7ZR6\QWKHWLF'LDPRQGV,GHQWLÀHGLQD3DUFHORI0HOHHVL]H
Yellow-Brown Diamonds
In late 2013, the Laboratoire Français de Gemmologie The first step in our examination was to
analysed a parcel of 7,000 melee-size (1 to 2.5 observe all the diamonds in long- and short-
mm in diameter) yellow-brown diamonds. They wave UV radiation (see Figure 15). Two of them
were presented as natural ‘cognac’ diamonds, and emitted an intense green luminescence to short-
reportedly had already been screened for synthetics. wave UV, but remained inert to long-wave UV
)LJXUH$SRUWLRQRIWKHPHOHHVL]H
diamond parcel is shown here in visible
light (top) and while being exposed to
ORQJDQGVKRUWZDYH89UDGLDWLRQ
DQGQPUHVSHFWLYHO\7KH
JHPDWSRVLWLRQ-KDVDQLQWHQVH
green luminescence under short-
ZDYH89DQGLVLQHUWWRORQJZDYH89
UDGLDWLRQ7KLVREVHUYDWLRQUDLVHG
VXVSLFLRQWKDW-³DVZHOODVDQRWKHU
JHPLQWKHSDUFHOQRWVKRZQ³DUH
synthetic diamonds. Photos by
A. Delaunay.
)LJXUH7KH'LDPRQG9LHZLPDJH
RIVDPSOH-PPLQGLDPHWHU
)LJXUH,QWKHWZRVXVSHFWVDPSOHVFORXGVRISLQSRLQWVOHIWRUEUHDGFUXPE is typical of synthetic diamond, with
inclusions (right) provide further indication of synthetic origin. Photomicrographs cubic and octahedral growth sectors.
E\$'HODXQD\PDJQLÀHGï Photo by A. Delaunay.
radiation (e.g. the gem at J18 in Figure 15). Such other breadcrumb-like inclusions. Such features,
behaviour may be indicative of high-pressure, due to remnants of the metal solvent used in the
high-temperature (HPHT)–grown synthetic growth process, are often observed in HPHT-
diamond (see, e.g., Shigley et al., 1986). grown yellow synthetic diamonds (see, e.g.,
The parcel was then subjected to infrared Kitawaki et al., 2008).
spectroscopy using a special automated batch To further study the two potentially synthetic
analysis system (HTS-XT, meaning High diamonds, we examined their growth structures
Throughput Screening eXTension) developed with the DiamondView, a high-energy ultra-
in partnership with Bruker Optics (Marne-la- short-wave (almost 220 nm) UV luminescence
Vallée, France), and later patented. The spectra imaging device. It is well known that HPHT-
of the two gems tagged earlier as potentially grown synthetic diamonds display cubic growth
synthetic showed them to be purely type Ib, with sectors, in addition to the typical octahedral
only isolated nitrogen impurities and no trace of growth sectors seen in natural stones. Both of
hydrogen. This is typical of synthetic diamonds the gems clearly showed a central square pattern
grown by the HPHT process, furthering our surrounded by the two types of growth sectors
suspicions. The other stones in the parcel were all (Figure 17), identifying them without ambiguity
type Ia with aggregated nitrogen and often with as HPHT-grown synthetics.
hydrogen impurities. Photoluminescence spectroscopy (e.g. Figure
Under magnification (Figure 16), one of the 18) of the two synthetic diamonds at liquid-
suspect gems revealed a cloud of pinpoints, the nitrogen temperature with 514 nm laser excitation
728
Ni centre
10000
637
N-V—
5000
Gem Notes 17
Gem Notes
showed the 728 nm emission that is attributed being mixed with natural diamonds on the French
to nickel impurities in diamond. Although Ni- market.
related defects may be found in some unusual Aurélien Delaunay and
natural diamonds (see e.g. Hainschwang et al., Emmanuel Fritsch
References
2013), nickel is also the most common solvent Hainschwang T., Fritsch E., Notari F., Rondeau B. and
used in HPHT diamond growth. Its presence, Katrusha A., 2013. The origin of color in natural C
in combination with the other characteristics center bearing diamonds. Diamond & Related Materials,
described above, is proof positive that these 39, 27–40.
diamonds are indeed synthetics. Kitawaki H., Abduriyim A. and Okano M., 2008.
Identification of melee-size synthetic yellow diamonds
These are the first synthetic diamonds ever in jewelry. Gems & Gemology, 44(3), 202–213.
identified in our laboratory, from more than Shigley J.E., Fritsch E., Stockton C.M., Koivula J.I., Fryer
100,000 stones submitted. This discovery thus C.W. and Kane R.E., 1986. The gemological properties
provides an initial indication that even with careful of the Sumitomo gem-quality synthetic yellow
screening, yellow-brown synthetic diamonds are diamonds. Gems & Gemology, 22(4), 192–208.
MISCELLANEOUS
)LJXUH6RPHRIWKHUHFHQWSURGXFWLRQIURPWKH/LDQ
6KDQPLQHFRQVLVWVRIVSLQHOTXDUW]EOXHDSDWLWHDQGJUHHQ
WRXUPDOLQH3KRWRE\87LQ+ODLQJ
Gem Notes 19
Learning Opportunities
CONFERENCES
Learning Opportunities 21
Learning Opportunities
EXHIBITS
Learning Opportunities 23
Feature Article
Galileo as Gemmologist:
The First Attempt in Europe at
6FLHQWLÀFDOO\7HVWLQJ*HPVWRQHV
A. Mottana
Galileo Galilei is credited with being one of the greatest contributors to the
¶VFLHQWLÀFUHYROXWLRQ·SDUWLFXODUO\EHFDXVHRIKLVGLVFRYHULHVLQDVWURQRP\+H
DOVRLQWURGXFHGLQWR(XURSHDQJHPPRORJ\KLV¶ODQJXDJHRIPDWKHPDWLFV·LH
H[SHULPHQWDO VFLHQFH ZLWK WKH LQYHQWLRQ RI WKH bilancetta OLWWOH >K\GURVWDWLF@
EDODQFH +H FRQFHLYHG LW WR UHFKHFN $UFKLPHGHV· GHWHUPLQDWLRQ RI WKH JROG
FRQWHQWRIDUR\DOFURZQDQGDOVRXVHGWKLVEDODQFHWRPHDVXUHWKHPDVVRI
JHPVDPSOHVLQDLUDQGLQZDWHU+RZHYHUPXFKRIKLVGDWDZDVLQFRQVLVWHQW
ZLWK WKH LQIHUUHG LGHQWLW\ RI KLV VDPSOHV VLQFH PDQ\ ZHUH VLPXODQWV 7KH
UHVXOWVRIKLVLQYHVWLJDWLRQVGLGQRWFLUFXODWHDQGRQO\DIWHUWKUHHFHQWXULHVZDV
*DOLOHR·VKDQGZULWWHQtavola WDEOHRIJHPGDWDGLVFRYHUHG
Galileo as Gemmologist 25
Feature Article
7DEOH,7KHJHPPDWHULDOVVWXGLHGE\*DOLOHRZLWKWKHLULQIHUUHGLGHQWLÀFDWLRQYLDFDOFXODWHG6*YDOXHVa
Weight
1DPHJLYHQE\ Expected SG Weight in air Calculated 5DQJHRINQRZQ
in water ,QIHUUHGLGHQWLÀFDWLRQ
Galileo rangeb JUDLQVc SGd SGse
JUDLQVc
6HVVLRQ
Session 2
a
The screened rows refer to simulants.
b
Expected values if the gem names given by Galileo were correct (Dominy, 2013).
c
Fractions have been converted to decimals; in units of Florentine grains (1 grain = 0.5894 gram).
d
Calculated here from the weights in air and water measured by Galileo.
e
Empirical measurements on relevant gem-quality minerals (Dominy, 2013).
f
9DOXHVUHSRUWHGDUHIRUDTXDPDULQHDVWKHUHDUHQRW\SLFDO6*YDOXHVIRUKHOLRGRUJLYHQLQWKHOLWHUDWXUH
Galileo as Gemmologist 27
Feature Article
had an SG of 3.07, corresponding to uvite, which Glass imitations are known from Roman times and
is occasionally found together with spinel in the were not uncommon during the late Middle Ages,
Uva Valley gravel beds (Dunn et al., 1977). where the production of glass of various colours
Galileo used the names zaffiro and smeraldo for and forms had advanced considerably although
blue and green stones, respectively, irrespective of only by empirical methods (O’Donoghue, 1997).
their measured values. However, two green stones Notably, not all crisolito samples measured by
did yield measurements giving SG = 2.72, which Galileo were imitations. Indeed, two of them had
is within the range of emerald (Dominy, 2013). SG = 3.37, which is consistent with olivine that
Another sample with the SG of beryl was referred is intermediate in the forsterite-fayalite series (i.e.
to as aquamarine, but its description as ‘tenera’ (soft) peridot).
is inexplicable. As for the three samples labelled At the time of Galileo one would already easily
sapphires, none of them was corundum: one was distinguish between massive dark blue lapis lazuli
a blue spinel (SG = 3.57); another was possibly and light blue turchina (turquoise), which displays
a gahnospinel (SG = 3.83), which is a gem that variable specific gravity due to its porous texture
only recently was encountered in the European (for Galileo’s samples, SG = 2.73 and 2.77). One
market; and the third one (SG = 2.58) may have would also be able to distinguish garnets from
been either cobalt-blue glass or cordierite (i.e. other red stones (Gilg, 2008), although there was
iolite). All these gem varieties are known from not yet knowledge that garnets constitute a large
some Sri Lankan basement rocks and related group. Indeed, Galileo used granata (garnet) to refer
gravel beds (Oltean et al., 2011; Gorghinian et al., to a stone that, on the basis of its SG value (3.61)
2013). They additionally support Sri Lanka as the might have been the orange hessonite variety of
possible origin of some gems available in Europe grossular, and also to another sample that could
during the Renaissance, although we cannot rule have been pyrope-almandine (SG = 3.98). In the
out the possibility of their coming from elsewhere same way, he was unable to distinguish between
in southern Asia. pearls from what were later known to be from a
The case of Galileo’s yellow topazio is rather Pinctada sp. mollusc (SG = 2.59) and a Strombus sp.
peculiar. None of the three topazio stones weighed gastropod (i.e. conch; SG = 2.88).
by Galileo met the SG requirements of topaz: two
appear to have been beryl (SG = 2.75), in the yellow
variety that came to be known as heliodor in the Conclusion
early 20th century, and the other one apparently Within the framework of late Renaissance
was citrine, the yellow variety of quartz (SG = gemmology, Galileo was unique as a scientifically
2.66). At that time, citrine was the most widespread inclined researcher, which also made him a pioneer
yellow gem available, as it was found sparsely in for all Western Europe. At his time, almost all
the Bohemia-Saxony silver-bearing ore district. treatises on minerals and gems consisted of the
Notably, true topaz was also well known there, mere description of a number of stones from
and was commonly mistaken for citrine if yellow the viewpoint of a traditional set of external
or for diamond if colourless (i.e. Adamas Bohemicus: characteristics such as colour, shape, transparency
Bohemian diamond; de Boot, 1609, p. 219). and hardness. Most often, this objective
Quartz (cristallo, i.e. the colourless variety known information would be provided with remarks on
as rock crystal) was measured by Galileo with their mysterious properties, mostly of a mystical
amazing precision (SG = 2.66 versus D = 2.655 nature, which had been passed down from the
g/cm3). The calcidonio, with SG = 2.61, fits well Middle Ages (Mottana, 2006). Galileo introduced
into the highly variable properties of chalcedony, a scientific measurement that, eventually, would
which is always less dense than macrocrystalline prove to add significantly to the characterization
quartz because of its porous texture. By contrast, of minerals and gems (e.g. Figure 5).
Galileo’s amatista was by far too light (SG = 2.24) In actuality, the young Galileo had no idea
to be amethyst; it may have been purple glass. It about specific gravity as a property of materials,
appears that one of his crisolito (chrysolite) samples nor had he developed systematic thought about
was also glass, with a relatively low SG of 2.48. it: he only conceived an instrument appropriate
Galileo as Gemmologist
Feature Article
iis olea, salia, tincturae, essentiae, arcana & magisteria arte Leonardi C., 1502. Speculum lapidum clarissimi artium et
chymica confici possint, ostenditur. Claudium Marnium & medicinae doctoris Camilli Leonardi Pisaurensis. Valerii
Heredes Ioannis Aubrii, Hanouiae, Germany, 576 pp. Superchii Pisaurensis physici epigramma. Quidquid in humanos
+ index. gemmarum partitur usus Terra parens: uasti quicquid &
Della Porta G.B., 1589. Magiae naturalis libri XX. Ab unda maris. Ioannem Baptistam Sessa, Venetiis, Italy,
ipso authore expurgati, et superaucti, in quibus scientiarum 66 pp.
naturalium diuitiae, & delitiae demonstrantur. Horatium Mottana A., 2006. Italian gemology during the
Saluianum, Neapoli, Italy, 303 pp. Renaissance: A step toward modern mineralogy. In
Dolce L., 1565. Libri tre di M. Lodovico Dolce; ne i quali si G.B. Vai and W.G.E. Caldwell, Eds., The Origins of
tratta delle diuerse sorti delle gemme, che produce la natura, della Geology in Italy. Geological Society of America Special
qualità, grandezza, bellezza & virtù loro. Gioan Battista Paper 411, Boulder, CO, USA, 1–21.
