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Autumn Pathway AB
Autumn Pathway AB
Covalent bonding
Key objective 2
BONDING, STRUCTURE & THE PROPERTIES OF MATTER
I can describe the key features of solids, liquids and gases as well as describe what covalent,
ionic and metallic bonds are.
I do
Millions of years ago the Earth formed as a giant ball of molten rock. The outer surface
cooled forming a thin, solid outer crust. Volcanic activity on the surface produced an
atmosphere containing the compounds carbon dioxide, ammonia, methane and water vapour.
Describe the bonding in any one of these compounds. You must include electronic structures
in your explanation.
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(4)
We do
Sodium reacts with chlorine to form the compound sodium chloride. 2Na + Cl2 → 2NaCl
Describe, in terms of electron arrangement, the type of bonding in: a molecule of chlorine;
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(3)
You do
Lithium reacts with bromine to form the compound Lithium bromide. 2Li + Br2 →
2LiBr Describe, in terms of electron arrangement, the type of bonding in: a molecule of
Bromine;
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(3)
Independent work
Q1.
(a) Table 2 shows the electronic structure of hydrogen and oxygen.
Table 2
Hydrogen 1
Oxygen 2,6
Figure 2 shows part of a dot and cross diagram of a molecule of water (H2O).
You should show only the electrons in the outer energy levels.
Figure 2
(2)
Oxygen and sulfur are examples of simple molecules.
covalent ionic metallic
oxygen molecule.
(1)
(c) Figure 3 shows the relative sizes of an oxygen molecule and a sulfur molecule.
Figure 3
How does the boiling point of sulfur compare with the boiling point of oxygen?
Figure 2 shows the outer energy levels in one molecule of oxygen (O2).
Figure 2
(2)
(2)
(c) A hydrogen atom contains 1 electron and a chlorine atom contains 17 electrons.
Complete Figure 1 to show a dot and cross diagram for a hydrogen chloride molecule.
Figure 1
(2)
This question is about compounds of fluorine.
(d) A fluorine atom has 7 electrons in the outer shell. Figure 1 shows part of a dot and
cross diagram of a molecule of hydrogen fluoride (HF). Complete the dot and cross
diagram in Figure 1.
Figure 1
(1)
Q3.
This question is about oxygen.
(a) One oxygen atom shares one pair of electrons with each fluorine atom in oxygen difluoride
(OF2). Complete the dot and cross diagram of oxygen difluoride below. You should show only the
electrons in the outer shells.
(2)
(b) Oxygen difluoride (OF2) has a melting point of – 224 °C and a boiling point of –145 °C
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(4)
Q4.
This question is about ammonia (NH3).
(2)
(b) The bonding in iodine is similar to the bonding in chlorine.
(2)
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(3)
(iii) Explain, in terms of particles, why liquid iodine does not conduct electricity.
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(2)
Q5.
(a) A particle of ammonia is represented by the formula NH3 or as:
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(1)
(ii) Draw a ring around the correct answer to complete the sentence.
an atom.
A particle of ammonia is called an ion.
a molecule.
(1)
(iii) Complete the dot and cross bonding diagram for ammonia.
(2)
Q6.
Sulfur dioxide is a gas at room temperature. The bonding in sulfur dioxide is covalent. Explain, in
terms of its structure and bonding, why sulfur dioxide has a low boiling point.
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Challenge
Compare the structure and bonding in sodium chloride and hydrogen chloride.
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(6)
2. Covalent bonding: Diamond and Graphite
Key objective 2
BONDING, STRUCTURE & THE PROPERTIES OF MATTER
I can describe the key features of solids, liquids and gases as well as describe what
covalent, ionic and metallic bonds are.
I do
Graphite and diamond are different forms of the element carbon. Graphite and
diamond have different properties. The structures of graphite and diamond are shown
below.
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(4)
We do
Graphite conducts electricity, but diamond does not.
Explain why.
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(3)
You do
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(3)
Independent task
Q1.
In graphite the carbon atoms are held together by bonds.
Figure 2
(a) How many bonds does each carbon atom have in graphite?
Use Figure 2.
1 2 3 4
(1)
(b) What type of bonds hold the carbon atoms together in graphite?
Covalent
Ionic
Metallic
(1)
Use Figure 2.
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(1)
Buckminsterfullerene
Diamond
Graphene
Nanotube
(2)
Q2.
Diamond has a giant covalent structure.
