ESTIMATION OF FERRIC IRON (Redox Titrations) Posted by Ritesh Jain | 10:59 | Applld Cnemisy |S comments » ‘Aim: To estimate the amount of Ferric iron in the whole of the given solution using a standard solution of Potassium Dich-omate ‘Apparatus: 100 mi stenderd flask, Burette, Conical Flask, 20 mi Pipette, Simple balance with weights Chemicals Required: K2Cr207, SnCI2, HgCl2, HCI, Ferric ion solution, H2S04, Ortho phosphoric acid, Diphenylamine & distilled water. Principle: Ferric Iron is reduce to ferrous iron by stannous chloride in the present of Hydrochloric acid at 2 temperature of 70-800, The excess stannous chloride Is remaved by the addition of mercuric chloride, The ferrous iron formed is titrated with standard Potassium Gichramate solution in the presence of Sulphuric acid ané Phosphoric acid using ¢iphenylamine as indicator Chemical reactions: 2FeCI3 + SnCI2 -> 2FeCI? + Sncla Sncl2 + 2HgCi2 -> Sncla + Hg2cl2 K2Cr207 + 4H2S04 -> K2504 + Cr2(S04)3 + 4420 + 3(0) 2FeSO4 + H2S04 + (0) -> Fe2(SO4)3 + H20 k2cr207 = 3(0) Procedure: 1. Preparation of standard potassium dichromate: Weigh out accurately the given pure crystalline sample of potassium dichromate and transfer into 100 mi standard (volumetric) flask provided with a funnel. Dissolve the dichromate in a small quantity of cistillec water, and make upto the mark, The contents in the flask are shaken well for Uniform concentration, Calculate the normality of potassium dichromate, 2, Estimation of ferric iron: Make up the given ferric iron solution upto the mark of the 100m! standard flask with distilled water and shake well for uniform concentration. Pipette out 20m! of the ferric solution into a clean conical flask and 10ml of conc. HCI and heat the solution to boiling. The colour of the solution changes to clear yellow. Add stannous chloride solution drop by drop into the hot iren solution from a burette til the yellow colour disappears. Cool the solution under a tap and add 10 mi of saturated solution of mercunc chloride in one portion silky white precipitate of mercurous chloride is obtained, (if the solution turns black, due to formation of finely divided mercury, Ciscard the solution anc take fresh solution of ferric iron and reduce) ade 20 mi of the acid mixture and 3 to 4 crops of diphenylamine indicator and titrate against standard solution of potassium dichromate til the green colour changes to blue violet, Repeat the titration for concurrent value and calculate the normality of iron solution. Preparation of Standard solution: jelght of bottle + substance ams feight of bottle = ons (Wiaw2y coms, WI-W2) X 10)/Equivatent = (wa-wa) x 10/49 To search, type and hit enter Enires (R88) EConments 8) 4 peopl keh Sgr Upta se wnat your ian Followers (6) Bar aw Cram] 8088 Microprocessor (8) 2015 (1) ‘gpl Creme (3) 20118) ‘Assorbly Language (6) C Programs (14) computer Graphice (2) DSP Preseam (2) MATLAB @) Hou (13) Sumeespress Click neve to submit your site to the svarch engines fr toe! htphwsubmitdomainnamNo] Vole af andard | Bares Reading | Volane oF selon V3) consume (VD bY Taitial | Final, oo 1 |20m 2 from 3 [rom vi=20al NI = Normality of K2Cr207 solution 1N2 = Normality of Ferric iron solution V1 = Volume of k2Cr207 solution V2 = Volume of Ferric iron solution = 20 ml Navi = N2v2 N2 = (NIV,)/V2 Normality of Ferric iron solution = N2 = (NA V4)/V2 ‘Amount of Ferric iron present in the whole of the given solution (100 ml) IN2 Xx 55.85)/10 Result: Amount of Ferric ron present In the whole of the given solution (200 mt) = om. 5 comments Unknow 14 Juy 20193 10:05 ‘Because C1207 ean onde erous to freon Ferre on canna bs oxdzed further eos as ts the most table oxedation stat of rn and generation of feret Janis so dficu needed extreme condi), Unknown 1/31 July 209 a 18:42 Wich normal stannous clorde i oped fr reduction? Unknown i 24 August 2019 09:06, Why we use suture acid? Unknown i! 17 Oster 2019 at 19:28 pretence of acide medium..2e te gvan above Unknown Maren 202% at 222 ‘The volo colors eo to wha comslex? ‘Suoserbe to: Bost Gamments (om)