Rosemount Liquid Analysis

Summary
Bibiana González

Jan’2019

Emerson Confidential
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 Agenda

Overview

Transmitters

Sensors

Applications

Q&A

Next Steps

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 Liquid Analysis Sales

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Liquid Analytical Product Offering
pH Conductivity
Toroidal – 228 Insertion
High Temp – PERpH-X 3500

Toroidal- 242 Flow Thru

Coating – TUpH 396 Contacting – 400

1066 Liquid Analysis

1056 & 1057 499A – Chlorine,
56 Oxygen, Ozone
5081
2 wire, FF
Sample
Systems
Transmitters Amperometric
Emerson Confidential Turbidity 4
Transmitters
 Rosemount Liquid Analysis
Transmitter Product Offering

Premium Offering
 Expandable to 2 Channels
Rosemount 56  Digital Communication
 Modular Measurement Boards
 Line Powered
 Data/Event Logger
 PID Control
Customer Value

Core Offering
 Expandable to 2/3 Channels
Rosemount 1056/1057  Digital Communication
 Modular Measurement Boards
 Line Powered

Rosemount 1066
Conventional Offering
 1 Channel
 Digital Communication
 Measurement Specific Boards
 Loop Powered
Rosemount 5081

Performance & Functionality

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 Liquid Analysis Competitive Comparison

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 pH Sensors

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 Complete pH Sensor

Seal
Seal

KCl Electrolyte
Solution

Ag/AgCl Ag/AgCl
Internal Wire Internal Wire

Buffered Fill
Reference Junction Solution

Glass Electrode

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 Junction Types
• Reference Junctions
– Double Junction
• General purpose
applications
– Triple Junction
• Longer reference
pathway
– TUpH Junctions
• Helical reference
pathway which slows
down poisoning ions,
extending the life of
the sensor
• Large surface area
provides resistance
to coating

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 pH Sensor
High Dirty and Coating Dirty and Coating Applications
General Purpose Steam Sterlizable
Purity Applications for Harsh Process Conditions

 
3900 385+ 389 3200HP 328A 3800 Hx338 Hx348 396 397 398 TF 396 3300HT 3400HT 3500P 372 RBI -
Non HF Sulfides
Glass Resistant Resistant

 
                                   

0-14 pH Range
ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü
Cracking Resistant
Glass
ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü
                ü ü ü ü ü ü ü ü ü
Abrasion Resistant

                ü ü ü ü ü ü ü ü ü
Coating Resistant

                        ü ü ü
Re-buildable
High Temperature and                         ü ü ü ü ü
Pressure

Retractable
  ü              ü   ü     ü     ü

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 Main Differentiators
Reference Junctions!! Remember this? 

General Purpose TUpH Coating PERpHx Rebuildable Special Applications

Resistant Sensors
(2 or 3 parallel
junctions) (Helical junction) (Rebuildable Junctions) (Unique junctions)

3900 (Double) 396 3300HT 328A
3900VP (Double) 396VP 3300HTVP 372
389 (Triple) 396R 3400HT Hx338+
389VP (Triple) 396RVP 3400HTVP 3800
385 (Triple) 396P 3500P 3200HP
385+ (Triple) 396PVP 3500VP RBI
397 TF396
398
398VP
398R
398RVP
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 VP8 Cable
Integral Cable Connection
Connection
Main Differentiators 3900 3900VP
VP (Variopol electrical connections)
Models in green are identical to the base
model except of the VP connection

General Purpose TUpH Coating PERpHx Rebuildable Special Applications

Resistant Sensors
(2 or 3 parallel
junctions) (Helical junction) (Rebuildable Junctions) (Unique junctions)

3900 396 3300HT 328A

3900VP 396VP 3300HTVP 372
389 396R 3400HT Hx338+
389VP 396RVP 3400HTVP 3800
385 396P 3500P 3200HP
385+ 396PVP 3500VP RBI
397 TF396
398
398VP
398R
398RVP
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 Updated Table with Red and Green Sensors
Removed
Down to 17 models, lets keep going!

