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Hoa-Huu-Co - Phan-Thanh-Son-Nam - Chapter-7-2013-Alkynes - (Cuuduongthancong - Com)
Hoa-Huu-Co - Phan-Thanh-Son-Nam - Chapter-7-2013-Alkynes - (Cuuduongthancong - Com)
Dr Nam T. S. Phan
Faculty of Chemical Engineering
HCMC University of Technology
Office: room 211, B2 Building
Phone: 38647256 ext. 5681
Email: ptsnam@hcmut.edu.vn
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Chapter 7: ALKYNES
An sp
hybridized
carbon
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NOMENCLATURE OF ALKYNES
The IUPAC name of an alkyne is obtained by replacing
the “ane” ending of the corresponding alkane with “yne”
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Lowest possible number, regardless of which
functional group gets the lower number
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Alkynes by elimination reactions
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REACTIONS OF ALKYNES
Acidic hydrogen
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Only for primary alkyl halides
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Additions of hydrogen halides (AE)
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Additions of halogens (AE)
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Additions of water – hydration reactions
Markovnikov’s rule
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Additions of boran – hydroboration & oxidation
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Regioselectivity
Markovnikov’s rule
Anti-Markovnikov 13
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Additions of hydrogen – hydrogenation
Product is
alkane
Product is
alkene
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Ozonolysis of alkynes
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Polymerizations
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