(a) What is the number of bonds formed by each carbon atom in diamond?
2 3 4 8
(1)
1.
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2.
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1.
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2.
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(2)
Q3.
This question is about structure and bonding.
Figure 1
Explain why diamond has a high melting point.
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(3)
Q4.
The diagrams show the structures of diamond and graphite.
Diamond Graphite
(b) Use the diagrams above and your knowledge of structure and bonding to explain
why:
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(2)
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(2)
(iii) graphite conducts electricity.
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Q5.
Scientists have recently developed a method to produce large sheets of a substance
called graphene. Graphene is made from carbon and is a single layer of graphite just
one atom thick.
• it conducts electricity
Use your knowledge of the bonding in graphite and the photograph of the structure to
help you to explain, as fully as you can:
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(2)
(b) Suggest why a sheet of graphite which has a large number of carbon layers
would not be suitable for the touchscreen.
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Challenge
This drill contains an electric motor.
The carbon contacts are made of graphite. Springs push the contacts against the copper
ring. The contacts conduct electricity to the copper ring. The copper ring rotates rapidly
but does not stick or become worn because the graphite is soft and slippery. Graphite has
properties which are ideal for making the contacts in an electric motor.
Explain, in terms of structure and bonding, why graphite has these properties.
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(Total 5 marks)
3. Metallic bonding
Key objective 2
BONDING, STRUCTURE & THE PROPERTIES OF MATTER
I can describe the key features of solids, liquids and gases as well as describe what
covalent, ionic and metallic bonds are.
I do
Magnesium is a metal. Describe the structure of a metal.
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(3)
We do
Glass can be coloured using tiny particles of gold. Gold is a metal. Describe the
structure of a metal.
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(3)
You do
Copper is a metal. Describe the structure of a metal.
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(3)
Independent task
Q1.
Steel is an alloy of iron and carbon.
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(3)
(b) Iron is alloyed with carbon and other metals to make stainless steel.
The table below shows the mass of each element in the fork.
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X = __________ g
(4)
Q2.
Metals and their alloys have many uses.
(a) Dentists use a smart alloy to make braces that gently push teeth into the right
position.
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(1)
(b) Pure copper is made up of layers of copper atoms. Brass is an alloy of copper
and zinc.
Why are the physical properties of brass different from the physical properties of
pure copper?
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(2)
(c) Nearly all zinc is obtained from ores that also contain lead. The metals zinc and
lead can be extracted by reducing their oxides using carbon.
(i) Choose one element from the box below to complete the sentence about the
reduction of zinc oxide.
Suggest how the lead metal and zinc metal are separated in the furnace.
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(2)
(Total 6 marks)
Q3.
The chart below shows the metals which are present in a coin.
(a) Identify the alloy used to make this coin.
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(2)
(c) Suggest what properties would make an alloy suitable for making a coin.
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Q4.
The Mary Rose was a wooden warship. The Mary Rose sank in 1545 but was lifted
from the sea bed in 1982. Scientists are now preserving the ship.
The image shows the Mary Rose being supported on poles. As part of the preservation
process, the ship was sprayed with water for a long time.
(a) (i) The table below gives information about two materials. These materials
could have been used to make the poles to support the Mary Rose.
Relative
Material Density in g / cm3 Cost in £ per kg
strength
Steel 7.85 1 4
Give two advantages and one disadvantage of using titanium rather than steel.
Use only the information from the table above to answer this question.
Advantage 1 ___________________________________________________
Advantage 2 ___________________________________________________
Disadvantage __________________________________________________
(3)
(ii) The preserving process used titanium poles. Tick (✔) one other property of
titanium which made titanium a suitable choice for the poles.
Electrical insulator
Shiny
(1)
(b) Some metal objects found on the Mary Rose were made of gold or iron. Draw
one line from each metal to its usual method of extraction.
Method of
Metal
extraction
Electrolysis of
molten compound
Gold
Iron
Reduction of metal
oxide with carbon
(2)
(c) Another metal found on the Mary Rose has the chemical symbol Ag.
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(i) Use the correct answer from the box to complete the sentence.
(ii) 88% of a bronze alloy is copper. What percentage of the alloy is tin?
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Q5.
Scientists in the 16th century used the symbol shown in Figure 1 for gold.
Figure 1
Gold
The scientists thought platinum was made from gold and silver, so they used the
symbol for gold in the symbol for platinum. The symbol for platinum is shown in Figure
2.