Marchio Sessa et Fratelli, Venetia, Italy, 100 pp. O’Donoghue M., 1997. Synthetic, Imitation, and Treated
Dominy G.M., 2013. The Handbook of Gemmology. Gemstones. Taylor & Francis, London, 203 pp.
Amazonas Gem Publications, Vancouver, Canada. Oltean F.M., Gorghinian A., Marcelli A., Esposito A. and
Dunn P.J., Appleman D., Nelen J.A. and Norberg J., 1977. Mottana A., 2011. Cause chimiche delle variazioni di
Uvite, a new (old) common member of the tourmaline colore degli zaffiri di Rathnapura (Sri Lanka). Rivista
group and its implications for collectors. Mineralogical Gemmologica Italiana, 6(1), 31–42.
Record, 8, 100–108. Stevin S., 1586. De Weeghdaet Praxis artis ponderariae,
Fantoni L. and Poggi L., 2012. La collezione di pietre beschreuenduer Simon Steuin van Brugghe. Christoffel
lavorate. In G. Pratesi, Ed., Il Museo di Storia Naturale Plantijn by François van Rephelingen, Leyden, The
dell’Università di Firenze, Vol. IV. Le Collezioni Netherlands, 43 pp.
Mineralogiche e Litologiche. Firenze University Press, Vassallo e Silva N., 1993. The Portuguese gem trade in the
Florence, Italy, 54–65. sixteenth century. Jewellery Studies, 6, 19–28.
Favaro A., 1879. Inedita Galilaeiana. Frammenti tratti Vitruvius, 1567. M. Vitruuii Pollionis De architectura
dalla Biblioteca Nazionale di Firenze, pubblicati ed libri decem, cum commentariis Danielis Barbari, ... multis
illustrati da Antonio Favaro: II. Studi sperimentali. aedificiorum, horologiorum, et machinarum descriptionibus,
Memorie del Reale Istituto Veneto di Scienze Lettere ed Arti, & figuris, unà cum indicibus copiosis, auctis & illustratis.
Apud Franciscum Franciscium Senensem & Ioan. Crugher
21, 444–447.
Germanum, Venetiis, Italy, 375 p.
Favaro A., Ed., 1890. Le opere di Galileo Galilei. Edizione
Nazionale, Vol. I. Barbèra, Florence, Italy, 423 pp.
Fermi L. and Bernardin G., 1961. Galileo and the Scientific
Revolution. Basic Books, New York, USA, 150 pp.
Ghetaldi M., 1603. Promotus Archimedis sev de varijs corporibus
generibus grauitate & magnetudine comparatis. Apud
Aloisium Zannettum, Romae, Italy, 72 pp.
Gilg H.A., 2008. Anthrax, carbunculus, and granatus: The Author
Garnet in ancient and Medieval times. In H.A. Gilg, Prof. Annibale Mottana
D. Kile, S. Liebetrau, P. Modreski, G. Neumeier and G. 'LSDUWLPHQWRGL6FLHQ]H8QLYHUVLWj5RPD7UH
Staebler, Eds., Garnet: Great Balls of Fire. Lithographie /DUJR 6 /HRQDUGR 0XULDOGR 5RPH
LLC, East Hampton, Connecticut, USA, 12–18.
,WDO\(PDLODQQLEDOHPRWWDQD#XQLURPDLW
Gorghinian A., Mottana A., Rossi A., Oltean F.M.,
Esposito A. and Marcelli A., 2013. Investigating the
colour of spinel: 1. Red gem-quality spinels (‘balas’) Acknowledgements
from Ratnapura (Sri Lanka). Rendiconti Lincei—Scienze $Q RUDO SUHVHQWDWLRQ RI WKLV HVVD\ ZDV JLYHQ
Fisiche e Naturali, 24(2), 127–140. DW &,*(6 ,9 WKH IRXUWK &RQYHJQR ,WDOLDQR
Heikamp D., 1963. Zur Geschichte der Uffizien-Tribuna GL *HPPRORJLD 6FLHQWLÀFD 1DSOHV
und der Kunstschränke in Florenz und Deutschland. 6HSWHPEHU7KHDXWKRUWKDQNV'UV+$
Zeitschrift für Kunstgeschichte, 26, 193–268.
*LOJ $ 5RPDQHOOR 0 0DFUu DQG 3 9LVFRQWL
Hodierna G.B., 1644. Archimede redivivo con la stadera del
IRU GLVFXVVLRQV DQG YDOXDEOH VXJJHVWLRQV
momento del dottor Don Gio. Battista Hodierna, dove non
solamente s’insegna il modo di scoprir le frodi nella falsificazione 0V -RVHSKLQH 3 0ROLWHUQR NLQGO\ UHYLHZHG
dell’oro e dell’argento, ma si notifica l’uso delli pesi e delle WKH (QJOLVK WH[W $OVR JUHDWO\ DSSUHFLDWHG DUH
misure civili presso diverse nationi del mondo, e di questo regno WKH FULWLFDO VXJJHVWLRQV FRQWULEXWHG E\ WKUHH
di Sicilia. Decio Cirillo, impressit Abbas Gelosus VD, DQRQ\PRXVVFLHQWLÀFUHYLHZHUV
impressit De Denti, Palermo, Italy, 72 pp.
Galileo as Gemmologist
Feature Article
Introduction
Alexandrite deposits were discovered near the with ultramafic rocks (Basílio et al., 2000, 2001;
town of Malacacheta in Minas Gerais, Brazil, Pedrosa-Soares et al., 2009). This is the classic
in 1975. These secondary (alluvial) deposits are formation mechanism of alexandrite in various
located about 20–30 km north of Malacacheta and deposits worldwide, such as in the Ural Mountains
west of Teófilo Otoni, along the Córrego do Fogo, of Russia, at Lake Manyara in Tanzania, and at the
Ribeiro Setubinha and Ribeiro Soturno rivers. Novello Claims in Zimbabwe.
Prior to the discovery of the Hematita deposit Purple to reddish purple chrysoberyl (also
in 1987, Malacacheta was the major alexandrite- designated as ‘red’ chrysoberyl) from the
producing area in Brazil (Bank, 1986; Proctor, Malacacheta area was briefly described by Proctor
1988; Cassedanne and Roditi, 1993; Basílio et (1988) and has also been mentioned more recently
al., 2000, 2001). It is situated within the so-called as a rare gem mineral from that area (e.g. D.
Eastern Brazilian pegmatite province in Minas Schwarz, pers. comm., 2011, 2012). However,
Gerais State (Pedrosa-Soares et al., 2009). to the knowledge of the present authors,
Based on the mineral assemblages present gemmological and mineralogical data for this type
in the secondary deposits and as inclusions in of reddish purple chrysoberyl are not available.
the alexandrites, a metasomatic-metamorphic Thus, the purpose of this article is to describe
formation is assumed, specifically an interaction two chrysoberyl samples with this rare coloration
of granite-related or pegmatitic Be-rich fluids (Figure 1) and to evaluate the cause of their colour.
Background
The pleochroism and colour-change behaviour of
typical chromium-bearing chrysoberyl (alexandrite)
recently have been studied in natural samples
from various sources and in synthetic material
produced by various techniques (e.g. Schmetzer
and Bosshart, 2010; Schmetzer and Malsy, 2011;
Schmetzer et al., 2012, 2013). The coloration and
colour change of individual samples is a complex
function of different parameters, mainly trace-
element contents (especially Cr, but also Fe and V),
crystallographic orientation and sample thickness.
Different coloration is observable in polarized
light (designated colours of X, Y and Z) and in
non-polarized light (designated colours parallel to
the a-, b- and c-axes).
Faceted alexandrites from various localities
Figure 1: These two purple to reddish purple chrysoberyls
that weigh about 0.5 to 1.0 ct and are accepted were studied for this report, and are shown here in daylight
in the gem trade as having a ‘good’ colour in (top) and incandescent light (bottom). The faceted stone
daylight and incandescent light (i.e. samples weighs 0.49 ct and the crystal is 1.91 ct. Photos by
that appear transparent and are not overly dark) K. Schmetzer.
generally contain 0.4–0.7 wt.% Cr2O3. Smaller
faceted samples showing good colour may a faceted gemstone of 0.49 ct, is from a private
have up to 1.0 wt.% Cr2O3 (see, e.g., Bank et al., collection and is known only as originating from
1988; Malsy, 2010; Schmetzer and Malsy, 2011). ‘Brazil’. According to this gem’s properties, it
Alexandrites with higher Cr are known, but are might have also come from the Malacacheta area,
mostly valued as collectors’ stones due to their but other contact metamorphic sources such as
interesting morphology and twinning, rather than Carnaíba cannot be ruled out completely.
for jewellery purposes. Samples from the Novello The growth structures, inclusions, and coloration
Claims in Zimbabwe, for example, reveal extremely of both samples were studied in immersion with
high chromium values of up to 3.2 wt.% Cr2O3 a horizontal gemmological microscope. Inclusions
(Bank et al., 1988; Okrusch et al., 2008; Schmetzer in the faceted stone were identified by micro-
et al., 2011). In reflected daylight, this material, Raman spectroscopy. Energy-dispersive X-ray
which in general is also heavily fractured, appears fluorescence (EDXRF) spectroscopy utilized
extremely dark green or nearly black. Relatively a Spectrace 5000 Tracor X-ray spectrometer.
dark alexandrite is also known from the Carnaíba Electron microprobe analyses were performed
and Campo Formoso mining areas in Bahia State, across the table of the faceted stone—and also
Brazil (Couto, 2000). These crystals may contain on a faceted 0.11 ct alexandrite from Hematita,
1–3 wt.% Cr2O3 (K. Schmetzer, unpublished for comparison—with a Cameca Camebax SX
research), but they are, in general, also heavily 50 instrument. The Hematita sample (from the
fractured and translucent at best. collection of author KS) appears intense blue-
green in daylight and purple in incandescent light;
it was selected for analysis because its thickness of
Samples and Methods 1.8 mm is somewhat comparable with that of the
Both of the samples described in this article 0.49 ct faceted chrysoberyl of the present study
(Figure 1) originated from Brazil. A twinned (2.4 mm). Ultraviolet-visible (UV-Vis) spectra were
crystal weighing 1.91 ct that shows intense purple recorded for both of the reddish purple Cr-rich
and colourless portions was purchased in 2006 samples, and for our faceted Hematita alexandrite,
from a local dealer in the Malacacheta area by one using a CCD-type Czerny-Turner spectrometer in
of the present authors (JH). The second sample, combination with an integrating sphere.
Table I: Mineralogical and gemmological properties of two Cr-rich chrysoberyls from Brazil.
UV-Vis spectrum Fe Cr Cr
X || a Y || b Z || c
with smaller b and c pinacoids; x, i and m prism to the dipyramid o. This chrysoberyl also contains
faces; and o and n dipyramids (Figure 4, Table birefringent platelets (Figure 8), identified as
I). This morphology, especially with c pinacoids phlogopite by micro-Raman spectroscopy.
and x prism faces, represents a habit that is typical Similar platelets have been previously described
for pegmatitic chrysoberyl from many localities, as inclusions in Malacacheta alexandrite (Basílio et
such as Sri Lanka (see, e.g., Schmetzer, 2011). The al., 2000, 2001), but they are not commonly seen
internal growth pattern observed in the coloured in samples from Hematita (Bank et al., 1988; Pohl,
portion consists of i prism faces in a direction of 1989). The growth structures seen in Hematita
view parallel to the a-axis (Figure 5), and of growth alexandrite (Schmetzer, 2011; Schmetzer and
faces parallel to the a pinacoid and parallel to the o Hainschwang, 2012) are also different from those
dipyramid in other directions of view. described in the two reddish purple chrysoberyls.
