Paper: Chemistry HSSC-II Test: 03 Session: RNT_FEB 2022

Name: _________________________________________

SECTION – A (Marks 13)

Q.1 Encircle the correct option i.e. A / B / C / D. Each part carries one mark. (1×13=13)
i) Which of the following class of organic compounds donot contains oxygen in their
functional groups?
⒜ Alcohols ⒝ Amides ⒞ Nitriles ⒟ Ethers
ii) The difference between the molecular masses of the alternating member of homologous
series is;
⒜ 14 a.m.u. ⒝ 28 a.m.u. ⒞ 1 a.m.u. ⒟ 10 a.m.u.
iii) Alkaloid is a nitrogen containing organic compounds having basic nitrogen. Which of the
following is NOT an alkaloid?
⒜ Morphine ⒝ Strychnine ⒞ Cellulose ⒟ Quinine
iv) In the detection of nitrogen in a compound, the greenish blue is the indication, which is
due to;
⒜ Na4[Fe(CN)6] ⒝ Fe4[Fe(CN)6]3 ⒞ Na4[Fe(SCN)6] ⒟ Fe4[Fe(SCN)6]3
v) Carbon dioxide turns lime water milky due to the formation of;
⒜ CaO ⒝ Ca(OH)2 ⒞ CaCO3 ⒟ CaSO4
vi) To obtained organic compounds form petroleum, ____ technique is used;
⒜ Fractional distillation ⒞ Stream distillation
⒝ Vacuum distillation ⒟ Carbonization
vii) Coal is a / an;
⒜ Rocky black solid formed under rocks by means of high temperature and pressure
⒝ Low boiling point hydrocarbons containing mainly methane
⒞ Low boiling point vicus black crude liquid formed between sedimentation of rocks
⒟ All of these
viii) Organic compounds are known by means of their functional group.
Which of the following is true for Non-Functional Group?
⒜ It serves as basis for nomenclature of organic compounds
⒝ It serves to classify organic compounds into classes/families
⒞ It is a site of chemical reactivity in a molecule
⒟ It serves as the basis of variation in the physical properties

Hard Work and Determination is the Key to Success

ix) Which of the following observation is NOT correct for following compounds?

⒜ Its LS firstly reacted with FeSO4 in alkaline medium and finally produces blue ppt upon reacting with FeCl3
⒝ Its LS reacted with AgNO3 after removing interfering radicals produces pale yellow ppt
⒞ Its LS reacted with acetic acid after treating the lead acetate paper turns black
⒟ All the observations are correct theoretically
x) Which is NOT a characteristic of homologous series?
⒜ Member of homologues series have same physical and chemical properties
⒝ Member of homologues series have same set of various elements
⒞ Member of homologues series has same general formula
⒟ Member of homologues series has same functional group
xi) Amino group is present in which of the following compound?
⒜ ⒞
⒝ ⒟
xii) Homologs must have same;
⒜ Chemical Properties ⒞ Melting Point
⒝ Functional Group ⒟ Molecular Mass
xiii) Which of the following homologous series have / has same general formula?
I- Alkenes II- Alkynes III- Cycloalkenes
⒜ I, II & III ⒝ I & II ⒞ II & III ⒟ I & III

Hard Work and Determination is the Key to Success

 Paper: Chemistry HSSC-II Test: 03 Session: RNT_FEB 2022

Name: _________________________________________

SECTION – B (Marks 24)

Q.2 Answered FOLLOWING Parts. The answer to each part should not exceed 5 to 7 lines.
(3×8=24)
i) Differentiate between Partial and Total Synthesis of Organic Compounds.
ii) Differentiate between CH3Cl, CH3Br and CH3I chemically.
iii) How would you detect heteroatom(s) from following organic compound, CH 3SCN?
iv) How would you convert ethene into ethyl bromide and back to ethene?
v) Why propene is more stable compare to ethene but less stable compare to 2-Butene?
vi) State Markownikov’s Rule. How this rule governs the hydrolysis of propene.
vii) Why alkanes donot react with any acids, bases, oxidizing agent or reducing agent?
viii) Nomenclature the following compounds according to IUPAC Nomenclature Rules.

a)

b)

c)

SECTION – C (Marks 13)

Attempt FOLLOWING question in detailed. [13 × 1 = 13]

Q.3 a) Write the Mechanism of the reaction in which Propene is converted into
Formaldehyde and acetaldehyde. [7]
b) How 2-Butene undergoes following reactions. [6]
i. Hydrobromination Reaction
ii. Ozonolysis Reaction
iii. Hydrolysis Reaction
Hard Work and Determination is the Key to Success