Chemistrypg 1

POST GRADUATE PROGRAMME 2.
Dissertation may be offered by regular students

only in lieu of one paper of Final Year
1. At each of the Previous and Final Year Examination as prescribed in the syllabus of the
Examination in a subject, a candidate must subject concerned. Only such candidates will be
obtain for a pass (i) at least 36 % marks of the permitted to offer dissertation who have secured
aggregate marks in all the papers prescribed at atleast 50% marks in the aggregate at the
the examination, and (ii) atleast 36% marks in previous examination.
practical, wherever prescribed, at the
examination; provided that if a candidate fails to Note: Dissertation shall be type-written and shall
secure 25% marks in each individual paper of be submitted in triplicate, so as to reach
theory at any of the examination and also in the Controller of Examinations atleast two
the Dissertation; wherever prescribed, he/she weeks before the commencement of
shall be deemed to have failed at the Examination.
examination, notwithstanding his/her having
3. There shall be atleast eight theory in Post-
obtained the minimum percentage of marks
Graduate Examination, 4 in Previous and 4 in
required in the aggregate for the examination.
Final year examinations of 100 marks each
Division will be awarded at the end of the Final
unless and otherwise prescribed. The non-credit
Examination of the combined marks obtained at
papers wherever prescribed will remain as such.
the Previous and the Final Examinations taken
The marks of these non-credit papers will not be
together as noted below. No Division will be
counted for division but passing in the same is
awarded at the Previous Examination.
compulsory.
First Division : 60 Percent of the total aggregate 4. Each theory paper will be of three hours duration.
Second Division: 48 Percent marks of Previous and 5. Wherever practicals are prescribed the scheme
will be included in the syllabus.
Third Division : 36 Percent Final year taken
together 6. A candidate who has completed a regular course
of study for one academic year and Passed M.A.
Note : The candidate is required to pass separately / M.Sc./ M.Com. Previous Examination of the
in theory and practicals. university shall be admitted to the Final Year
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Examination for the degree of Master of Arts / from re-appearing in a subsequent year in the
Master Of Science / Master of Commerce following papers :
provided that he / she has passed in atleast 50%
of the papers at the previous examination by (a) Where a candidate fails for want of securing the
obtaining atleast 36% marks in each such paper. minimum percentage in the aggregate marks,
he/she shall be exempted from re-appearing in
(a) For reckoning 50% of the papers at the previous such paper (s) Practical (s). Dissertation in which
examination, practical will be included and one he/she has secured atleast 36% marks; provided
practical will be counted as one paper. he/she is passing in atleast 55% of the papers.
(Here passing in each paper requires 36%
(b) Where the number of papers prescribed at the marks).
previous examination is an odd number it shall
be increased by one for the purpose of reckoning (b) Where a candidate secures the minimum
50% of the paper. requisite including dissertation wherever
prescribed but fails for want of minimum
(c) Where a candidate fails for want of securing percentage of marks prescribed for in each
minimum aggregate marks but secured 36% individual paper / dissertation, he / she shall
marks in atleast 50% of the papers, he/she will be exempted from reappearing in such paper (s)
be exempted from re-appearing in those papers dissertation in which he/she has secured atleast
in which he/she has secured 36% marks. 25% marks provided he/she is passing in atleast
50% of the paper (here passing in each paper
(d) Where the candidate secures requisite requires 25% marks)
minimum percentage in the aggregate of all the
papers but fails for want of the requisite minimum
percentage of marks prescribed for each
individuals paper he/she shall be exempted from
re-appearing in such paper (s) in which he /
she has secured atleast 25% marks.
7. A candidate who has declared fail at the Final

Year Examination for the degree of Master of
Science / Arts, Commerce shall be exempted
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M.Sc. (PREVIOUS) CHEMISTRY, PAPER-I
2004-2005 INORGANIC CHEMISTRY
The examination shall consist of four theory papers Time : 3 Hrs. M.M. 100
and one practical.
Note: The paper will be divided into THREE sections.
Paper & Course Hrs/week M. Marks Section-A : Ten questions (short type answer) two
from each Unit will be asked. Each question will be
Paper-I Inorganic Chemistry 4 100 of one mark and the candidates are required to attempt
all questions. Total 10 marks
Paper-II Organic Chemistry 4 100
Section-B : Five questions (answer not exceeding 250
Paper-III Physical chemistry 4 100
words) one from each Unit with internal choice will
be asked and the candidates are required to attempt
Paper-IV Recent Trends in
Chemistry 4 100
all questions. Each question will be of 10 marks.
Total 50 marks
Practicals (Three groups) 18 (per group) 200
Section-C : Four questions may be in parts covering
all the five Units (answer not exceeding 500 words)
will be asked. The candidates are required to attempt
any TWO questions. Each question will be of 20 marks.
Total 40 marks
UNIT-I
Metal ligand bonding - Limitations of CFT, Ligand

field theory, MOT-octahedral, tetrahedral and square
planar complexes, MO theory & π-bonding, correlation
(Walsh diagrams) dπ - pπ bonding.
Electronic spectra of transition metal complexes-

Spectroscopic ground states, Orgel and Tanabe -
Sugano diagram (d1 to d9 states), calculation of Dq, B
and b parameters, charge transfer spectra
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UNIT-II Books Recommended :
Metal π- complexes - I – Carbonyls, structure and 1. Advanced Inorganic Chemistry, F.A.Cotton and
bonding, use of vibrational spectra of metal carbonyls Wilkinson, John Wiley.
for bonding and structure elucidation, types of
carbonyls, their preparations and important reactions. 2. Inorganic Chemistry, J.E Huhey, Harpes & Row
UNIT-III 3. Chemistry of the Elements, N.N. Greenwood and

A. Earnshow, Pergamon
Metal π- complexes - II - Preparation, bonding,
structure and important reactions of transition metal 4. Inorganic Electronic Spectroscopy, ABP Lever,
nitrosyls, dinitrogen and dioxygen complexes. Elsevier
UNIT-IV 5. Magnetochemistry, R.L. Carlin, Springer Verlag
Boranes - Preparation and important reactions, 6. Comprehensive Coordination Chemistry (Eds.) G.

electron deficient characters of boranes, structure Wilkinson, R.D Gillars and J.A McCleverty,
and bonding in boranes, concept of multicentric Pergamon.
bonding and M.O description, Lipscomb concept of
bonding elements, semitopological description of s, t,
y and x nomenclature.
Silicones - Preparation, properties and structure of

silicones , their industrial and technical importance.
UNIT-V
Sulphur-Nitrogen compounds - Preparation, proper-

ties of tetrasulphur tetranitride, disulphur dinitride,
polythiozyl and other sulphonitrides, sulphur imides.
Phosphorus- Nitrogen compounds - Linear and cyclic

polymers, their synthesis and reactions, structure
and bonding, Allock’s skeletal π—bonding concept.
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PAPER-II Stereochemistry - Conformational analysis of
ORGANIC CHEMISTRY cycloalkanes, decalins, effect of conformation on
reactivity, conformation of sugars, steric strain.,
Time : 3 Hrs. M.M. 100 chirality, molecules with more than one chiral center,
threo and erythro isomers, methods of resolution,
optical purity, enantiotopic and diastereotopic atoms,
Section-A : Ten questions (short type answer) two groups and faces, stereospecific and stereoselective
from each Unit will be asked. Each question will be of synthesis, asymmetric synthesis, optical activity in
one mark and the candidates are required to attempt the absence of chiral carbon (biphenyls, allenes and
all questions. Total 10 marks spirane), chirality due to helical shape.
Section-B : Five questions (answer not exceeding 250 UNIT-II

Reaction mechanism, structure and reactivity -
Kinetic and thermodynamic control, Hammond’s
postulate, Curtin-Hammett principle, potential energy
Total 50 marks
diagrams, transition states and intermediates,
Section-C : Four questions may be in parts covering methods of determining mechanisms, iostope effects,
all the five Units (answer not exceeding 500 words) effect of structure on reactivity-resonance and field
will be asked. The candidates are required to attempt effects, steric effect, steric inhibition to resonance,
any TWO questions. Each question will be of 20 marks. substituent and reaction constants, Taft equation.
Total 40 marks
Aliphatic nucleophilic substitution - The SN2, SN1,
UNIT-I mixed S N 1 & S N 2, S N i and SET mechanisms,
neighbouring group participation.
Nature of bonding in organic molecules - Delocalized
chemical bonding-conjugation, cross conjugation,, Classical and nonclassical carbocations, phenonium
bonding in fullerenes, aromaticity in benzenoid and ions, norbornyl system, common carbocation,
non-benzenoid compounds, annulenes, ferrocenes and rearrangements, nucleophilic substitution at an
helicenes, alternant and non-alternant hydrocarbons, allylic, aliphatic trigonal and a vinylic carbon,
Huckel’s rule, energy level of π-molecular orbitals, reactivity-effects of substrate structure, attacking
anti-aromaticity, ψ-aromaticity, homo-aromaticity, nucleophile, leaving group and reaction medium,
PMO approach. ambient nucleophile, regioselectivity.
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Aliphatic electrophilic substitution - SE2 and SE1 reaction involving electrophiles, nucleophiles and free
mechanisms, electrophilic substitution accompanied radicals, regio and chemoselectivity, orientation and
by double bond shifts, effect of substrates, leaving reactivity, addition to cyclopropane ring, hydrogenation
group and the solvent polarity on the reactivity. of double bond, triple bonds and aromatic rings,
hydroboration, cyanoethylation.
UNIT-III
Aromatic electrophilic substitution - The arenium Addition to carbon-hetero multiple bonds -