The faceted stone is also twinned, with an Specifically, stones from Hematita frequently show
orientation of the twin boundary slightly oblique a distinct, jagged boundary between different
to the table facet, thus subdividing the table plane growth zones, while growth planes within the
into two different parts (Figure 6). Growth planes individual zones are weak. Occasionally, this
showing distinct zoning associated with layers growth feature is combined with colour zoning
having a lighter and darker coloration (Figures 6 consisting of an intensely coloured core and a
[left] and 7) are seen parallel to the pinacoids a and lighter but not colourless rim (for further details,
b, parallel to the prism faces i and m, and parallel see the references cited above).
to orient the different parts of the twin parallel to rough twin, however, revealed only weak Fe lines.
the light path in the microscope and to correctly In Table II, quantitative electron microprobe
observe the colours of X, Y and Z. analyses of the faceted stone are compared with
Consequently, for non-polarized light we data for alexandrite from the Malacacheta and
can give just an approximate description of Hematita areas. The analyses of the 0.49 ct faceted
the pleochroism in daylight and incandescent reddish purple chrysoberyl show a strong variation
light, since only a slight deviation from the ideal in Cr concentration across the table facet. This
direction causes a large divergence in the colour wide range (1.36–2.23 wt.% Cr2O3), which is
that is visible to the observer. Observations with consistent with the observed colour zoning (see
both polarized and non-polarized lighting are again Figure 7), is quite unusual, and the average
summarized in Table I. value (1.54 wt.% Cr2O3) is also much higher than
Compared to the colour change seen in the range of chromium contents reported in the
alexandrite, the most significant difference in the literature for alexandrite from Malacacheta. The
coloration of these Cr-rich samples is for Y in Fe content of this stone, on the other hand, is
polarized light. Y is normally the lightest of the comparable to the values given in the literature for
three colours, but shows the largest hue angle alexandrite from this deposit.
difference between daylight and incandescent light.
For typical Cr-bearing chrysoberyl (alexandrite), Figure 8: Birefringent platelets of phlogopite form inclusions
Y is yellow-green or yellowish green in daylight in the faceted chrysoberyl from Brazil. Immersion, crossed
SRODUL]HUVÀHOGRIYLHZïPP3KRWRPLFURJUDSKE\
and yellow-orange to orange in incandescent
K. Schmetzer.
light. In contrast, for the two Cr-rich samples
examined, Y is yellowish orange in daylight and
reddish orange in incandescent light. The colour
of X and Z, on the other hand, is less significantly
changed: X is violet-purple to purple in daylight
and reddish purple to purplish red in incandescent
light for typical alexandrite. For our samples, the
redness of X only slightly increased from daylight
to incandescent light. The third colour, Z, of
our samples is blue-green in both daylight and
incandescent light.
Table II: Chemical properties of a reddish purple chrysoberyl from Brazil and typical alexandrites from
Malacacheta and Hematita, Minas Gerais, Brazil.*
Variety Reddish purple chrysoberyl Alexandrite
Variety Alexandrite
Locality Hematita
Reference This paper Bank et al. (1988) Pohl (1989) Malsy (2010)
Range Range Range Range
Oxide (wt.%) Average
(10 analyses) (12 samples) (18 samples) (46 analyses)
TiO2 0.08–0.12 0.10 na nd–0.34 na
* Abbreviations: na = not analysed, nd = not detected. All analyses are by electron microprobe except for those of Malsy
(2010), which are by laser ablation–inductively coupled plasma–mass spectrometry.
The Cr content of our intense blue-green/ Hematita alexandrite. The spectrum of the dark
purple alexandrite from Hematita is at the upper part of the colour-zoned crystal specimen was
range measured for material from this important similar to the spectrum of the faceted reddish
Brazilian deposit. This is understandable since the purple chrysoberyl depicted in Figure 9, while
other studied samples were described as having the colourless portion showed only some weak
varying colour intensities, some of which were Fe3+ absorption lines. This is consistent with the
substantially lighter than our stone. In addition, chemical data of both samples (Tables I and II).
our stone was a relatively small sample of only The main difference in the spectra of the
0.11 ct. In general, the Fe contents measured for reddish purple chrysoberyl and the alexandrite
the different samples from Hematita are higher from Hematita is an elevated intensity of the
than those observed for alexandrite from the Cr3+ absorption. This difference is caused by the
Malacacheta area. enriched Cr contents of the reddish purple material,
The absorption spectra of the faceted reddish which is more than twice the value measured for
purple chrysoberyl and the analysed alexandrite the Hematita alexandrite. The elevated intensity
from Hematita (Figure 9) both show the known of the Cr3+ absorption bands results in a distinctly
Cr3+ absorption bands of chrysoberyl, with some lower transmission for the absorption minimum at
additional weak Fe3+ bands in the spectrum of the about 490 nm in the blue-green range.
Absorbance
Cr3+
thickness 2.4 mm). In the sample
with higher Cr, the transmission in Fe3+
the blue-green range at about 1.0 Fe3+
490 nm is distinctly reduced.
Cr3+
Cr3+ Cr
3+
0.5
JOG
Feature Article
,GHQWLÀFDWLRQ&KDUDFWHULVWLFVRI
1DWXUDODQG,PLWDWLRQ+RUQELOO,YRU\
Jie Liang, Haibo Li, Taijin Lu, Jun Zhang,
Meidong Shen and Jun Zhou
1DWXUDO KRUQELOO LYRU\ IURP WKH ELUG Rhinoplax vigil LV D UDUH JHP
PDWHULDODQGLQUHFHQW\HDUVLPLWDWLRQVDQGFRPSRVLWHVKDYHDSSHDUHG
RQWKH&KLQHVHJHPPDUNHW,QWKLVVWXG\WKHJHPPRORJLFDOSURSHUWLHV
RI WKHVH SURGXFWV ZHUH V\VWHPDWLFDOO\ LQYHVWLJDWHG XVLQJ PLFURVFRSLF
REVHUYDWLRQ)7,5VSHFWURVFRS\DQG89ÁXRUHVFHQFH7KHNH\LGHQWLÀFDWLRQ
IHDWXUHV IRU QDWXUDO KRUQELOO LYRU\ DUH D OD\HUHG VWUXFWXUH ZLWK PLQXWH
SLJPHQWHGGRWVZKLFKZHUHQRWSUHVHQWLQSRO\PHUUHVLQLPLWDWLRQV$LU
EXEEOHV ZHUH GHWHFWHG LQ ERWK WKH LPLWDWLRQV DQG LQ FRPSRVLWHV PDGH
IURPKRUQELOOLYRU\DQGUHVLQ)7,5VSHFWURVFRS\LVXVHIXOIRUFRQÀUPLQJ
WKHSUHVHQFHRIUHVLQ
The Journal of Gemmology, SS²
7KH*HPPRORJLFDO$VVRFLDWLRQRI*UHDW%ULWDLQ
2 %UDFHOHW PPLQ 3DWFK\\HOORZ :D[\ <LQHUWWRZHDN < 5 $OO\HOORZSRUWLRQV
EHDGV GLDPHWHU HDFKEHDGKDGD 7UDQVOXFHQWWR ZKLWLVKEOXH LQHUWWRYHU\ZHDN ZHUHQDWXUDO
URXQGUHGVSRW RSDTXH 5ZHDN²PRGHUDWH DOOUHGVSRWVH[FHSW
EOXLVKZKLWH RQHZHUHFRPSRVLWH
3 %HDG PPLQ <HOORZZLWKUHGVSRW +LJKO\ZD[\ <LQHUW <LQHUW 1DWXUDO
GLDPHWHU ERWKSDWFK\ 7UDQVOXFHQW 5ZHDN²PRGHUDWH 5LQHUWWRYHU\
EOXLVKZKLWH ZHDN
4 &DUYLQJ ïï 2UDQJH\\HOORZDQG :D[\ - <LQHUW <LQHUW 1DWXUDO
PP SDWFK\UHGZLWKVRPH 7UDQVOXFHQWWR 5PRGHUDWHEOXLVK 5ZHDN
JWRWDO GDUNEURZQVWUHDNV RSDTXH ZKLWH
5 6DZQ ïPP 2UDQJH\\HOORZ 'XOOZD[\ - - <ZKLWLVK <LQHUW 1DWXUDO
IUDJPHQW J ZLWKYLYLGUHGHQGV 7UDQVOXFHQWWR 5PRGHUDWHEOXLVK 5ZHDNEOXLVK
RSDTXH ZKLWH ZKLWH
6 5DZPDWHULDO aïPP <HOORZDQG :D[\ - - <LQHUW <LQHUW 1DWXUDO
JWRWDO SDWFK\UHG 2SDTXH 5PRGHUDWHEOXLVK 5ZHDN
ZKLWH
%UDFHOHW PPLQ 2UDQJH\\HOORZ :D[\ <LQHUWWRYHU\ <LQHUWWRYHU\ 2QO\RQHEHDGZDV
EHDGV GLDPHWHUDYJ SDWFK\DQGYLYLGUHG 7UDQVOXFHQWWR ZHDNEOXLVK ZHDN QDWXUDORWKHUVZHUH
PRVWO\HYHQ RSDTXH 5LQHUWWRZHDN 5LQHUW LPLWDWLRQV
EOXLVKZKLWH
%UDFHOHW PPLQ 3DWFK\\HOORZDQGGDUN :D[\ <LQHUWWRVWURQJ <LQHUW ZHUHQDWXUDO
EHDGV GLDPHWHUDYJ EURZQLVKUHG 7UDQVOXFHQWWR ZKLWLVK 5ZHDNEOXLVK DQGWKUHHZHUH
RSDTXH 5LQHUWWR FRPSRVLWHV
PRGHUDWHEOXLVK
a
Abbreviations: Y = yellow and R = red part of sample.
b
Lower values (1.48–1.49) correspond to polymer resin imitations.
1 2 3
4 5 6
Figure 2: Eight samples were examined for this study: (1) a hand-carved pendant with a Buddha motif that is mostly orangey
yellow with a red portion framing the upper part of the head, and a red dot added to the forehead (50×30 mm); (2) a beaded
bracelet showing bright red patches (each bead is ~20 mm in diameter); (3) a single loose bead (12 mm in diameter); (4)
a hand-carved art piece made from a beak and associated casque which has been polished so the red layer is very thin,
producing a paler red colour (115×35 mm); (5) a sawn fragment with red patches at both ends (35×8 mm); (6) the beak,
casque and part of the skull of a hornbill (~200×125 mm); (7) a beaded bracelet with most pieces showing even yellow and
red coloration (average 16 mm in diameter); (8) a beaded bracelet displaying colour patches that are mostly brownish and
GDUNUHGDYHUDJHPPLQGLDPHWHU6HH7DEOHIRUWKHLGHQWLÀFDWLRQRIHDFKVDPSOHDVQDWXUDOLPLWDWLRQRUFRPSRVLWH
Photos by Jie Liang.
patches commonly ranged from light pinkish red, which was more easily observed in the unpolished
dull red and brownish red to vivid red, and in some raw material and/or larger carved pieces with red
samples they were very dark brownish red (nearly areas preserved. In the beads, the layered structure
brown-black). The best colours after polishing was not always observed in the red portion.
were bright orangey yellow with vivid red. The However, the boundary between the red and
coloration of the resin imitations was quite similar yellow areas may show dark brown striations (e.g.
(typically orangey yellow and vivid red), but more Figure 5, left). In addition, there were commonly
even. small cracks oriented almost perpendicular to
The genuine hornbill ivory samples displayed a these dark brown striations. By contrast, the resin
waxy lustre, and were translucent to nearly opaque. imitation did not show any layered structures,
By comparison, most of the resin imitations had brown striations or small cracks.
a highly waxy to vitreous lustre and were mostly
translucent. Microscopic Characteristics
Important differences were seen in the Observed with the microscope using low
structural features of the hornbill ivory and magnification, the colour boundary in the hornbill
the resin imitations. The yellow portion of the ivory appeared vague. At higher magnification,
hornbill ivory was layered (Figure 3), resembling the more translucent samples showed pigmented
the growth structure of shells. The layers were of spots along the boundary between the two colours
variable thickness and were marked by differences (Figure 5). These tiny dots were yellow in the yellow
in transparency and saturation of the yellow colour. region and red or brownish red in the red part (or
The layers were not always perfectly parallel; some dark brown in the brown coloured patches).
were wavy and others displayed intersections at The imitation hornbill ivory showed a sharp
various angles. The red portions of the hornbill colour boundary in the full-resin beads, and only
ivory also displayed layered growth (e.g. Figure 4), a somewhat sharp boundary in the hornbill-resin
Figure 3 (top left): A layered structure is apparent in this bead of hornbill ivory
VDPSOHQRPPLQGLDPHWHU3KRWRPLFURJUDSKE\-LH/LDQJPDJQLÀHGï
Figure 4 (bottom left): The layered structure of hornbill ivory is obvious in unpol-
ished sample no. 6 (125 mm tall). The red colour forms a thin layer over the yellow
core. Photo by Jie Liang.
