B-H BEB BMMW(ERMABRET ROR, MERA ER 2E2E(G, lt t}-F KAMA Schrodinger HEA tro fu-pew+ pe > 2mp pea Rog ame ~ Deen ee aay tek Pik pee rot EEA, ? ICT, i MILT, Rp HRP MR RATES Bory MBF i BS REE, ro HR MALT é AOE BS, mp Fm PBI PMP RE, Zee Me DAK PA Fi BT, BO FA ER. SOR BAR ARF Bir, BURBE FR Bohr 3478 ay HM fir, fe Be FA hacteee 4 3 (ir, AT i Bh, wT ag = a = 5.292 X LO~%em = 0.5292 A me’ Thartree= f= 27.21eV # (11) AP PaO PA R, ~ 2; R, fa nme me? mp = mm, BUC1.1) RE 1110224~ 2 imo =; -3 oe DB VE mn “er” * Ey RMF ” SEM", BURL E SUR Fe fie Be aR A Schrédinger 35 #3 i le ZZ = —~Vigg “ { = 2m, V? xy 2 v z Rog +>1-y 40 ew (1.2) bck Ti pa TPE ASIN EF cydberg > HE BE Cir, BD 1 tydberg = + hartree JXBY , Schrddinger HHA MPR: 1 2ZZq {-Stu- Dvit De 221\y - EW (3) pe PPE FH RIND Fk RAVE A Schrédinger HH (1.2) HR, He Sy BUI Born-Oppenheimer FE ( BVIL (WY), Hellmann-Feynman ARLBER. S-KEBKENCATHOWSH, ARR EWAN. 1.1 Born-Oppenheimer 32 (Ri (U) TAR TKR SAW FX 10°—10° HED F pay WF ME SF RAS, Uke Bi) zE FTE AUN BY , IBIS SAY LF AB IL ET a, BIS +26SL EMRAS AMBRE RRR, HERE RY HT, BERARMM BARA, AN, Rte We Tea PSE. TE HE x BP HEB AR, Born Oppenheimer 4bJ8 T43-F KAW AS Schrddinger 772 (1.2), HD FP RWB ME TED BAK WAKA Born-Oppenheimer EC RRL). FAAV(R 8) RRB (1.2) AB HEM VR) — 224 Ze sR a 2) moe e mp > 2mp RAUL. BPMN, my = 10°—10° Veu Vou = Vu Vie = Vie RY MEARNS =M—RMTUM A, MME sh aie — Si bow + VR ue = Eve 7 2me 2 2B.BA AHR BELO TAT -+ Dive + V(R,r)a = ECR) (1.6) -> ve + E(R)v = 60 (7) e mp FRAOKERHAZROLEN KAN BF BWR DE CL.) HeHBHHR. HhTaavet, WER) RREB PRN KAWETEER, LEER BHAE tA Ry Ries Whe Bw ECR). AT MRM, Bie BER Re Bm. Fit, ZE Born-Oppenheimer HEE, AT 4k RAVI PH Bk BL C15) KABA, Mi «CR, 1) M CR) RHE (1.6) C7) Se. ECR) ASFRAM ANB RRR, WB C17) RE, CESRBHARHHH. LAH, BH ECR) S Rw A, BRRHHRH. FARSI MDSHA RLS RUMMAGE TD REY Ri, kXK-LBBERED, Ll MRFAF SC FLINT MID — IRS PRT La PR MET Ah ED Born-Oppenheimer 92 BASS BF. LORE —TAT RIEMOB RRA, B2TAF RARER Gr, 0, 6) RS, FRM LAA, BRO ER) ASRS RES 6 AK MS 0 Rd HH, WE (1.6) (1.7) EMA {-D4vi+ Vou fam BC) as) {---wi- Lute} as) lms 2m* PPPS RRR i PRFARRNWBR, TORI M2 RB 1M 2ACRTR. PREMERA ESS! Me BH i. 112 Fah BBB), BE-TIARAD, RULER OBA BRK, BREE MRI RR. WIA, foo E-TUOARAWLMAE, BO m Mm. WRT MRSA 1 Bi, EMERY. MM Se TH mats + mtr : my b m2 (1.10) r=rn—n r= oseaia ror, —-—t—r m +m mor, +—t-r m +m, FREE ZAR AA MI vya=v - ey m, + mz v=v. +—t_v m, + mz Sth vy, Av. RARER 1 M2 BMRB, ve MV ROR 13GB) BEBE AA AY is BR. HR, Be T ATA BIH 1 T= J mvt + inv ins +t qu) TARA RBaHae MAM B MAES, m,= mm + om mymz m, +m, m, ARVGE, # ROW RRRITS RE. IRE, HE 1.9) RAR {-2-vi- 2 w+ Be }emer Qa) 2p 2m, 2 o = o(r. oer) HE.12)) BERS T FTE: vier.) = eile) (13) 