ion mechanism, orientation and reactivity, energy Mechanism of metal hydride reduction of saturated
profile diagrams, the ortho/para ratio, ipso attack, and unsaturated carbonyl compounds, addition of
orientation in other ring systems, diazonium coupling, Grignard reagents, organozinc and organolithium
Vilsmeir - Haak reaction, Bischler-Napieralske reagents to carbonyl and unsaturated carbonyl
reaction, Pechmann reaction. compounds, Wittig reaction, mechansim of conden-
sation reaction involving enolates, Mannich, Benzoin,
Aromatic nucleophilic substitution - The SNAr, SN1,
Perkin and Stobbe reactions, hydrolysis of esters and
benzyne and SRN1 mechanisms, reactivity - effect of
amides ammonolysis of esters.
substrate structure, leaving group and attacking
nucleophile. The Von Richter, Sommetet-Hauser and
Elimination reaction - The E2, E1, ElcB and E2c
Smiles rearrangements.
mechanisms and their spectrum, orientation of the
Free radical reaction - Types of free radical reactions, double bond, reactivity-effect of substrate structures,
free radical substitution mechanism, neighboring attacking base, the leaving group and the medium,
group asistance, reactivity for aliphatic and aromatic stereochemistry, elimination v/s substitutions,
substrate at a bridgehead, reactivity in the attacking pyrolytic eliminations.
radicals, the effect of solvents on reactivity, allylic
halogenation (NBS), oxidation of aldehydes to UNIT-V
carboxylic acids, autooxidation, coupling of alkynes
Reagents in organic synthesis - Use of the following
and arylation of aromatic compounds by diazonium
reagents in organic synthesis and functional group
salts, Sandmeyer reaction, free radical rearrange-
transformation, Gilman’s reagent, lithium dimethyl
ment, Husdiecker reaction.
cuprate LDA, dicyclohexylcarbodiimide, trimethyl silyl
UNIT-IV iodide, tributyltin hydride, DDQ, Baker yeast, Peter-
Addition to carbon-carbon multiple bonds - sons synthesis, Merrifield resins, 1,3 - dithiane,
Mechanistic and stereochemical aspects of addition selenium oxide, osmium tetroxide.
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Books Recommended : PAPER-III
PHYSICAL CHEMISTRY
1. Advanced Organic Chemistry-Reactions,
Mechanism and Structure, Jerry March, John Time: 3 Hrs. M.M. 100
Wiley.
2. Advanced Organic Chemistry, F.A. Carey and R.J.
Sundberg, Plenum Section-A : Ten questions (short type answer) two
from each Unit will be asked. Each question will be
3. A Guide book of Mechanism in Organic
of one mark and the candidates are required to attempt
Chemistry, Peter Sykes, Longman
4. Structure and Mechanism in Organic Chemistry,
Peter Sykes, Longman Section-B : Five questions (answer not exceeding 250
5. Modern Organic Reactions, H.O. House, Benjamin be asked and the candidates are required to attempt
6. Principles of Organic Synthesis, R.O.C. Norman
Total 50 marks
and J.M. Coxon, Blackie Academic & Professional
7. Reaction Mechanism in Organic Chemistry, S.M. Section-C : Four questions may be in parts covering
Mukherji and S.P. Singh Macmillan. all the five Units (answer not exceeding 500 words)
8. Stereochemistry of Organic Compounds, D. any TWO questions. Each question will be of 20 marks.
Nasipuri, New Age International. Total 40 marks
9. Stereochemistry of Organic Compounds, P.S Kalsi, UNIT-I

New age International.
Quantum chemistry - The Schrodinger equation and
10. Organic Reaction and Their Mechanisms, P.S.
the postulates of quantum mechanics, solutions of
Kalsi, New Age International.
the Schrodinger equation to some model system viz..
11. Organic Reaction Mechanism, V.K. Ahluwalia and particle in a box, the harmonic oscillator.
R.K. Parshar, New Age International.
Approximate methods - The variation theorem and
12. Stereochemistry of Organic Compounds, E.L. Eliel. its applications, hydrogen atom.
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Angular momentum - Ordinary angular momentum, microcanonical ensembles, corresponding distribution
generalized angular momentum, eigen functions and laws (using Lagrange’s method of undetermined
eigen values of angular momentum, operators, algebra multipliers)
of operators, ladder operators, addition of angular
momenta, spin, antisymmetry and Pauli’s exclusion Partition function, translational, rotational, vibrational
principle. and electronic partition functions, calculation of
thermodynamic properties in terms of partition
Electronic structure of atoms - Electronic configu- functions, applications of partition functions.
ration, Russell-Saunder’s terms and coupling
schemes, molecular orbital theory, Huckel theory of Chemical equilibrium and equilibrium constant in
conjugated systems, bond order and charge density terms of partition functions, Fermi-Dirac statistics,
calculations, application to ethylene and butadiene. Bose-Einstein statistics, distribution law.
UNIT-II Non-equilibrium thermodynamics - Thermodynamic

criteria for non-equilibrium states, entropy production
Classical thermodynamics - Brief resume of concepts and entropy flow, entropy balance equations for
of laws of thermodynamics, free energy, chemical different irreversible processes (e.g. heat flow,
potential and entropies, partial molar properties, chemical reaction etc.) transformations of the
partial molar free energy, partial molar volume and generalized fluxes and forces, non – equilibrium
partial molar heat content and their significance, stationary states. phenomenological equations,
determinations of these quantities. microscopic reversibility and Onsager’s reciprocity
relations.
Non-ideal systems - excess function for non-ideal
solutions, activity, activity coefficient. UNIT-III
Debye-Huckel theory for activity coefficient of Chemical dynamics - Methods of determining rate
electrolyte solutions, determination of activity and laws, collision theory of reaction rates, steric factor,
activity coefficients, ionic strength. activated complex theory, Arrhenius equation and the
activated complex theory, ionic reactions, kinetic salt
Statistical thermodynamics - Concept of distribution, effects, steady state kinetics, kinetic and
thermodynamic probability and most probable thermodynamic control of reactions, chain reactions,
distribution, ensemble averaging, postulates of photochemical reactions (Hydrogen-bromine and
ensemble averaging, canonical, grand canonical, and hydrogen-chlorine reactions) oscillatory reactions,
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(Belousov-Zhabotinsky reaction), homogeneous Guoy-Chapman, Stern, Graham-Devanathan-
catalysis, kinetics of enzyme reactions, general Mottwatts, Tobin, Bockris, Devanathan models, over
features of fast reactions. potentials, exchange current density, derivation of
Butler-Volmer equation, Tafel plot, semiconductor
UNIT-IV interfaces, theory of double layer at semiconductor,
electrolyte - solution interfaces, structure of soluble
Surface adsorption chemistry - Surface tension, Gibbs
layer interfaces, effect of light at semiconductor
adsorption isotherm, estimation of surface area (BET
solution interface, electrocatalysis, electrocardio-
equation), surface films on liquids (Electrokinetic
graphy, bioelectrochemistry.
phenomenon), catalytic activity at surfaces.
Book Recommended :
Micelles - Surface active agents, classification of
surface active agents, micellization, hydrophobic 1. Physical Chemistry, P.W Atkins, ELBS
interaction, critical micellar concentration (CMC),
2. Introduction to Quantum Chemistry, A.K.
factors affecting the CMC of surfactants, counter ion
Chandra, Tata McGraw Hill
binding to micelles, thermodynamics of micellization,
solubilization, micro-emulsion, reverse micelles. 3. Quantum Chemistry, I. N. Levine, Prentice Hall
Macromolecules - Definition, types of polymers, 4. Coulson’s Valence, R. McWeeny, ELBS

electrically conducting, fire resistant and liquid 5. Chemical Kinetics, K.J. Laidler, Mcgraw-Hill
crystal polymers, kinetics of polymerization, mecha-
nism of polymerization, molecular mass, number and 6. Kinetics and Mechanism of Chemical Transfor-
mass average molecular mass, molecular mass mations, J. Rajaraman and J. Kuriacose,
determination (osmometry, viscometry, diffusion and McMillan.
light scattering methods), sedimentation. 7. Micelles, Theoretical and Applied Aspects, V.
Moroi, Plenum
UNIT-V
8. Modem Electrochemistry Vol. I and Vol.II, J.O.M.
Electrochemistry - Debye-Huckel-Onsager treatment
Bockris and A.K.N. Reddy, Plenum
and its extension, ion-solvent interactions, Debye-
Huckel-Jerum mode, derivation of electro-capillarity, 9. Introduction to Polymer Science, R.Gowarikar,
Lippmann equations (surface excess), methods of N.V. Vishwanaman and J. Sridhar, Wiley Eastern.
determination, structure of electrified interfaces,
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PAPER-IV industrial pollution due to cement, sugar distillery,
RECENT TREND IN CHEMISTRY drug, paper and pulp, thermal and nuclear power
plants, metallurgical and polymer industries, a brief
Time: 3 Hrs. M.M. 100 idea of toxicological effects of arsenic , lead, cadmium,
mercury, ozone, PAN, cyanide, pesticides, oxides of
nitrogen, sulphur and carbon, carcinogens
Section-A : Ten questions (short type answer) two
UNIT-II
from each Unit will be asked. Each question will be of
one mark and the candidates are required to attempt Analysis of pollution – Sampling and monitoring of
all questions. Total 10 marks air and water, determination of total dissolved solids,
conductivity, acidity, alkalinity, hardness, chloride,
sulphate, fluoride, phosphate and different forms of
nitrogen, phenols, pesticides, surfactants, DO, BOD
and COD, microorganisms-the catalysts of aquatic
chemical reactions, water pollution laws and
Total 50 marks
standards.
Section-C : Four questions may be in parts covering UNIT-III
will be asked. The candidates are required to attempt Microwave spectroscopy - Theory, selection rules,
any TWO questions. Each question will be of 20 marks. diatomic molecule as non-rigid rotator, symmetric top
Total 40 marks molecules, P-Q-R-bands, instrumentation, limitations
and application.
UNIT-I
Raman spectroscopy – Theory, Stokes and anti-Stokes
Environmental chemistry – Atmosphere-chemical lines, Raman depolarization ratio, instrumentation,
and photochemical reactions in the atmosphere, intensity of Raman peaks, applications.
oxygen and ozone chemistry, green house gases and
effect, hydrosphere - physical chemistry of sea water, Mossbauer spectroscopy – Theory, Mossbauer
eutrophication, sewage treatment, lithosphere and nuclides, instrumentation and applications
chemistry involved, smog formation, acid rains, Bhopal
Photoelectron spectroscopy – Franck - Condon
gas tragedy, Chernobyl, minamata disasters,
principle, types of electron spectroscopy, ESCA-theory,
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instrumentation and applications, Auger emission to FORTRAN. The instructor may choose another
spectroscopy–theory, instrumentation and applica- language such as BASIC or C and the features may
tions. be replaced appropriately). Elements of the computer
language, constants and variables, operations and
Atomic absorption spectroscopy – Principle, symbols, expressions, arithmetic assignment state-
instrumentation and applications ment, input and output, format statement, termi-
nation statements, branching statements such as IF
UNIT-IV
or GO TO statement, LOGICAL variables, double
Green chemistry – Green reagent-dimethyl carbonate precision variables, subscripted variables and
and other polymer supported reagents, green DIMENSION, DO statement, FUNCTION and SUB-
catalysts-acid catalyst, basic catalysts, oxidation ROUTINE, COMMON and DATA statements.
catalysts, polymer supported catalysts, photocatalyst,
green synthesis-phase transfer catalyst. microwave Programming in chemistry – Determination of (i)
induction, ultrasound assisted, green solvents- activity coefficient using Debye-Huckel limiting law
reactions in acidic and neutral ionic liquids, green (ii) root mean square, average and most probable
synthesis of polycarbonates, paracetamol, ibuprofen , velocities (iii) critical constants of a gas (iv) disso-
citral, urethane, adipic acid and styrene. ciation constant of a weak acid from equivalence
conductance (v) electronegativity of an atom using
UNIT-V Pauling’s relation (vi) normality, molarity and molality
of solution (vii) solubility of sparingly soluble salts (viii)
Introduction to computers and Computing (only
concentration of complex using Beer-Lambert’s Law
overview required) – Basic structure and functioning
(ix) half life and average life of radioactive nucleus
of computers with a PC an an illustrative example,
(x) lattice energy of a crystal using Born-Lande
memory, I/O devices, secondary storage, specification
equation.
of a typical PC, operating systems with DOS as an
example, introduction to UNIX and WINDOWS, data Books Recommended :
processing, principles of programming, algorithms and
flow-charts, brief idea of packages such as MATLAB, 1. Modern Spectroscopy, J.M. Hollas, John Wiley
MS-OFFICE and FOXPRO
2. Applied Electron Spectroscopy for Chemical
Computer programming in FORTRAN/C/BASIC - Analysis, Ed.H. Eindawi and F.L.H. Wiley Inter-
(The language features are listed here with reference science.
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3. NMR, NQR, EPR and Mossbauer Spectroscopy in M.Sc. (PREV.) CHEMISTRY, 2004-2005
Inorganic Chemistry, R.V. Parish, Ellis Harwood.
Duration 16 Hrs M.M. 200
4. Physical Methods in Chemistry, R.S. Drago,
Saunders. (i) Inorganic Practicals 60 Marks
5. Basic Principles of Spectroscopy, R. Chang, (ii) Organic Practicals 60 Marks