Figure 5 (below): On the left, a hornbill ivory bead from sample no. 8 shows tiny
yellow-pigmented dots, which are easiest to observe along the colour boundary;
note also the underlying brown striations in this area. On the right is a composite
bead from sample no. 2, which displays a sharp curved boundary between the
hornbill ivory (top) and the resin (bottom). Air bubbles in the resin create a sponge-
like structure, while tiny red- and yellow-pigmented dots are visible in the hornbill
LYRU\3KRWRPLFURJUDSKVE\-LH/LDQJPDJQLÀHGïOHIWDQGïULJKW
Figure 6: This imitation hornbill ivory Figure 7: These beads from sample no. 8 (16 mm in diameter) proved to be com-
bead from a bracelet (sample no. 7; 16 posites of hornbill ivory (orangey yellow) and resin (red). Both show the boundary
mm in diameter), shows a sharp and ZLWKWKHUHVLQDVDGLVWLQFWOLQHLQUHÁHFWHGOLJKW,QWKHOHIWSKRWRDVPDOODPRXQW
regular colour boundary. It appears that of red hornbill ivory was retained, with resin added on top of it; note the higher
the red portion was set into the yellow lustre in the resin. The sample on the right shows distinct polishing lines on both
area and then the sample was fashioned the hornbill and resin portions, and the boundary is clear. Photomicrographs by
into a bead. Photo by Jie Liang. Jie Liang.
composites (Figures 6 and 7). In both of those 3300–2860 cm–1 and 1750–1200 cm–1, with the
products, a distinct line could be seen with reflected strongest absorption at ~1650 cm–1 (Figure 10,
light on the beads’ surface, which corresponded top). The imitations showed a series of absorption
to the boundary between the two coloured areas. bands that were different from the natural
Careful observation of the resin with transmitted material, with the strongest at 1730 cm–1 (Figure
lighting showed a grainy sponge-like structure due 10, bottom). Spectra from the imitations were
to the presence of numerous minute air bubbles, as consistent with polymer resin (Wang et al., 1990).
well as larger and more distinct bubbles (Figure 8).
These features provide proof of artificial origin.
,GHQWLÀFDWLRQ)HDWXUHV
Other Gemmological Properties Identification criteria are summarized in Table II.
RI readings taken from the hornbill ivory were All of the imitations examined in this study had a
significantly higher (1.51–1.54) than those red colour patch. Material showing such coloration
measured from the resin (1.48–1.49; Table I). In should be carefully screened. In natural hornbill
addition, most hornbill ivory samples showed ivory, the red area (if present) is restricted to a thin
some areas of whitish blue to bluish white UV outer layer surrounding the orangey yellow core.
fluorescence (stronger to long-wave [Figure 9] The amount and distribution of any red patches
than short-wave UV), while the resin was inert. in carved or otherwise polished samples should
be consistent with this distribution in the raw
Infrared Spectroscopy material. In addition, red patches that are deeply
Both the yellow and red parts of the hornbill ivory coloured or show an even vivid red colour should
samples showed the same absorption bands, at arouse suspicion.
imitation (bottom).
1542
1455
$EVRUEDQFH
1241
1443
:DYHQXPEHUFP²)
Table II: Gemmological properties of natural hornbill ivory, its resin imitation and composite material.
FTIR spectroscopy. Other tests, such as RI and Zhang Beili 2006. Systematic Gemmology, 2nd edn.
UV fluorescence observations, provide additional Geological Publishing House, Beijing, China, 554–
distinguishing criteria but not conclusive 558 (in Chinese).
identification.
References
Brown G. and Moule A.J., 1982. Hornbill ivory. Journal of
Gemmology, 18(1), 8–9.
Espinoza E.O. and Mann M.J., 1991. Identification The Authors
Guide for Ivory and Ivory Substitutes. 38 pp., Liang Jie*, Li Haibo, Dr Lu Taijin, Zhang Jun,
http.//www.cites.org/sites/default/files/eng/ Shen Meidong and Zhou Jun
resources/pub/E-Ivory-guide.pdf. 1DWLRQDO*HPVWRQH7HVWLQJ&HQWHU)
Hurwit K., 1997. Lab Notes: Hornbill “ivory”. Gems &
%XLOGLQJ&*OREDO7UDGH&HQWHU1RUWK
Gemology, 33(1), 57–58.
International Union for Conservation of 5LQJ(DVW5G%HLMLQJ&KLQD
Nature, 2012. Rhinoplax vigil. IUCN Red
(PDLOOLDQJMLHJHP#JPDLOFRP
List of Threatened Species, Version 2013.2,
www.iucnredlist.org/details/22682464/0. Acknowledgements
Kane R.E., 1981. Hornbill ivory. Gems & Gemology, 17(2),
96–97. 7KHDXWKRUVDUHJUDWHIXOWR3URI4L/LMLDQ
Zheng Zhenduo, 1947. Si Yi Guang Ji. Republished IRUVKDULQJKLVNQRZOHGJHDQGIRUVXSSO\LQJ
manuscript written by Shen Maoshang during the VDPSOHV:HDOVRWKDQNDOOWKHFROOHFWRUVZKR
Ming Dynasty. National Central Library, Taiwan (in ORDQHGWKHVDPSOHVIRUWKLVVWXG\HVSHFLDOO\
Chinese).
+XDQJ:HQSLQJ:HL+XD=KDQJ%LQDQG
Wang Zongming, He Xinxiang and Sun Dianqing, 1990.
Practical Infrared Spectra, 2nd edn. Petroleum Industry =KDQJ-XQ
Press, Beijing, China, 208–228.
Introduction
Most imaging techniques in gemmology have been
developed to analyse the properties of a gemstone
(or pearl) itself and to examine its inclusions.
However, little research has been done on detecting
the presence of gems inside their host rock. Some
gems mined from primary deposits—such as
marble-hosted ruby (e.g. Figure 1), schist-type
emerald and others—may not be directly visible
without crushing or sawing the rock in which they
formed, which could lead to breakage or damage
of valuable gem material.
This study investigates whether X-ray
computed tomography (CT) can be used to
reveal the presence of a gem within its host rock,
using instrumentation developed for medical
applications. CT is a non-destructive technique that
visualizes the internal structure of objects, and is
dependent on variations in the density and atomic )LJXUH0DUEOHKRVWHGUXELHVVXFKDVWKLVÀQHFU\VWDOIURP
Jegdalek, Afghanistan, need to be exposed from their host
composition of the material. Besides a wide range
rock before they can be evaluated for gem rough or used as
of applications in medical science, the use of CT mineral specimens. The piece shown here measures
has also been explored in geology, such as imaging 3 cm across and is courtesy of Jim and Gail Spann; photo
the interior of fossils or meteorites, examining by Thomas Spann.
Methods
This study utilized a piece of white granular marble
measuring approximately 75×50×40 mm that
showed some small ruby fragments on the surface
(Figure 4). We wondered if the marble contained
more ruby crystals inside.
The sample was initially investigated with a
Figure 4: The ruby-bearing marble specimen used in this 10× loupe, a microscope and a spectroscope. To
study measured approximately 75×50×40 mm. Photo by get information about the internal structure, we
A. Bouts. then used a Philips Brilliance CT 64-slice scanner
(typical for medical investigations). The marble
a fragment was placed in the CT scanner, together
with a faceted synthetic ruby and a natural ruby
crystal to compare and calibrate the imaging
results. In addition, pieces of feldspar, quartz,
fluorite, topaz, beryl and amber were tested with
the CT scanner, to use as separation values for
various other gem materials.
Three scan series were performed with different
settings as follows: (1) 120 kV voltage and 199 mAs
(milliampere seconds), (2) 80 kV and 400 mAs,
(3) 140 kV and 197 mAs. The voltage determines
the beam quality or the ability of the beam to
penetrate the object. The mAs value controls the
beam intensity or the number of X-ray photons
b
in the beam. The thicker the object, the more
absorption of X-rays occurs, requiring higher mAs
values. CT slices of the sample were generated at
1 mm intervals.
Results
The surface of the specimen showed a pink-red
opaque crystal of 7×3 mm with a dull vitreous lustre.
In addition, three other pink-red crystals of smaller
size and one brown-black crystal were present on
the surface of the stone. The pink-red crystals were
Figure 5: (a) This CT scan shows a slice through the marble
semi-translucent and had no discernible crystal
specimen, underneath the exposed ruby crystal at the top
of the piece showing a mean HU value of +2879. (b) A slice
habit. Parallel striations were present on the faces
through the centre of the sample revealed a crystal with a of the largest crystal, and the absorption spectrum
mean HU value of +2812, which proved to be a ruby. in general was typical for ruby.
References
To confirm the CT results, the marble specimen Baruchel J., Buffiere J.-Y. and Maire E., 2000. X-ray
was then cut open, revealing a ruby crystal in the Tomography in Material Science. Hermes Science, Paris,
expected position inside the host rock (Figure 6). France, 204 pp.
The ruby crystal was also the size predicted by the Bellin M.F., Renard-Penna R., Conort P., Bissery A.,
CT scanning. Meric J.B., Daudon M., Mallet A., Richard F. and
Grenier P., 2004. Helical CT evaluation of the
chemical composition of urinary tract calculi with a
discriminant analysis of CT-attenuation values and
Discussion and Conclusion density. European Radiology, 14(11), 2134–2140.
This study indicates that computed tomography Cnudde V., Masschaele B., Dierick M., Vlassenbroeck
can be used to identify the presence of a ruby J., van Hoorebeke L. and Jacobs P., 2006. Recent
within its marble host rock. Whether CT can be progress in X-ray CT as a geosciences tool. Applied
Geochemistry, 12, 826–832.
used to detect other gem materials inside their
Cnudde V. and Boone M.N., 2013. High-resolution X-ray
host rocks needs to be analysed: this depends on computed tomography in geosciences: A review of
the difference in HU between the gem material the current technology and applications. Earth-Science
and the surrounding material. Reviews, 123, 1–17.
Kalender W.A., 2000. Computertomographie—Grundlagen, Wehrmeister U., Goetz H., Jacob D.E., Soldati A., Xu W.,
Gerätetechnologie, Bildqualität, Anwendungen. Publicis Duschner H. and Hofmeister W., 2008. Visualization
Corporate Publishing, Erlangen, Germany, 180 pp. of the internal structures of cultured pearls by
Karampelas S., Michel J., Zengh-Cui M., Schwarz J.-O., computerized X-ray microtomography. Journal of
Enzmann F., Fritsch E., Leu L. and Krzemnicki M.S., Gemmology, 31(1/2), 15–21.
2010. X-ray computed microtomography applied to
pearls: Methodology, advantages, and limitations.
Gems & Gemology, 46(2), 122–127.
Ketcham R.A. and Carlson W.D., 2001. Acquisition,
optimization and interpretation of X-ray computed
tomographic imagery: Applications to the geosciences.
Computers & Geosciences, 27(4), 381–400.
Krzemnicki M.S., Friess S.D., Chalus P., Hänni The Author
H.A. and Karampelas S., 2010. X-ray computed Dr Antonia Bouts
microtomography: Distinguishing natural pearls from Antonia Bouts MD PhD FGA is a paediatric
beaded and non-beaded cultured pearls. Gems &
Gemology, 46(2), 128–134. nephrologist in the Emma Children’s Hospital,
Landis E.N. and Keane D.T., 2010. X-ray micro- Academic Medical Center, Amsterdam, The
tomography. Materials Characterization, 61, 1305– Netherlands. She is a member of the Dutch
1316. Association of Professional Gemmologists
Mees F., Swennen R., Van Geet M. and Jacobs P., 2003. (NVVE). Email: a.h.bouts@amc.nl.
Applications of X-ray Computed Tomography in the
Geosciences. In F. Mees et al., Eds., Applications of
X-ray Computed Tomography in the Geosciences. Geological Acknowledgements
Society Special Publication, London, 215, 1–6. The author thanks her teacher, Peter
Patel S.R., Haleblian G., Zabbo A. and Pareek G., *URHQHQERRP IRU SURYLGLQJ WKH VDPSOHV
2009. Hounsfield units on computed tomography used in this study, and for stimulating me in
predict calcium stone subtype composition. Urology
WKHÀHOGRIJHPPRORJ\7KDQNVDUHDOVRJLYHQ
International, 83(2), 175–180.
Prokop M., Galanski, M., van der Molen A.J. and to Roel Jansen and Martin Poulus (radiology
Schaefer-Prokop C., 2003. Spiral and Multislice Computed technologists) and Anne Smets (paediatric
Tomography of the Body. Georg Thieme Verlag, Stuttgart, UDGLRORJLVWIRUDVVLVWLQJZLWKWKH&7DQDO\VLV
Germany, 1,104 pp.
This author was invited by goal was to produce a unique mineralogical and gemmological
gem dealer Federico Barlocher film documentary for television variety of Mogok.
