Water Purification Process Design 111

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WATER QUALITY - Measure of acids in solution

- As defined by RA 9275 or the Philippine Clean Water Act - It is the quantitative capacity of water to neutralize a strong
(CWA) of 2004, water quality is “the characteristics of base to a selected pH level
water which define its use in terms of physical, chemical, - Level of acidity 0.02 N
biological, bacteriological or radiological characteristics
by which the acceptability of water is evaluated.”  3. Alkalinity
- Acid-neutralizing capacity comprised of total of all titratable
CLASSIFICATION OF WATER  bases.
 On source:  - Necessary in determining the amount of lime or soda for
1) Ground Water  - that portion of rainwater w/c has percolated softening (ex. For corrosion control)
into the earth to form underground deposits called aquifer - H2SO4 of 0.02 N
(water-bearing soil formation)
2) Surface Water - mixture of surface run-off and groundwater. 4. Chloride 
Surface sources includes lakes, rivers, ponds and - Naturally occurs in groundwater, lakes, and streams but the
impounding reservoirs. presence of very high chloride (about 250 mg/L) in fresh
water may indicate pollution.
 On quality: 
1) Potable water – safe to drink, with pleasant taste, and may use - Maximum allowable concentration: 250 mg/L
for domestic purposes. 
2) Palatable water – esthetically pleasing but may contain 5. Chlorine Residual
chemicals that may not harm  human health  - Amount of chlorine maintained in water distribution system
3) Contaminated (polluted) water – contains unwanted physical, to ensure safe quality of water.
chemical, biological, or radiological substances, and - Allowable amount of chlorine residual in water is 0.2 to 0.5
unfit for domestic use as well as for human mg/L
consumption.
4) Infected water – contaminated with pathogenic organisms  6. Sulfate 
- Sulfate ions (SO42-) are naturally occurring in water and
A. PHYSICAL PARAMETERS OF WATER QUALITY wastewater.
1. Turbidity - Usually caused by leaching  of natural deposits of
- A measure of the degree of cloudiness and muddiness of Magnesium Sulfate (Epson Salt) or sodium sulfate (Glauber’s
water. Salt) 
- Describes the clarity of water - Maximum level is 250 mg/L
- Maximum level: 5 NTU
7. Nitrogen
2. Temperature - Most of Nitrogen is in the form of Organic and Ammonia if
- Degree of hotness or coldness of a thing the water is contaminated with  sewage and then, transformed
- 10-15 deg. celcius – palatable for most people to nitrites and nitrates by microbes.  
- MAL for Nitrate: 50 mg/L , Nitrite: 3 mg/L
3. Color
- Objectionable for esthetic reasons, not for health reason 8. Fluoride 
- Maximum level: 10 CU - Fluoride ions (F-) in drinking water are beneficial to dental
health. 1It is effective in preventing tooth decay.
4. Taste and Odor - Maximum level allowed: 1.0 mg/L
- Foreign matter such as organic materials, inorganic
compounds, or dissolved gases. 9. Iron (Fe) and Manganese (Mn) 
- May come from natural, domestic, or agricultural sources - Both do not cause health problems but may cause bitter taste
to drinking water even at low concentration. 
- Allowable level: No objectionable taste and odor
- Maximum level: Iron: 1 mg/L, Manganese: 0.5 mg/L
5. Solids
10. Copper and Zinc 
- May occur in water either in suspension or solution which - Both are nontoxic at small concentration. 
can be identified by using a glass fiber filter that the water
- Beneficial for plants, animals and human health. 
samples pass through.
- May cause undesirable taste in drinking water.
- TDS Maximum level: 600 mg/L
- Maximum Level Copper: 1.0 mg/L, Zinc: 5.0 mg/L 
6. Electrical Conductivity (EC)
- Measure of the ability of solution to conduct or carry an 11. Hardness
electrical current. - Term used to express highly mineralized waters
CHEMICAL PARAMETERS OF WATER QUALITY - Maximum level: 300 mg/L as CaCO3
1. pH
12. Dissolved Oxygen (DO) 
- Negative logarithm of the hydrogen ion concentration
- One of the most important parameters of water quality in
- Measure of how acidic or basic water is
streams, rivers and lakes.
- Safe range of pH in drinking water 6.5-8.5
- Key test for water pollution 
2. Acidity
- The higher the concentration of dissolved oxygen in water,
the better the water quality is. 4. Protozoa
- Single-celled microscopic animal
13. Biochemical Oxygen Demand (BOD) - They consume solid organic particles, bacteria and algae for
-  The need for oxygen is called Biochemical Oxygen food
Demand. - Zooplankton is aquatic protozoa floating freely in water.