Figure 2
Platinum
(ii) Elements are different from each other because they have different numbers of
Give the name and number of the atoms which have joined together to make the
compound Ag2O
Use the Chemistry Data Sheet to help you answer this question.
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(3)
Challenge
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(4)
4. Conservation of mass
Key objective 3
QUANTITATIVE CHEMISTRY
I can recall relevant formulas and rearrange them to solve calculations including balancing
formulas.
I do
(i) H2 + O2 → H2O
(1)
(ii) Al + O2 → Al2O3
(1)
(b) Briefly explain why an unbalanced chemical equation cannot fully describe a
reaction.
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(2)
We do
(a) Cola drinks contain phosphoric acid, H3PO4. The two equations show how
phosphoric acid can be made from phosphorus.
(1)
(1)
You do
Balance equation.
Independent task
Q1.
This question is about silver iodide.
Silver iodide is produced in the reaction between silver nitrate solution and sodium
iodide solution.
Beaker A and
78.26 108.22
contents
Beaker B and
78.50 48.54
contents
Explain how the results demonstrate the law of conservation of mass.
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(2)
(b) Suggest how the student could separate the insoluble silver iodide from the
mixture at the end of the reaction.
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(c) Suggest one impurity that was removed by rinsing with water.
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Q2.
A student investigated the law of conservation of mass.
The law of conservation of mass states that the mass of the products is equal to the
mass of the reactants.
When lead nitrate solution and potassium chromate solution are mixed, a reaction
takes place.
Pb(NO3)2(aq) + K2CrO4(aq) ⟶ PbCrO4(s) + 2KNO3(aq)
(a) What would the student see when the reaction takes place?
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(1)
Mass in g
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(2)
(c) Another student also tests the law of conservation of mass using the same
method.
Na2CO3(aq) + 2HCI(aq) ⟶ 2NaCl(aq) + CO2(g) + H2O(I)
Explain why this student’s results would not appear to support the law of
conservation of mass.
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Q3.
Metals are extracted from ores in the Earth’s crust.
Some ores contain metal carbonates and some ores contain metal oxides.
(a) (i) Name the type of reaction that happens when a metal carbonate is
heated.
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(1)
copper
copper nitrate
copper oxide
copper sulfide
(1)
(b) A student investigated heating four metal carbonates. Figure 1 shows the
apparatus used.
Figure 1
The student heated each metal carbonate for five minutes. The table below shows the
results.
Mass of Mass of
metal solid after Observation
Metal carbonate
carbonate at heating for 5 s
start in g minutes in g
Limewater
Copper carbonate 10.0 6.9
turns cloudy
Magnesium Limewater
10.0 9.1
carbonate turns cloudy
Limewater
Potassium
10.0 10.0 does not turn
carbonate
cloudy
Limewater
Zinc carbonate 10.0 8.3
turns cloudy
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(3)
(ii) Suggest how the reactivity series can be used to predict which metal carbonate
reacts most easily when heated.
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(2)
Complete and balance the equation for a reaction to produce iron from iron oxide.
Challenge
(1)
b) _PCl3 + _H2O -> _P(OH)3 + _HCl
(1)
(1)
d) _C2H5OH + _O2 -> _CO + _H2O
(1)
e) _HCl + _MnO2 -> _MnCl2 + _H2O + _Cl2
(1)
5. The Mole
Key objective 3
QUANTITATIVE CHEMISTRY
I can recall relevant formulas and rearrange them to solve calculations including
balancing formulas.
I do
Another student placed a conical flask containing 1.00 g of a Group 1 carbonate (M2CO3)
on a balance. He then added 50 cm3, an excess, of dilute hydrochloric acid to the flask and
measured the mass of carbon dioxide given off.
(i) Calculate the amount, in moles, of carbon dioxide in 0.12 g carbon dioxide.
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We do
The equation for the reaction is:
(i) Calculate the amount, in moles, of carbon dioxide in 0.32 g carbon dioxide.
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(i) Calculate the amount, in moles, of carbon dioxide in 0.62 g carbon dioxide.
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Page 7 of 16
Q3. How many atoms are there in 1 g of argon? The Avogadro constant is 6.02 × 1023
per mole. Relative atomic mass (Ar): Ar = 40
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Calculate the number of moles of copper that can be produced from 1 dm3 of this
solution.
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Calculate the number of moles of ammonium nitrate in the bag of fertiliser. Give your
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