General Purpose TUpH Coating PERpHx Rebuildable Special Applications

Resistant Sensors
(2 or 3 parallel
junctions) (Helical junction) (Rebuildable Junctions) (Unique junctions)

3900 396 3300HT 328A

372
389 396R 3400HT Hx338+

396P 3500P
385+ RBI
397 TF396
398

398R

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 Retractable Options
Models in orange are retractable

General Purpose TUpH Coating PERpHx Rebuildable Special Applications

Resistant Sensors
(2 or 3 parallel
junctions) (Helical junction) (Rebuildable Junctions) (Unique junctions)
3900 (Double) 396 3300HT 328A
389 (Triple) 396R 3400HT 372
385+ (Triple) 396P 3500P Hx338+
397 RBI
398 TF396
398R

3300HT 3400HT

24 in. (60 cm.) or 36

in. (91 cm.) tube
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 Nearly Done – 396 Family
General Purpose TUpH Coating PERpHx Rebuildable Special Applications
Resistant Sensors
(2 or 3 parallel
junctions) (Helical junction) (Rebuildable Junctions) (Unique junctions)

3900 (Double) 396 3300HT 328A

389 (Triple) 396P 3500P 372
397 Hx338+
398 RBI
TF396

The 396P, 397, and 398 are 396s with special body or mounting types
396 body type is SST
396 pH Sensor
Sensor Difference from 396
396P* Polypropylene body instead of SST
*(Highest Running 396 Sensor)
397 Polypropylene body in a Quik-Loc mounting assembly

398 Titanium body instead of SST

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 Left with Core and Special Sensors
General Purpose TUpH Coating PERpHx Rebuildable Special Applications
Resistant Sensors
3900 (Double) 396 3300HT 328A
389 (Triple) 3500P 372
Hx338+
RBI
TF396

5 Core Sensors and 5 Special Sensors

Steps to arrive at this offering (Write this down!!)

1. Remove soon to be obsolete models
2. Remove VP versions of models
3. Remove retractable versions of models
4. Remove additional body types

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 pH/ORP Sensor Product Offering
General Purpose
• Just Water? 3900/3900VP
• Chance for Poisoning or Contains Chemicals? 389/389VP/385+

Tough Applications
• High Temperature? PERpH-X Family:
3300HT/3300HTVP/3400HT/3400HTVP/3500P/3500VP
• Dirty? TUpH Family: 396/396VP, 396R/396RVP, 396P/396PVP, 397,
398/398VP, 398R/398RVP

Special Applications
• High Purity Water (< 5 µS/cm): 3900/3900VP with Low Flow Panel or
3200HP
• Non-Glass Requirement (ISFET): TF396
• Sanitary/Hygienic, Steam Sterilizable: Hx338, 3800/3800VP
• Hydrofluoric Acid (HF): 372
• Poisoning Chemicals or Contains Sulfides: RBI

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 pH Sensor Slope
• A theoretically perfect pH sensor will have a slope value of 59.16
mV/pH at 25°C
• Slope describes how much mV charge is equivalent to a single pH unit
(sensitivity)
• Example:
• In a 4 pH buffer solution, a perfect sensor would output a 177 mV
signal
(7-X) x 59.16 mV, where X = pH of solution
(7-4) x 59.16 mV = 177 mV

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 Calibration Diagnostics - Slope
• pH slope can be seen as an indication of the health of the pH glass
• Slope naturally decreases as the sensor ages
• Slope decreases faster with exposure to elevated temperatures

The usual high slope limit is 62

mV/pH. This could indicate:
- Most likely an error was made
during calibration
- Calibration was rushed
Slope Indication - Temperature was not stable
- Buffer values are inaccurate
50 to 59.16 mV/pH Sensor is good and is still
usable
48 to 50 mV/pH Sensor is reaching end of life
and should be considered for The usual low slope limit is 47
mV/pH. This could indicate:
replacement - Sensor is worn out
< 48 mV/pH Sensor is worn out and should - Sensor has a high impedance
short
be replaced - Sensor is coated
- An error was made during
calibration

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 ORP

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 Why Measure ORP?
• ORP is best for determining the
endpoint in a reaction
• This graph shows that if ORP is
below zero then enough sulfite
ORP (mV) REDUCTION OF HOCl WITH SULFITE
800

has been added to remove all the

chlorine (HOCl) in the process
600

– This is called dechlorination 400 Exact values depend on

pH, temperature, salt
concentration, and other
• The measurement is directly in 200
factors.

mV and can indicate if a foreign

substance has been introduced 0

– Many contaminants consume chlorine -200

– Used in water quality systems for
water security -400
Percent100
Reaction
0 20 40 60 80 120 140 160 180 200
• ORP is not a good indication of:
– how much chlorine is in process
– how much excess sulfite is in process
– how much added contaminants there
is