(Lugano, Switzerland), who has containing unseen footage of We travelled in a four-wheel-
over 30 years of gem-trading mining for rubies and other drive minibus from Mandalay,
experience in East Asia, and gems in Mogok. via the historic route through
especially in Myanmar, on a trip to For reference during Thabeikkyin, and then to
Mogok. This area was re-opened the trip, the author brought Mogok. The trip took about
to foreigners in July 2013 (after the book Gems and Mines seven hours on a good paved
being closed for approximately of Mogok (Themelis, 2008), road. On the way we passed
10 years), although access to which was of fundamental through Latpanhla village,
Mogok still requires special visa importance for understanding which is known for tourmaline-
permission from the Burmese the relations between the bearing pegmatites. However,
government. Accompanying us local geomorphology and the mining activities were stopped
were videographer Bryan geology and distribution of the at least three years ago by
Swoboda (BlueCap Productions, gem mines. The book was also the government. Most of the
Honolulu, Hawaii, USA), former helpful for learning about the tourmaline was recovered in
mineral collector and dealer history of Mogok mining and 2006–2008. The area produced
Dave Wilber (Tucson, Arizona, the nature and quality of the several tens of kilograms of
USA), and mineral specimen gem material from each mine. vivid pink gem tourmaline of
miner and speleologist Marco Also, Atichat and Hughes (2013) faceting and carving quality, and
Lorenzoni (Lucca, Italy). The trip provide a useful introduction also crystals in pegmatite matrix,
took place from 28 November to to the geologic processes that were sold in markets in
10 December, and Barlocher’s responsible for the exceptional Mandalay and Yangon.
Excursions 55
Excursions
D E F
G H
(A) A complex network of timbers, scaffolding and cables is seen here at Kodoke-tat, at about 200 m depth. (B) Local miners
pause at the 380 m level of Kodoke-tat. (C) Winches are perched on top of marble outcrops at Kodoke-tat. (D) This old mining
operation at Dattaw is being reopened. (E) A miner looks for rubies in a tunnel at Dattaw. (F) Large piles of tailings mark the
location of peridot mines at Pyaunggaung. (G) A miner makes explosive charges at Pyaunggaung. (H) A wooden chute is used
to remove mined material from the shaft at a peridot mine in Pyaunggaung. Photos by M. Lorenzoni (A, B, E, G and H) and
F. Pezotta (C, D and F).
Excursions 57
Excursions
ruby-bearing layer. The deposit saw complex systems of ropes miners at Kodoke-tat, in both
has been mined in an enormous and winches that were used the trench and underground
trench excavated along the near- to bring the excavated marble workings, was around 6,000 at
vertical ruby-mineralized band. to the surface, where it was the time of our visit. At least as
The trench is interrupted by routed to crushing and washing many people were working at
wooden barriers representing machines. The rubies were the surface, making this one of
the limits of the mining claims hand-picked from the washed the largest mining operations in
assigned to different companies. and crushed marble. The marble the world for a primary coloured
Down-dip below the trench tailings were then dumped into a gemstone deposit.
are subvertical interconnected publically accessible area where
galleries that have been excavated local people (mostly women Dattaw: This mining area is
to a depth exceeding 400 m. The and children) tried their luck in located north-west of Mogok.
workings are supported by a few finding small fragments of ruby. Dattaw hill is composed of
rock pillars and by thousands of A single mine at Kodoke- exceptionally coarse-grained cal-
timbers. Wooden ladders with tat can have around 200–300 cite marble that contains several
small landings are attached to miners, with two groups of ruby-bearing bands. Tunnels
the marble walls to allow access workers allowing 24 hours of have been driven along these
to the bottom of the mine. We activity. The total number of bands, and also follow residual
A B
C D E
(A) A peridot miner rests next to buckets containing powdered rock and rolls of explosives. (B) This pendant containing a large
faceted peridot gemstone was seen in Mogok. (C) Miners excavate gem-bearing soil at Pyant-Gyi, a source of high-quality red
spinel. (D) Women search for gems at Pyant-Gyi. (E) Residual deposits are mined from weathered karst in this open pit at Htin-
Shu-Myaing. Photos by M. Lorenzoni (A–D) and F. Pezzotta (E).
D E
F G
(A) Miners operate a small washing plant at Htin-Shu-Myaing. (B) At the end of the day, gems are hand-picked from the jig at
Bernardmyo. (C) This view from a helicopter shows a portion of the Mogok valley. (D) The Kodoke-tat mine is visible on the left
skyline in this aerial photo. (E) A merchant examines rough rubies in the Mogok market. (F) These spinel crystals were pre-
sented at the home of a local dealer. (G) A woman examines a rough blue gem in the busy Mogok gem market. Photos by
F. Pezzotta (A), F. Barlocher (B and D) and M. Lorenzoni (C, E and F).
Excursions 59
Excursions
This author visited the Mogok a hillside above Ball Lone Gyi
Many karst outcrops in the Mogok
area with Henry Ho (Jewelry Trade village. A portion of the village area are topped with a golden
Center and Asian Institute of actually had to be moved so that stupa. This one (~1 m tall) is
Gemological Sciences, Bangkok, mining could take place. Piles located near Pyaunggaung.
Thailand) and two of his associates, of crushed marble from the
Ho Yu Low and Win Aung. We mine were evident throughout
flew from Bangkok to Mandalay, the village, where the material
where we met with ‘Jordan’ Aung had been processed for gems.
Naing, a Mogok miner who was It was not difficult to find well-
our guide. We then drove to the recrystallized greyish blue calcite
Mogok area, an approximately specimens with a bright red ruby
six-hour trip, with about four of spot. The primary deposit was
those spent on very windy roads. being worked by mechanized
From 10–15 December we equipment, but the most visible
visited mines and the two local activity was a crowd of locals
markets: the morning ‘crystal’ looking through the crushed
market and the afternoon gem rock. They used metal blades (as
market. seen almost everywhere in the
We were told that about 100 Mogok area) to sort through the
‘billionaires’ live in the Mogok centimetre-size pieces of marble
valley. This may explain why in search of ruby and other gems.
you can find excellent bottles We purchased on-site a large
of Bordeaux wine for sale (e.g. number of small ruby crystals
Pauillac vintage 2002 for about of excellent colour. The euhedral
US$45), but there is no heating crystals were mostly bipyramids
available in the hotel rooms! up to 1 cm in their longest
With an estimated 1,200–1,500 dimension, with an almost
gem mines, and innumerable prismatic appearance. A smaller
shrines, the Mogok area exhibits number of blue sapphires were
something seen nowhere else in offered. Although they were
the world: wherever you turn, larger sized (up to ~3 cm), they
you see either a mine or a stupa were generally translucent at best.
(Buddhist shrine). Polished surfaces of these crystals
showed typical pseudohexagonal
Ball Lone Gyi: Located growth patterns highlighted by
approximately 10 km west of whitish silk. Also available was
Mogok, this ruby deposit is zircon, although small and of
marked by a large white scar on greyish colour. Unidentified green
and black crystals were shown to
* All photos by the author. us as well.
Excursions 61
Excursions
A B
Yadana Shin: Located on top to four workers who sorted into a large jig. The concentrate
of a hill, this highly mechanized through it with metal blades. was then sorted further by hand.
operation was active both The tailings were then deposited The mud leaving the jig was
underground (in a small shaft) down the hill in a spectacular panned outside the limits of
and on the surface (in an open stream of muddy debris, where the mine by many locals, who
pit). As we often saw in the they were processed further by commonly find small red spinel
Mogok region, the excavators small groups of local people. octahedra.
were large, numerous, of top The mine mainly produces
brand and appeared quite new. Shunt Pann (Shon-Ban-Lay) rubies ranging from light red
This gives an indication of Mine: At this large open- to purple- red, some several
the financial backing behind pit mine owned by ‘James’ centimetres in size. We also
such ventures. The treatment Bhone Myint Aung, the miners observed large non-gem
plant was most impressive. The extract gem gravel, or byon, spinel octahedra, tabular black
mined material was first routed from the bottom of ancient tourmaline, brown zircon,
through a large screen (mesh size underground river and cave light blue apatite, and quartz
~10 cm) and then passed into deposits in the weathered karst. and feldspar. Some of the
a concrete holding area where The marble landscape exhibits transparent quartz crystals had
four people used water jets to typical karst relief, with subsurface translucent central cores filled
wash everything into a large depressions that have captured with tiny whitish fibres.
triple jig. The concentrate was and accumulated accessory
poured onto a conveyer belt and minerals—including gems— Dragon Ruby Mine: We were
hand-picked for ruby, red spinel, concentrated by erosion. told that we were among the
moonstone and other gems. The The byon was excavated, first foreigners to visit this
oversize and rejected material stockpiled and then processed famous mine, where a 128 ct
was passed through a crusher, with hydraulic washing. The piece of ruby was discovered in
washed, and then delivered resulting slurry was pumped August 2013. The mine extends
Excursions 63
Excursions
A B
A B
C D
(A) At the Dragon Ruby mine, buckets made from recycled tyres are stacked on boulders of marble awaiting processing.
(B) After the mined material is crushed and washed at the Dragon Ruby mine, it is passed into these two sorting lines. Note the
‘Safety First’ sign, absent from most mines of the area. (C) Local people look for peridot and other gems in mine tailings near
Pyaunggaung. (D) This man collected a handful of peridot crystals from the mine tailings.
over 100 m underground via (U Tint Aung), and the mine’s marble with lapis-lazuli, which
three sequential vertical shafts. office contains a display of all deserves special mention, as
The ruby-bearing marble layer the rocks found there, properly magnificent pieces of lapis
dips at about 45° and is up to labelled. This display itself have been unearthed in this
2 m thick. The marble is brought showed the diversity of Mogok’s area (and are quite unexpected
to the surface for crushing and geology: next to ruby)
hand sorting, and that morning a multiplicity of white marble garnet-biotite gneiss
we saw only half a dozen rubies, varieties (not as coarsely skarn (i.e. formed by the
a few millimetres in size, come recrystallized as the ‘blue’ reaction between granite and
from the ore. marble that hosts the ruby marble)
Compared to other mines mineralization) that locally black phlogopitite (more
we visited in the Mogok area, contain spinel, graphite, familiar at an emerald deposit
this one seemed to be operated phlogopite and sometimes than next to a ruby mine)
with the most sophistication. dark brown titanite (up to Also found in the mine area
They employ a mine geologist 3 cm) or dark green diopside are huge colourless scapolite
Excursions 65
Excursions
crystals, with one over 10 cm up to 1 cm in size within small tables and wait for dealers to
across that was on display. Some talc-lined ‘pockets’. We were also offer gems. We were presented
broken scapolite pieces showed shown a large piece of brown mostly ruby, sapphire and
an attractive, fairly dark pink transparent rough material, up spinel, but also some peridot
colour, but were not gemmy. to 20 cm long, that was probably and zircon. We also saw a fine
an amphibole. In the tailings yellow star sapphire, which is
Peridot Deposits: In the we observed pieces of what not a common sight anywhere.
Pyaunggaung area, next to the they called agate, but they were Attractive large crystals, mostly
main peridot mine (Panlin- actually veins of common opal. corundum, were also offered for
Pyaunggaung F7/8) are several sale. However the prices seemed
small ones consisting of a single Local Markets: Almost every well above market value. Food
shaft or small incline. There afternoon around 3:00, the was often offered on the various
was little activity at these small Mogok gem market opens. Upon tables, a pleasant testimony to
mines, with no significant finds arriving, we were impressed by the Burmese hospitality toward
in over a year. We visited locals the perfect, almost crystalline foreigners and potential cust-
working the tailings of the small organization of the numerous omers. This author’s favourites
mines, and they were finding motorbikes. Inside, under large were Mogok fried chicken,
well-formed crystals of peridot umbrellas, customers sit at clementine oranges and papayas.
A B
Another attraction was the identity, leading to animated Mogok gem tract. This explains
so-called ‘crystal market’, which discussions (provided one speaks why, despite the religious con-
takes place early in the morning. Burmese). We saw little evidence straints on mining in this area,
On both sides of the street, gem- of any imitations or synthetics. local people sometimes dig at
selling women (recognizable night in search of treasure. A
by their straw hats or woolly Other Attractions: Just above few hundred metres down the
bonnets) offered small treasures town, in a beautiful, luxuriant road, just outside the limit of
on brass plates or simply laid out setting, is the former home of the sacred ground, we saw three
on white bed sheets. They had famed gemmologist A.C.D. locals removing byon from the
everything from river pebbles to Pain. This wooden structure weathered karst and washing it
modest faceted gems. Ruby and has been abandoned for years with water.
sapphire of lower quality were but was in the process of being Although the Mogok area
quite common, as was red spinel. restored, with the goal of has been mined for centuries,
Some of the parcels looked like turning this historical building numerous holes are opened
little more than gravel. Feldspar into a gem museum. every week in search of rich
rough was cheap, as were local One of the most spectacular gem gravel still hidden in the
black tektites, some reaching well monuments in the Mogok area thousands of cubic kilometres
over 20 cm. Fine hackmanite and is the Kyauk Pyat That temple, of unexplored weathered karst.
deep violetish blue lapis could be perched on a weathered black
found as well. There was a variety karst outcrop. From the top of Dr Emmanuel Fritsch is professor
of unusual rocks and ornamental the temple (accessible only to of physics at the University
stones (e.g. cabochons consisting men) there is a wonderful view of Nantes and Institut des
of graphic intergrowths of above the village of two old mines Matériaux Jean Rouxel (IMN)–
feldspar and quartz mined from in which painite was found. It is CNRS, Team 6502, France.
local pegmatite). For the more said that the sacred ground just Email: Emmanuel.Fritsch@
bizarre samples, the sellers around the temple hides some cnrs-imn.fr
were not always certain of their of the best blue sapphires of the
Crowning a karst outcrop, the Kyauk Pyat That temple offers a view of nearby painite occurrences,
and reportedly hosts a blue sapphire deposit on its sacred ground.