2m, = vi + Er) bene) = (6 — & oar) (1.14) = 66HELM) RANBIWHE, BBN) RDFHOHE, ERAGE, 6 ALLE LARA P, & AAW. Hie NSE TASS ae a if A HI Bh, 113 aAbseap PLT OAS VEN EE C114), Beer BR ZIAEERS, 3 ORAM eK, BIS Hen, HAHAHA Er). RAMA, DBA ~i 16,8, 2 { Qe rt Or” Ot Beet + EO Son —(e—e)ve (ts) SOL HARPS RS i ra [4 inp OB L tas 36 8? ag + nto ra SREB, vat) = R'(r)¥im( O56) BE) ~if@,2 4), 1+ 7 { Al attr ar \+ ar eS 10) =(e—e)R’ (i.16) BES LY (8,6) = 1 #1) Yn 8,6) Yin( 0,6) HR, fash BR ADT Hie BI A = 1, ELMAR Rr) = rR'Cr) HFEC16), SMEHBENHE 1 @R i +1) tL + t+) Qe dr [zo + 2pr? |r =(e—6)R (1.17) BEAD HALE Besoi+ 1) Quer? FAS FS Mee Bh, AFP = 0,1, 2,007, THR L— DER AEH « — &, A MMA BOR r), REAR Rr) Meer). KE BA HEP te RK 4, AMER AKL. 114 BH AER ORAL, TURES FAO BUG + PGES BURBS ro HE RRA. ATARI, TUN RATS PA FERRE Lt 2p} EMAEABE EE vnt0,0) = SLED y,,(0,6) C8) are 22ers LAER FAY He Sb HE eo 4D) I+ (= 0,1,2,-+*) (1.19) Qari 21 RH l— ari, MHRHRR. BINA TOURER FOTO PRR . KERART MIL, 4= 1; eR RAR HORTA CGS Mfr, RAAT a LIS Ra CRD SWEDE. BABES -25 +EG)R=(e-e— eR (1.20) FEF BH fi ET AE, rants dE 2 (aE E(r) = E(ro) + (22) + = (ee) tees BeHF r= ro tH A A dE a ).,7° PE EC E(r) = BCr) + See BABB a= (46 @E =). E(ro) REBEL HEN KART IOGER (OBBIIHEEGED, Fie. RAC.20)K,8 1 Ry type aa ge tT TtPR mee (421) EMAL, ROMBRTMERHE. Hh &y —™ € — By — Ey — Be ARAOEE. BIA, NFR, = nt+t)o (n= 0,1, 2,+++) on fk x R- (ad q) tence AERA ep a= (pao)? Hak) RAH of HY Hermite STA. Bib CREME RATS FED BABA RAY PH sh OA RAS AE A ABTA Ba BAR Rae BES em eet ey +b, + (1.22) EREAL,«, HH &, AY 100 fF, &, LHIH 6, AY 100 fi, uo1.1.6 Morse 3 ft & LAE DFG Rah 1 Hh RAH, RE AE WURDE. Mors: HBL — 7S OE AS BUR FB fe BK E(r) = Dl een) — 2e-er70) J] (1.23) HPD Me HBWSM, + Mr DEO IAB. Fim Babiig—F Cr) WHE. DR, r= oo Mt, E(oo) = 0, BRE, BATKTSEED ANA, BH HEATH a. 7 "Mr = ro bt, E(n) = —D AEC) = D[—2aen Bm) 20010 pe, ir bre #EQ) — 2p. >0 f° HHL BRL, ECr) 4 ro MAT BRAM, BOSS OG TES ro KAU MEIER, : JERI iD AA Eto) fie. ! ALAR T EC) 1 Mr WLR. £r=0, \ Morse 3 BE SUCHCA PiRAHL ff \ HOB MHRA. % \ THR, Ahm : Sete BY HE MR A) HERMES E, OR XI PATA WBE fe B, > BIBS RE RE ALL SURF Foy AeA AR D,=D—+ te —— Morse fH 3 2 —— KKB RAK (1.24) oeSot hea (RAS IRAE, Te DLR De (1.24) ah ese HENS Ae D PPE BE ATU «, RM PI Morse SHALES HUET. ST GEF Morse 3 HTM, RAIA Ee RAR AY Le PA ARH 1.2. Hellmann-Feynman ¢32 SFA FARK, HEASHY Schtédinger 77 FELE Born-Oppenheimer UT ARB BAWHRTUSH Ha = E(R)u (1.25) H--> ivi +V(R,r,) Sh ROARS REAL, 1 OR i PTL, +H BBR REI (6 Bo (uluy = VRE 125) WR, RATTLE SHRP SA EADS ECR) ZI RAK, HAF PK E(R) = (u|H{x) EEE PRA RAS © (2) + (2 BER) _ (, fal 2 2) ) daze +l H#FAFERRE XA PER) 5 (u gty+ (Bela “reo +Gleh) AF # BYS— (689, Ans — Diy 0, |.) 