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 Conductivity

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 Conductivity Key Features
Four Flow Through
Contacting Sensors Toroidal Sensors
Electrode Sensors

140 141 142 150 400 402 403 404 410VP 225 226 228 222 242 245

Clean Liquid ü ü ü ü ü ü ü ü ü ü ü ü ü ü ü
Coating
Processes
ü ü ü ü ü ü

High
Conductivity ü ü ü ü ü ü ü

Retractable ü ü ü
Hygienic/ ü ü ü ü
Sterilizable

High Solids
Tolerant
ü ü ü ü

Corrosion
Resistant
ü ü ü ü

VP ü ü ü ü
High
Temperature
ü ü ü

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 Contacting Conductivity Sensors
Used for accurate low range conductivity
measurements in clean, non-corrosive liquid
applications 400
– Ultrapure to Surface Water

Various Installation Configurations:

– 400/400VP = Screw-In Type Sensor
– 402/402VP = Retractable Type Sensor 402

– 403/403VP = Sanitary Type Sensor

– 404 = Integrated Low Flow Cell
– Cell Constants of 0.01/cm, 0.1/cm and 1.0/cm
– 410VP = Four Electrode Sensor 403

410VP 404

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 Toroidal Conductivity Sensors

Ideal for Dirty, Coating, High

Conductivity Applications
• Minimal Maintenance
• Corrosion Resistant Materials 228
226
• Suitable for Clean-In-Place,
Coating, Viscous, or Abrasive
Applications
• % Concentration Measurements

228 = Standard Insertion Type Sensor 225 222

226 = Large Bore Hole for High
Suspended Solids
225 = Non-Metal Sanitary Sensor
222/242 = Flow Through Type Sensors
245 = Sanitary Flow Through Type 242 245

Sensor

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Amperometric
 Amperometric Key Features
Steam
Sterilizable
Chlorine Ozone Dissolved Oxygen
Dissolved
Oxygen
498CL 499ACL 499AOZ 499ADO 499ATrDO Hx438
Free Chlorine Free Chlorine Trace DO ppm/ppb
Monochloramine
Total Chlorine

Temperature Compensated
Amperometric Measurement ü ü ü ü ü ü
Replaceable Membrane/Sensing
Cap ü ü ü ü ü ü
Minimal Flow Sensitivity           ü
Tolerates Repeated CIP Cycles           ü

RDO – Optical EMR Product

Dissolved Oxygen Private Label
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 Rosemount FCL
• Complete System Includes:
– One Rosemount 499ACL-01-54-VP
Free Chlorine Sensor
– One 4 ft. VP6 Interconnecting Cable
– One Transmitter (Rosemount 1056 or
56)
– One Constant Head Flow Controller
– One Low Flow Cell
– Tubing
– Three Replacement Membranes
– One 4 oz Bottle of Electrolyte Solution
– Back Plate
– Optional Rosemount 3900VP-02-10 Rosemount FCL
with pH Correction
pH Sensor with Additional and Rosemount 1056 Transmitter
Interconnecting Cable and Low Flow
Cell
• Range = 0 to 10 ppm as Cl2
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 Rosemount MCL
• Complete System Includes:
– One Rosemount 499ACL-03-54-VP
Monochloramine Sensor
– One Transmitter (Rosemount 1056
or 56)
– One 4 ft. VP6 Interconnecting Cable
– One Constant Head Flow Controller
– One Low Flow Cell
– Tubing
– Three Replacement Membranes
– One 4 oz Bottle of Electrolyte
Solution
– Backplate Rosemount MCL
with Rosemount 56
• Range = 0 to 6 ppm as Cl2 Transmitter

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 Rosemount TCL
• The TCL system is used for the
continuous determination of total
chlorine in water
• Components:
– Sample conditioning system
– One total chlorine sensor
– One transmitter (1056 or 56)
– One flow cell
– Overflow sampler
– Reagents sold separately
• Can be used with seawater
• Not for use in hazardous
environments

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 Rosemount RDO
• Optical Dissolved Oxygen System
– Contains one sensor and one
transmitter
• Ideal for use in wastewater aeration
basins and ponds
• Oxygen sensor utilizes the
fluorescence quenching method
• Range: 0 to 20 ppm O2
• Operating Temperature: 0 to 50°C
• Maximum Pressure: 314 psig

