Celdas electrolíticas y sus

componentes
Electrolyzer doubler

Magnet doubles hydrogen yield from water splitting

A gently bubbling electrolyzer (left) suddenly doubles its output of hydrogen
and oxygen when a magnet is placed next to the anode (right).

https://cen.acs.org/physical-chemistry/Magnet-doubles-hydrogen-yield-water/97/web/2019/06 Nat. Energy 2019, DOI: 10.1038/s41560-019-0404-4

 8O Is2 2s2 2p4

¿Cuántos e- hay en O2 ?

¿Cómo se acomodan los

orbitales moleculares?

¿PARAMAGNÉTICO?

TRIPLETE
1s

Mutiplicidad = 2 |Σspin| + 1
Mutiplicidad = 2 |(+½ + ½)| + 1 = 3
Son de la Negra
Negrita de mis pesares
ojos de papel volando
negrita de mis pesares
ojos de papel volando

A todos diles que sí

pero no les digas cuándo

así me dijiste a mí
por eso vivo penando.
 Electrocoagulation:
Uses the products from both sides

+ -
OH- H2
Fe2+
OH-
 Electrocoagulation of
Oily Wastewater

a) Stabilization of an oil-
water emulsion by a
surfactant

b) Early stages in the

coalescence of oil
droplets.
 Electrocoagulation of
Oily Wastewater

Experimental Set-up
 Electrocoagulation of
Oily Wastewater

GC analysis of
fatty acids
extracted with
hexane and
derivatized with
sodium methoxide

Time
 Electrocoagulation of oily wastewater

Variation of sunflower
seed oil concentration
with electrolysis time
Electrocoagulation in a plastic pipet or a 10-mL beaker

O O

S
O
Br

Me
Me OH
Br
N N Br Br
OH
CO 2 H NMe 2

Methyl red Bromocresol green

 Simultaneous production of electroluminescence
Is it possible to obtain convergent simultaneous
production of electroluminescence ?
2,3-aminophthalohydrazide

NaOH NaOH + luminol

Anodic Electroluminescence
of Luminol

Luminol in a basic medium (pH = 9)

 How about generating an oxidant at the cathode?
ClO- known to produce CL with luminol

Frost diagram of Cl species

11
Luckily ClO2- does NOT!!!
10

7
0
6
-10

Current (µ A)
5
pH 0
-nE

-20
4 pH 14 -30

3 -40

2 -50

1 -60
-1000 -800 -600 -400 -200 0 200 400
0
Potential (mV vs. Ag/AgCl)
-1

Cathodic LSV
-2
-1 0 1 2 3 4 5 6 7 8

Oxidation number

for ClO2-
 Energy Optimization:
Simultaneous Electroluminescence

9-V
battery

Luminol in NaOH + H2O2

 Anodic Cathodic

OPTICAL FIBER OCEAN OPTICS SPECTROPHOTOMETER

3000 600

2500 500
Intensity (counts)
Intensity (counts)

2000 400

1500 300

200
1000
100
500
0
0 200 300 400 500 600 700 800 900
200 300 400 500 600 700 800 900 Wavelength(nm)
Wavelength (nm)
Added bonus: Minute wandering stars
20
= Luis Michael

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