2a le Oxp lta] Ge Oxe Ox, |Sea BE(R) _ (2 av |») Ove nt OE(R) _ = (42 “ Oz5 oa REULEKG WeE(R) = (ul WeVl 4) = (eV) (1.26) SATPE RATER? SL (Fr) = —(¥eV) = —VPE(R) (1.27) Sorh( ASP AOS S , RLAE Hellmann-Feynman IE; EOTARY, (EER e PR LBA ST ECR) Aik MAR RARE. KGSRUTSRH SH, KREBERRI, TURDAR ES IMS ESTELNA RBWVAY ECR), PARSER TUR SH oD. Alt AeA BRA ee PL, ELBA TAY SSI fe. 12.1 REFAF ?@% Hellmano-Feynman FH MAWAT, RIT RRFS F (ry.8) BN rs LA aN . 4 ° o HAL.2 RFA PABRRCO ALA) 1.2 aR, ARAB RE hh. BATS 126FHM, AERA LWON y,2 ADRS TS B (1.27) KEE A REMAN © 7 Fa, ~ —BECRY 7 Ox, - —4ECR) OR. aR Ox, Sh R ATU F RAIA BE SB R=%—*, Br dE(R & Fy, = SEE (128) 2 Fae : — 4EtR) Fy BRE, Per cee FUER. B-FH,HO27)KRA Fae = —(VaxV) - -{ at OY. ude kA seek ve Zaza. — 2s _y Ze ia xt aa ras ae, re PHAR i SEFRRT BAMBAER. ARR RIE a | ZZ, Zs ly Ze Farm -j u* 2[2 abn = = 2s \uae ar Rx 7 ra VG ta) + im ya? + Gs = on? ros VG — a + Ci — yn + Ce — 2 BEG yt) BB i PRPS, MA - 13Fuam — teks i Df Zt G8 wade (1.29) The tas LARD EM AAT LP ETT AY de = duyduy-+-don do, RMB I STORE. HEARTS « FEBOT PRAY LAC1.29) RAAT FRAT ATE HY & Fas — Fake + {Zs a (ta) uae ma TA NABFURE. Ae an) =f utudesden: doy RRB—TATHLEGRSH, ROBSON SREB RF JL BED en) = Nel) | ‘ - nj wtudvidoy:++duy A Prope —2a28 4 24 | oe) 3 Gatsby R TA KB, RAAT Ti 1. HA 12 7 ae zx, ——A4 = cosO, Ta it Fae ~ 2220 + 24) 9 2208 ay (1.30) SESAME S Ae Fag 22a — 24) 9 S88 de G31) #(1.28) sR : Fag = 2ECRQ aR citea SF ae m Feud #5 (1.30) #1 (1.31) RRALR, SD ZZ ZacosO, , ZacosOs)\, Zale A Af (Zacee@e + eee Zaconts\ sy age +2 1\toao 4.32) Fas = — ae f= ZncosO 4. Zncosy Zscosy rh rh FULL f > 0 90 fF < 0 ADHAIRIE (1.32) RATA DERE BD = —2aZ5 +f, 4 . Faw ade + Z| fede + | fede (133) ASAD — TCR BY A AOI LARA 0 T° RARLIERY SURE f > 0 RTS RA HEEB Beh Ze — is FSDRRE | 0 AY SST, HAD PE EA, ME} Za) meat! Rex 12.2 SRTAF #838 Hellmann-Feynman € #2 (PARP RA LAD Fy = —VaE(R) = Wl —v.V [a> son ves 4pm Ze pea Rog Fok Tak ea The RAMEE Rw Re_ Ziq Rag Zi ud: 7 >a Rig Rag + DI va(Z 7b )pude ZsZq Rag Z,%, Byes Ran Se Oe ce FATA BRGY EM EP SSA ETT ON, HOARE o(r) AEM SRM, EA BEIBSLARIERS, cy EMA BE. (1.35) RAAB —- WEEE RA A BEY Coulomb FAWAH, Boi ART ERN TR, CHARAN BT BED the BRE. “4DFRALT PORE, AEST PRLS FB, Ake a 22 Rea (F8 o(rae = 1.36 Det le e(r)dv = 0 (1.36) 6sTURE s MET, ot) BRR 8 DOR, mba ahe oC) AS BEBE IR METTT AT DUET 3 FS SEE ET. ELIE or) JE HE NSA EK, HE C136) AHA RE or). VIB, HH Hellmann Feynman $2 FER ESE RE LF BE 3 i BK Cr), E ARETE RAF Schrddinger Fy HK SS. 13 #82 13.1 BERRA AAT RATE DA 2 ARF (TANK) AVS F RIAN Schrodinger DEW HSE e AEM —-TRAR. ATHE, PATHS, Be PTA GO, 9, 2) ARMAS hid X3p-2 = ey ‘“ Kp = yO o Xap = 2 TU RLF RAB PRBE— EOD 