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JEE ADVANCED
2023
Question Paper,
Key & Solutions Paper 1
ALL INDIA OPEN CATEGORY
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SINGARAJU VENKAT KOUNDINYA KALLAKURI SAINADH SRIMANTH

Appl. No.: 230310124339 Appl. No.: 230310286801
CLASSROOM STUDENT FROM GRADE I -XII
CLASSROOM STUDENT FROM GRADE I -XII
Total Qualified Ranks for
18136
JEE Advanced-2023
G) srichaitanya.net Study With The Best, Rise Above The Rest. \!' 040 66 06 06 06
Sri Chaitanya IIT Academy., India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office, Madhapur – Hyderabad
JEE-ADVANCE-2023-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Multiple Correct
Sec – I(Q.N : 1 – 3) +4 -2 3 12
Choice with partial mark
Questions with Single Correct
Sec – II(Q.N : 4 – 7) +3 -1 4 12
Choice
Questions with non-negative Integer
Sec – III(Q.N : 8 – 13) +4 0 6 24
Answer Type
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60
PHYSICS:
Sec – I(Q.N : 18 – 20) +4 -2 3 12
Sec – II(Q.N : 21 – 24) +3 -1 4 12
Choice
Sec – III(Q.N : 25 – 30) +4 0 6 24
Answer Type
Total 17 60
CHEMISTRY:
Sec – I(Q.N : 35 – 37) +4 -2 3 12
Sec – II(Q.N : 38 – 41) +3 -1 4 12
Choice
Sec – III(Q.N : 42 – 47) +4 0 6 24
Answer Type
Total 17 60
Sri Chaitanya IIT Academy 04-06-2023_JEE-Advance-2023-P1-QP & Sol’s
MATHEMATICS Max Marks: 60
SECTION – I
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 ONLY if (all) the correct option(s) is (are) chosen;
Partial Marks: +3 if all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 if three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 if two or more options are correct but ONLY two options are chosen, and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –2 in all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
1. Let S  0,1  1,2  3,4 and T  0,1,2,3. Then which of the following statements
is(are) true?
A) There are infinitely many functions from S to T
B) There are infinitely many strictly increasing functions from S to T
C) The number of continuous functions from S to T is at most 120
D) Every continuous function from S to T is differentiable
Ans. AD
0 1 2 3 4
Sol.
S   0,1  1,2   3,4
T   0,1,2,3
Domain of function f : S  T has infinitely many elements in set S
 Strictly increasing function is not possible as number of points in domain is infinite but
co–domain has only 4 elements.
If number of points in domain are n, then number of functions possible from S to T are 4n
as n    4n  
Page 2
Number of continuous functions possible are 4C1  4C1  4C1 = 64
Because domain has 3 regions, so continuous functions are 64
As the range of continuous function is a single element in the set T which is a constant, so
every function is differentiable in all intervals as the derivative is 0 always.
x2 y 2
2. Let T1 and T2 be two distinct common tangents to the ellipse E :   1 and the
6 3
parabola P : y 2  12 x. Suppose that the tangent T1 touches P and E at the points A1 and
A2 , respectively and the tangent T2 touches P and E at the points A4 and A3 ,
respectively. Then which of the following statements is (are) true?
A) The area of the quadrilateral A1 A2 A3 A4 is 35 square units
B) The area of the quadrilateral A1 A2 A3 A4 is 36 square units
C) The tangents T1 and T2 meet the x-axis at the point 3,0
D) The tangents T1 and T2 meet the x-axis at the point 6,0

Ans. AC
A1 y 2  12 x
A2
x2 y 2
 1
6 3
A3
A4
Sol.
Consider the equation of tangent as y  mx  c
Page 3
3 3
y  mx  c Tangent to y 2  12 x  c  y  mx 
m m
x2 y2
It is also tangent to ellipse  1
6 3
2
 3 9
 m  
    6 m 2  3  2  6m 2  3
m
6m4  3m2  9  0
3
m 2  1, (Not possible)
2
m  1
y  x  3, y   x  3 Are the tangents
Point of intersection of tangents is (–3, 0)
A1  3,6 A2  2,1 A3  2, 1 A4  3, 6
Area of quadrilateral A1 A2 A3 A4
1 3 2 2 3 3

2 6 1 1 6 6
1 1
  3  12   2  2  12  3  18  18  70  35 sq.units
2 2
x3 5 17
3. Let f : 0,1  0,1 be the function defined by f  x   x 2  x  . Consider the
3 9 36
square region S  0,10,1. let G   x, y   S ; y  f  x be called the green region
and R   x, y   S ; y  f  x be called the red region. Let Lh   x, h  S ; x  0,1 be
the horizontal line drawn at a height h   0,1. Then which of the following statements is
(are) true?
Page 4
 1 2
A) There exists an h   ,  such that the area of the green region above the line Lh
 4 3 
equals the area of the green region below the line Lh
 1 2
B) There exists an h   ,  such that the area of the red region above the line Lh equals
 4 3 
the area of the red region below the line Lh
 1 2
C) There exists an h   ,  such that the area of the green region above the line Lh
 4 3 
equals the area of the red region below the line Lh
 1 2
D) There exists an h   ,  such that the area of the red region above the line Lh equals
 4 3 
the area of the green region below the line Lh
Ans. BCD
x3 5 17
Sol. f  x    x2  x 
3 9 36
3x2 5 5 2 4
f /  x   2 x   x 2  2 x    x  1 
3 9 9 9
1 5
f /  x  0  x  ,
3 3
1 Green region  1 181

 3 , 321
y=f(x)
 13 
17  1, 
Red region 36
36
0 1 1 2 0 1
3
1
3
1 1
A)  1  h dx    h  f  x dx if h lies above y = f(x)
0 0
Page 5
1 3
1  2h  h   A is incorrect.
2 4
1 1
B)  hdx    f  x  h dx
0 0
1 1
 2h   h  if h lies below the curve y = f(x)  B is correct
2 4
1
1 1
C&D) Area of green region =  1  f  x  dx  1  2  2
0
1
1 1
Area of red region =  1  f  x dx  1  2  2
0
12
A2
3
A1 yh
A3
1
4
0 1
3
1
1 1
 A2    A2  A3   Option C 
2 2
 A2  A1  A3  Option D
By using intermediate value theorem  Option C and D are correct
y = f(x) is a curve, x = h is a line which divides the curve such that the area between the
line and curve are equal.
Page 6
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: −1 in all other cases
 1 1
4. Let f : 0,1   be the function defined as f  x   n if x   ,  where n  . Let
 n  1 n 
x
1 t
g : 0,1   be a function such that  dt  g  x   2 x for all x  0,1. Then
x2
t
lim f  x  g  x 
x 0
A) Does NOT exist B) is equal to 1

