09-07-23 JR - Iit Star Co-Sc (Model-A) Jee Adv 2017 (P-II) Wat-11 QP Final

Sec: JR.
*CO SC(MODE-A) Date: 09-07-23

Time: 3 Hrs WAT-11 Max. Marks: 183
Name of the Student: ___________________ H.T. NO:
09-07-23_JR.* CO-SC(MODEL-A)_JEE-ADV_WAT-11_SYLLABUS
PHYSICS: PRESENTWEEK (80%): Circular motion: Kinematics of Circular
Motion, Angular Velocity, Angular Acceleration, Dynamics of
Circular Motion, Banking Of Road, Radius of Curvature,
Centrifugal Force (Exclude: Vertical Circular Motion)
PREVIOUS WEEK (20%): Contact Force and its components, Dry
Friction, Static and Dynamic Friction, Laws of Friction, Angle of
Friction & Repose, Rolling Friction
CHEMISTRY: PRESENTWEEK (80%): Chemical Equilibrium: Equilibrium
involving physical processes: solid - liquid; liquid - g as and solid -
gas. General charecterstics of equilibrium involving physical process,
Equilibrium involving chemical processes, characteristics of
equilibrium state, Law of mass action, equilibrium constant,
characteristics of equilibrium constant, Law of mass action, Kp, Kc &
relation, Degree of disassociation, reaction quotient, Lechatlier’s
principle - factors effecting equilibrium concentration, pressure,
temperature and effect of catalyst, principle applied for synthesis of
ammonia and sulphur trioxide and other typical reactions,
Thermodynamics of equilibrium constant. Significance of ΔG and ΔG˚
in chemical equilibrium
PREVIOUS WEEK (20%): Thermochemistry: Enthalpy change and
Internal energy change of a reaction, Kirchoff reaction, Enthalpy of
formation, Enthalpy of combustion, Hess law, Bomb calorimeter,
Enthalpy of atomisation, Neutrlisation, hydrogenation, Enthalpy of
phase transition, Enthalpy of solution, Bond enthalpy, Resonance
energy
MATHEMATICS: PRESENTWEEK (80%): Graphs of Trigonometric Functions,
Periodicity and extreme values
PREVIOUS WEEK (20%): Conditional Identities, Summation of
Trigonometric series, Miscellaneous problems on Transformation
Narayana IIT Academy 09.07.2023-JR. * CO SC (MODEL-A)_2017-P2_WAT-11_QP
2017-P2 MODEL
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 7) Questions with Single Correct Options +3 -1 7 21
One of More Correct Options Type
Sec – II (Q.N : 8 – 14) +4 -2 7 28
(partial marking scheme) (+1)
Questions with Comprehension Type
Sec – III (Q.N : 15 – 18) +3 0 4 12
(2 Comprehensions – 2 + 2 = 4Q)
Total 18 61
CHEMISTRY
Sec – II (Q.N : 26 – 32) +4 -2 7 28
Sec – III (Q.N : 33 – 36) +3 0 4 12
Total 18 61
MATHEMATICS
Sec – II (Q.N : 44 – 50) +4 -2 7 28
Sec – III (Q.N : 51 – 54) +3 0 4 12
Total 18 61
Jr.IIT_*CO SC Page No: 2

PHYSICS Max. Marks: 61
SECTION – I
(SINGLE CORRECT CHOICE TYPE)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.
Marking scheme +3 for correct answer , 0 if not attempted and -1 in all other cases.
1. A plank of mass M1  8kg with bar mass of M 2  2kg placed on its rough surface, lie
on a smooth floor of elevator ascending with an acceleration g/4. The coefficient of
1
friction is   between M1 and M 2 . A horizontal force F = 30N is applied to the
5
plank. Then the acceleration of bar and the plank in the reference frame of elevator are (
g  10m / sec 2 )
g/4
M2
M1
F
50
A) 3.5m / s 2 , 5 m / s 2 B) 5m / s 2 , m / s2
8
25
C) 2.5 m / s 2 , m / s2 D) 4.5m / s 2 , 4.5 m / s 2
8
2. A block of mass 4kg is presses against a wall by two perpendicular horizontal forces as
shown in the figure. F1 is perpendicular to the wall and F2 is parallel to the wall.
s  0.8 ,  k  0.5 and g  10 m / s 2 .