21, 22, 3, 154, Ze-2 Xan, X90. TNE HR PS Pen PE: my mz m3 =m, my ms = mg MP ++, mapoa = Mapa = Mp = ME - +> ABBRELTA , spa» mip—is mse BACK H P PAF AI. RAL MWNE , Schrodinger HES AW —yi 1 of 4 (v-z)y =0 (1.37) 7 2m; Ox? PERM xy ETS BE 2 8F_ 4 Vga (yi oF ao | 2m, 82,001 Ox, ax FRU x, *, HER A ORAL AD ——— 1 7 ag 8V gx = Sa(eseea) + Dn ad + v= Bers, 22 =0 * k oa.137) RA 1 ay* VE = St VE Bn Bel RAERG «OF _ owt or le mm =.) @ Ox,0x1 Os} Oxy + Dn BY or =o (1.38) & tk SABIE F—SARIL ov _ owt or ae Sx,0x1 Ox? Oxy on OF 423 a (gu. 8 x *b4) (1.39) Ox, ox, HF (1.39) RELA C1. 8) x, FM AMF RRR = J *>(- Fm oa ‘m, Ox1 ne fre 8) yer 8 | =e Ory, 2m, Ox,|" Ox,\ +) Sage wrUde =0 ESF BM ROD SR PE RD BEE (SE ROLE IO, TF zz af 1 je(-Ssk oe --if¢ “(- Dey ear (1.40) SCT, LRA EO tk a EA SES, a ROP RHE. o18 6F, ASG ©, RA. BS (1.40) & =U 1) = ~F{-Sind™) al av 2 (Sage a4’) BARRRRTRBEROAR, Me SAF RM STARE TR RIN RED ESS SE BPS 1/2 RIK , BRE VE PRATT ARE MK, REDE Ver, tro, 008, tem) = OV (01, m2, +, 30) (41) Set HE BR LM ORGIES OV ant SG OV Aer 1, REFER BEATS OY =v a2) Ox, PEAR ORD, He HES A Pe A Be A SS AE R => (1.43) BFA (1.43) ALLRAERSHEM EIS EE AME, ALR SAMA ED EH FS, MALERRO RHR, B30 WT RRI RR, al 3 Vm tet m2 Alka (1.41) h ABBR +RoR SURO HE ME IB EAN, ZEA (153) KR Tea = —ECReq) (Vea = 2 E(Rea) DA ss Sd BS , BIR — oo BY, (T). = —E(%) (Ve = 2 EC) SEH, AAPOR eg MOS BARA MB ti BS A RAF FD BRAT PAIR TH, SRM HEN Bl AT = (Te)eo — (Todor = —[E(co) — E(Ra)] AV = (Vn — (V)ea = 2[E(c) — E(Ra)] MFRS FRR, E(Req) < E(0) HAMEL D = E(00) — E(Rey) Ae AT=—D a.59) AV=2D ERE, YRAORATD FARRAR, BFE Bu TAI MM, RA RIK, MT A ROTARY, Ha FAY Sb BEI, iT KARI HRS 2236Some wa mw TERT ACAETH 16 BY UE Dy ES DE RR Ja Wt ARS GTZ. AENBEHEOBA RE, FURR E OI ERERO RWC RERA RU RE SHER A BR a Fa EEA BARRERA eR, 2S RB URGE AHN Schrddinger HE ‘HY = £9 Qa) FH Ae Eo SE, SE, <-+> SH MN RBRH ee PRT RANDLE RAT, EE (2.1) REED RAR, FASE EIR RAF 4S BU AEB RR. 2553 ET BGR OF: PEN ERR PE EER ©, FR Fy (22) iE IL. : TEBE MAN. RAF HATER Y, ARP ERIA— KMNCARA WA Deda) = 1 HES HARA RRRART BA +240H- Dal OIE = DIE) Oily) Tal = DEG : (2.3) nF Eo= El BI JM H — Eo SCE, — Bo) |< (@\CH — By)1) = S1CE, — Bo) (O18) |? i Fo RARE KAA E, — By > 0, AIL, LAS DWAAKATREFS, RUA (®|(H — Eo)|®) > 0 RD MO1H1®) Sp (olay RE REM BAAR. PRATT ASF WL FE SY RS, BEE i — ED PROPEL OCs a, a2,++ +, 07), HR gy, o2,2++, a IPRS ak, BGeiy an, +7101) = SAAMI & By DURE SAAB, (EE BAMA WER BL (2.1) ae AHEM Eo, TAMER TNO RETOUNRAR BM KAMER BEA DERE 8F 0 (k= 1,2, -0D (ay Oa, SRI Ds A BE OB ° 256WE) TE Bla. BRE Oo GH ay Bl SAGE DA BCTE 26 (Gol) = (110) = +++ = (H,,4|0) = 0 (2.5) HK H= = E,|@,<@,) En = 3) Enl Pi) El HAR HB, = S3CE, — eo BALL (OH — E10) = 9 Es — Ba) e114 ALAR (2.5), WS ™ (UH — £4310) = 35 (Bs = Bad 110)? SRABAT RETR BL (®|(H — E,,)|®) So Bp <®|H|®) (0/0) 2En (2.6) BRARRLAWES RA. A (2.6) KR, TOG RMR BM RK AA -BRA BMRA SUE MBM. Se Br , A ELOR I , HE A Oe (RAE Mo RH OL, DH BU, RH ., RAMP, AMHR $M En. 22 8% RF ARTA BURT 2 Bl AC PABA 2 5) RSE AD RRTA-TRFRMATEF OPA: 2266a 2 SUR Fp FG SAVE A Schrodinger 7B HY =ED =j=-lgilyi2zi2y,i H 7 vi 3 vi os + 7 (2.7) EAS—-MA—WUD MAMAS T MADER, nr. BEIM PAS HF BARES, re OP FAP BS. 22.1 REUPHEPSRMED BR TRI a(r) = JZ z (2.8) = CHOBE NER, (ARIE ZW BATA SE, HK ar) BIH kelay = Zl entytay sin O40 — Fe etter 1 = 13) =1 SR RURF HY Schrodinger BE [(2.7) KIMIA ARERR ® (nm, r2) = @ (1) @(2) See ag 9) = TUR © te V—1t Ay eae(O10) — CaC1)a(2)] a1 a(2)> = (a(1) aC) + Se + (2 = D(oCa)aC2) [2] aC1992)) +(Z = 2)(aC1)4¢2) I a(1)a(2)) + (oda(29|4 a(1)a(2)) = 2¢a(1)a(2)|HY eo + + 2(4(1)a(2)| + aC1Da(2)) a(1)4(2)) wo + (oerae2| = 2 (a/H| - 2s+ a¢1)aC2)| a(1)aC2)) . an Este BUS Bit NF Zz (al Helo) = 2) e-e(—L ys — Zena zt = (2.12) XTRA FRAA Bh + Ze RAM TAMA ER. (o|4 “= zy et L. py sin ddd - sar femrar = (2.3) ERD (ecde@2| 4 a(1)«C2)) ABPOHORAFARD A iti SWRA A. RUTER—-F ADEE FAA 2 2296RABE ri, O15 bay 125 Pay. b25 ATEN m1, O> diy rary Oy X TOR ORD, FE MPRA adr = dudv, = ridr, sin Od0ddyr3dr, sin 0,d0,dd. = ridry sin O,dO,ddyrhdry singdpdX (2.14) ae r= rit rh — 2nrycosh Yon re RA BLA 2 db PORBRAR 2 ndry = 2 nrnsindd FEA (2.14) KA dt =dndvy = rydry sin dO dgyradraradrdh Ae, BFHRRD (ea@a| aC1)a(2)) ‘ = z ee Par drirdridry sin O,d0,dg,dX = ender | “erndral dry 0 ° Zs. = try a oo oo itr - 824" endl etndral ary + flemmnan le manf er) LXE S PRMRD BS Mi aC1)«¢2)| 4] a¢1)*(2)) " = 16244 endl tind arn - s2zi(” errand er dr, 306~3z 8 H(2.12), (2.13) #1 (2.15) RELA (2.11) ROE (@| He) = 2 (a|H?la) +2(Z — 2y¢a|4 D) + a(t eC2)| + aC1)a(2)) 2 aziz 8 Fe p= |H 10) {®|®> =z—22¢ 8 BM BMRZ BURR ED = SE nz — 27 dZ 8 =—0 BD 27 == Zz 1é 1.69 FEA (2.17) RK, BADR BUR Be AS AUT TO A E= -2Y = —2.848 16 He WL BE DL aE ASD OK aa Z ae : zen za2 16 Qs) (2.16) (2.17) (2.18) (2.19) (2.20) gee ons URE ARO REE 9 2.902 a.u., EIT SI o3leFA 0.054 a. u., 49484 1.5 eV, (AM RAMEN. RRR TF OR RRO, WRBRABH w Zr. 4 pa(1ye(2) — (281) (2.21) J 2 SR, oM ee DMRRAT ARE Z PURER TE WEP, DRE REF a WT RS BT BARA MEAIB fe TE EAS FS BY E+68E a — (Ct + 8C')H(C + 8C) B+ 8 = (Gr aCM(C + 8C) RBI, E+ 6p = C'HC + sCtHC + C'HsC. C'HC + aCtHC + C'HsC on ON _ SC'MC + C*MeC \ omc(1+ 20M) SELL AR ES BOSS PERMIT TEAR EI — 2 AN C'HC + sCtHC + C'HsC E+6E= CMC sC'MC + C*MsCt x (1 Ge ) RIES FRED NE LA E+sE _ CHC Ge + eaalecHe + CtHsC _ CtHC _ cre EEEocme — € HE croc | Re CHC _ , cmc BSE a CH — c BE = alge [oCt(H — EM)C + C1(H — EM)sC) (2.32) EAREMLEREA