McGraw Hill.
(iii) Physical Practicals 60 Marks
6. Computers and Common Sense, R. Hunt and J.
(iv) Seminar 20 Marks
Shelley, Prentice Hall.
Total 200 Marks
7. Computational Chemistry, A.C. Norris.
INORGANIC PRACTICALS
8. Microcomputer Quantum Mechanics, J.P. Killng-
back, Adam Hilger. Duration 6 Hrs. (one day) M.M. : 60
9. Computer Programming in FORTRAN IV.V Distribution of Marks:

Rajaraman, Prentice Hall.
1. Qualitative analysis 18 Marks
10. An Introduction to Digital Computer Design, V. (3 marks for each radicals)
Rajaraman and T. Radhakrishnan, Prentice Hall
2. Quantitative analysis Volumetric 12 marks
11. Spectroscopy of Organic Compounds, P.S Kalsi,
New Age International Ltd. 3. Preparation/ Chromatrography 10 Marks
12. Green Chemistry, P.Anastas, RSC. 4. Viva-Voce 10 Marks
13. Environmental Chemistry, S.E. Manahan, Lewis 5. Sessional/Record 10 Marks

Pub.
Total 60 Marks
14. Environmental Chemistry, Sharma and Kaur,
List of Experiments -
Krishna Pub.
1. Qualitative analysis - Qualitative analysis of
15. Environmental Chemistry, A.K. De, Wiley Eastern
inorganic mixture containing SIX radicals from the
16. Environmental Chemistry, C. Baird, W.H. Freem following list: (at least two from Group B)
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Ten mixtures are compulsory to be done during the (iv) Prussian Blue, Turnbull’s Blue.
session.
(v) Co[(NH 3)6][NO 2]6
Group A - Carbonate, Sulphite, Sulphate, Sulphide,
Nitrite, Acetate, Oxalate, Nitrate, Chloride, Iodide, (vi) Cis-[Co(trien)(NO 2)2]Cl.H 2O
Phosphate, Fluoride, Borate, Silver, Lead Mercury,
(vii) Hg[Co(SCN)4]
Bismuth, Copper, Cadmium, Tin, Arsenic, Antimony,
Aluminium, Chromium, Iron, Nickel, Cobalt, Zinc, (viii) [Co(Py)2Cl2]
Manganese, Calcium, Barium, Strontium, Magnesium,
Ammonium. (ix) [Ni(NH 3) 6]Cl 2
Group B - Thiosulphate, Cyanate, Thiocyanate, Hypo- (x) Ni (dmg)2

chlorite, Chlorate, Percholrate, Iodate, Persulphate,
(xi) [Cu(NH 3) 4]SO 4.H 2O
Silicate, Chromate, Arsenate, Benzoate, Thalium,
Tungsten, Molybdenum, Vanadium, Beryllium, Ura- (xii) VO(acac) 2
nium, Thorium, Titanium, Zirconium, Cerium.
OR
2. Quantitative analysis -
Separation of cations and anions by paper chroma-
Volumetric determination of two components ( binary)
tography/column chromatography/ ion exchange.
mixture containing any two of the following; Copper,
Zinc, Silver, Nickel, Calcium, Magnesium, etc. (three
exercises to be performed in practice).
3. Preparation of any ten complexes
(i) TiO(C9H8NO)2. H2O
(ii) Cis-K[Cr(C 2O 4) 2(H 2O) 2]
(i) Na[Cr(NH 3) 2(SCN) 4]
(ii) Mn(acac) 3
(iii) K 3 [Fe(C 2 O 4 ) 3]
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ORGANIC PRACTICALS (iii) Estimation of glucose by titration using Felhing’s
solution/Benedict solution
Duration 6 Hrs. (one day) M.M. 60
(iv) Estimation of carbonyl group by using 2,4-
Distribution of Marks
dinitrophenylhydrazine
Exercises
(v) Determination of iodine and saponification value
1. Qualitative analysis 20 Marks of an oil sample
2. Quantitative analysis 10 Marks 3. Organic synthesis (One experiment to be

performed from the following in the examination)
3. Organic Synthesis 10 Marks
4. Viva-voce 10 Marks Acetylation - Acetylation of salicyclic acid using

acetyl chloride
5. Record 10 Marks
Benzoylation - Benzoylation of phenol/aniline/glycine
Total 60 Marks
Oxidation - Phenathquinone from phenanthrene
List of Experiments
1. Qualitative Analysis - (Organic mixture) Sandmeyer reaction - p-Chlorotoluene from p-

toluidine
Separation, purification and identification of
compounds in a binary mixture (solid-solid or solid- Acetoacetic ester condensation - Synthesis of ethyl-
liquid). One mixture to be given in the examination, n-butylacetoacetate
suitable derivatives to be prepared, wherever possible.
Cannizaro reaction – Any p- substituted benzaldehyde
2. Quantitative Analysis (one experiment to be as substrate
performed in the examination)
Backmann rearrangment – Acetanilide from
(i) Determination of equivalent weight of an acid by acetopheone
silver salt method
Claisen-Schmidt condensation – Benzalaceto-
(ii) Estimation of phenol/aniline using bromate- phenone/ benzalacetone/dibenzalacetone from
bromide solution or acetylation method. benzaldehyde
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Books Recommended : M.Sc. (PREVIOUS) CHEMISTRY, 2004-2005
1. Advanced Practical Organic Chemistry, N.K. PHYSICAL PRACTICALS

Vishnoi
Duration 6 Hrs. (one day) M.M. 60
2. A Hand Book of Organic Analysis, H.T Clarke
3. Systematic Quantitative Organic Analysis, H.
Middleton, Edward Arnold Lts. Exercises
4. Text Book of Practical Organic Chemistry, Arthur 1. Experiment-I 20 Marks

I Vogel, ELBS.
2. Experiment-II 20 Marks
3. Viva-voce 10 Marks
5. Record/sessional 10 Marks
Total 60 Marks
Exercises -
1. Adsorption
To study surface tension-concentration relationship

for solutions (Gibb’s equation)
2. Phase equilibria
(i) Determination of congruent composition and

temperature of a binary system (e.g. diphenyla-
mine-benzophenone system).
(ii) Determination of glass transition temperature of

a given salt ( e.g CaCl2) conductometrically.
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3. Chemical kinetics (iii) Determination of the activity coefficient of zinc
ions in the solution of 0.002 zinc sulphate using
(i) Determination of the effect of (a) change of
Debye-Huckel’s limiting law.
temperature (b) change of concentration of
reactants and catalysts and (c) ionic strength of (iv) Verify Ostwald dilution law and calculate disso-
media on the velocity constant of hydrolysis of an ciation constant of weak acid
ester or ionic reactions.
(v) Verify Kohlrausch’s law
(ii) Determination of the velocity constant of
hydrolysis of an ester or ionic reaction in micellar (vi) Determine basicity of weak organic acid
media.
(vii) Determine the solubility of sparingly soluble salts
(xiii) Determination of the primary salt effect on the and its solubility product.
kinetics of ionic reactions and testing of the
Bronsted relationship (iodide ion-persulphate ion) 5. Potentiometry/pH metry
(xiv) Determination of the rate constant for the (i) Determination of strength of halides in a mixture
oxidation of iodide ions by hydrogen peroxide (the potentiometrically
kinetics as an iodine clock reaction).
(ii) Determination of the valency of mercurous ions
(xv) Flowing clock reactions potentiometrically
(xvi) Oscillatory reaction.
(iii) Determine the strength of strong and weak acids
4. Conductometry in a given mixture using a potentiometer/pH meter
(i) Determination of velocity constant and order of (iv) Determination of the formation constant of copper
the reaction for saponification of ethyl acetate by - ammonia complex and stoichiometry of the
sodium hydroxide conductometrically. complex potentiometrically
(ii) To study the effect of solvent on the AgNO3/acetic (v) Determination of activity and activity coefficient
acid and to determine the degree of dissociation of electrolytes
and equilibrium constant in different solvents and
in their mixture (DMSO, DMF, dioxane, acetone, (vi Determination of the dissociation constant of
water) and to test the validity of Debye - Huckel- acetic acid in DMSO, DMF, acetone and dioxane
Onsager theory. by titrating it with KOH.
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(vi) Determination of the dissociation constant of 2. Experimental Physical Chemistry, Berman and
monobasic or dibasic acid. Tipper
6. Polarimetry 3. Practical Physical Chemistry, Arthur M. James
(i) Determination of rate constant for hydrolysis/ 4. Advanced Physical Chemistry Experiment, J. Rose
inversion of sugar using a polarimeter
5. Experiments in Physical Chemistry, Wilson, New
(ii) Enzyme kinetics-inversion of sucrose Cowrbe, Denaro, Rickert and Wincent
7. Chromatography
6. Practical Physical Chemistry, J.B. Yadav
Separation of inorganic ions or organic compounds by
7. Experiments in Physical Chemistry, J.C. Ghosh
paper chromatography or thin layer chromatography
8. Findlay’s Practical Physical Chemistry revised by
8. Distribution law
B.P. Levitt.
(i) Complex formation between copper sulphate and
9. Experimental Physical Chemistry, D.P. Shoe-
ammonia
maker, C.W Garland and J.W Niber.
(ii) Equilibrium constant of the reaction between
iodine and potassium iodide.
9. Photochemistry
(i) Photochromism in Aberchrome 540 or malachite

green or potassium ferrocyanide-phenolphthalein
system
(ii) Determination of quantum yield
(iii) Photooxidation of leucomethyl crystal violet.
Books Recommended :
1. Practical Physical Chemistry, Alexander and