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Turbidity
 Objective 1 – Product Information
Clarity II Turbidimeter Description:
• Dual-sensor turbidimeter loop compliant with U.S. EPA 180.1 and ISO
7027 standard methods

• Loop components:
1. 4-wire Analyzer: 1056 / 56 Turbidity(ex.1056-27-XX)
• Based on T1055: languages, menus, backlit display
2. Optical sensor:
– Incandescent (EPA) lamp or LED (ISO) near-IR lamp
3. Measuring Chamber with a two-stage debubbler:
• Receiving sample: lower chamber, debubbler
• Measuring sample: upper chamber, allows pressurizing
4. Cable

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 Clarity II
• Complete System
• Single or Dual Sensor Input
• Cable
• Molded Debubbler/Measuring Chamber
• USEPA Method 180.1 or ISO Method ISO 7027
• Resolution 0.001 NTU
• Ideal for Low Level Turbidity for DW Plant Needs
• Full Featured Analyzer with Seven Languages
• NEMA 4X (IP65) Analyzer
• Two 4-20 mA Outputs
• 4 programmable Alarms (-02 and -03 power supplies)
• Suitable for final treated Wastewater Discharge and
Industrial Process Water Applications

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Applications

Water Treatment
 Remember: Follow the water

Raw water

Water treatment

Cooling water Boiler water

Other uses

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Analytical in
Water Treatment
Follow the Water
 Typical RO plant
 What’s in it for us?

raw water NaOCl

filter Na micron
softener dechlorination filter
NaHSO3
T Cl or ORP
pre-treated
water (RO
feedwater feedwater)
C
combined
pH C permeate permeate C: conductivity
reject Two-stage RO unit pH
C
ORP
permeate Cl: chlorine
T: turbidity
reject C

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 Cooling Water

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 Cooling water system
• What’s in it for us?
warm water return

Cl
pH
C

cooling tower
T

blowdown
makeup water

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 Scale and Corrosion
Scale costs $$ in three major categories: Scale
Tube Scale in a Cooling
1) Decreased heat transfer Water Bundle

2) Decreased flow
3) Under deposit corrosion* Scale also decreases the
diameter of a tube impeding heat
Scale reduces the efficiency of heat exchangers transfer rates
including cooling and boiler heat exchangers Cold Side
• Scale is an insulator (think of it as a layer
of rock) Tube
• Scale decreases flow further decreasing Wall
heat transfer rates Hot Side
• Scale attracts more scale
Under deposit corrosion: Creates a super Tube
concentrated highly corrosive spot on a surface Wall
scale
under-deposit tube wall
corrosion heat
Under Deposit
Corrosion

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 Boiler Water

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 Boilers
• What’s in it for us?

pH C pH
C steam C pH

boiler DO *
condensate
returns

makeup water
C

*For systems with deaeraters.

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 Poor pH Control Will Allow Corrosion
Basic Failures from Corrosion Pitting
• Localized corrosion (pitting) can rapidly
penetrate wall leading to a tube leak
• Uniform Corrosion reduces wall thickness to
the point where the tube can no longer hold
the pressure and the tube bursts Corrosion in a Tube

• Corrosion causes Permanent Damage to Area of

equipment that can will cause maintenance Uniform
and other costs Corrosion

Typical sources of corrosion

• Dissolved Oxygen makes water more
corrosive

Water
• Temperature – Water can become more Thin Walled Tube Failure

corrosive at high temperature

• Flow –Fast moving water is more corrosive
than slow moving water
• Under Deposit Corrosion from Scale
• Low pH Dissolves and Removes Metal from Waterwall Tube
Pipes
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 Controlling scale
• Boiler scale has two sources…
– Precipitation of contaminants that have accumulated and
concentrated in the boiler.
• Calcium, magnesium, alkalinity, sulfate, silica, and iron
– Deposition of corrosion products formed in the condensate and
feedwater system
steam

boiler condensate
returns
precipitation of
soluble
contaminants
makeup water
corrosion products
&
contaminants

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 Remember: Follow the water

Raw water

Water treatment

Cooling water Boiler water

Other uses

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 Drinking water treatment

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 Drinking water filter plant
 What’s in it for us?
coagulant/flocculant
screens
raw water settling basin