sE=0 a> -37 6CIMC = (7|v)>0 FRU RR BOR aCt(H — EM)C + Ct(H — EM)sC =0 (2.33) A OC TE ERAN NSE 1b 9B aC am iC, ER —isCt(H — EM)C + Ct(H — EM)i8C = 0 = (2.34) SE (2.33) Wl (2.34) BX, BE 6C'(H — EM)C =0 Ct(H — EM)sC = 0 FEAF oC BRAM BE, oC! ha A ERASE IL, BT WAR (H — EMDC=0 BWA HC = EMC (2.35) BREEMC HKAMEM LALEDE, HHHMMRE BU AY fi FURR, (2.35) REBAR PRUARKRBAE DH, ED Maer E1240) BRB 1, 2,°°+, Co BREN SVM, HART ARBLAAS. HM |H — EM| =0 (2.36) ISH AAD. HM REAAS, MXP TARE AY nih ; E,,E2,°**,Eo HRSA 2.35) XK, DERM AAR, FARA MA 2 ae Gy, 82,00 Tn CATR Schrodinger 772 Hy =Ev AY 2 7S fie BBR OE LE. FEO, 0, +++, O, EH ERIA— (CM BMM, WERE M= + 3861, PMAEDE (2.35) RE MREDE . HC = EC (2.37) AMOAEDEH {H— Ell =0 (2.38) 232 PRAEABWIER C1) ER ERR HR” MAMET BE ((2.35) RT HC = EMC : 3X H 2 Hamilton 368%, M 4 BSE, F HHEB, C Hx AAT ATEAE, LAMAWRY Cte CtHC = EC'MC (2.39) REAMALEDERS (HM HB RND CtH = E*C'M HERARU C,H C'HC = £*C'MC @.40) sy (2.39) Fl (2.40) SRABBR FEL (E — E*)C'MC =0 (2.41) ax c'MC>0 RA E-E*=0 (BUA TEIE BSc, @) BFARAEEMAERMER EH, AEE HC, = E,MC, RELA C!H = E,C/M BRAC, 7: - CIHC, = £,C/MC, (2.42) 2396x . HC, = £,MC, ERY Cl, CIHC, = £,C/MC, (2.43) (2.42) Rm (2.43) XK, WAT (E, — E,)CIMC, = 0 AM E,; > Ey, EXER CIMC, = 0 (2.44) Bn (w,|8;) = 0 (345 E; 3b s HAR, BUR MIRAE 5 eR a BY A GO, 9, wo BY MAW ARRARA CP, CP, 6, CH LFA Schmidt TE22 (675 25 PI VAIS » TART A RAE EY, BRAES CHEIMC? =0, Yk AT Bt (2.48) (ky ll, 2,08s,5) (AIBA SAD BERS AY 2 MR Bec BIA PORE ARPS BY E\ Hy = (8 | (Ho + Hi) 12) = (FO [He] 1) + CHP ALLY) = EO + (89H EP) (2.67) 1 c-|° A Soh EO HMPA AIT RE. RAE 3} Be AY GE AER STEAL. AERA HE ADI ih, er (2.64) ae Em Ay + > HyCHals — Hos )7'Ha (2.68) seo = Ay — Ha —Hs +++ —A His — Hyp =| 2 Ha Mx vs Hn Hy = —Hes +++ Hi Ae AUS AERS Fa TG NE, FG SE Ta RAT 1 Fy — Aa 0 (Auls — Has)" = Ay — Hy, 0 —— An — Hon 4hHRA (2.68) XH » 6; Sui _, = > ‘H, = a Hy — Ha" AH, —A=e Ha ot oes = EO 4 (yo 0) _ Aun EO + (WO [ELLE D) + 2 Fig — Ha (2.69) ELMEUT 6 = (Eb — Ha) "Hn b=! by = SS} Aus — Hes) ifn yy Ou fa An — Has = — Ay (2.70) An — Ha Ha Hy — Han RAEN FRB, ZEAE NT IEAR OEP , SES) BEA — BEA OLE RB IT Se BEV MTUAR—E, 2) 4% Hy Hy ot) = Ha 8s Hy Gast lyst 2,--+52) RAK mms. (2.65) R ESR M - ~ 1456Hus = Ea REBEA IAs — EL,| = 0 - LE s Wie, pallet aed Big sR E®,EY, +E AM ATE AL aa, +++ a CARE EH HE VA — EN, He SAR TE aA 3 9 cafe pai? : [ ’ | | 0 | LRAREE Ee ARREN-REUAR, BRAS RIEMGRKLEFCEROREEUDE A BEDORA, HEANOR OBA, GAMA DRAKE, 25 SPEARS EB ARDENT UREA BE, PORT, Z 2.24 bt RARTH EAR. PRMD Tk mE BIER, “AFA FAR, Hamilton $75 H ae aviv 7 - 5 Be DL vce Rog FG a ei TRE SHEAR, WKAR rot = . 