C) is equal to 2 D) is equal to 3
Ans. C
 1 1
Sol. f  x   n , x   , 
 n 1 n
1 1 1
 x   n 1  n
n 1 n x
1 1 1 1
 n   1 and n   n  1 and n
x x x x
lim f  x g  x  ______
x 0
x x
1 t 1 t
 t
dt  g  x   2 x  f  x  t

dt  f  x  g  x   f  x  2 x 
2 2
x x
 x 
1 t 1  1
 
 2 t
dt    1  f  x g  x  
  x  x
2 x  
x
 x 
1 t 1 
 lim   dt    1  lim f  x  g  x   lim 2
x 0  2 t   x  x0 x 0
x 
Page 7
 2
  x 1  x   x 1  x  sin
1
x  sin 1  x   1  x 

 lim    lim f  x  g  x   2
x 0  x  x 0
 
 1  0  1  0  lim f  x g  x  2
x0
 lim f  x g  x  2
x0
5. Let Q be the cube with the set of vertices  x1 , x2 , x3    3 : x1 , x2 , x3  0,1. Let F be
the set of all twelve lines containing the diagonals of the six faces of the cube Q. Let S
be the set of all four lines containing the main diagonals of the cube Q; for instance, the
line passing through the vertices 0,0,0 and 1,1,1 is in S. For lines l1 and l2 , let
d l1, l2  denote the shortest distance between them. Then the maximum value of d l1 , l2 ,
as l1 varies over F and l2 varies over S , is
1 1 1 1
A) B) C) D)
6 8 3 12
Ans. A
Sol.
(0,0,1) (1,0,1)
F G
(0,1,1)
E D
(1,1,1)
O A
(1,0,0)
B C
(0,1,0) (1,1,0)

F  OG, AF , BD, CE , CG , AD, BF , OE , DF , GE , OC , AB 
S   OD, BG, CF , AE
i) AF , OD
AF  1,0,0  t 1,0  1
Page 8
OD   0,0,0  s 1,1,1
1 0 0
1 0 1
1 1 1 1 1
Shortest distance = = =
i j k i 1  j  2  k 1 6
1 0 1
1 1 1
ii) OD, AB
OD = (0, 0, 0) + S (1, 1, 1)
AB  1,0,0   1, 1,0
1 0 0
1 1 0
1 1 1 1
Shortest distance = 
i j k 6
1 1 1
1 1 0
iii) OD, BF
OD = (0, 0, 0) + s (1, 1, 1)
BF = (0, 1, 0) + r  0,1, 1
1
Shortest distance =
6
1
 Similarly for other lines also the value will be
6
   
For OD, DF OD, AD OD, OC the shortest distance is zero.
1
So, Maximum value of d  1,  2  is
6
Page 9
 x2 y 2 
6. Let X    x , y      :   1and y 2
 5 x . Three distinct points P, Q and R are
 8 20 
randomly chosen from X . Then the probability that P, Q and R form a triangle whose
area is a positive integer, is
71 73 79 83
A) B) C) D)
220 220 220 220
Ans. B
Sol.
 2, 10 
 0,0
 2,  10 
x2 y2
 1 y 2  5x
8 20
x2 5x x2 x
 1   1  x2  2 x  8
8 20 8 4
2
  x  1  9 x2
x  1, y 2  5  y  5
(1, 0) (1, 1) (1, 2) (1, –1) (1, –2)
(2, 0) (2, 1) (2, 2) (2, 3) (2, –1) (2, –2) (2, –3)
Number of ways to select 3 points = 12 C3
12  11  10
= = 2  11  10 =220
6
Area of e PQR is an integer
Triangle has two vertices on x = 1 or x = 2
1, y11, y2   2, y3  (or) 1, y3   2, y1  2, y2 
Page 10
1
Area of e  1  y1  y2 
2
 y1  y2  is an even integer

Number of ways = 3 C2  2C2 7C1 for x  1 
 
= 4 C2  3C2 5C1 for x  2
Number of triangles = 28 + 45 = 73
73
Probability =
220
7. Let P be a point on the parabola y 2  4ax, where a  0. The normal to the parabola at
P meets the x-axis at a point Q. The area of the triangle PFQ, where F is the focus of
the parabola, is 120. If the slope m of the normal and a are both positive integers, then
the pair a, m is
A) 2,3 B) 1,3 C)  2, 4 D) 3, 4
Ans. A
Normal Tangent
F Q
Sol.

P at 2 ,2at 
Equation of normal is tx + y = 2at + at 3

Q 2a  at 2 ,0  F  a,0 
P at 2 ,2 at 
Area of e PFQ = 120
1
 
 a  at 2  2at   120
2
 
 a 1  t 2  at   120
Page 11
Slope of normal = – t
– t, a are integers
 
 a 2t 1  t 2  120    815 = –2(4) (3.5) = –4(3) (10)
m = – t = 3, a = 2
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
Designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks: +4 If ONLY the correct integer is entered; Zero Marks: 0 in all other cases.
  
8. Let tan 1  x   ,  , for x  . Then the number of real solutions of the equation
 2 2 
 3         3 
1  cos 2 x   2 tan 1  tan x  in the set  ,     ,    ,  is equal to
 2 2   2 2   2 2 
Ans. 3
1  cos  2 x   2 tan 1  tan x 
2 cos x  2 tan 1  tan x

2
1
No. of solutions = 3
3 0  3
 
2 2 2 2


2
Sol.
Page 12
9. Let n  2 be a natural number and f :  0,1   be the function defined by
 1
 n 1  2 nx  if 0  x 
 2n

 2 n  2nx 1 if 1  x  3

f  x   
2n 4n
 3 1
 4n 1  nx  if x
 4n n
 n 1
 nx  1 if  x  1
 n 1 n
If n is such that the area of the region bounded by the curves x  0, x  1, y  0 and
y  f  x  is 4, then the maximum value of the function f is