Findlay.
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M.Sc. (FINAL) CHEMISTRY, 2005-2006 PAPER–I
GROUP THEORY AND SPECTROSCOPY
The examination shall consist of four theory papers
and one practical. The candidate will select two papers Time: 3 Hrs. M.M. 100
from any group- Group A, B, C or D.
Paper & Course Hrs/week M. Marks
Paper-I Group theory and from each Unit will be asked. Each question will be of
Spectroscopy 4 100
one mark and the candidates are required to attempt
Paper-II Photochemistry and
Supramolecular
Chemistry 4 100
Elective Papers
Paper-III-A Coordination and Organo-
metallic Chemistry 4 100
Paper-IV-A Modern Interfaces of
Inorganic Chemistry 4 100 Total 50 marks
Paper-III-B Modern Aspects of Organic
Chemistry 4 100
Paper-IV-B Chemistry of Heterocyclic
and Natural Products 4 100 will be asked. The candidates are required to attempt
Paper-III-C Chemical Kinetics 4 100
Total 40 marks
Paper-IV-C Quantum Mechanics and
Photochemistry 4 100
UNIT-I
Paper-III-D Electroanalytical and
Separation Methods 4 100
Symmetry and group theory in chemistry –
Paper-IV-D Analytical Chemistry and Symmetry elements and symmetry operations,
Spectral Metods 4 100
definitions of group, subgroups, relation between
Practicals Group A 18 200
orders of a finite group and its subgroup, similarity
Group B 18 200 transformation and classes, point groups, Schonflies
Group C 18 200 symbols, representation of groups by matrices
Group D 18 200 (representation for the Cn, Cnv, Cnh, Dnh, etc. groups to
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be worked out explicitly), character of a represen- Nuclear magnetic resonance spectroscopy – Theory,
tation, the great orthogonality theorem (without proof) instrumentation, chemical shift, spin-spin coupling,
and its importance, character tables and their use. coupling constants, factors affecting chemical shift,
vincinal coupling and stereostructure, proton
UNIT-II exchange reactions, geminal non-equivalence
(rotation around single bonds), ring inversion, shifts
Applications of group theory – The reduction formula,
reagents, spin decoupling, deuterium labelling and
hybridisation in BF 3, CH 4 or [PtCl 4 ] 2- , vibrational
exchange, nuclear overhauser effect, C 13 n.m.r.,
modes in H2O, BF3, crystal field splitting of orbitals
applications of 1H and 13C n.m.r spectroscopy, brief
in octahedral complexes, delocalisation energy of
idea of COSY, NOESY, DEPT, INEPT, APT, 2D nmr and
butadiene.
INADEQUATE techniques.
UNIT-III
UNIT-IV
Ultra-violet and visible spectroscopy – Electronic Mass spectrometry - Ionisation of a molecule on
transitions, instrumentation, shift of bands with electron impact-EI, CI, FD, FAB, instrumentation,
solvents, the isolated double bond, conjugated dienes, molecular ion, the base peak, the metastable peak,
effects of geometrical isomerism (steric effect, effect the nitrogen rule, the effect of isotopes, mass spectra
of alkyl substitution and ring residues), exocyclic of different classes of compounds, McLafferty re-
double bonds, Woodward-Feiser rule, effect of strain arrangement, Retro Diels-Alder reaction.
around the diene chromophore, polyenes, UV spectra
Optical rotatory dispersion – Principle, Cotton effect
of carbonyl compounds, unsaturated aldehydes and
curve, octant rule, applications.
ketones, UV spectra of benzene and its derivatives,
other applications of UV spectroscopy. Electron spin resonance spectroscopy - Principles,
instrumentation, applications, Combined applications
Infra-red spectroscopy – Molecular vibrations, of UV-visible, I.R., NMR and Mass spectroscopy for
calculation of vibrational frequencies, instrumen- elucidation of structure of some simple molecules
tation, finger print region, i.r of alkanes and effect of
UNIT-V
some functional groups, effect of hydrogen bonding,
Fermi resonance, overtones, shifting of bands due to Vibrational spectroscopy – Symmetry and shapes of
inductive and mesomeric effects, aromatic and AB 2 , AB 3 , AB 4 , AB 5 and AB 6 molecules, mode of
heteroaromatic compounds, effect of ring strain, bonding of ambidentate ligands, ethylene diamine and
applications of IR spectroscopy, brief idea of FT-IR. diketonato complexes.
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NMR of paramagnetic substances – The contact and PAPER–II
pseudo contact shifts, factors affecting nuclear PHOTOCHEMISTRY AND
relaxation, applications to inorganic systems including SUPRAMOLECULAR CHEMISTRY
biochemical systems.
Time: 3 Hrs. M.M. 100
Nuclear quadrupole spectroscopy – Quadrupole,
nuclear quadrupole moments, electric field gradient, Note: The paper will be divided into THREE sections.
coupling constant splitting and applications.
Books Recommended - from each Unit will be asked. Each question will be of
1. Group Theory and its Application to Chemistry, all questions. Total 10 marks
K.V. Raman, Tata McGraw Hill, New Delhi
2. Symmetry and Group Theory, Ramashanker and words) one from each Unit with internal choice will
S.C. Ameta, Himanshu Publications. be asked and the candidates are required to attempt
3. Group Theory, F.A Cotton.
Total 50 marks
4. Spectroscopy of Organic Compounds, P.S Kalsi,
Wiley Eastern.
5. Application of Absorption Spectroscopy of Organic will be asked. The candidates are required to attempt
Compounds, J.R. Dyer, Prentice-Hall any TWO questions. Each question will be of 20 marks.
Total 40 marks
6. Carbon-13 NMR Spectroscopy, J.B Stothers,
Academic Press. UNIT-I
7. Mass Spectroscopy-R Davis, M. Frearson, Wiley Photochemistry

Eastern. Photochemical reactions – Interaction of electro-
magnetic radiations with matter, types of excitations,
8. Spectrophotometric Identification of Organic
fate of excited molecule, quantum yield, transfer of
Compounds, Silverstein and Basseler, Wiley
excitation energy, actinometry.
9. Spectroscopy, Y.R Sharma, S. Chand and Co, New
Determination of reaction mechanism – Classifi-
Delhi
cation, rate constants and life times of reactive energy
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states - determination of rate constants of reactions, UNIT-IV
effect of light intensity on the rate of photochemical Supramolecular chemistry–I - Introduction, nature
reactions, types of photochemical reactions, photo- of supramolecular interactions, cation binding hosts,
dissociation, gas-phase photolysis. crown ethers, lariat ethers, podands, cryptands,
Photochemistry of alkenes – Intramolecular spherands, macrocyclic and template effects,
reactions of the olefinic bond-geometrical isomerism, calixarenes, siderophores, binding of anions- two
cyclisation reactions, rearrangement of 1,4 – and 1,5- dimensional and cyclophane hosts, guanidinium
dienes. based, organometallic and neutral receptors, anti-
crowns, hydride sponge and other Lewis acid chelates,
UNIT-II
binding of neutral molecules, solid states clathrates,
Photochemistry of carbonyl compounds – Intra- fullerene as guest, host and superconducting inter-
molecular reactions of carbonyl compounds-saturated, calation compounds.
cyclic and acyclic, β, γ-unsaturated and α, β-unsatu- UNIT-V
rated compounds, cyclohexadienones, inter-molecular
Supramolecular chemistry–II - Templates and self-
cycloaddition reactions-dimerisations and oxetane
assembly-tennis balls and soft balls, catenanes and
formation.
rotaxanes, helicates, molecular knots, supramolecular
Photochemistry of aromatic compounds - Isomeri- photochemistry, semiochemistry, molecular electronic
sations, additions and substitutions devices-swithes, wires and rectifiers, dendrimers
Miscellaneous photochemical reactions - Photo- Books Recommended :
Fries reactions of anilides, Photo-Fries rearrange- 1. Photochemistry, J.G Cavert and J.N. Pitts, Wiley
ment, Barton reaction, singlet molecular oxygen 2. Molecular Photochemistry, N.J. Turro, Benjamin
reactions, photochemical formation of smog, photo-
3. Fundamentals of Photochemistry, K.K. Rohatgi
degradation of polymers, photochemistry of vision.
Mukherji, New Age
UNIT-III
4. Photochemistry, R.P. Wayne, Butterworth
Pericyclic reactions – Electrocyclic reactions, 5. Analytical Chemsitry of Macrocyclic and Supra-
cycloaddition reactions and sigmatropic reactions, molecular compounds, S.M. Khopkar
frontier molecular orbital and perturbation molecular
6. Supramolecular Chemistry, J.M. Lehn, VCH
orbital methods, correlation diagram and selection
7. Supramolecular Chemistry, J.W Stead and J.L.
rules.
Atwood, John Wiley.
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ELECTIVE PAPERS UNIT-II
PAPER–III (A) Coordination compounds - I.R spectra of transition

COORDINATION AND ORGANOMETALLIC metal complexes, theoretical principles and interpre-
CHEMISTRY tation of experimental observations, isomerism of co-
ordination compounds, magnetic properties of co-
Time: 3 Hrs. M.M. 100 ordination compounds, paramagnetism, ferro-and anti
– ferromagnetism, measurement of magnetic suscep-
Note: The paper will be divided into THREE sections. tibility and temperature effect.
Section-A : Ten questions (short type answer) two Optical activity of coordination compounds, symmetry
from each Unit will be asked. Each question will be of requirements for optical activity, study of ORD,
one mark and the candidates are required to attempt circular dichroism, cotton effect with special reference
all questions. Total 10 marks to complexes of Cr, Co, Ni and Pt .
Section-B : Five questions (answer not exceeding 250 UNIT-III