7a BBW Bt ay Hamilton HIF H(e) = o? > (-4v:) +aV. =—@T + oV 7 JER E eH Ea), WI +466£0 (Ha) |) Be) = §9l(eT + aV)/%) (oi) = @(T) + a{V) SEB GR UREA ERR AOE OR, Yam 1h, ECL) WET EOR MMR BAER, ERY EC) OBE Bde dE@)| 29 : de lat 5D 2m ib thay HEF. RECRRAH DAM HR Bh RN WHR A EMAE TEEN” Be F, 4 ARE Cl —m+1) +B. Mm, PK A, 4 BE CL — m + 1) MEL ET Fa FE( 3.18) BT WEB RR M(1, ms ple) 4p = OR FE 3.18) BLO PAB 06) HE HRA AN AAA. AA MCs ms ple) — Dats ms phere) 3.24) 556¥ SEH LC, ms p) BIRT s HORM. Paa(e) BREE (m + 5) Rm Yr HOBEAY Legendre BB, HBT B 3.17) BRK BIER HON, m > 0 ME ERRA DE (3.18) 1H, IPFA Legendre RE wae : fla 0 dro] + [m+ Om eb 1) — dpa a(n) = 0 BRYA Dl-@ + Om +s4+1)-A4 = + pelt, m, pyPans (Ce) = 0 FES RE A Pra. BRAVES — 1 1 l+m)y 2 PrPtdp — +m 8 fi preten G—m),2i+1°" HERR P(e) FEM MRD RT [—Cm + hm +k +1) — Alt, m, 2) 22m + AY Qm+2k+ 1)at x fhm (aPC ddan = 0 GAB Legendre RN BIER RK (2D + LePT = CL + m)PPa + CE — m+ PTs MERA-KRR BRASH LC, m, p) BIER + SGsmspye {- 8 tem D Fae ellie + AevGnttsy) 2m+2k4+3 + (m+ km t kt D+ ahaa, ms p) +566=p Qm +k + 12m +h + 2) (Am + 2k + 3)(2m + 2k + 5) kA-1) * Gr EIR Gm IEP MHMP G2) He BTS, ZEANSK (3.24) BORAT ED, BEAU s BLAS TH, BR Fass ls ms p) 33.1 Hi g) lo, HH lo. SHSRA R=0 |R=0.4 |R=1.0 |R=2.0 |R=4.0 | R=8.0 lo, -E£ | 4.00000 | 3.60157 | 2.90356 | 2.20525 | 1.50216 | 1.25514 ft. |1.0000 | 1.0081 {1.0926 | 1.1450 | 1.5780 | 5.3036 fr | 0.00000 | 0.01621 | 0.08598 | 0.29844 | 1.2575 | 10.957 t. | 0.000000 | 0.000040 | 0.001076 | 0.011461 | 0.14072 | 3.5141 te 0.000006 | 0.000184 | 0.006535 | 0.48848 h 0.000002 | 0.000167 | 0.03811 ho 9.000003 | 0.001904 fa 0.000066 te 0.000002 ew ft 1 1 1 1 1 #, |9.0000 | 0.0010 | 0.0062 | 0.0168 | 0.0313 | 0.0335 e: | 0.0000 | 0.0001 | 90.0003 | 0.0004 | 0.0002 | 0.0000 10% -E | 1.00000 | 1.02158 | 1.12962 | 1.33507 | 1.39110 | 1.24721 h 1.0000 | 1.0025 | 1.1071 | 1.0842 | 1.4102 | 3.4774 ts | 0.000000 | 0.001638 | 0.01146 | 0.05717 | 0.29540 | 2.1260 hs 0.000001 | 0.000037 | 0.000861 | 0.018184 | 0.42668 fr 0.000006 | 0.000543 | 0.043288 tr 0.000010 | 0.002655 fa 0.009109 fa 0.000003 ew {1 1 1 1 1 1 ge: | 1.0000 | 0.6418 | 0.2935 | 0.1019 | 0.0480 | 0.0341 gz, | 0.0000 | 0.0001 | 0.0005 | 0.0005 } 0.0002 | 0.0000RA s APR. UA AR A + om SR, » By Bl, Hl + m HAR, s BRAK. AN G.24) BREMEN DORAN AAS AR, ARBRE, WRB LRA VGABI PTE I PC, m, MERA Rh, ME FEL, m, pH UR R BLED. TER 3.1, BLA HT AY lo, lo, SHC mp) AURA AEN & HMR, TS (3.19) a aL(a) ah lor ane | + (4 +2RA— pe— ene =0 EV=12bAAA. OHRAA, CMT RHER. & LQ) = t= 18a + De YL) (3.26) rp o= Rm 1 (3.27) ? inl = (3.28) HF (3.36) RRA 3.19) KE 2 ay sa — ey SE + [—Cm + 26 — 1)? +26 —2p—1) +(m+1)] a + Lolo + mg +olt+2p)+ m(m+l+o)+A —ply=o0 (3.29) WIT BILAL RBER S Y= Set G30) +BRALER AH 0 TNR. 2 WERAR ogi — Bigs + igi = 0 (3.31) rp a=(¢+1)G+m+1) B= 2°4+(4p—2oH—A+t p—2po —(m + 1)(m + 0) r= G@—-1—olt-1—o—m) (3.32) FA ag, OR 3.31) SX, RR ¢ POM AIRIR, UG EUBLAR SEB (3.30) HORTLE , M&F co i ATO 7 aig tt a-—l fig, fa mento G33) ensue smal. 4 + mee, eu)” oy om, TEA — 1 Sh, BM RA LILAC BEALL 0 Bil0o, SK HERED GURRLARTE. BUA ga = 0, FE, aA 331) ATM og: — Bego = 0 (3.34) BLE (3.30) RIERA BAO, NEATH BOT OER SE. US oo 1 ALR BR SMEG) RE SIERAAM ¢,. H 3.1 BPI Hi Alo, Filo, SHY goes Bl gs HIE. DIR, oS a, 8 Rl 7, BH, CMLL m, p, Ae Bioeth (3.31) a (3.33) RBI — PF m, ps A Flo AR. (LA SEE m, p HI) BRUTE, Bait o fit ih m, pA) REN EMMA AT ESI, HALLO te RADA, MATRA RRE TRE o HUH DR. PBR. m, 1 Ae EM, BOTAN REIEA AK 16 AAD CATR BI o AO STREETERS TE Dm fa BARI, o AUIS AU AT RAL, RATS ALE APA, FBLA Btn, @O—) tee WERE. Bont, FR +596Cn — DART BAR B+ o HOTT HER BBA, AA n—I>l FEAL | REBUM 0 FPRGHYTE MER, All » PRR 1 FPR TE eH. it WE AREN 2,1, mM p. BA-MEN o SHAM. Ta tS 2 HRP. HH (3.27) Al (3.20) TS , OBR BETELHE FF fe a9 Fa Fie oh YH ’ 2 BE Gt m+ 1p - {Ho Skin, 1, m Ale EMD, hie RSW RAR, Alt BPM n,m RI R OREN. EEA) SER, E RRSP. FARAY Hy RAY Hie SHORE E=r++ R WEARER, 2 Ae RE R ERY EE AER FE tha i. 3.2.2 BHA ALR LA), M(x) Fl Cb) RA (3.16) KR, IRE Ti BG3.15) BORE. TEM, BER AM —PRA. WE HMONRBA, MRAM, RARER Mn, Me He, A n—1>1 l>m m feb 0 FRAN. A ASPB PM 2, 2 Am IR AREAT BE. ATRIA WOM 2. MS 1,2, 3,+° RAR MF l= 0,1, 2-6: ss ps do ++ RRs WF m= 0,1, 2, -++sF os w, O5°--R. Mh HT RABRRSOF,A Do, BEM ARE, EMM, A RAath RES R. SRR FA BRBRAE, AEH, Ae RR. BRKRWCRKEES 4 BER + BAR. + 60+WH, 4S RB FO Tey md By PA ROAR RS TA FR Ad wr por ote Ak, LQ) AaB. ME (3.24) Rh, Es WES G+ m)— Boke M(—n) = D5 (—1)P 2.) =(-D"M (a) HE Dp + 2) = (—-1)"(4) FRE FO, wd + x) = (-1)9C, ws $) BURA SRE TPR, 5) AE. SRL, METRPAME ME RAISS, Wa PR FR oO sa, 2s0, | 350, 2 pc, | 3 P04 3do, 3 pity 3am, 3d, FL #2 BU AT Ho 2, m A gu) RAR. (LAA = ll e(u) RAV WBEX, 9 Ml R—PRSOE + 61sAACR BASS 2 1 ES, RRR RO FRE RSS PCRS BCP MCE Ah BD I SOR, OE Bh ED RGSNA PRS OS IRR ER A, Moy, 20,,°--H Ings? wg, +++ XM PIEH RK PAFREABRMAFAT, CNA Do SRE FERN. OFRRRRFOF, BPE Fi Cow ST ERE Fd FOR OREM PR OR EINER ES. BR SH PRA-T+H FORA, MAFF ESRF ARB ARFLShARRARE TRU, WOT HMS—TEF AOI Bh INS BIO ie FA PE — AEISBAG, F HE LUE STS A FE AE PAV). ARAM T HT PAV Fias), Aiba EA Ws. 3.2.3 RR AK BK ROB TE 5S FS AY AR BR AK 3.2 AD EAS PTET HO BS FR ee HS AS LS Be A ee TS SB Bh eR A IRAE 4 SRL, CE HERARA. SA 3.2 BL, BRIT 0 0 WY, ARAL eh IC RA. RRR T REIL TOA. 4 REF ON MMF Hy We Hy} +H + Ht ARF REBE-MRP LE, REFERRERS BS HEE, BN ; 2 Hp 1,2, 3, +++, AH PRP TRAE RE RE FRBAN , PLRABFLA MERWE. Mle, M1 le, MEL, les, 20, A Ing SMF Ls 3h BUA FB Fithn = 112 AER. 626 E,=—