Excursions 67
Get closer to the source and venture to
Idar-Oberstein
GEMMODUL®
MODUL 5 MODUL 6
Spectroscope and Modules combined into a GemLab at 2 1/2 feet UV LW/SW unit
Coldlight Base
The Journal of Gemmology has published many ground-breaking and thought-provoking articles over
the years. We thought it would be interesting to reprint some of the best which show us what gemmology
was like yesteryear and how in some cases it has barely changed. This article demonstrates the
historical importance of visualizing pearl structures to help determine their natural vs. cultured origin.
A comparison between the X-radiographs in this article and those shown, for example, in the Gem
Notes section of this issue (pp. 13–15) clearly illustrates the advancements in technology for imaging
pearls, and the need for a highly trained gemmologist to interpret such images.
frame will be readily revealed by the density of illustrated by the radiograph of part of a human
shadow given by the bones, containing the atoms hand. Fig. 1.
of calcium (atomic weight 40) and phosphorus The radiography of pearls is based upon the same
(atomic weight 30), as against that of the flesh principle of differential X-ray transparency, but
which is made up of the light atoms, carbon, owing to the very fine structures usually involved,
nitrogen, oxygen and hydrogen (with atomic special techniques are necessary. Gemmologists
weights of 12, 14, 16, and 1 respectively). This is know that a genuine pearl consists of a mineral
part, calcium carbonate (CaCO3 ), usually in the
form of pseudo-hexagonal twinned crystallites of
* Reprinted from The Journal of Gemmology, Vol. 4, No. 8, aragonite arranged in concentric layers with their
October 1954, 325–334. vertical axes radial to the centre, cemented with an
Fig. 5. Button-
shaped cultured
pearls with oval-
shaped nuclei.
Radiograph
by Robert
Crowningshield
of New York.
Fig. 7. The two cultured pearls with light coloured centres
were found to have nuclei made of steatite (soapstone).
Conferences
IGE 2014 International Gemmological Congress and 16th FEEG Symposium
On 17–19 January, in Madrid, Spain, the IGE Vol. 33, No. 7–8, 2013). Dr Pilar Diago Diago
2014 Congress was organized by the Spanish (Zaragoza University, Spain) provided an
Gemmological Institute (Instituto Gemológico overview of the problem of ‘conflict diamonds’
Español or IGE), and held together with the in international trade, with a general explanation
annual Symposium and Diploma Ceremony of the Kimberley Process and related international
of the Federation for European Education in and European laws. Igor Klepikov (St. Petersburg
Gemmology (FEEG). More than 200 attendees State University, Russia) and co-authors presented
from 16 countries took part in the event. Sixteen a detailed spectroscopic study of diamonds from
oral and four poster presentations were given, alluvial deposits of the north-eastern Siberian
and nine workshops and demonstrations were platform. Optical absorption, infrared, PL and
held, covering a wide range of topics related to electronic paramagnetic resonance spectroscopy
modern gemmology. All materials from the event, were used to characterize nitrogen aggregates
including extended abstracts of the presentations, and crystal structure defects in 120 diamonds.
can be downloaded at www.ige.org/congress2014. The micromorphology of diamond crystals from
Diamonds were covered in various the north-eastern Siberian platform was reported
presentations. Juan Cózar (IGE Gem Testing by Nadezhda Erysheva (St. Petersburg State
Lab, Madrid) and co-authors explained the use of University, Russia), who found a direct relationship
a combination of advanced techniques—Raman between microrelief features and crystal habit.
and photoluminescence (PL) spectroscopy and the G.F. Anastasenko (St. Petersburg State University,
DiamondView—for the detection of colourless Russia) and co-authors studied the morphological
HPHT- and CVD-grown synthetic diamonds and characteristics of alluvial diamonds from the
HPHT-treated colourless diamonds. A comparison north-eastern Siberian Platform by scanning
of PL spectra recorded at room temperature and electron microscopy. The crystals were dominated
at –180ºC confirmed the necessity of cryogenic by octahedral, dodecahedral and combined forms,
testing when performing PL spectroscopy. In with flat- and curve-sided shapes. Anastasenko
another presentation, Cózar (with Anthony and co-authors also described a diamond collection
Cáceres) provided colour grading data for in the mineralogical museum of St. Petersburg
hundreds of diamonds examined in his lab using State University consisting of more than 1,000
a Sarin Colibri colorimeter, and compared these rough samples. The collection started in 1875 with
results to traditional visual grading with diamond the acquisition of diamonds first from Brazilian
master stones. The Colibri instrument showed deposits and then from South Africa. After the
variations of up to four colour grades from discovery of diamonds in Yakutia (Siberia) in
visual grading, especially in diamonds with non- 1954, the museum obtained a large number from
typical colours. Geoffrey Dominy (Gemmologist both primary and secondary deposits.
FGA with Distinction, Canada) focused on the Among coloured stone presentations,
importance of the cut grade in diamond valuation, Miguel Ángel Pellicer García and Dr Cinta
including the role of the cutter, the importance of Osácar Soriano (Zaragoza University, Spain)
yield, and how shape, clarity, colour, cut, optical discussed the challenges of the geographic origin
phenomena and market considerations affect the determination of coloured stones (Figure 1),
overall value of a faceted diamond. (In a separate with some examples from published studies on
presentation, he also presented his new book titled emerald, ruby, sapphire and garnet. The authors
The Handbook of Gemmology, which was reviewed emphasized the importance of using comparison
on pages 252–253 of The Journal of Gemmology, samples of known origin in such studies, and
Conferences 73
Conferences
also the necessity of establishing the range of may help differentiate amber from other natural
property variations within each deposit. Dr and synthetic resins.
Klaus Schollenbruch (DGemG, Idar Oberstein, Three presentations covered evolving
Germany) summarized glass filling treatments for technology. Helena Calvo del Castillo
ruby and sapphire, including the processes used, (University of Liège and Belgian Gemmological
diagnostic features and stability issues for the Association, Belgium) presented a review of a
treated stones. José Antonio Espí (Madrid School wide range of advanced spectroscopic techniques
of Mines, Spain) explained the geological setting, used in gemmology, their principles, advantages
formation process and mining of larimar (blue and limitations, as well as examples of their
pectolite) deposits in the Dominican Republic. He use to resolve contemporary problems. Mikko
showed spectacular photos of larimar substituting Åström and Alberto Scarani (M&A Gemological
for ancient fruit and tree trunks. He found greater Instruments, Finland and Italy) described their
amounts of vanadium and copper in larimar GemmoRamanPL-532SG instrument, a scientific
samples with a deeper blue coloration. Espí grade Raman-PL spectrometer for gemmological
also described the origin and geology of amber laboratories. They also explained some applications
deposits in the Dominican Republic. The amber of this instrument beyond standard gem
is hosted by two major geographic domains: the identification, such as identifying jade and spinel
Cordillera Septentrional (or Northern Range, treatments, characterizing emerald, determining
where primary deposition sites occurred in clay- the colour origin of cultured freshwater pearls and
rich host rocks) and Cordillera Oriental (or Eastern coral, discriminating Imperial topaz according to
Range, where remobilization and concentration chromium content and quickly separating type I
of amber occurred in alluvial paleochannels from type II diamonds. Menahem Sevdermish
with an abundance of organic material). Texture and Guy Borenstein (GemeWizard, Ramat
and sometimes colour are related to the specific Gan, Israel) presented the latest developments
conditions of amber formation. Oscar R. of GemeWizard, a digital colour communication
Montoro (Madrid Complutense University, Spain) and analysis system for coloured gemstones and
and co-authors provided evidence of chemical fancy-colour diamonds. The system allows users
processes that occurred during the formation of to describe, grade, price and communicate the
fossil resins, by examining the reactivity of pure colour of gems. A digital colour-based online
communic acids and comparing their FTIR and gem marketplace, GemeShare, is used to perform
Raman spectra to those of fossil resins. The results colour analysis on a vast scale, and a search engine
enables the user to search for a stone of a specific GemeWizard system, by Menahem Sevdermish
colour. and Guy Borenstein, Gemewizard.com
In other presentations, Gonzalo Moreno Díaz- 'HWHFWLRQ RI V\QWKHWLF GLDPRQGV XVLQJ WKH
Calderón (IGE, Madrid) explained the Virtual DiamondView, by Juan Cózar and Anthony
Gemmological Laboratory, an online educational Cáceres, IGE Gem Testing Laboratory
tool from IGE designed for distance learning 2*, 6FDQR[ 3ODQQHU +' D GHYLFH IRU WKH
of gemmology. Students are taught how to use digital analysis of diamond cut quality, by Juan
basic gemmological equipment and even virtually Cózar and Anthony Cáceres, IGE Gem Testing
analyse gems using a polariscope, refractometer, Laboratory
spectroscope, hydrostatic balance and microscope. ,QFOXVLRQ SKRWRPLFURJUDSK\ XVLQJ 0DFUR5DLO
Dr Pilar Diago Diago (Zaragoza University, products and software, by Óscar Fernández
Spain) and Dr Cinta Osácar Soriano provided Arcís, MacroRail.com
an example of cooperative and interdisciplinary $XWRPDWHG ' SKRWRJUDSK\ DSSOLHG WR
education through seminars on the legal aspects of gems and jewellery, by Óscar Fernández Arcís,
gemmology that are attended by students of both MacroRail.com
gemmology and law, as well as professionals from $GYDQFHG PHWKRGV IRU WKH GHVLJQ DQG
the jewellery sector. Viktor Tuzlukov (College of manufacture of new gem cuts: GemCad,
Gem Cutting, Moscow, Russia) provided his vision GemRay and DiamCalc, by Egor Gavrilenko,
of lapidary work as an artistic creation process. He IGE
showed how his designs can evoke symbols in the $QDO\VLVRI MHZHOOHU\DQGSUHFLRXVPHWDOVZLWK
pattern of their facets. X-ray fluorescence, by Joan Pujol, Fischer
The following workshops and demon- Instruments S.A.
strations were held during the Congress:
5DPDQ DQG SKRWROXPLQHVFHQFH VSHFWURVFRS\ The FEEG Diploma Ceremony and the IV
in the gemmological laboratory, by Mikko Antonio Negueruela Jewelry Design Awards
Angstrom and Alberto Scarani, M&A Ceremony took place during the last evening of
Gemological Instruments, GemmoRaman.com the Congress.