Reaction mechanism of transition metal complexes
- Energy profile of a reaction, reactivity of metal
complexes, inert and labile complexes, kinetics,
Total 50 marks
application of valence bond and crystal field theories,
Section-C : Four questions may be in parts covering kinetics of octahedral substitution, acid hydrolysis,
all the five Units (answer not exceeding 500 words) factors affecting acid hydrolysis, base hydrolysis,
will be asked. The candidates are required to attempt conjugate base mechanism, direct and indirect
any TWO questions. Each question will be of 20 marks. evidences in favour of conjugate mechanism, anation
Total 40 marks reactions, reactions without metal ligand bond
cleavage, substitution reactions in square planar
UNIT-I complexes, the trans effect, mechanism of the
substitution reaction, redox reactions, electron
Complexion equilibria – complex ion equilibrium in transfer reactions, mechanism of one electron
solution, stability constants (step wise and overall transfer reactions, outer sphere type reactions, cross
stability constants), factors affecting stability cons- reactions and Marcus Hush theory, inner sphere type
tants, methods of determining stability constants reaction.
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UNIT-IV Books Recommended :
1. Principle and Applications of Organotransition
Metal storage transport and biomineralization,
Metal Chemsitry, J.P. Coliman, L.S Hegsdus, J.R.
ferritin, transferrin and siderophores
Norton and R.G. Finke, University Science Books.
Calcium in biology - Calcium in biology in living cells, 2. The Organometallic Chemistry of the Transition
transport and regulation, molecular aspects of inter- Metals, R.H. Crabtree, John Wiley.
molecular processes, extracellular binding proteins
3. Metallo-Organic Chemistry, A.J. Pearson, Wiley
Metalloenzymes - Zinc enzymes-carboxypeptidase and 4. Principles of Bioinorganic Chemistry, S.J. Lippard
carbonic anhydrase, iron enzymes-catalase, peroxi- and J.M. Berg, University Science Books
dase and cytochrome P-450, copper enzymes-
5. Bioinorganic Chemistry, I. Bertini, H.B. Gray, S.J.
superoxide dismutase, molybdenum oxatransferase
Lipparad and J.S Valentine, University, Science
enzymes-xanthine oxidase, coenzyme vitamin B12.
Books
Metal - nucleic acid interactions – Metal ions and 6. Inorganic Biochemistry Vols I and II. Ed G.L.
metal complex interactions, metal complexes-nucleic Eichhorn, Elsevier
acids. 7. Progress in Inorganic Chemistry, Vols 18 and 38
Ed. J.J. Lipparad, Wiley
UNIT-V
Transition metal π-complexes – Transition metal π-

complexes with unsaturated organic molecules,
alkenes, alkynes, allyl, diene, dienyl, arene and
trienyl complexes, preparations, properties, nature of
bonding and structural features, important reactions
related to nucleophilic and electrophilic attack on
ligands and to organic synthesis, Transition metal
compounds with bonds to hydrogen
Fluxional organometallic compounds – Fluxionality

and dynamic equllibria in compounds such as η2 –
olefin, η2 -allyl and dienyl complexes.
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PAPER IV-A reactions, promt and delayed photochemical reactions,
MODERN INTERFACES OF INORGANIC d-d- and charge transfer reactions.
CHEMISTRY
Photochemical reactions of coordination compounds
Time: 3 Hrs. M.M. 100 - Chromium (III) complex, cobalt (III) complexes,
radium (III) complex, complexes of transition elements,
complexes of lanthanides and actinides.
Applications of photochemical reactions of
coordination compounds – Synthesis, catalyst,
chemical actinometry, photochromism and photocalo-
rimetry
words) one from each Unit with internal choice will UNIT–II
Inorganic polymers - Classification of inorganic
polymers, general properties, preparation of conden-
Total 50 marks
sation, addition and coordination polymers.
Silicone polymers - General preparation, properties
and applications of silazanes, polysilazenes, organo-
siloxy and poly - carbosilanes.
Total 40 marks Ferrocene - Synthesis and applications of ferrocene
UNIT-I containing polyamide and polyurea polymers.
Inorganic photochemistry - Ligand field excited state, UNIT-III

charge transfer excited state, ligand to metal, metal
Phosphorus-nitrogen polymers - Synthesis and
to ligand, charge transfer to solvent, tenteraligand
important properties of organo metallic poly -
stage, metal to metal stage, Thexi stage and OSENCO
phosphazene, liquid-crystalline-high refractive index
state.
polyphosphazene, polycarbo phosphazene, poly thio
Photochemical reactions - Photosubstitution phosphazene and other types of phosphazenes such
reaction, photo - rearrangement reaction, redox as organic polymer with cyclophosphazene side groups,
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cyclo linear and cyclomatrix material, inorganic Books Recommended
ceramics derived phosphazene, applications of
polyphosphazene and other related polymers such as 1. Environmental Chemistry, S.E. Manahan, Lewis
advanced elastomers and premedical materials. Pub.
UNIT-IV 2. Environmental Chemistry, Sharma and Kaur,

Krishna Pub.
Environmental inorganic chemistry -
3. Environmental Chemistry, A.K. De, Wiley,
(i) Inorganic pollutants and monitoring - Eastern.
Air pollution – Types of air pollutants, sources and 4. Environmental Chemistry, C. Baird, W.H. Freem
control, ozone layer depletion and effect on biotic
community, climate protection of ozone layer, sampling 5. Concepts of Inorganic Photochemistry, A.W.
and monitoring, analysis of CO, NO x , SO 2 , H 2 S, Adamson and P.D Fleischauer, Wiley.
particulate matter.
6. Photochemistry of Coordination Compounds, V.
Water pollution and monitoring - Inorganic Balzani and Carassiti, Academic Press.
chemicals, metals and minerals as pollutants,
7. Elements of Inorganic Photochemistry, G.J.
radioactive materials and their effects, sampling and
Ferraudi, Wiley.
monitoring of water pollutants.
8. Inorganic Polymers - Grahm and Stone.
UNIT-V
9. Development in Inorganic Polymer Chemistry,
Industrial pollution - Cement, nuclear power plants,
M.F. Lappert and G.J. Leigh.
pollution due to metallurgy and mining activity.
10. Inorganic and Organometallic Polymers, M.
Metallic medicine - Metal deficiency and disease,
Zeldon, K.J. Wynne and H.R. Allcock.
metals used in diagnosis and chemotherapy with
particular reference to cancer drugs, tracer technique
in biological systems.
Toxicology - Biochemical effects of As, Cd, Pb, Hg,

Co, NOx, SO2, CN -
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M.Sc. (FINAL) CHEMISTRY, 2005-2006 3. Spectrophotometric Determinations
PRACTICALS, GROUP-A (i) Manganese/Chromium/Vanadium in steel sample
(ii) Nickel/Molybdenum/Tungsten/Vanadium/Ura-
Duration: 18 Hrs. (Spread over three days) M.M. 200
nium by extractive spectrophotometric method.
(iii) Fluoride/Nitrite/Phosphate.
1. Exercise 1 is compulsory 50 Marks (iv) Iron-phenanthroline complex by Job’s method of
continuous variations.
2. Out of unit 2-9, three exercise would
be given selecting not more than one (v) Zirconium-alizarin Red-S complex by mole ratio
from each unit : 25 x 3 = 75 Marks method
3. Seminar 20 Marks (vi) Copper-ethylenediamine complex by slope-ratio

method.
4. Report on Industrial Tour 15 Marks
(vii) Stability constant by Bjerrum’s method.
(viii) Stability constant by Turner-Anderson method
4. Sessional/Record 20 Marks
4. Flame photometric determinations
Total 200 Marks
(i) Sodium and potassium, when present together
Exercises (ii) Lithium/Calcium/Barium/Strontium
1. Volumetric estimation of two or three component (iii) Cadmium and magnesium in tap water
in a mixture (cations as well as anions) from (i)
Synthetic mixture (ii) Ores and minerals (iii) 5. Nephelometric determinations
Alloys (iv) Water/Industrial effluent samples (i) Sulphate
2. Preparation of selected inorganic compounds and (ii) Phosphate

their physico-chemical studies. (atleast 15
preparations) (iii) Silver
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6. Chromatographic separations PAPER–III (B)
MODERN ASPECTS OF ORGANIC
(i) Cadmium and zinc CHEMISTRY
(ii) Zinc and magnesium Time: 3 Hrs. M.M. 100
(iii) Thin layer chromatography; Separation of nickel, Note: The paper will be divided into THREE sections.
manganese, cobalt and zinc, Determinations of
Rf values. Section-A : Ten questions (short type answer) two
(iv) Separation and identification of the sugars present one mark and the candidates are required to attempt
in the given mixture of glucose, fructose and all questions. Total 10 marks
sucrose by the paper chromatography and
determination of Rf values
7. Solvent extraction (any one) be asked and the candidates are required to attempt
all questions. Each question will be of 10 marks
a. Uranyl nitrate from thorium nitrate with the help Total 50 marks
of tributyl phosphate
b. Separation of metal from a mixture all the five Units (answer not exceeding 500 words)
c. Study of the solvent extraction of Hg and Al with
8-hydroxyquinoline.
Total 40 marks
8. Magnetochemistry (one exercise) - UNIT-I
Determination of magnetic susceptibility and Reagents containing phosphorus, silicon and boron
moment by Gouy’s method. – preparation, properties and applications of following
in organic synthesis and mechanistic details.
9. Polarography – Determination of cadmium, lead,
etc. Selective organic name reactions – Hoffmann-Loffer-
Fretag reaction, chichibabin reaction, Sharpless,
asymmetric epoxidation, Barton reaction, ene
reactions, Stork enamine reaction.
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UNIT-II interconversions, elementary idea of disconnection
in Diels-Alder reaction, 1,3 – and 1, 5- difunctionalised
Oxidation – Introduction, different oxidative
compounds, α, β - unsaturated carbonyl compounds,
processes, hydrocarbons (alkenes, aromatic rings,
Michael reaction, Robinson annelation.
activated and inactivated saturated C - H groups),
alcohols, diols, aldehydes, ketones, ketals and Protecting group – Principle of protection of hydroxy,
carboxylic acids, singlet oxygen, ruthenium tetroxide amine and carbonyl groups.
and Tl (III) nitrate as oxidizing agent, Provost reaction,
Wacker’s process, Barbier-Wieland degradation UNIT-V
Reduction – Introduction, different reductive Bonds weaker than covalent - Addition compounds,
processes, hydrocarbons (cyclo alkanes, alkenes, crown ether complex and cryptands, inclusion
conjugated system, alkynes and aromatic rings), compounds, cyclodextrins, catenanes and rotaxanes.
carbonyl compounds, nitro, azo and oxime compounds,
Applications of the following in the organic
hydrogenolysis, reductions using Wilkinson’s catalyst,
synthesis – Phase transfer catalysts, polymer
Meerwein –Pondrof - Verley reduction.
supported reagents. biocatalysts, microwave and
UNIT-III ultrasound induced reactions.
Rearrangements - General mechanistic consi- Chemistry of fullerenes

derations-nature of migration, migratory aptitude,
Books Recommended :
memory effects.
1. Modern Synthetic Reactions, H.O. House, W.A
A detailed study of the following rearrangements -
Benjamin
Pinacol-Pinacolone, Wagner-Meerwin, Demjanov,
Benzil - Benzilic acid, Favorskii, Arndt-Eistert 2. Some Modern Methods of Organic Synthesis, W.
synthesis, Neber, Backmann, Hofmann, Curtius, Carruthers, Cambridge Univ. Press.
Schmidt, Benzidine, Bayer-Villiger and Shapiro
reaction. 3 Principles of Organic Synthesis, R.O.C Norman
and J.M. Coxon, Blackie Academic & Professional
UNIT-IV
4. Advanced Organic Chemistry, F.A Carey and R.J.
Disconnection approach – An introduction to Sundberg.
synthons, synthetic equivalents, functional group
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5. Rood’s Chemsitry of Carbon Compounds, S. Coffey. PAPER IV (B)
CHEMISTRY OF HETEROCYCLIC AND
6. Organic Synthesis-Concept, Methods and Starting NATURAL PRODUCTS
Materials, J. Fuhmop and G. Penzillin.
7. Guide Book to Organic Synthesis, R.K. Mackie &
D.M. Smith, ELBS. Note: The paper will be divided into THREE sections.
8. Organic Synthesis, V.K. Ahuwalia and Renu Section-A : Ten questions (short type answer) two
Agarwal, Narosa from each Unit will be asked. Each question will be of
9. Synthesis, Approaches in Organic Chemistry, R.K. all questions. Total 10 marks
Bansal, Narosa
10. Advanced Organic Chemistry -Reactions, Mecha- words) one from each Unit with internal choice will
nism and Structure, Jerry March, John Wiley. be asked and the candidates are required to attempt
11. Designing Organic Synthesis, S.Warren, Wiley.
Total 50 marks