Ans. 8
 1
 n 1  2nx  , if 0 x
2n

 2n  2nx  1 1 3
, if  x
 2n 4n
Sol. y  
 4n 1  nx  3 1
, if x
 4n n
 n 1
  nx  1 , if  x 1
n 1 n
1
if y  n 1  2nx  if y  0  x  and if x  0  y  n
2n
1 3
if y  2n  2nx  1  if y  0  x  and if x   yn
2n 4n
1 1
if y  4n 1  nx  if y  0  x  and if x   y  n
n n
n 1
y  nx  1 , if y  0  x  and if x  1  y  n
n 1 n
Page 13
y
A1 A2 A3
0 x
1 3 1 1
2n 4n n
1 1 1 1 1  1
A1  . . n , A2  . . n , A3  1   . n
2 2n 2 2n 2  n
Total Area = A1  A2  A3  4
1 1 1 1 1  1 1 1 7
 . . n  . . n  1   . n  4   n  1  4    n  8
2 2n 2 2n 2  n 2 2 2
Maximum value of y = n = 8

r 
10. Let 75.......57 denote the  r  2 digit number where the first and the last digits are 7
and the remaining r digits are 5. Consider the sum

99 

98 
7 5.......57  m
S  77  757  7557  ......  75.......57 If S  , where m and n are
n
natural numbers less than 3000, then the value of m  n is
Ans. 1219
98
Sol. S  77  757  7557  ........  75.......57
 
= 7 10  102  103  .....  1099  50 1  11  111  .......  7  99
7 10100  10 50
=  10  1  102  1  ....  1098  1  7  99
9 9
Page 14
7  10100 70 50  1099  10 
=     98  7  99
9 9 9  9 
50 99
=
7  10100 
9 
10  1 50 
  99  7  99 
70
9 9 9
50 99
=
7  7  10100 
9  
10  1  1280  70
9
 99
75.......57  1210
=  m  1210, n  9
9
m + n = 1219
1967  1686i sin  
11. Let A   :   . If A contains exactly one positive integer n, then
 7  3i cos  
the value of n is
Ans. 281
1967  1686 i sin  7  3i cos
Sol. 
7  3i cos  7  3i cos 
=
1967  1686 i sin   7  3i cos 
49  9cos 2 
1967 7  1686 3 sin  cos   i 1967 3cos   1686sin   7
=
49  9cos 2 
 Imaginary part = 0
 5901 cos   11802sin   0
1
 tan  
2
Page 15
1   2 
1967 7  1686 3   
5  5 68845  10116
n   281
 4  245  36 
49  9   5 
 5  5
12. Let P be the plane 3 x  2 y  3 z  16 and let

 7
S  iˆ   ˆj   kˆ :  2   2   2  1and the distance of ,  ,   from the plane P is .
 2 
        
Let u , v and w be three distinct vectors in S such that u  v  v  w  w  u . Let V
  
be the volume of the parallelepiped determined by vectors u , v and w. Then the value of
80
V is
3
Ans. 45
O
x

B v

A u
xQ
 
C w
P1
P xP
Sol.
Let P : 3 x  2 y  3 z  16
7
Let P1 bet the plane which is at a distance of units from P.
2
   
Let A u , B v , C w are 3 points on P1 such that u  v  w  1 and
u v  vw  wu
Page 16
Let P and Q are the projections drawn from origin ‘O’ to the planes P and P1 respectively.
7 1
 OP  4, QP   OQ  and OA = OB = OC = 1
2 2
1 3
 AQ  BQ  CQ  1  
4 2
3 3 3 3  1
 AB    2. .  
4 4 2 2  2
 e ABC is equilateral triangle and Q be its circumcentre)
u .u u . v u . w
3 9 1 2
 u  v   1  1  2u . v   u . v  and u v w   v .u v .u v . w
2 4 8
w.u w. v w. w
1 1
1
8 8
1 1  1  1  1 1  1  1 1
= 1  1           
8 8  64  8  8 64  8  64 8 
1 1
1
8 8
 1  2  1 1  243 9 3 80V
= 1         V  u vw    45
 64  8  8 64  256 16 3
13. Let a and b be two nonzero real numbers. If the coefficient of x 5 in the expansion of
 2   
4 7
 ax  70  is equal to the coefficient of x5 in the expansion of ax  1 2  , then the
 27bx   bx 
value of 2b is
Ans. 3
4 r
 2 70  2 4  r  70 
Sol. In  ax 
 27bx 
4
 , General term Tr 1  Cr ax    
27bx 
Page 17
r
4 4  r  70  8 3r
= Cr a   . x
27b
7 S
 1  7 7S  1 
In  ax   , General term TS 1  CS  ax    
 bx 2  bx 2 
S
7  S  1
7
= CS . a .  . x 7  3 S
 b
4 7
 70   1 
5
Given that coefficient of x in  ax 2   = coefficient of x 5 in  ax  2 
 27bx   bx 
4 2
4 3  70  7 3  1 70 1
 C1 . a   C4 . a    4.  35 .
 276   b 27b b4
27 3
 b3   b   2b  3
8 2
Page 18
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists: List-I and List-II.
 List-I has four entries (I), (II), (III) and (IV) and List-II has five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
Full Marks: +3 ONLY if the option corresponding to the correct combination is chosen;
14. Let ,  and  be real numbers. Consider the following system of linear equations
x  2y  z  7
x   z  11
2x  3 y   z  
Match each entry in List-I to the correct entries in List-II.
List-I List-II
1
(P) If   7  3 and   28, then the
2
system has (1) a unique solution
1
(Q) If   7  3 and   28, then the
2
system has (2) no solution
1
(R) If   7  3 where   1 and   28,
2
then the system has (3) infinitely many solutions
1
(S) If   7  3 where   1 and   28,
2
then the system has (4) x  11, y  2 and z  0 as a
solution
(5) x  15, y  4 and z  0 as a
solution
The correct option is:
A) P – 3, Q – 2, R – 1, S - 4 B) P – 3, Q – 2, R – 5, S - 4
C) P – 2, Q – 1, R – 4, S - 5 D) P – 2, Q – 1, R – 1, S – 3
Ans. A
Page 19
Sol. x + 2y + z = 7 _______ (1)
x   z  11 _______ (2)
2x  3y   z   _______ (3)
7 3  2 21  2
3  1  2   3  7 x  z  3  2   21  2 If  
1  11
1
 7  3  2     7  3 and 77  21  2  r  28
2
1
If    7  3 and   28 then the system has infinitely many solutions  P  3
2
1
If    7  3 and   28 , then the system has no solution  Q  2
2
1
If    7  3 , where   1 and   28 , then the system has unique solution  R  1
2
1
If    7  3 where   1 and   28 , then x = 11, y  2 , z = 0 is a solution to the
2
given system S  4 .
15. Consider the given data with frequency distribution
xi 3 8 11 10 5 4
fi 5 2 3 2 4 4
List-I List-II
(P) The mean of the above data is (1) 2.5
(Q) The median of the above data is (2) 5
(R) The mean deviation about the mean
of the above data is (3) 6
(S) The mean deviation about the
median of the above data is (4) 2.7
(5) 2.4
A) P – 3, Q – 2, R – 4, S – 5 B) P – 3, Q – 2, R – 1, S – 5
C) P – 2, Q – 3, R – 4, S – 1 D) P – 3, Q – 3, R – 5, S – 5
Ans. A
Page 20
Sol. xi fi c. fi
3 5 5
4 4 9
5 4 13
8 2 15
10 2 17
11 3 20
x
 fi xi  6  P  3 N  20,
N
 10
 fi 2
Median = Size of observation whose cumulative frequency just greater than or equal
to 10= 5 Q2
fi xi  x
Median deviation about mean =  2.7 R4
fi
fi xi  M
Mean deviation about median = = 2.4 S 5
fi
 