*HP5DP5DPDQJHPLGHQWLILFDWLRQV\VWHPE\
Ignacio Sánchez-Ferrer Robles, Microbeam S.A. Egor Gavrilenko (info@ige.org)
'LJLWDO JUDGLQJ DQG SULFLQJ RI FRORXUHG Spanish Gemmological Institute
stones and fancy-colour diamonds with the Madrid, Spain
Conferences 75
Conferences
the only samples that can be reliably ascertained of a yellowish colour that mimics traditional
as natural colour are those mined during the early incandescent lamps.
part of the 20th century (mostly from Brazil) Craig Lynch (Somewhere In The Rainbow
that have been kept in museums since that time. Collection) described the challenges of building
Extremely high residual radioactivity may be a world-class gemstone and modern jewellery
shown by diamonds irradiated by direct contact collection. In addition to the problem of finding
with radium salts, particularly those with residues available pieces due to their rarity, establishing a
that are trapped in open cracks and cavities. By fair price for them can be difficult since there are
contrast, diamonds that have been treated by so few top-end pieces for comparison.
modern irradiation methods (e.g. with electrons) Dr Lore Kiefert (Gübelin Gem Lab, Lucerne,
pose no radiation risk to the end user. Switzerland) documented the mining and
Hainschwang then reviewed luminescence gemmology of sapphires from Mogok, Myanmar.
phenomena in diamond and their importance During a 2013 visit to the mines, she witnessed
in gem testing. The colour and distribution of extensive sapphire mining activity, and she noted
luminescence can be a useful indicator for the that some of the stones recently produced (which
origin of a diamond’s colour, but extensive are of metamorphic origin) may be confused with
experience is needed. Similar luminescence sapphires of basaltic origin.
colours may be caused by a variety of defects, so Shane McClure (Gemological Institute of
photoluminescence spectra are needed to assess and America, Carlsbad, California, USA) examined the
measure defects at extremely low concentrations potential for the co-diffusion of multiple elements
when determining the origin of colour or whether into sapphire. Relatively thick layers (up to 1 mm)
a diamond is natural or synthetic. of diffused blue colour due to Ti and Fe have
Manfred Eickhorst (Eickhorst & Co., Ham- been seen recently in both natural and synthetic
burg, Germany) explored applications of LED sapphires, and the presence of surface-related
lighting in gemmology, including refractometer concentrations of additional elements such as Mg,
stands with built-in strong yellow LEDs, Ga, V and/or Be suggests that they may enhance
polariscopes with LEDs that provide diffuse the diffusion process.
lighting, and microscopes with intense illumination Brendan M. Laurs
of learning the properties of gems, and how a Gary Bowersox (GeoVision Inc., Honolulu,
collection of journals and the Photoatlas books are Hawaii, USA) described his multiple trips over
gemmological tools in themselves. 42 years to Afghanistan for exploring mines,
Tino Hammid (Tino Hammid Photography purchasing gem rough, and helping the local people
Inc., Los Angeles, California, USA) discussed through education and donations. He mentioned
gem photography while showing examples of that access to the Panjshir Valley emerald deposits
spectacular images (e.g. Figure 2) to illustrate is much easier since a new road from Kabul to
several points: (1) lighting defines an object, and Khenj was constructed in 2013. However, reaching
the use of selective and subtle reflections helps the original lapis lazuli mines at Sar-e-Sang in
to convey its shape; (2) shadows provide a sense Badakhshan Province is much more difficult, as
of place, and reflections of the object below the shown in a fascinating film clip that he screened for
stone add reality to the image; and (3) colour the audience.
accuracy is critical, and using a ColorChecker card
and a monitor calibrator are highly recommended. Brendan M. Laurs
Conferences 77
Gem-A Notices
MEMBERSHIP
At a meeting of the Council of the Association held on 5 March 2014, the following were elected to
membership:
Gem-A Notices 79
New Media
The Fundamentals of Mining for Gemstones and Mineral Specimens
Jim Clanin, 2012. New The next couple of chapters cover site
England Historical management and logistics, and there is also
Publications, Boston, a comprehensive first aid section detailing
Massachusetts, USA, the potential injuries associated with mining
402 pages, illus., and their appropriate treatment. This is
hardcover, followed by a section describing the author’s
www.jcmining.com, experience with local customs and etiquette
ISBN 978-0-615-50108-6. in the areas where he has worked. Such
US$49.95. considerations are especially important when
working in remote localities.
A very interesting part of the book is a
This book covers fundamental knowledge for section describing eight case studies showing
small-scale mining, covering aspects of geology, how mining techniques are customized for
mineralogy, mining practices and marketing, as different localities and mineral types. Some
well as the all-important but readily forgotten examples include open-pit mining for emeralds
aspects of local regulations, first aid and safety. in Madagascar, alluvial deposits in Tanzania
Following an introduction to gem mining, the that produce a range of gems, ruby deposits in
author covers several topics from basic geology Kenya and underground mining for fluorite in
to how to map and understand the potential northern England. Each case study reinforces
scope of a gem deposit. He describes the various the fundamentals discussed in the previous
types of mining tools available and the best way sections with real-life scenarios and whether
of investing in them, from hand tools to large the mining ventures were successful.
equipment such as excavators. Also discussed The book has colourful photography and
is the proper way to use explosives so as not to several detailed annotated diagrams. Its only
damage and devalue gem material or specimens, disappointments are the need for editing and
as well as best practices for safely handling and the fragmented nature of the layout on some
storing explosives. Then the main types of pages. Nevertheless, the author has managed
mining are described, detailing the most cost- to share his 35 years of hands-on mining
effective methods of extraction of gem material. experience in a clearly passionate way, and
The author proceeds to explain a number of the book should therefore be inspiring and
different processes for cleaning and preparing educational for any gem or mineral miner.
mineral specimens for sale. Davina Dryland BSc (Hons) FGA
A Geologist Speculates
John M. Saul, 2014. This book’s subtitle, ‘On Gemstones, Origins
Les 3 Colonnes, Paris, of Gas and Oil, Moonlike Impact Scars on
France, 149 pages, illus. the Earth, the Emergence of Animals and
in colour and black-and- Cancer’ is, at first sight, a very disconnected
white, paperback, series of topics. But a revealing comment on
ISBN 978-2-37081-004-5. page 119 indicates the fundamental motivation
€28. of the author in light of a discussion with
Professor Théodore Monod deep in Egypt’s
Western Desert. They explored the twin tasks
of scientists in describing nature in all its
detail and of synthesizing these descriptions in the features of Earth history, which of course is very
search for reasons and understanding. Monod was relevant to gem occurrences. On p. 87 he quotes
a prolific devotee of the former task while Saul Lyell’s ‘…the present is key to the past…’ (1833)
made the case for periodic review and synthesis, and comments on the discussions this generated
and this book is the timely result of one such about uniformitarianism and catastrophism—with
assessment. the ultimate general acceptance of the former. At
Of immediate and absorbing interest for first sight, Saul’s emphasis on the uniqueness of
gemmologists is the first section in which the features may not seem to fit comfortably within
topics addressed include not only gem rarity but the uniformitarian framework, but Lyell’s principle
also other ways in which gems are peculiar and continues to have merit so long as ‘key’ is not
the important but infrequently tackled question of misinterpreted to mean ‘the same as’.
why they are so transparent. There is considerable In Section 4 Saul first outlines six major gem
analysis and discussion of metamorphism, deposits that lie along the circumference of a
pressure and temperature and the role of each circular topographic feature about 300 km in
in the genesis of gems, with copious notes, diameter in Kenya/Tanzania, all within rocks
explanations and references augmenting the 30 that emit noticeable foul-smelling odours when
pages of text and illustrations in this section. The cracked apart. The rest of the section then deals
marked concentration of beautiful gem minerals with the development of single- and multi-celled
in only a few geographical locations is attributed to life, the ways they survive in dealing with oxygen
a pattern of continental drift and collision which and calcium toxicities, links with the Pan-African
brings into play much recent thinking on global mountain-building events just before the explosion
tectonics and mineral age determination. of life in Cambrian times, and the ‘sudden’ global
In my career as a geologist having mapped a availability of phosphorus. These developments
number of new areas, I have often seen how easy and conditions enabled the first biominerals to
it is to miss certain features of the rocks that one form which in turn enabled shells (exoskeletons)
only appreciates with another look after seeing and bones (endoskeletons) to form, with a few
surrounding areas. I think Saul may be keenly being preserved for posterity as fossils. This has
aware of this aspect of scientific understanding particular relevance for gemmologists studying the
as revealed in his comment (p. 94) ‘…once we origin of ivories and pearls. Regarding the latter,
had the idea in mind…’. The relative significance Saul also speculates about which factors might
and connectedness of different features of gems control secretion of calcite or aragonite.
is important to understand, and sections 2 and The last section of the book is very short and
3 of the book on deep carbon and impact scars highlights the relatively new situation where the
go a long way to augment and clarify the ideas principles and laws of physics, chemistry and
developed in the first gem section. biology, which controlled the development of
Section 2 summarizes evidence for the abio- Earth materials, have been joined by mental and
genic origin of most deep carbon in the form of historical parameters that have a great influence on
gas and oil; diamond is also briefly discussed in human evolution. The elements of consciousness
this context. Section 3 is the longest in the book. and desire are major factors in what we do and
It deals in detail with ascribing to asteroid impacts how we do it, and the discussion includes a number
a wide range of features on the earth’s surface that of pointers to a contemporaneous book by the
are visible from space, and includes linking some author titled The Tale Told in All Lands. We are all,
of the plainly visible arcuate patterns with specific ultimately, stardust, and in that book astronomy is
gem deposits in a most convincing way. Linkages demonstrated to have had as great an influence on
are also made with hydrocarbons (Section 2) not the mental activities of humans (from the earliest
only because they appear in these generally arcuate times) as it has in the formation and history of the
areas but also because they are sometimes found earth.
within inclusions in gems such as tanzanite. A few minor aspects detract somewhat from the
While looking all the time for patterns, Saul book: there is no index, and the black-and-white
repeatedly emphasizes the uniqueness of particular photographs are poorly reproduced (in contrast
New Media 81
New Media
to the beautifully clear black-and-white aerial one provisionally accepts this, the book goes on to
photograph on the back cover). In terms of ideas, assemble such a large, well-referenced collection
one also has to consider the limitations imposed of information that the ideas gain considerable
by the relatively few gem species the author is credibility and provide a platform to stimulate the
considering. But the author quite clearly states in next wave of thinking about the origins of gems.
the title that the book is about speculations, and if Roger Harding
New Media 83
Literature of Interest
Coloured Stones Taijin, Rock and Mineral Analysis, 32(4), 2013, 608–612
Connoisseur’s Choice: Liddicoatite, fluor- (in Chinese with English abstract).
liddicoatite, and liddicoatitic tourmalines, On the origin of digit patterns in gem opal.
Anjanabonoina District, Madagascar. R.B. Cook, B. Rondeau, J.-P. Gauthier, F. Mazzero, E. Fritsch,
Rocks & Minerals, 88(4), 2013, 346–353, http://dx.doi. Y. Bodeur and B. Chauviré, Gems & Gemology,
org/10.1080/00357529.2013.796756. 49(3), 2013, 138–146, http://dx.doi.org/10.5741/
Crystal-filled cavities in granitic pegmatites: GEMS.49.3.138.
Bursting the bubble. D. London, Rocks & Minerals, Research of genesis of black bands in Burma
88(6), 2013, 527–538, http://dx.doi.org/10.1080/003 jadeite. Jian MAO, Lin-tao CHAI, Xue-liang
57529.2013.826090. LIU, Jian-liang FAN, Jia-yuan XU and Zhi-yuan
JIN, Spectroscopy and Spectral Analysis, 33(9), 2013,
The curious tale of the lost liddicoatite crystals:
2411–2415, www.gpxygpfx.com/qikan/public/
How a long-misplaced lot of gem liddicoatite
tjdjl_en.asp?wenjianming=2013-09-2411&houzhui=.
crystals from Madagascar was rediscovered
pdf&id=20977.
after some thirty-five years. E.S. Greene, Rocks &
Minerals, 88(4), 2013, 322–327, http://dx.doi.org/ Tourmaline: A giant of a ‘mineral’. R.B. Cook,
10.1080/00357529.2013.796752. Rocks & Minerals, 88(4), 2013, 316–321, http://dx.doi.
org/10.1080/00357529.2013.796751.
The definition and classification of Hetian jade.
CHEN Gengxin and WANG Changzheng, China The trace element contents and color comparison
Gems & Jades, 106(5), 2013, 142–146 (in Chinese). in rubies. ZHANG Binquan, China Gems & Jades,
106(5), 2013, 162–167 (in Chinese).
Dichromatism, the cause of the usambara and
alexandrite colour change effect. G. Pearson and D. Diamonds
Hoover, Australian Gemmologist, 25(2), 2013, 62–70.
Beyond Hope: Some other notable diamonds at
Elemental characterization of some Nigerian the Smithsonian Institution—Part 1. R.C. Feather
gemstones: Tourmaline, fluorite and topaz by II, Rocks & Minerals, 89(1), 2014, 27–29, http://dx.
instrumental neutron activation analysis. S.O. doi.org/10.1080/00357529.2014.842832.
Aigbe, I.O.B. Ewa, P.O. Ogunleye and M.O.A. Collecting diamonds and the Kimberley Process.
Oladipo, Journal of Radioanalytical and Nuclear Chemistry, J.H. Betts and T. Nikischer, Rocks & Minerals, 89(1),
295(1), 2013, 801–805, http://dx.doi.org/10.1007/ 2014, 89–91, http://dx.doi.org/10.1080/00357529.
s10967-012-1954-0. 2014.842843.
Farbzonierung bei Quarz und mehrfarbige Color in natural diamonds: The beauty of defects.
Quarze [Colour zoning in quartz and multi- E. Gaillou and G.R. Rossman, Rocks & Minerals, 89(1),
coloured quartz]. U. Henn and R. Schultz-Güttler, 2014, 66–75, http://dx.doi.org/10.1080/00357529.
Gemmologie: Zeitschrift der Deutschen Gemmologischen 2014.842839.