Total 40 marks
UNIT-I
Nomenclature of heterocycles - Replacement and

systematic nomenclature (Hantzsch-Widman system)
for monocyclic, fused and bridged heterocycles.
Small ring heterocycles - Three membered hetero-

cycles with one and two hetero atoms-synthetic
methods, physical, spectroscopic and chemical
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properties of aziridines, oxiranes, thiiranes, diaziri- synthesis of the following representative molecules -
dines, diazirines, oxaziridines, four membered Citral, Geraniol, a-Terpineol, Menthol, Farnesol,
heterocyclic compounds - Synthetic methods, physical, Zingiberene, Santonin, Phytol, Abietic acid and β -
spectroscopic and chemical properties of azetines, Carotene
azetidines, oxetanes, thietanes and their carbonyl
Porphyrins - Structure and synthesis of haemoglobin
derivatives.
and chlorophyll.
UNIT-II UNIT-IV
Benzo-fused five membered heterocycles - Synthetic Alkaloids - Definition, nomenclature and physiological
methods, physical and chemical properties of action, occurrence, isolation, general methods of
benzopyrroles, benzofuranes and benzothiophenes. structure elucidation, degradation, classification
based on nitrogen heterocyclic ring, role of alkaloids
Six-membered heterocycles - Synthetic methods, in plants, structure, stereochemistry, synthesis and
physical and chemical properties of pyrilium salts, biosynthesis of following - Ephedrine, (+) - Coniine,
pyrones, quinolizinium salts, pyridazines, pyrimidines, Nicotine, Atropine, Quinine and Morphine.
pyrazines, acridines and phenanthridines
Plant pigments - Occurrence, nomenclature and
Seven membered heterocycles - Synthetic methods, general methods of structure determination, isolation
physical and chemical properties of azepines, and synthesis of Apigenin, Luteolin, Quercetin,
oxepines, thiepines and diazepins. Myrcetin, Quercetin-3-glucoside, Vitexin, Diadzein,
Butein, Aureusin, Cyanidin-7, arabinoside, Cyanidin
Meso-ionic heterocycles - Synthetic methods, and Hirsutidin.
properties of 1,3-oxazolium-4-olates, 1,3-oxathiolium-
Biosynthesis of flavonoids - acetate pathway and
4-olates, 1,3-diazolium-4-olates, 1,2,3-oxadiazolium-
shikimic acid.
5-olates and 1,2-diathiolium-4-olates
UNIT-V
UNIT-III
Steroids - Occurrence, nomenclature, basic skeleton,
Terpenoids and carotenoids - Classification, Diel’s hydrocarbon and stereochemistry, isolation,
nomenclature, occurrence, isolation, general methods structure determination and synthesis of Cholesterol,
of structure determination, isoprene rule, structure Bile acids, Androsterone, Testosterone, Estrone,
determination, stereochemistry, biosynthesis and Progestrone, Aldosterone, biosynthesis of steroids.
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Prostaglandins – Occurrence, nomenclature, classifi- M.Sc. (FINAL) CHEMISTRY, 2005-2006
cation, biogenesis and physiological effects, synthesis
of PGE2 and PGF2α. PRACTICALS, GROUP-B
Pyrethroids and Rotenones – Synthesis and reactions Duration: 18 Hrs. (spread over three days) M.M. 200
of pyrethrodis and rotenones.
Books Recommended-
1. Mixture 50 Marks
1 Heterocyclic Chemistry, R.R Gupta, M. Kumar and
2. Estimation 30 Marks
V. Gupta, Springer Verlag.
3. Preparation (Synthesis/Natural
2. The Chemistry of Heterocycles, T. Eicher and S.
Sources) 25 Marks
Hauptmann, Thieme.
4. Spectrophotometric estimation/
3. Heterocyclic Chemistry, J.A Joule, K. Mills and
Spectral analysis 20 Marks
G.F. Smith, Chapman and Hall
5. Seminar 20 Marks
4. Heterocyclic Chemistry, T.L. Gilchrist, Longman
Scientific Technical 6. Report on Industrial Tour 15 Marks
5. An Introduction to the Heterocyclic Compounds, 7. Record/ Sessional 20 Marks

R. M. Acheson, John Wiley.
6. Comprehensive Heterocyclic Chemistry, A.R
Kartritzky and C.W Rees. Total 200 Marks
7. Stereoselective Synthesis: A Practical Approach, Exercises

M. Nogradi.
1. Qualitative Analysis - Separation, purification and
8. New Trends in Natural Products Chemistry, Atta- identification of components of a mixture of three
ur-Rahman and M.I. Choudhary. organic compounds (three solids or two solids-one
liquid), separable by ether, NaHCO 3, solution, dil.
9. Chemistry of Natural Products, S.N. Bhat NaOH, dil. acid and distillation, derivatives of
components to be prepared, wherever possible.
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2. Quantitative Analysis - (one experiment to be Benzillic acid rearrangement -
given in the examination)
Benzoin → Benzil → Benzilic acid
(i) To estimate the percentage of nitrogen in the
Fisher-Indole synthesis - Preparation of 2-phenylin-
given organic sample by Kjeldahl’s method.
dole or 2-methylindole or 1,2,3,4-tetrahydrocarbazole.
(ii) To estimate a halogen in the given sample by the
Enzymatic reduction- Reduction of ethyl acetoacetate
alkaline reduction method (Modified Stepenow
using Baker’s yeast to yield enantiomeric excess of S
method).
(+) ethyl-3-hydroxybutanoate and to determine its
(iii) To estimate the percentage of sulphur in the given optical purity
organic sample by Messenger’s method. Synthesis using microwaves -
3. Synthesis of organic compounds (one synthesis Alkylation of diethyl malonate with benzyl chloride
to be given in the examination). The exercise should
illustrate the use of organic reagents and may involve Synthesis using phase transfer catalyst -
purification of the products by chromatographic
Alkylation of diethyl malonate or ethyl acetoacetate
technique.
with alkyl halides.
Photochemical reaction - OR
Benzophenone → Benzpinacol → Benzpinacolone Extraction of organic compounds from natural
sources (any one experiment is to be given in the
Backmann rearrangement -
examination).
Benzophenone → Benzophenone oxime → Benzanilide
1. Isolation of caffein from tea leaves
→ Benzoic acid.
2. Isolation of casein from milk (the students are
Acetophenone → Acetophenone oxime → Acetanilide
required to try some typical colour reactions of
→ p-Nitroacetanilide or p- bromoacetanilide.
proteins).
Hoffman and Sandmeyer reaction - 3. Isolation of lactose from milk (purity of sugar
should be checked by TLC and PC and Rf value
Phtahlic anhydride → Phthalimide → Anthranilic acid
reported).
→ o-Chlorobenzoic acid.
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4. Isolation of nicotine dipicrate from tobacco. Characterization of simple organic compounds on the
basis of given xerox copies of spectra (UV, IR, PMR
5. Isolation of cinchonine from cinchona bark
and Mass)
6. Isolation of lycopene from tomatoes Books Recommended :
7. Isolation of piperine from black pepper. 1. Systematic Identification of Organic Compounds,
R.I Shriner, R.C. Fusen and D.Y. Curtin.
8. Isolation of β-carotene from carrots
2. Spectrometric Identification of Organic Com-
9. Isolation of oleic acid from olive oil (involving the
pounds, R.M. Silverstin, C.G. Bassler and T.C.
preparation of complex with urea and separation
Merruill.
of linoleic acid).
3. Spectral and Chemical Characterisation of
10. Isolation of eugenol from cloves. Organic Compounds, W.J. Criddle and G.P. Ellis.
11. Isolation of (+) limonine from citrus rinds. 4. Experimental Organic Chemistry, M.P. Doyle and
W.S. Mungall.
4. Spectrophotometric (UV/VIS) Estimation (any
one experiment is to be given in the examination). 5. Experimental and Techniques in Organic
Chemistry, D. Pasto. C. Jhonson and M. Miller.
- Amino acids
6. Elementary Practical Organic Chemistry, Arthur
- Proteins I. Vogel.
- Carbohydrtates 7. Comprehensive Practical Organic Chemistry, V.K.
Ahluwalia and R. Aggrawal.
- Cholesterol
8. Advanced Practical Organic Chemistry, N.K.
- Ascorbic acid
Vishnoi.
- Aspirin 9. A Hand-book of Organic Analysis, Hans T. Clarke
- Caffeine 10. An Introduction to Chromatography, David Abbott
and R.B. Andrews.
OR
11. Systematic Qualitative Organic Analysis, H.
Spectral Analysis
Middleton
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PAPER-III (C) UNIT-II
CHEMICAL KINETICS
Principles of reactivity - Significance of entropy,
Time: 3 Hrs. M.M. 100 enthalpy and Gibb’s free energy, Arrhenius equation,
uses of activation parameters, potential energy
Note: The paper will be divided into THREE sections. diagrams and models, curve-crossing model, nature
of activation barrier in chemical reaction
Structure effect on rate - Linear free energy
constants relationship, Hammett equation, substi-
tution constants, theories of substituent effect,
interpretation of σ values and reaction constant ρ,
Section-B : Five questions (answer not exceeding 250 deviation from Hammett equation, the Taft model, σI
words) one from each Unit with internal choice will and σR scales, steric acceleration, molecular measu-
be asked and the candidates are required to attempt rements of steric effect upon rates.
all questions. Each question will be of 10 marks. UNIT-III
Total 50 marks
Kinetic isotope effect - Theory of isotope effects,
Section-C : Four questions may be in parts covering primary and secondary kinetic effect, heavy atom
all the five Units (answer not exceeding 500 words) isotope effect, tunneling effect, solvent isotope effect.
Solvation and solvent effect on rate - Factors
affecting reaction rate in solution, quantitative
Total 40 marks
understanding of solvent solute effects on reactivity -
thermodynamic measures of solvation, effect of
UNIT-I
solvation, effect of solvation on reaction rate, solvent
Techniques for rate determination - Slow reactions effect on ion - ion, ion – dipole and dipole – dipole
(solution and gas phase), fast reactions - stopped flow, reactions, preliminary idea about diffusion - controlled
relaxation, shock – tube method, flash photolysis, reactions.
NMR, optical and laser methods UNIT-IV
Methods for determining reaction mechanism and rate Homogeneous catalysis - Acid-base catalysis, specific
law. and general catalysis, Bronsted catalysis, nucleophilic
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and electrophilic catalysis, acidity function and their PAPER-IV(C)
applications, QUANTUM MECHANICS AND
PHOTOCHEMISTRY
Electron transfer processes in solution - Inner-
sphere, outersphere, bridged transition states, Marcus Time: 3 Hrs. M.M. 100
theory and its modifications, one equivalents and two
equivalent exchange reaction, reactions of solvated Note: The paper will be divided into THREE sections.
electron with metal ions. Section-A : Ten questions (short type answer) two
UNIT-V from each Unit will be asked. Each question will be of
Reaction on surfaces - Adsorption isotherm, structure all questions. Total 10 marks
of solid surface and adsorbed layers, mechanism of
surface reactions, unimolecular and bimolecular Section-B : Five questions (answer not exceeding 250
surface reactions, transition state theory of surface words) one from each Unit with internal choice will
reactions, surface chemistry in industrial processes. be asked and the candidates are required to attempt
Gas phase reaction - Hydrogen-oxygen reaction, Total 50 marks
combustion of hydrocarbons, decomposition of N2O5
and acetaldehyde, Gold, Finger- Lettort –Niclause rule Section-C : Four questions may be in parts covering
and inhibition mechanism. all the five Units (answer not exceeding 500 words)
Books Recommended : any TWO questions. Each question will be of 20 marks.
Total 40 marks
1. Surface activity and Detergency, K. Durham, Ed.
McMillan. UNIT-I
2. Emulsion and Foams, S. Berkman and G. Egloff, Experimental foundation of quantum theory, mathe-
Reinhold. matical techniques, postulates of quantum theory and
consequences of the postulates, Heisenberg principle
3. Surface Chemistry, J.B. Bikeman, Academic
of uncertainty, angular momentum, eigen values.
4. Chemical Kinetics, K.J. Laidler
Solution of the Schrodinger equation for some simple
5. Chemical Kinetics and Mechanism, A.A Frost and systems - Particle in a box, rigid rotator, harmonic
R.G. Pearson oscillator and the hydrogen atom.
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Approximate methods – Variation principle and UNIT-IV
peturbation theory, time dependent perturbations.
Stern-Volmer equation, excimer and excited state,
UNIT-II quenching by added substances, charge transfer
mechanism, quenching by oxygen, nitric oxide, para-
Group theory and symmetry properties – Definition of magnetic metal ions and triplet energy states,
group, symmetry operation and point groups, intramolecular energy transfer, energy transfer
representation of group characters, reducible repre- processes in rare earth chelates and coordination
sentation, relationship of group, group characters and compounds, fast multi step migration of excitation
reducible representation. energy.
Huckel molecular orbital theory and its applications Classification of photochemical reactions, rate
to organic chemistry-simple molecular orbital calcu- constants and lifetimes of reacting energy states,
lations, calculation of electron densities, bond order effect of light intensity on the rate of photochemical
and free valence. reaction, photofragmentation, isomerization and other
rearrangement reactions.
Ligand filed theory of the free atom, the atom in
UNIT-V
complex, energy level diagrams, magnetic and spectral
properties of complexes. Light sources and their standardization, actiono-
metry, chemical actinometry, measurement of emis-
UNIT-III sion characteristics, fluorescence, phosphore-scence
and chemiluminescence, techniques for study of
Laws of photochemistry, units and dimensions, types
transient species in photochemical reactions, laser
of electronic transitions, charge transfer transitions,
and photochemical reactions.
potential energy diagram, Franck-Condon principle,
crossing of potential energy surfaces, geometry of Origin of life, mutagenic effects of radiation, photo-
some electronically excited molecules. synthesis, photoelectrochemistry of excited state
redox reactions, solar energy conversion and storage.
Types of photophysical pathways, radiation less
transitions, internal conversion (IC) and intersystem Books Recommended :
crossing (ISC), fluorescence emission and structure,
1. Basic Quantum Chemistry by Leon, Wiley (1965)
triplet states and phosphorescence emission, delayed
fluorescence. 2. Quantum Chemistry, R.K. Prasad
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3. Photochemistry, J.G. Cavert and J.N. Pitts, Wiley M.Sc.(FINAL) CHEMISTRY, 2005-2006
(1966)
PRACTICAL, GROUP-C
4. Molecular Photochemistry, N.J. Turro, Benjamin
(1966) Duration: 18 Hrs. (spread over three days) M.M. 200
5. Fundamentls of Photochemistry, K.K. Rohatgi- Distribution of Marks