OZ mixer T
ozone
ozone contact filters
generator
chamber
backwash
pump
NaOCl
Cl Cl pH T
contact T
tank backwash reclaim pond
to screens

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 Free chlorine: Model FCL
chlorine pH • Two versions
sensor sensor
– FCL-01 chlorine only
– FCL-02 chlorine with pH
correction
• Constant head flow
controller--no valves or
pressure regulators to
worry about
• Minimum flow about 11 lph
• Everything mounted on a
back plate
• Sensor cables pre-wired to
the analyzer
inlet drain
flow controller

NO REAGENT NEEDED – BIG ADVANTAGE

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 Model MCL
monochloramine • Constant head flow controller--
sensor no valves or pressure
regulators needed.
• Minimum flow: 11 lph
• Linear range: 0 - 15 ppm
• Linearity: 2% (typical)
• Electrolyte life: about three
months

inlet
drain flow controller

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Liquid Industrial
Applications
Leak Detection in
Heat Exchangers

• Conductivity can detect leaks in

Cooling heat exchangers.
Water In • Leaking Heat exchangers reduce
product revenue and waste
energy.
 Can sometimes use pH
Cool
Acid

Hot C Conductivity Loops:

Acid Cooling
Water Out 1 per Critical heat exchanger

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 Measurements in Scrubbers
scrubbed • Scrubbers are used to remove
gas harmful or smelly gases from a
gas stream.
• A chemical reaction between the
objectionable gas and a scrubbing
scrubbing liquid removes the gas.
liquid • As the gas is scrubbed out, the
concentration of scrubbing liquid
decreases.
• Either pH or conductivity can be
gas to be
used to measure the
scrubbed
concentration.

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 Oil and Gas Drilling
Sample conductivity trend
 Oil drillers use various fluids to lubricate the
drills and bring up rock to the surface
 Analyzing the fluids provides feedback on the
rock formation and can give advance notice
of when petroleum products will be
encountered.
 (See ADS 2900-11 for more details)
 Toroidal conductivity sensors (especially the
model 226) are ideal for this service because
they resist coating and plugging.

Model 226
installed in
mudlogging
system

Typical mudlogging unit

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 Refineries: The Crude Unit Overhead
Manual Amine
Valve Neutralizer
Reflux Tank

Distillation Accumulator
Tower
Water
Cooling Water
Sample

Crude
Oil Separator
pH

To Drain

• The lighter ends of the crude tower yield product with some acid water
content that must be neutralized before discharge.
• Most of the amine neutralizer is added at a constant flow rate because of
the time lag in the control system. (See ADS 2900-01 for more details)

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Industry Training
Pulp and Paper
pH ORP

pH
Head
Box
Waste pH
Treatment

Paper Machine
Bleach
C White
Liquor Towers

pH
Machine
Refiner
C Chest

Stock Preparation

Logs
Digester Black Chipper
C
Liquor
 pH in Pulp and Paper
Locations:
• Pulp stock lines (pH control reduces the variability in the paper product)
• Process water (pH control reduces corrosion in the process piping)
• Wastewater (pH control reduces environmental damage caused by
effluent from bleaching and pulping operations.

Sensors:
 The coating resistant model 396P, 396R recommended for
pulp
 Chlorine Dioxide applications should use the model 398
 PERpHX sensor is best for physical, temperature stress,
long life where maintenance is practiced.

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 Conductivity in Pulp and Paper

Applications:
• Chemical Recovery (control of alkali strength)
• Steam/Power Plant (boiler protection)

Sensors:
 The flow through model 242 is a good option for heavy
solids
 The retractable model 228 sensor is most common

 The ENDURANCE line can be used in the steam plant

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 Pharmaceutical Processing Solutions
• Water For Injection
– Demineralizers
– Reverse Osmosis
• Fermentation
– Steam Sterilizable
• Clean-In-Place
• Chemical Synthesis
• Waste Treatment

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 Be a trusted advisor
• Your customers need you to recommend
improvements to their process
– You don’t need to be an expert on their process if you can ask
the right questions…
– but you will want to know more than they do about our
products!
• Sensor selection is the key!
– Nearly all sensors are compatible with all analyzers
– First… Select the best sensor for the customer’s process and
installation requirements
– Then… Select the instrument to be compatible with the
customer’s power, enclosure, area classification,
communication, and other needs.

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 Comments / Questions

Thank you

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