Gesellschaft, 62(3/4), 2013, 85–98 (in German with
English abstract). Coming to terms with diamonds: A matter of
facts. C.A. Francis and J.H. Betts, Rocks & Minerals,
The FTIR spectroscopy characteristics of black 89(1), 2014, 30–34, http://dx.doi.org/10.1080/00357
jadeite jade and similar jade. LIN Jinchang and LI 529.2014.842834.
Jihong. Science & Technology Information, 11, 2013, 66–67
(in Chinese). Connoisseur’s Choice: Diamond, Dutoitspan
mine, Kimberley, northern Cape Province, South
Gemological characteristics of lilac jade. ZHANG Africa. P.W. Pohwat, Rocks & Minerals, 89(1), 2014, 54–
Wentao, Science & Technology Information, 21, 2013, 67 65, http://dx.doi.org/10.1080/00357529.2014.842838.
and 72 (in Chinese).
How diamond performance attributes: Brilliance,
The green spots in nephrite—grossularite. FENG scintillation and fire depend on human vision
Xiaoyan, SHEN Meidong, ZHANG Yong and LU features. S. Sivovolenko, Y. Shelementiev, G.
Literature of Interest 85
Literature of Interest
GRS expedition to the Mogok ruby, sapphire Primary corundum from Mirisataehela in Sri
and spinel mines. A. Peretti, JNA, October 2013, Lanka (Part 2). Chan Chi Keung, Journal of the
54–58, www.gemresearch.ch/news/2013-10-16_ Gemmological Association of Hong Kong, 34, 2013,
MogokExped/Gem.Mogok.JNA.Oct2013.pdf. 24–29, www.gahk.org/journal/GAHK_Journal_2013.
pdf (in Chinese with English summary).
Grüne und rosafarbene Turmaline aus Ruanda
[Green and pink tourmaline from Rwanda]. U. Record-breaking discovery of ruby and sapphire
Henn, Gemmologie: Zeitschrift der Deutschen Gemmologischen at the Didy mine in Madagascar: Investigating
Gesellschaft, 62(3/4), 2013, 105–110 (in German with the source. A. Peretti and L. Hahn, Contributions to
English abstract). Gemology, No. 13, May 2013, www.gemresearch.ch/
journal/No13/No13.pdf.
Hibonit aus Myanmar (Burma) [Hibonite from
Myanmar (Burma)]. M. Wild and C.C. Milisenda, Rock talk – A Mogok geology primer. W. Atichat
Gemmologie: Zeitschrift der Deutschen Gemmologischen and R.W. Hughes, InColor, 24, 2013, 46–50.
Gesellschaft, 62(1/2), 2013, 25–30 (in German with Study on gemmological characteristics of
English abstract). turquoise from Dian’anshan, Anhui Province.
Investigating the colour of spinel: 1. Red gem- Hui DAI, Xiaoping JIANG, Lijian QI, Liyi YANG,
quality spinels (“balas”) from Ratnapura (Sri Qing ZHANG and Yan ZHOU, Journal of Gems
Lanka). A. Gorghinian, A. Mottana, A. Rossi, F. & Gemmology, 15(4), 2013, 37–45 (in Chinese with
Maria, O. Adolfo Esposito and A. Marcelli, Rendiconti English abstract).
Lincei. Scienze Fisiche e Naturali, 24(2), 2013, 127–140, Study on the micro-FTIR and Raman spectra of
http://dx.doi.org/10.1007/s12210-013-0223-7. the alluvial diamonds from Yangtze Craton and
their geological significances. ZENG Xiangqing,
Jadeitite formed during subduction: In situ zircon
ZHENG Yunlong, YANG Zhijun, AI Qun and
geochronology constraints from two different
HU Piaoye, Spectroscopy and Spectral Analysis, 33(10),
tectonic events within the Guatemala Suture
2013, 2694–2699, www.gpxygpfx.com/qikan/public/
Zone. K.E. Flores, U.C. Martens, G.E. Harlow,
tjdjl_en.asp?wenjianming=2013-10-2694&houzhui=.
H.K. Brueckner and N.J. Pearson, Earth and Planetary
pdf&id=21036 (in Chinese with English abstract).
Science Letters, 371–372, 2013, 67–81, http://dx.doi.
org/10.1016/j.epsl.2013.04.015. Study on XRD and infrared spectroscopy of
nephrites from Xinjiang and Xiuyan, Liaoning.
Mozambique rubies: Market, mine and the CHEN Quanli, BAO Deqing and YIN Zuowei.
original source of the Montepuez deposit. A. Spectroscopy and Spectral Analysis, 33(11), 2013,
Fanka and C. Sutthirat, Journal of the Gemmological 3142–3146, www.gpxygpfx.com/qikan/public/
Association of Hong Kong, 34, 2013, 39–47, www.gahk. tjdjl_en.asp?wenjianming=2013-11-3142&houzhui=.
org/journal/GAHK_Journal_2013.pdf. pdf&id=21128 (in Chinese with English abstract).
New aspects and perspectives on tsavorite Three occurrences of Oregon sunstone. D. Pay,
deposits. J. Feneyrol, G. Giuliani, D. Ohnenstetter, R. Weldon, S. McClure and K. Schumacher, Gems
A.E. Fallick, J.E. Martelat, P. Monié, J. Dubessy, & Gemology, 49(3), 2013, 162–171, http://dx.doi.
C. Rollion-Bard, E. Le Goff, E. Malisa, A.F.M. org/10.5741/GEMS.49.3.162.
Rakotondrazafy, V. Pardieu, T. Kahn, D. Ichang’i,
Update on gemstone mining in Luc Yen,
E. Venance, N.R. Voarintsoa, M.M. Ranatsenho,
Vietnam. P. Van Long, V. Pardieu and G. Giuliani,
C. Simonet, E. Omito, C. Nyamai and M. Saul,
Gems & Gemology, 49(4), 2013, 233–245, http://dx.doi.
Ore Geology Reviews, 53, 2013, 1–25, http://dx.doi.
org/10.5741/GEMS.49.4.233.
org/10.1016/j.oregeorev.2013.01.016.
Vanadium- and chromium-bearing chrysoberyl
The ore-forming geological background and
from Mogok, Myanmar – Examination of two
gemological characteristics of labradorite in
historical samples. K. Schmetzer, H.-J. Bernhardt and
Guyang, Neimeng. Zhao Yueming, Bai Wannian,
C. Cavey, Australian Gemmologist, 25(2), 2013, 41–45.
Zhao Yusheng, Zhang Zhixiang, Wang Tao, Zhang
Youkuan, Zhang Ai, Meng Genghua and Liang Lixin, Miscellaneous
Western Resources, 2, 2013, 161–164 (in Chinese).
Analysis of causes in difficulty of jewelry
An ornamental sapphirine-cordierite-sillimanite liquation and construction of jewelry appraisal
rock from South India. G. Choudhary, Australian system. Gang LI, Journal of Gems & Gemmology, 15(4),
Gemmologist, 25(4), 2013, 146–151. 2013, 64–69.
Literature of Interest 87
Literature of Interest
Echte Perlen und Zuchtperlen: ein Grundkonzept New generation of synthetic diamonds reaches
und seine Variationen [Natural pearls and the market (Part A): CVD-grown blue diamonds.
cultured pearls: A basic concept and its A. Peretti, F. Herzog, W. Bieri, M. Alessandri, D.
variations]. H.A. Hänni, Gemmologie: Zeitschrift der Günther, D.A. Frick, E. Cleveland, A.M. Zaitsev and
Deutschen Gemmologischen Gesellschaft, 62(1/2), 2013, B. Deljanin, Contributions to Gemology, No. 14,
3–18 (in German with English abstract). November 2013, 1–14, www.gemresearch.ch/news/
2013-11-07_BlueDiamond/CVD-BlueDiamond.
Inside the black pearl. WEI Xinquan, LI Guoze
pdf.
and SAI Hongyu, China Gems, 5, 2013, 193–195 (in
Chinese). A simple approach to separate natural from
synthetic ametrine. F. Payette, Australian Gemmologist,
Investigation on the coloring mechanism of
25(4), 2013, 132–141.
freshwater cultured pearls with different color.
YAN Jun, HU Xianchao, WANG Juan, YAN Xuejun, Some uncommon sapphire ‘imitations’: Blue
HU Danjing, LIU Peijun and FANG Shibin, Rock and Co-zirconia, kyanite & blue dumortierite. M.S.
Mineral Analysis, 32(2), 2013, 263–268 (in Chinese with Krzemnicki, Journal of the Gemmological Association of
English abstract). Hong Kong, 34, 2013, 62–64, www.gahk.org/journal/
GAHK_Journal_2013.pdf.
Organic matter in nacre and its mineralization
effect. ZHANG En, HU Linyu, HUANG Fuquan Study on gemmological characteristics of an
and PENG Mingsheng, Acta Petrologica et Mineralogica, imitated aquamarine. Xiao-chuan ZHAO, Shi-
32(1), 2013, 129–136 (in Chinese with English qi WANG and Ting WANG, Journal of Gems &
abstract). Gemmology, 15(3), 2013, 56–59 (in Chinese with
English abstract).
Some new knowledge of the integrated model of
cultured pearl’s internal structure. MA Hongyan,
HUANG Bei, ZHANG Beili, YANG Lixin and Treatments
SHEN Meidong, Acta Mineralogica Sinica, 33(1), 2013, Characteristics of coated jadeite jade. J. Zhang, T.
45–48 (in Chinese with English abstract). Lu and H. Chen, Gems & Gemology, 49(4), 2013, 246–
251, http://dx.doi.org/10.5741/GEMS.49.4.246.
Social Studies Cobalt-doped glass-filled sapphires: An update.
China’s pearl industry—An indicator of T. Leelawatanasuk, W. Atitchat, V. Pisutha-Arnond,
ecological stress. L.E. Cartier and S.H. Ali, Journal P. Wattanakul, P. Ounorn, W. Manorotkul and R.W.
of the Gemmological Association of Hong Kong, 34, 2013, Hughes, Australian Gemmologist, 25(1), 2013, 14–20.
18–21, www.gahk.org/journal/GAHK_Journal_2013. Electronic and vibrational spectra of
pdf. tourmaline—The impact of electron beam
Marange diamonds and Zimbabwe’s political irradiation and heat treatment. Y. Ahn, J. Seo and
transition. F. Maguwu, Journal of Peacebuilding & J. Park, Vibrational Spectroscopy, 65, 2013, 165–175,
Development, 8(1), 2013, 74–78. http://dx.doi.org/ http://dx.doi.org/10.1016/j.vibspec.2013.01.002.
10.1080/15423166.2013.789271. Identification of treated quartzite imitating
Research of relationship between jewelry and B-jade and B+C-jade. Tay Thye Sun and Loke Hui
luxury goods. Deqing BAO, Bin LI, Zuowei YIN, Ying, Australian Gemmologist, 25(4), 2013, 152–153.
Pengfei ZHANG and Qishen ZHOU, Journal of Gems Korunde mit blauem kobalthaltigem Bleiglas
& Gemmology, 15(4), 2013, 55–63 (in Chinese with gefüllt [Corundum with blue cobalt-bearing lead
English abstract). glass filling]. C.C. Milisenda, K. Schollenbruch
and S. Koch, Gemmologie: Zeitschrift der Deutschen
Synthetics and Simulants Gemmologischen Gesellschaft, 62(1/2), 2013, 19–24 (in
Characteristics of lamellar growth structure German with English abstract).
and ultraviolet fluorescence of CVD synthetic Smoke and mirrors: The enhancement and
diamonds. Xiaomin LV, Yubing ZHANG, Yan LAN, simulation of gemstones in Renaissance Europe.
Ting DING, Zhonghua SONG, Jian ZHANG, Taijin J. Whalley, The Renaissance Workshop: The Materials and
LU, Meidong SHEN and Jie KE, Journal of Gems Techniques of Renaissance Art (D. Saunders, M. Spring
& Gemmology, 15(3), 2013, 30–35 (in Chinese with and A. Meek, Eds.), Archetype Publications Ltd.,
English abstract). London, 2013, 79–89.
Literature of Interest 89
)XUWKHU\RXUFDUHHUZLWKWKH*HPPRORJ\'LSORPDWKHPRVW
SUHVWLJLRXVLQWHUQDWLRQDOJHPPRORJ\TXDOLILFDWLRQLQWKHJHP
DQGMHZHOOHU\WUDGH
*HPPRORJ\'LSORPD
)RXUPRQWK'D\WLPHVWXG\SURJUDPPHLQ/RQGRQRSHQRQO\WRWKRVHZKR
KDYHFRPSOHWHGWKH*HPPRORJ\)RXQGDWLRQFRXUVH
6WDUWGDWH6HSWHPEHU²-DQXDU\
&ODVVGD\V7XHVGD\:HGQHVGD\7KXUVGD\
&RXUVHIHH
6HOIVWXG\GD\
View publication stats