16.      
Let l1 and l2 be the lines r1   iˆ  ˆj  kˆ and r2  ˆj  kˆ   iˆ  kˆ , respectively. Let
X be the set of all the planes H that contain the line l1. For a plane H , let d  H  denote
the smallest possible distance between the points of l2 and H . Let H 0 be a plane in X
for which d  H 0  is the maximum value of d  H  as H varies over all planes in X .
List-I List-II
(P) The value of d  H 0  is (1) 3
(Q) The distance of the point (0, 1, 2)
1
from H 0 is (2)
3
(R) The distance of origin from H 0 is (3) 0
(S) The distance of origin from the
point of intersection of planes
y  z , x  1 and H 0 is (4) 2
1
(5)
2
Page 21
A) P – 2, Q – 4, R – 5, S – 1 B) P – 5, Q – 4, R – 3, S – 1
C) P – 2, Q – 1, R – 3, S – 2 D) P – 5, Q – 1, R – 4, S – 2
Ans. B

Sol. 1 : r1    i  j  k   a   b

 2 : r2  j  k    i  k   c   d
0 1 1
Here,  a  c b d   1 1 1 1 0
1 0 1
 1 and  2 are skew – lines.

 H 0 is the plane containing 1 and parallel to  2
x y z
 Equation of H 0 is 1 1 1  0  x  z  0
1 0 1
1
P) d  H 0  = Shortest distance between 1 and  2 =
2
02
Q) d   2
2
00
R) d  0 H 0 passes through (0, 0, 0)
2
S) Point of intersection of given planes and H 0 is (1, 1, 1)
Distance from origin = 1  0 2  1  0 2  1  0 2  3

P  5, Q  4, R  3, S  1
Page 22
3
17. Let z be a complex number satisfying z  2 z 2  4 z  8  0, where z denotes the
complex conjugate of z. Let the imaginary part of z be nonzero.
List-I List-II
2
(P) z is equal to (1) 12
2
(Q) z  z is equal to (2) 4
2 2
(R) z + z  z is equal to (3) 8
2
(S) z  1 is equal to (4) 10
(5) 7
A) P – 1, Q – 3, R – 5, S – 4 B) P – 2, Q – 1, R – 3, S – 5
C) P – 2, Q – 4, R – 5, S – 1 D) P – 2, Q – 3, R – 5, S – 4
Ans. B
Sol. Let z = x + iy
3
 
  x 2  y 2   2 x 2  y 2  4 x  8  i  4 xy  4 y   0
 
If 4xy – 4y = 0  x = 1  y  0
3

If x  1   1  y 2   2 1  y 2  4  8  0
  
  1  y2   2 1  y 2
   
 y2  1  4  y2  3
  
 z  1  i 3  or  1  i 3 
Page 23
2 2 2 2
 z  4, z  z  12, z  z  z  8
2
z 1  7
P  2, Q  1, R  3, S  5
Page 24
PHYSICS Max Marks: 60
SECTION – I
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s).
Full Marks: +4 ONLY if (all) the correct option(s) is (are) chosen;
Partial Marks: +3 if all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 if three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 if two or more options are correct but ONLY two options are chosen, and it is a correct option;
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks..
18. A slide with a frictionless curved surface, which becomes horizontal at its lower end, is
fixed on the terrace of a building of height 3h from the ground, as shown in the figure. A
spherical ball of mass m is released on the slide from rest at a height h from the top of

the terrace. The ball leaves the slide with a velocity u0  u0 xˆ and falls on the ground at a
distance d from the building making an angle  with the horizontal. It bounces off with

a velocity v and reaches a maximum height h1. The acceleration due to gravity is and
1
the coefficient of restitution of the ground is . Which of the following statement(s)
3
is(are) correct?
 
A) u0  2 ghxˆ B) v  2 gh  xˆ  zˆ
d
C)   60 D) 2 3
h1
Key: - ACD
Page 25
Sol:- By conserving energy
1
mgh  mV02
2
V0  2gh

V0  2 gh x
After loosing contact with wedge
V y2  V y2  2as V y2  0  6 gh V y  6 gh
Vy 2  3h
tan    3   600 d  V0t d  2 gh  2 3h
Vx g
V y1 1
After collision,  e  V y1  6 gh V y1  2 gh
Vy 3
V y2 d
h1  h  2 3
2g h1
19. A plane polarized blue light ray is incident on a prism such that there is no reflection
from the surface of the prism. The angle of deviation of the emergent ray is   60 (see
Figure-1). The angle of minimum deviation for red light from the same prism is
min  30 (see Figure-2). The refractive index of the prism material for blue light is 3.
Which of the following statement(s) is(are) correct?
A) The blue light is polarized in the plane of incidence.

B) The angle of the prism is 45°.
C) The refractive index of the material of the prism for red light is 2 .
D) The angle of refraction for blue light in air at the exit plane of the prism is 60°
Key :- ACD
Page 26
Sol:- brewstr’s angle  tan 1     600

 ie A
60  60  e  A
e A
1sin 60  3 sin r1  r1  30
3sin  A  r1  sin A
3sin Acos30  3 cos Asin30  sin A
sin A 3
 cos A A  600
2 2
 sin  A   30  60 
sin  sin 
 2   2 
   2
A  60 
sin sin  
2  2
20. In a circuit shown in the figure, the capacitor C is initially uncharged and the key K is
open. In this condition, a current of 1 A flows through the 1 resistor. The key is closed
at time t  t0 . Which of the following statement(s) is(are) correct?
[Given: e1  0.36 ]
A) The value of the resistance R is 3.