Mukherjee, New Age
1. Experiment-I 50 Marks
6. Photochemistry, R.P. Wayne, Butterworth, (1970)
2. Experiment-II 50 Marks
7. Quantum Chemistry, I. Levine
3. Experiment-III 25 Marks
4. Seminar 20 Marks
5. Report on Industrial Tour 15 Marks
6. Viva-Voce 20 Marks
7. Record/Sessional 20 Marks
Total 200 Marks
Exercises :
1. Thermodynamics
(i) Determination of partical molar volume of solute

(e.g. KCl) and solvent in a binary mixture.
(ii) Determination of the temperature dependence of

the solubility of a compound in two solvents having
similar intermolecular interactions (benzoic acid
in water and in DMSO- water mixture) and
calculation of the partial molar heat of solution.
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2. Spectroscopy (v) To study the kinetics of potassium dichromate
and oxalic acid reaction.
(i) Determination of pKa of an indicator (e.g. methyl
red) in (a) aqueous and (b) micellar media. (vi) Determination of activation energy and entropy
of activation.
(ii) Determination of stoichiometry and stability
constant of inorganic (e.g. ferric-salicyslic acid) 5. Conductivity
and organic (e.g. amine-iodine) complexes.
(i) Conductometric titration of a mixture of KCl and
(iii) Characterization of the complexes by electronic KI.
and IR spectral data.
(ii) Determination of hydrolysis constant of aniline
(iv) Estimate P as P 2 O 5 in given sample of rock hydrochloride
phosphate.
(iii) To verify Debye-Huckel-Onsager limiting law
(v) Estimate iron in given sample of lime, dolomite,
(iv) Determination of solubility and solubility product
etc.
of sparingly salts (e.g. PbSO4, BaSO4)
3. Polarography
6. Photochemistry :
Determination of dissolved oxygen in the aqueous
(i) Kinetics of photohydration of pyridine in aqueous
solution of organic solvents.
solution
4. Chemical kinetics
(ii) Photochemical reduction of Fe(III) by citrate ion
(i) To study primary salt effects in oxidation of iodide
(iii) A Chemiluminescence clock reaction
ion by persulphate ion.
(iv) Chemical Actinometry
(ii) The effect of solvent on alkaline hydrolysis of
crystal violet. Books Recommended :
(iii) Reduction of aqueous solution of ferric chloride 1. Practical Physical Chemistry, Alexander and
by stannous chloride. Findlay.
(iv) To study the kinetics of reaction between 2. Experimental Physical Chemistry, Berman and
persulphate and iodide. Tipper
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3. Practical Physical Chemistry, Arthur M. James. PAPER-III(D)
ELECTROANALYTICAL AND SEPARATION
4. Advanced Physical Chemistry Experiments, J. METHODS
Rose.
5. Experiments in Physical Chemistry, Wilson, New
Cowrbe, Denaro, rickert and Wincent. Note: The paper will be divided into THREE sections.
6. Practical Physical Chemistry, J.B. Yadav. Section-A : Ten questions (short type answer) two
7. Experiments in Physical Chemistry, J.C. Ghosh. one mark and the candidates are required to attempt
8. Findlay’s Practical Physical Chemistry, Revised,
B.P. Levitt. Section-B : Five questions (answer not exceeding 250
9. Experimental Physical Chemsitry, D.P. Shoe-
maker, C.W Garland and J.W Niber.
Total 50 marks

Total 40 marks
UNIT-I
Polarographic techniques - A.C. polarography, square

wave and pulse polarography, oscillopolarography
Voltammetry - Reversible and irreversible electrode

process, equation for cathodic and anodic waves,
current controlled by linear diffusion towards special
surfaces, llkovic equation, kinetic and catalytic
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currents, coupled chemical reactions and their signi- Gel permeation/size exclusion chromatography -
ficance. introduction, theory and applications.
UNIT-II UNIT-V
Ion-exchangers - Theory, action of ion-exchange

Voltammetric sweep techniques - Single sweep
resins, ion-exchange chromatography, exchange
technique, cyclic voltammetry, differential pulse
capacity, ion-exchange resins and liquid ion-exchange
polarography, anodic stripping voltammetry (ASV),
resins, applications of cation and anion ion-
differential pulsed anodic stripping voltammetry,
exchangers.
advanced chromotechniques.
Solvent extraction - Introduction, principles, factors
Ion selective electrodes - Principles, construction that influence solvent extraction, ion association
and selection, general applications, applications in complexes and applications of solvent extraction.
analysis of common ions.
Books Recommended :
UNIT-III
1. Analytical Chemistry, G.D Christian, J. Wiley.
Separation techniques - 2. Fundamental of Analytical Chemistry, D.A Skoog,
D.M. West and F.J. Holler, W.B. Saunders.
Adsorption and partition chromatography - (a)
Definition of terms, techniques and chemical 3. Analytical Chemistry-Principles and Techniques,
concepts, (b) Column adsorption chromatography, (c) L.G. Hargis, Prentice Hall.
Partition chromatography-column, paper and TLC
4. Analytical Chemistry-Principles, J.H. Kennedy,
UNIT-IV W.B. Saunders.
5. Principles of Instrumental Analysis, D.A Skoog and

High performance liquid chromatography -
J.L. Loary, W.B. Saunders.
Introduction, choice of the system, instrumentation
and applications. 6. Quantitative Analysis, R.A Day, Jr. and A.L.
underwood, Prentice Hall
Gas liquid chromatography - Introduction, choice of
the system, instrumentation, qualitative and 7. Environmental Solution Analysis, S.M. Khopkar,
quantitative analysis of mixtures. Wiley Eastern.
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8. Basic Concept of Analytical Chemistry, S.M. PAPER-IV (D)
Khopkar, Wiley Eastern. ANALYTICAL CHEMISTRY AND SPECTRAL
METHODS
9. Handbook of Instrumental Techniques for
Analytical Chemistry, F. Settle, Prentice Hall Time: 3 Hrs. M.M. 100
10. Instrumental Methods of Analysis, Chatwal and Note: The paper will be divided into THREE sections.
Anand.
11. Vogel’s Textbook of Quantitative Inorganic from each Unit will be asked. Each question will be of
Analysis, L. Barret et al. ELBS (Longmann’s Ed.) one mark and the candidates are required to attempt