14. Chemical Oxygen Demand (COD)  MAXIMUN ALLOWABLE LEVEL OF DIFFERENT


- Parameter that measures all organics that includes the PARAMETERS
biodegradable and non-biodegradable substances. 
- A chemical test using strong oxidizing chemicals (potassium PHYSICAL AND CHEMICAL QUALITY FOR
dichromate), sulfuric acid and heat. Results are available in ACCEPTABILITY ASPECTS OF DRINKING WATER
just 2 hours.  PARAMETERS MAXIMUM
- Compared to BOD, COD Values are always higher. ALLOWABLE LEVEL
Taste No Objectionable Taste
15. Toxic Inorganic Substances  Odor No Objectionable Odor
- May be found in water in trace or very small amounts but Color (Apparent) 10 CU
Turbidity 5 NTU
still can danger health.
Aluminum 0.02 mg/L
- May occur naturally but many occur due to improper Chloride 250 mg/L
hazardous waste management or industrial activities. Copper 1.0 mg/L
- 2 groups: Metallic Compounds and Nonmetallic Compounds Total Hardness 300 mg/L
Hydrogen Sulfide 0.05 mg/L
16. Toxic Organic Substances  Iron 1.0 mg/L
- Not naturally found in water but usually man-made pH 6.5-8.5
pollutants  Sodium 200 mg/L
- Includes the following:  Sulfate 250 mg/L
 Insecticides  Total Dissolved 600 mg/L
 Pesticides  Solids
 Solvents 
 Detergents  INORGANIC CHEMINCAL PARAMETERS
 Disinfectants  PARAMETERS MAXIMUM ALLOWABLE
LEVEL
Antimony (Sb) 0.002 mg/L
17. Radioactive Substances 
Arsenic (As) 0.01 mg/L
- Sources include wastes from nuclear power plants, industries,
Barium (Ba) 0.70 mg/L
or medical research using radioactive chemicals and mining of Boron (B) 2.00 mg/L
uranium ores or other radioactive materials. Cadmium (Cd) 0.003 mg/L
Chromium (Cr) 0.05 mg/L
BIOLOGICAL PARAMETERS OF WATER QUALITY Cyanide (CN-) 0.50 mg/L
- The presence or lack or living organisms and is one of the Fluoride (F-) 1.50 mg/L
most helpful indicators of water quality.  Lead (Pb) 0.01 mg/L
Manganese (Mn-) 0.4 mg/L
- Bodies of water with large number of well-balanced species
Mercury (Hg) 0.001 mg/L
is considered as  healthy system 
Nickel (Ni-) 0.07 mg/L
- Other organisms are used as indicators of the presence of Nitrate (NO3-) 50.00 mg/L
pollutants. Nitrite (NO2-) 3.00 mg/L
Selenium (Se) 0.04 mg/L
1. Bacteria 
- Considered as single-celled plant cells due to their structure ORGANIC CHEMINCAL PARAMETERS FROM
and how they ingest food.  INDUSTRIAL POLLUTION OF DRINKING-WATER
PARAMETERS MAXIMUM
ALLOWABLE LEVEL
Benzene 0.01 mg/L
2. Algae
Benzo(a)pyrene 0.0007 mg/L
- Microscopic plants that contains photosynthetic pigment Carbon Tetrachloride 0.004 mg/L
such as chlorophyll. 1,2 - Dichlorobenzene 1 mg/L
- Creates taste and odor problems to drinking water. 1,4 - Dichlorobenzene 0.3 mg/L
1,2 - Dichloroethane 0.03 mg/L
3. Viruses 1,2 - Dichloroethene 0.05 mg/L
- Considered as the smallest biological structures and can only Dichloromethane 0.02 mg/L
be seen by a powerful electronic microscope. Di(2-ethylhexyl) 0.008 mg/L
- They pass through filters which do not permit the passage of phthalate
bacteria. Ethylbenzene 0.3 mg/L
Styrene 0.02 mg/L
- Most waterborne viruses can be killed by disinfection
Tetrachloroethene 0.04 mg/L
process in water treatment plants.
Toluene 0.7 mg/L aquatic resources and intended for
Vinyl Chloride 0.0003 mg/L commercial and sustenance fishing
Xylenes (total) 0.5 mg/L 2. Recreational Water Class II - For boating,
fishing, or similar activities
3. Marshy and/or mangrove areas declared as
TABLE 1. WATER BODY CLASSIFICATION AND fish and wildlife sanctuaries
USAGE OF FRESHWATER Class SD Navigable waters
Classificati Intended Beneficial Use
on
Class AA Public Water Supply Class I - Intended
primarily for waters having watersheds, which
are uninhabited and/or otherwise declared as
protected areas, and which require only approved
disinfection to meet the latest PNSDW
Class A Public Water Supply Class II - Intended as
source of water supply requiring conventional
treatment (coagulation, sedimentation, filtration
and disinfection) to meet the latest PNSDW
Class B Recreational Water Class I - Intended for
primary contact recreation (bathing, swimming,
etc.)
Class C 1. Fishery Water for the propagation and
growth of fish and other aquatic resources
2. Recreational Water Class II - For boating,
fishing, or similar activities
3. For agriculture, irrigation, and livestock
watering
Class D Navigable waters

TABLE 2: WATER BODY CLASSIFICATION AND


USAGE OF MARINE WATERS
Classification Intended Beneficial Use
Class SA 1. Protected Waters - Waters designated as
national or local marine parks, reserves,
sanctuaries, and other areas established by law
(Presidential Proclamation 1801 and other
existing laws), and/or declared as such by
appropriate government agency, LGUs, etc.
2. Fishery Water Class I - Suitable for
shellfish harvesting for direct human
consumption
Class SB 1. Fishery Water Class II - Water suitable for
commercial propagation of shellfish and
intended as spawning areas for milkfish
(Chanos chanos) and similar species
2. Tourist Zones - For ecotourism and
recreational activities
3. Recreational Water Class I - Intended for
primary contact recreation (bathing,
swimming, skin diving, etc.)
Class SC 1. Fishery Water Class III - For the
propagation and growth of fish and other

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