B) For t  t0 , the value of current I1 is 2 A.
C) At t  t0  7.2S , the current in the capacitor is 0.6 A.
D) For t  , the charge on the capacitor is 12C.
Page 27
Key :- ABCD
Sol:- By applying kirchoff’s law
15   i1  1 R  5  11  i1  3  i1  2  R3
Potential difference across capacitor before closing the switch
3  2  3  6V  qmax  CV  2  6 C
qmax  12C
1 3 18
Req   3 Req   3    ReqC
1 1 5 3
 1
3 3
 t 
18
  2  7.2 s q  12c 1  e  
3  
t
12c  12
i e imax   0.36  0.6
 7.2
SECTION – II
Negative Marks : −1 In all other cases
21. A bar of mass M  1.00 kg and length L  0.20 m is lying on a horizontal frictionless
surface. One end of the bar is pivoted at a point about which it is free to rotate. A small
mass m  0.10 kg is moving on the same horizontal surface with 5.00ms1 speed on a
L
path perpendicular to the bar. It hits the bar at a distancefrom the pivoted end and
2
returns back on the same path with speed v. After this elastic collision, the bar rotates
with an angular velocity . Which of the following statement is correct?
A)   6.98 rad s1 and v  4.30 ms1 B)   3.75 rad s1 and v  4.30 ms1
C)   3.75 rad s1 and v  10.0 ms1 D)   6.80 rad s1 and v  4.10 ms1
Page 28
Key :- A
Sol:-Before collision
O
5
O 
After collision
v
O
O 
Conserving angular momentum about O.
L L ML2
mv0   mv  
2 2 3
2
0.2 0.2 1 0.2 4
0.1  5   0.1v    5  v 
2 2 3 3
since collision is elastic,
Velocity of approach = velocity of separation
0.2
50  v
2
 300
5v   6.98 v  4.30
10 43
Page 29
22. A container has a base of 50 cm  5 cm and height 50 cm, as shown in the figure. It has
two parallel electrically conducting walls each of area 50 cm  50 cm. The remaining
walls of the container are thin and non-conducting. The container is being filled with a
liquid of dielectric constant 3 at a uniform rate of 250 cm3s1. What is the value of the
capacitance of the container after 10 seconds?
[Given: Permittivity of free space 0  9 1012 C 2 N 1m2 , the effects of the non-
conducting walls on the capacitance are negligible]
A) 27 pF B) 63 pF C) 81 pF D) 135 pF
Key :- B
Sol:- 2500 = 250 y y = 10
3  9  1012  500  104 20 0 0  104
C 9  1012  2
 63  1012 F
2 5  10
5  10
23. One mole of an ideal gas expands adiabatically from an initial state TA ,V0  to final state
T f ,5V0 . Another mole of the same gas expands isothermally from a different initial
state TB ,V0  to the same final state T f ,5V0 . The ratio of the specific heats at constant
TA
pressure and constant volume of this ideal gas is  . What is the ratio ?
TB
A) 51 B) 51 C) 5 D) 51
Key :- A
 1 TA
Sol:- TAV  1 = TB  5V0   5 1
TB
Page 30
24. Two satellites P and Q are moving in different circular orbits around the Earth (radius ).
The heights of P and Q from the Earth surface are hP and hQ , respectively, where
R
hP  . The accelerations of P and Q due to Earth’s gravity are g P and gQ , respectively.
3
g P 36
If  , what is the value of hQ ?
g Q 25
A) 3 /5 B) /6 C) 6 /5 D) 5 /6
Key :- A
1
2
 R
gP  4 
3
Sol:- 
gQ 1
 R  h 2
2 2
36 9  R  h 64  h 3R
  1   h
25 16 R 2 25  R 5
SECTION-III
(INTEGER ANSWER TYPE)
• This section contains EIGHT (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
25. A Hydrogen-like atom has atomic number . Photons emitted in the electronic
transitions from level n  4 to level n  3 in these atoms are used to perform
photoelectric effect experiment on a target metal. The maximum kinetic energy of the
photoelectrons generated is 1. 95 eV. If the photoelectric threshold wavelength for the
target metal is 310 nm, the value of is _______.
[Given: hc  1240 eV  nm and Rhc  13.6 eV , where R is the Rydberg constant, h is
the Planck’s constant and c is the speed of light in vacuum]
Key :- 3
Page 31
Sol:- K .Emax  E photon  
E photon  K .Emax   E photon  5.95eV
 1 1 7
13.6 Z 2  2  2   5.95 Z 2  13.6   5.95 Z2  9 Z 3
3 4  144
26. An optical arrangement consists of two concave mirrors M 1 and M 2 , and a convex lens
L with a common principal axis, as shown in the figure. The focal length of L is 10 cm.
The radii of curvature of M 1 and M 2 are 20 cm and 24 cm, respectively. The distance
between L and M 2 is 20 cm. A point object S is placed at the mid-point between L and
M 2 on the axis. When the distance between L and M 1 is n / 7 cm, one of the images
coincides with S. The value of n is _______.
Key :- 80 or 220 or 150

Sol:-
f =10 cm f =10 cm f = 12 cm
I '' I1
O V
V = 60
80 20 cm
V' U '  80
7
Page 32
1 1 1 1 1 1
   
V 10 12 V 10 12
V  60 U |  60  20
1 1 1 80
U |  80   V
V | 80 10 7
This image should be at centre of curvature of M 1 (or) at pole of M1
for the image to be formed at object itself
80 80 220
distance between M & L can be Or 20  
7 7 7
 n  80 (or) 220
If lens forms first image then it becomes parallel light beam and falls on mirror which
forms image at 10cm from M 1 then it again falls on lens and then again it M 2 and finally
image is formed at object.
1 1 1 1 8 1 80 150
    x  10 x
80 x  10 10 x  10 80 80 7 7
27. In an experiment for determination of the focal length of a thin convex lens, the distance
of the object from the lens is 10  0.1cm and the distance of its real image from the lens
is 20  0.2 cm. The error in the determination of focal length of the lens is n%. The value
of n is _______.
Key :- 1
1 1 1 1 1 1 20
Sol:-     f 
v v f 20 10 f 3
f U V f  0.2 0.1  20
    
f 2 U2 V2 f  400 100  3
f 0.6 20 f
 100    100  100  1%
f 400 3 f
Page 33
28. A closed container contains a homogeneous mixture of two moles of an ideal monatomic
 5  7
gas    and one mole of an ideal diatomic gas   . Here,  is the ratio of the
 3  5
specific heats at constant pressure and constant volume of an ideal gas. The gas mixture
does a work of 66 Joule when heated at constant pressure. The change in its internal
energy is ________ Joule.
Key :- 121
Sol:-Work done = nRT