Total 50 marks

Total 40 marks
UNIT-I
Introduction - Role of analytical chemistry,

classification of analytical methods, classical and
instrumental, types of instrumental analysis,
selecting an analytical method, neatness and
cleanliness, laboratory operations and practices,
analytical balance, techniques of weighing, errors,
volumetric glassware-cleaning and calibration of
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glasswares, sample preparations-dissolution and turbidity, total solids, conductivity, acidity, alkalinity,
decompositions. gravimetric techniques, selecting and hardness, chloride, sulphate, fluoride, silica, phos-
handling of reagents. laboratory notebooks, safety in phates and different forms of nitrogen, heavy metal
the analytical laboratory. pollution-public health significance of cadmium,
chromium, copper, lead, zinc, manganese, mercury
Errors and evaluation - Definition of terms - mean
and arsenic, general survey of instrumental
and median, precision standard deviation, relative
techniques for the analysis of heavy metals in aqueous
standard deviation, accuracy-absolute error, relative
systems, measurements of DO, BOD and COD,
error, types of errors in experimental data-deter-
pesticides as water pollutants and analysis, water
minate (systematic), indeterminate (or random) and
pollution laws and standards.
gross, sources of errors and the effects upon the
analytical results, methods for reporting analytical UNIT-III
data, statistical evaluation of data, indeterminate
errors, the use of statistics. Analysis of soil, fuel, body fluids and drugs
UNIT-II (a) Analysis of soil - Moisture, pH, total nitrogen,

phosphorus, silica, lime, magnesia, manganese,
Food analysis - Moisture, ash, crude protein, fat, sulphur and alkali salts.
crude fibre, carbohydrates, calcium, potassium,
sodium and phosphate, food adulteration-common (b) Fuel analysis - Solid, liquid and gas, ultimate and
adulterants in food, contamination of food stuffs, proximate analysis, heating values-grading of coal,
microscopic examination of foods for adulterants, liquid fuels-flash point, aniline point, octane
pesticide analysis in food products, extraction and number and carbon residue, gaseous fuels-
purification of sample, HPLC, gas chromatography for producer gas and water gas-calorific value.
organophosphates, thin-layer chromatography for
(c) Clinical chemistry - Composition of blood-
identification of chlorinated pesticides in food
collection and preservation of samples, clinical
products.
analysis, serum electrolytes, blood glucose, blood
Analysis of water pollution - Origin of waste water, urea nitrogen, uric acid, albumin, globulin,
types of water pollutants and their effects, sources of barbiturates, acid and alkaline phosphates,
water pollution-domestic, industrial, agricultural, soil immunoassay, principles of radio immunoassay
and radioactive wastes as sources of pollution, (RIA) and applications. the blood gas analysis -
objectives of analysis-parameters for analysis- colour, trace elements in the body.
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(d) Drug analysis - Narcotics and dangerous drugs, Nephelometry and Turbidimetry - General discu-
classification of drugs, screening by gas and thin ssion, instrumentation and applications
layer chromatography and spectrophotometric
measurements. Books Recommended :
UNIT-IV 1. Analytical Chemistry, G.D Christian, J. Wiley.
Flame photometry - Basic principles, experimental 2. Principles of Instrumental Analysis, D.A. Skoog
techniques, schematic diagram and its applications and J.L. Loary, W.B.Saunders.
in analytical work with special reference to alkali
3. Instrumental Methods of Analysis, B.K. Sharma
and alkaline earth metals.
4. Instrumental Methods of Analysis, Chatwal and
Atomic absorption spectroscopy - Basic principles,
Anand.
advantage over flame photometer techniques, detec-
tion limit and sensitivity, interference and its appli- 5. Vogel’s Textbook of Quantitative inorganic Analysis
cations in trace element analysis. L. Barret et.al. ELBS (Longmann’s Ed.)
Mossbauer and Photoelectron spectroscopy -

Principles and applications.
UNIT-V
Emission spectroscopy - Principle, excitation spectra,

equipment for spectrographic analysis, qualitative and
quantitative analysis.
Microwave spectroscopy - Theory, techniques and

analytical applications.
Fluorescence and Phosphorescence methods -

Fluorescence intensity as related to concentration,
filter fluorometers, phosphorescence spectrometer,
phosphorescence methods, excitation conditions, X-
ray fluorescence techniques, theory and applications.
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M.Sc. (FINAL) CHEMISTRY, 2005-2006 6. Separation of amino acids by ion exchange and
chromatographic method
PRACTICALS, GROUP-D
7. Analysis of oils and fats-saponification and iodine
Duration: 18 Hrs (spread over three days) M.M. 200 value
Distribution of Marks - 8. Colorimetric estimation of fluoride, Fe in drinking
1. Exercise-I 50 Marks waters
2. Exercise -II 50 Marks 9. Determination of fats, protein and solid in milk
3. Exercise -III 25 Marks 10. Polarimetric estimation of sugar
4. Seminar 20 Marks 11. Analysis of aspirin, sulpha drugs and vitamin C.
5. Report on Industrial Tour 15 Marks 12. Potentiometric estimation of Ni, Zn, etc.
6. Viva-Voce 20 Marks 13. Analysis of lime, brass and gun-metal.
7. Record/Sessional 20 Marks 14. Analysis of HCl extract or fusion with Na2CO3 for
Al, Fe, Ca, Mg, P and K
Total 200 Marks
15. Estimation of soluble salts in soils by conducto-
Exercises -
metric method
1. Estimation of Ca, Na, K, by flame photometry.
16. Separation and identification of most common
2. Determination of Ca, Mo, Zn, Cu, phosphate and acidic and basic drugs by TLC
silica contents of soil samples
17. Analysis of fertilizers
3. Analysis of sludge obtained from Zinc Smelter
18. Estimation of lead and tin in solder or bismuth,
4. Analysis of cement cadmium and lead in low melting alloys such as
Woods metal using EDTA (volumetrically)
5. Determination of water in mixture by Karl-Fisher
method 19. Analysis of German silver (copper, zinc and nickel)
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Mohanlal Sukhadia University
Udaipur (Raj.)
Syllabus
Scheme of Examination and Courses of Study
FACULTY OF SCIENCE
M. Sc. CHEMISTRY
Published by :
Mohanlal Sukhadia University
Udaipur
Previous Examination : 2004-2005
Final Examination : 2005-2006
Printed at :
National Printers
124, Chetak Marg, Udaipur
Phone : 2523830, 2561030
"Offset House" Bhuwana
Edition : 2004 Price : Rs.30/- Phone : 2440994
M.Sc. CHEMISTRY - 2004 - 200 M.Sc. CHEMISTRY - 2004 - 200

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POST GRADUATE PROGRAMME 2.

Dissertation may be offered by regular students

7. A candidate who has declared fail at the Final

Metal ligand bonding - Limitations of CFT, Ligand

Electronic spectra of transition metal complexes-

UNIT-III 3. Chemistry of the Elements, N.N. Greenwood and

UNIT-IV 5. Magnetochemistry, R.L. Carlin, Springer Verlag

Boranes - Preparation and important reactions, 6. Comprehensive Coordination Chemistry (Eds.) G.

Silicones - Preparation, properties and structure of

Sulphur-Nitrogen compounds - Preparation, proper-

Phosphorus- Nitrogen compounds - Linear and cyclic

Section-B : Five questions (answer not exceeding 250 UNIT-II

Aromatic electrophilic substitution - The arenium Addition to carbon-hetero multiple bonds -

9. Stereochemistry of Organic Compounds, P.S Kalsi, UNIT-I

UNIT-II Non-equilibrium thermodynamics - Thermodynamic

Macromolecules - Definition, types of polymers, 4. Coulson’s Valence, R. McWeeny, ELBS

5. Basic Principles of Spectroscopy, R. Chang, (ii) Organic Practicals 60 Marks

9. Computer Programming in FORTRAN IV.V Distribution of Marks:

12. Green Chemistry, P.Anastas, RSC. 4. Viva-Voce 10 Marks

13. Environmental Chemistry, S.E. Manahan, Lewis 5. Sessional/Record 10 Marks

Group B - Thiosulphate, Cyanate, Thiocyanate, Hypo- (x) Ni (dmg)2

3. Preparation of any ten complexes

(i) TiO(C9H8NO)2. H2O

(ii) Cis-K[Cr(C 2O 4) 2(H 2O) 2]

(i) Na[Cr(NH 3) 2(SCN) 4]

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2. Quantitative analysis 10 Marks 3. Organic synthesis (One experiment to be

4. Viva-voce 10 Marks Acetylation - Acetylation of salicyclic acid using

1. Qualitative Analysis - (Organic mixture) Sandmeyer reaction - p-Chlorotoluene from p-

1. Advanced Practical Organic Chemistry, N.K. PHYSICAL PRACTICALS

4. Text Book of Practical Organic Chemistry, Arthur 1. Experiment-I 20 Marks

To study surface tension-concentration relationship

(i) Determination of congruent composition and

(ii) Determination of glass transition temperature of

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6. Polarimetry 3. Practical Physical Chemistry, Arthur M. James

(i) Photochromism in Aberchrome 540 or malachite

(ii) Determination of quantum yield

(iii) Photooxidation of leucomethyl crystal violet.

1. Practical Physical Chemistry, Alexander and

7. Mass Spectroscopy-R Davis, M. Frearson, Wiley Photochemistry

PAPER–III (A) Coordination compounds - I.R spectra of transition

Section-B : Five questions (answer not exceeding 250 UNIT-III

Transition metal π-complexes – Transition metal π-

Fluxional organometallic compounds – Fluxionality

Inorganic photochemistry - Ligand field excited state, UNIT-III

UNIT-IV 2. Environmental Chemistry, Sharma and Kaur,

Toxicology - Biochemical effects of As, Cd, Pb, Hg,

PRACTICALS, GROUP-A (i) Manganese/Chromium/Vanadium in steel sample

3. Seminar 20 Marks (vi) Copper-ethylenediamine complex by slope-ratio

Exercises (ii) Lithium/Calcium/Barium/Strontium

2. Preparation of selected inorganic compounds and (ii) Phosphate

Rearrangements - General mechanistic consi- Chemistry of fullerenes

Section-C : Four questions may be in parts covering

Nomenclature of heterocycles - Replacement and

Small ring heterocycles - Three membered hetero-

5. An Introduction to the Heterocyclic Compounds, 7. Record/ Sessional 20 Marks

7. Stereoselective Synthesis: A Practical Approach, Exercises

5. Fundamentls of Photochemistry, K.K. Rohatgi- Distribution of Marks

5. Report on Industrial Tour 15 Marks

Total 200 Marks

(i) Determination of partical molar volume of solute