66  3RT
RT  22
3  5
U  2  RT   1 RT
2  2
11
U  RT U  121J
2
29. A person of height 1.6 m is walking away from a lamp post of height 4 m along a
straight path on the flat ground. The lamp post and the person are always perpendicular to
the ground. If the speed of the person is 60 cms1 , the speed of the tip of the person’s
shadow on the ground with respect to the person is _______ cm s1
Key :- 40
Sol:-s
4 1.6
tan   
x1  x2 x2
5
 x  x   x2
2 2 1
3
x2  x1
2
Differentiating it
3 dx2 dx1 dx2 2
   60 Vr  40
2 dt dt dt 3
Page 34
30. Two point-like objects of masses 20 gm and 30 gm are fixed at the two ends of a rigid
massless rod of length 10 cm . This system is suspended vertically from a rigid ceiling
using a thin wire attached to its center of mass, as shown in the figure. The resulting
torsional pendulum undergoes small oscillations. The torsional constant of the wire is
1.2108 N m rad 1 . The angular frequency of the oscillations in n 103 rad s1 . The
value of n is _____
Key :- 10
Sol:- I    K
K K
   
I I
2 2
 m2   m1 
I  m1    m2 
 m1  m2   m1  m2 
 mm  1.2  108
I   1 2  2  
 m1  m2  60
 103  102
5
  102   n  103  n  10
Page 35
SECTION – IV
(MATCHING TYPE)
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Negative Marks: –1 In all other cases.
31. List-I shows different radioactive decay processes and List-II provides possible emitted
particles. Match each entry in List-I with an appropriate entry from List-II, and choose
the correct option.
List-I List-II
P) 238
92 U  91
234
Pa 1) one  particle and one   particle
Q) 214
82 Pb  82
210
Pb 2) three   particles and one  particle
R) 210
81 T   82
206
Pb 3) two   particles and one  particle
S) 228
91 Pa  88
224
Ra 4) one  particle and one   particle
5) one  particle and two   particles
A) → 4, → 3, → 2, →1 B) → 4, → 1, → 2, →5
C) → 5, → 3, → 1, →4 D) → 5, → 1, → 3, →2
Key :- A

Sol:- ZA X   ZA24 X  

A
Z X   Z A1Y   

A
Z X   Z A1Y   
238
92 U  91
234
Pa 42 He 0 1 e
214
82 Pb  82
210
Pb 42 He  20 1 e
210
81 T   82
206
Pb 42 He  30 1 e
228
91 Pa  88
224
Ra 24 He 01 e
Page 36
32. Match the temperature of a black body given in List-I with an appropriate statement in
List-II, and choose the correct option.
hc
[Given: Wien’s constant as 2.9103 m  K and  1.24 106 V  m ]
e
List-I List-II
(P) 2000 K (1) The radiation at peak wavelength can lead to emission of
photoelectrons from a metal of work function 4 eV.
(Q) 3000 K (2) The radiation at peak wavelength is visible to human eye.
(R) 5000 K (3) The radiation at peak emission wavelength will result
in the widest central maximum of a single slit diffraction.
(S) 10000 K (4) The power emitted per unit area is 1/16 of that
emitted by a blackbody at temperature 6000 K.
(5) The radiation at peak emission wavelength can be
used to image human bones.
A) → 3, → 5, → 2, →3 B) → 3, → 2, → 4, →1
C) → 3, → 4, → 2, →1 D) → 1, → 2, → 5, →3
Key :- C
hc hc
Sol:-   b EP  EP  T T  2000 K
 b
 is maxima therefore widest central maxima For T = 3000 K.
1
P of P of black body at 6000K For T = 5000 K
16
 580nm so part of visible spectrum
For T 10,000K
E  4.1eV it can emit photons from metal of work function 4eV
Page 37
33. A series LCR circuit is connected to a 45sin t  Volt source. The resonant angular
frequency of the circuit is 105 rad s1 and current amplitude at resonance is I 0 . When the
angular frequency of the source is   8104 rad s1 , the current amplitude in the circuit
is 0.05 I 0 . If = 50 mH, match each entry in List-I with an appropriate value from List-II
and choose the correct option.
List-I List-II
(P) I 0 in mA (1) 44.4
(Q) The quality factor of the circuit (2) 18
(R) The bandwidth of the circuit in rad s1 (3) 400
(S) The peak power dissipated at resonance in Watt (4) 2250
(5) 500
A) → 2, → 3, → 5, →1 B) → 3, → 1, → 4, →2
C) → 4, → 5, → 3, →1 D) → 4, → 2, → 1, →5
Key :- B
1
Sol:-  0 
LC
V
C  2  109 F I0  0
R
5 V0 9  103
I0  R 
100 2 4 399
R2   X L  X C 
V
R  112.5  I0  0  400mA
R
1 L r 
Q  44.4 Q   Bandwidth  r
R C Band width Q
V2
B.  = 2250 Hz Peak power  0  18 watt
R
Page 38
34. A thin conducting rod MN of mass 20 gm, length 25 cm and resistance 10 is held on
frictionless, long, perfectly conducting vertical rails as shown in the figure. There is a
uniform magnetic field B0  4T directed perpendicular to the plane of the rod-rail
arrangement. The rod is released from rest at time = 0 and it moves down along the
rails. Assume air drag is negligible. Match each quantity in List-I with an appropriate
value from List-II, and choose the correct option.
[Given: The acceleration due to gravity g  10 ms2 and e1  0.4 ]
List-I List-II
(P) At = 0.2 s, the magnitude of the induced emf in Volt (1) 0.07
(Q) At = 0.2 s, the magnitude of the magnetic force in Newton (2) 0.14
(R) At = 0.2 s, the power dissipated as heat in Watt (3) 1.20
(S) The magnitude of terminal velocity of the rod in m s1 (4) 0.12
(5) 2.00
A) → 5, → 2, → 3, → 1 B) → 3, → 1, → 4, → 5
C) → 4, → 3, → 1, → 2 D) → 3, → 4, → 2, → 5
Key. D
dv B 2 2v v dv t 1 g  kv
Sol.  g   g  kv 0 g  kv 0 dt
  n t
dt mR k g
 B 22 
1 g  kv g mgR  
 n
k g
t
k

v  1  e kt  v  2 2 1  e mR t 
B   


0.2  10  1
2 
 1  e 5 0.2   2 1     4  0.25  1.2 = 1.2
 e
16   0.25
2 
P 0.14   1.2 VT  2 FB  = 0.12
R R
Page 39
CHEMISTRY Max Marks: 60
SECTION – I
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Negative Marks : –2 In all other cases.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks..
35. The correct statement(s) related to processes involved in the extraction of metals is(are)
A) Roasting of Malachite produces Cuprite.
B) Calcination of Calamine produces Zincite.
C) Copper pyrites is heated with silica in a reverberatory furnace to remove iron.
D) Impure silver is treated with aqueous KCN in the presence of oxygen followed by
reduction with zinc metal.
Key: BCD
Sol: A) Roasting of malachite produce cupric oxide  CuO not cuprite  Cu2O
B) Calcination of calamine  ZnCO3  produce zincite  ZnO 
C) Copper pyrite is heated with silica to remove iron as ferrous silicate FeSiO3
D) Statement D is correct
Page 40
36. In the following reactions, P,Q,R and S are the major products
The correct statement(s) about P,Q,R and S is(are)

A) Both P and Q have asymmetric carbon(s).
B) Both Q and R have asymmetric carbon(s).
C) Both P and R have asymmetric carbon(s).
D) P has asymmetric carbon(s), S does not have any asymmetric carbon.
Key: CD
Sol:
Page 41
Page 42
37. Consider the following reaction scheme and choose the correct option(s) for the major
products Q,R and S.
A)
B)
C)
D)
Key: B
Page 43
Sol:
Page 44
SECTION – II
Negative Marks : −1 In all other cases
38. In the scheme given below, X and Y , respectively, are
A) CrO42 and Br2 B) MnO42 and Cl2 C) MnO4 and Cl2 D) MnSO4 and HOCl
Key: C
Sol: Metal halide is MnCl2
MnCl2  NaOH 
 Mn (OH ) 2  2 NaCl
(P) (Q)
2 Mn  OH  2  5 H 2 SO4  PbO2 
 PbSO4  2 HMnO4  4 H 2O
(P) (X)
2 NaCl  2 H 2 SO4  MnO(OH ) 2 

 Cl2  Na2 SO4  MnSO4  3H 2O
(Q) (Y)
Page 45
39. Plotting 1 / m against c  m for aqueous solutions of a monobasic weak acid (HX)
resulted in a straight line with y-axis intercept of P and slope of S. The ratio P/S is
[ m = molar conductivity
0m = limiting molar conductivity
c = molar concentration
K a = dissociation constant of HX]
A) K a m0 B) K a 0m /2 C) 2 K a 0m D) 1 /  K a 0m 
Key: A
c 2
Sol: m  K a 
1 
  
2

c  0 
m
 m 
Ka 

1  0m
m
 
2

K a  K a . 0m  c  0m 
m   
m
Ka Ka c m 1
 0   0
m m 0  2
m
m
1 c m 1
  0
m K .0 2
m
a m
1
S
K a .0m 
2
1
P
0m
P 1
 0  K a .m0 
2
S m
 K a . m0
Page 46
40. On decreasing the H from 7 to 2, the solubility of a sparingly soluble salt (MX) of a
weak acid (HX) increased from 104 mol L1 to103 mol L1. The pK a of HX is
A) 3 B) 4 C) 5 D) 2
Key: B
Sol: MX  H 2O  M   aq  X   aq ; K sp  108
K sp
MX  H   M   HX ;
Ka
102 103 103
10 8 10 6
 2  10 4  K a  104  pK a  4
K a 10
41. In the given reaction scheme, P is a phenyl alkyl ether, Q is an aromatic compound; R
and S are the major products.
The correct statement about S is

A) It primarily inhibits noradrenaline degrading enzymes.
B) It inhibits the synthesis of prostaglandin.
C) It is a narcotic drug.
D) It is ortho-acetylbenzoic acid.
Key: B
Sol:
Page 47
SECTION-III
(INTEGER ANSWER TYPE)
• This section contains EIGHT (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. The stoichiometric reaction of 516 g of dimethyldichlorosilane with water results in a
tetrameric cyclic product X in 75% yield. The weight (in g) of X obtained is___.
[Use, molar mass  g mol 1  : H = 1, C = 12, O = 16, Si = 28, Cl = 35.5]
Key: 222
Sol: CH3  2 SiCl2 M.wt=129
To get tetramer, 4 moles must be taken
The M.wt. of tetrameric cyclic product x is 296
If 100% yield is there then 296
75
For 75% yield we get 296   222
100
43. A gas has a compressibility factor of 0.5 and a molar volume of 0.4 dm3mol 1 at a
temperature of 800 K and pressure x atm. If it shows ideal gas behaviour at the same
temperature and pressure, the molar volume will be y dm3mol 1. The value of / is ___.
[Use: Gas constant, R  8102 L atm K 1mol 1 ]
Key: 100
Sol: PV  ZRT
0.5  RT
P  1.25RT  x
0.4
1
1.25 RT  Vm  RT Vm  y
1.25
x 1.25 RT 2
  (1.25) 2 RT  8  102  800  1.25  100
y  1 
 
1.25 
Page 48
1
44. The plot of log k f versus for a reversible reaction A g   P  g  is shown.
T
Pre-exponential factors for the forward and backward reactions are 1015 s1 and 1011 s1 ,
respectively. If the value of log K for the reaction at 500 K is 6, the value of log K b at
250 K is ___.
[K = equilibrium constant of the reaction
k f = rate constant of forward reaction
kb = rate constant of backward reaction]
Key: 5
Kf
Sol: K
Kb
At T  500 K
K f  109
K  106
Kf
 Kb   103
K
K b  1011 e Ea / RT
Ea
e
At 500K, log Kb  11  log10  RT
Page 49
e
3  11  log10  R Ea
500
 log  R Ea
e
10
500
8
e Ea
At 250 k log K b  11  log10
R  250
 11   8 2
 5
log K b  5
45. One mole of an ideal monoatomic gas undergoes two reversible processes
( A  B and B  C ) as shown in the given figure:
A  B is an adiabatic process. If the total heat absorbed in the entire process

( A  B and B  C ) is RT2 ln10, the value of 2 logV3 is ___.
5
[Use, molar heat capacity of the gas at constant pressure, C p ,m  R ]
2
Key: 7
Sol: Q  Q AB  QBC
V 
RT2 ln10  0  1 RT2 ln  3 
 V2 
Page 50
V3
 10
V2
A  B  T .V  1  constant
 1
TV
1 1  T2V2 1
2 2
 60010 3   60 V2  3
2 5
V2  3  10 3
5
V2  10 2
V3  10V2
7
V3  10 2
2 log V3  7
46. In a one-litre flask, 6 moles of A undergoes the reaction A g   P  g . The progress of
product formation at two temperatures (in Kelvin), T1 and T2 , is shown in the figure:
If T1  2T2 and G2  G1   RT2 ln x, then the value of x is ___.

[ G1and G2 are standard Gibb’s free energy change for the reaction at temperatures
T1 and T2 respectively.]
Key: 8
Sol: T1  A  P
t=0 6 0
t = 6 0
KT1  2 T2  A  P
Page 51
t=0 6 0
t = 4 2
1  1
KT2  G20  G10  RT2 ln 2  R  2T2  ln    RT2 ln8 x8
2  2
47. The total number of sp 2 hybridised carbon atoms in the major product P (a non-
heterocyclic compound) of the following reaction is ___.
Key: 28
Sol:
Page 52
SECTION – IV
(MATCHING TYPE)
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Negative Marks: –1 In all other cases.
48. Match the reactions (in the given stoichiometry of the reactants) in List-I with one of
their products given in List-II and choose the correct option.
List-I List-II
(P) P2O3  3 H 2 O  (1) P OOCH 3 Cl2
(Q) P4  3 NaOH  3 H 2O  (2) H 3 PO3
(R) PCl5  CH 3COOH  (3) PH 3
(S) H 3 PO2  2 H 2O  4 AgNO3  (4) POCl3
(5) H 3 PO4
A) P  2; Q  3; R  1; S  5 B) P  3; Q  5; R  4; S  2
C) P  5; Q  2; R  1; S  3 D) P  2; Q  3; R  4; S  5
Key: D
Sol: (P) P2O3  3H 2O 

 2 H 3 PO3
(Q) P4  3NaOH  3H 2O 
 3NaH 2 PO2  PH 3
(R) PCl5  CH 3COOH 

 CH 3COCl  HCl  POCl3
(S) H 3 PO2  2 H 2O  4 AgNO3 

 4 Ag  4 HNO3  H 3 PO4
Page 53
49. Match the electronic configurations in List-I with appropriate metal complex ions in List-
II and choose the correct option.
[Atomic Number: Fe = 26, Mn = 25, Co = 27]
List-I List-II
2
(1)  Fe H 2O 6 
6 0
(P) t2g eg
2
(2)  Mn  H 2O 6 
3 2
(Q) t3g eg
3
(R) e 2t 23 (3) Co  NH 3  
 6 

4 2
(S) t2g eg (4)  FeCl4 
2
(5) CoCl4 
A) P  1; Q  4; R  2; S  3 B) P  1; Q  2; R  4; S  5
C) P  3; Q  2; R  5; S  1 D) P  3; Q  2; R  4; S  1
Key: D
6 0
[Co( NH 3 )6 ]3
Sol: (P) t2 g eg 
[ Mn( H 2O)6 ]2

(Q) t23g eg2 
[ FeCl4 ]
(R) e2t 23 
4 2
[ Fe( H 2O)6 ]2
(S) t2 g eg 
Page 54
50. Match the reactions in List-I with the features of their products in List-II and choose the
correct option.
List-I List-II
(P) (1) Inversion of configuration
(Q) (2) Retention of configuration
(R) (3) Mixture of enantiomers
(S) (4) Mixture of structural isomers

(5) Mixture of diastereomers
A) P  1; Q  2; R  5; S  3 B) P  2; Q  1; R  3; S  5
C) P  1; Q  2; R  5; S  4 D) P  2; Q  4; R  3; S  5
Key: B
Sol: P) As chiral carbon is not involved in the reaction, no change in the configuration
P2
Q) S N 2 reaction of optically pure compound gives inversion of configuration
 Q 1
R)
R3
S)
Page 55
51. The major products obtained from the reactions in List-II are the reactants for the named
reactions mentioned in List-I. Match List-I with List-II and choose the correct option.
List-I List-II
ZnHg , HCl
(P) Etard reaction (1) Acetophenone  
i  KMnO4 , KOH ,
(Q) Gattermann reaction (2) Toulene    
ii SOCl2

(R) Gattermann-Koch reaction (3) Benzene 

CH3Cl
anhyd . AlCl3

(S) Rosenmund reduction (4) Aniline   

NaNO2 / HCl
273278 K
Zn ,
(5) Phenol  
A) P  2; Q  4; R  1; S  3 B) P  1; Q  3; R  5; S  2
C) P  3; Q  2; R  1; S  4 D) P  3; Q  4; R  5; S  2
Key: D
Sol: 1)
2)
Used in Rosenmund reduction  S  2
Page 56
3)
Used in Etard reaction  P  3
4)
Used in Gattermann reaction  Q  4
5) R5
Page 57

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:'{ :::;�, :.: ..

Sri Chaitanva 1nfinit:· ·. ·;'

ALL INDIA OPEN CATEGORY

SINGARAJU VENKAT KOUNDINYA KALLAKURI SAINADH SRIMANTH

Total Qualified Ranks for

C) The tangents T1 and T2 meet the x-axis at the point 3,0

D) The tangents T1 and T2 meet the x-axis at the point 6,0

and R   x, y   S ; y  f  x be called the red region. Let Lh   x, h  S ; x  0,1 be

1 Green region  1 181

A) Does NOT exist B) is equal to 1

1  cos  2 x   2 tan 1  tan x 

2 cos x  2 tan 1  tan x

y  f  x  is 4, then the maximum value of the function f is

12. Let P be the plane 3 x  2 y  3 z  16 and let

 1 and  2 are skew – lines.

Distance from origin = 1  0 2  1  0 2  1  0 2  3

A) The blue light is polarized in the plane of incidence.

Sol:- brewstr’s angle  tan 1     600

A) The value of the resistance R is 3.

Conserving angular momentum about O.

E photon  K .Emax   E photon  5.95eV

Key :- 80 or 220 or 150

Sol:-Work done = nRT

The correct statement(s) about P,Q,R and S is(are)

2 NaCl  2 H 2 SO4  MnO(OH ) 2 

The correct statement about S is

kb = rate constant of backward reaction]

A  B is an adiabatic process. If the total heat absorbed in the entire process

If T1  2T2 and G2  G1   RT2 ln x, then the value of x is ___.

Sol: (P) P2O3  3H 2O 

(R) PCl5  CH 3COOH 

(S) H 3 PO2  2 H 2O  4 AgNO3 

[ Mn( H 2O)6 ]2

(P) (1) Inversion of configuration

(Q) (2) Retention of configuration

(R) (3) Mixture of enantiomers

(S) (4) Mixture of structural isomers

(R) Gattermann-Koch reaction (3) Benzene 

(S) Rosenmund reduction (4) Aniline   

Used in Rosenmund reduction  S  2

Used in Etard reaction  P  3

Used in Gattermann reaction  Q  4

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