F1
F2
For F1  75N and F2  30N then the force of friction is

A) 30N B) 40N C) 50N D) 45N
3. Two moving particles P and Q are 10m apart at a certain instant. The velocity of P is 8
m/s making an angle of 300 with the line joining P and Q and that of Q is 6 m/s making
an angle of 300 with PQ as shown in the figure. Then, angular velocity of P with respect
to Q is
6 m/s
30º
P
30º Q
8 m/s
A) zero B) 0.1 rad/s C) 0.4 rad/s D) 0.7 rad/s

4. A point moves along a circle with a velocity v  t , where   0.5 ms 2 . Find the total
acceleration of the point at the moment when it covered the nth (n = 0.10) fraction of the
circle after the beginning of motion.
A) 0.16 m / s 2 B) 0.8 m / s 2 C) 0.32 m / s 2 D) 0.4 m / s 2
5. Two particles tied to different strings are whirled in a horizontal circle as shown in
figure. The ratio of lengths of the strings so that they complete their circular path with
equal time period is (left diagram is to right diagram).

60º
L1 L2
30º
m m
(a) (b)
3 1
A) B) C) 1 D) 3
2 3
6. A particle moves along a circle with a constant angular speed  . Its displacement with
respect to the position of the particle at time t = 0 is plotted against time. The graph
would look like :
A) B)
C) D)
7. A car is negotiating a curved road of radius R. The road is banked at an angle  . The
coefficient of friction between the tyres of the car and the road is s . The maximum
safe velocity on this road is
g  s  tan   g  s  tan     s  tan    s  tan  

A) B) C) gR 2 D) gR
R 1  s tan   R 2 1  s tan   1  s tan  1  s tan 

SECTION-II
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 7 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
8. A chain of mass m forming a circle of radius R is slipepd on a smooth round cone with
half-angle  . Find the tension of the chain if it rotates with a constant angular velocity
 about a vertical axis coinciding with the symmetry axis of the cone.
5mg  22 R  2mg  2 R 
A) T   cot    B) T   cot   
3  g  3  g 
mg  2 R  mg  2 R 
C) T   cot    D) T   cot   
2  g    2g 
9. If a particle is moving along a circular path with increasing speed, then which of the
following options are correct?
A) Acceleration and velocity can never be perpendicular to each other
B) Acceleration is always directed towards centre
C) Angular acceleration and angular velocity are along the axis of rotation in the same
direction
D) Tangential acceleration and angular acceleration are always perpendicular to each
other
10. As shown in figure ‘AB’ represents an infinite wall tangential to a horizontal semi
circular track. O is a point source of light on the ground at the centre of the circle. A
block moves along the circular track with speed ‘v’ starting from the point where the
wall touches the circle. If the velocity and acceleration of shadow along the length of
the wall is respectively ‘V’ and ‘a’ then
vt vt 
A) V  v cos B) V  v sec 2  
R R

v2  vt   vt  2v 2  vt   vt 
C) a  sec 2   tan   D) a  sec 2   tan  
R R R R R R
11. A car moves with a constant tangential acceleration a t  0.62 m / s 2 along a horizontal
surface circumscribing a circle of radius R = 40m. The coefficient of sliding friction
between the wheels of the car and the surface is   0.20 . What distance will the car ride
without sliding if at the initial moment of time its velocity is equal to zero?
A) 60 m B) 40 m C) 20 m D) 10 m
12. Two identical discs of same radius R are rotating about their axes in opposite directions
with the same constant angular speed  . The discs are in the same horizontal plane. At
time t = 0, the points P and Q are facing each other as shown in the figure. The relative
speed between the two points P and Q is v r . In one time period (T) of rotation of the
discs, v r as a function of time is best represented by:
A) B)

C) D)
13. A car moving along a circular track of radius 50.0 m, accelerates from rest at 3.00 m s 2 .
Consider a situation when the car`s centripetal acceleration equals its tangential
acceleration.
A) The angle around the track does the car travel is 1 rad.
B) The magnitude of the car`s total acceleration at that instant is 3 2 ms 1 .
50
C) Time elapses before this situation is s.
3
D) The distance travelled by the car during this time 25m.
14. A particle of mass m1 moves in a circular path of radius R on a rotating table. A string
connecting the particles m1 and m 2 passes over a smooth hole made on the table as
shown in figure. If mass m1 does not slide relative to the rotating table, mark the correct
options as applicable.
A) The friction force acting on the block m1 is ( m12 R  m 2 g ) along radial rotation
towards center
of rotation.
B) The friction force acting on the block m1 is m12 R  m 2 g along tangent direction in
the direction

opposite to v .
 m 2  m1  g
C) The maximum angular velocity of the particle is  
 m1 R
 m 2  m1  g
D) The minimum angular velocity of the particle is  
 m1 R
SECTION – III
(PARAGRAPH TYPE)
This section contains 2 groups of questions. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 15 and 16:
A Small block mass of m, is at rest on the floor of a railroad boxcar that has length 2 as
shown in the figure. The coefficient of kinetic friction between the floor of the car and
block is  . There is no friction between car and ground. The car, originally at rest,
begins to move with constant acceleration a. (Assume a  g )
15. According to paragraph which of the following is incorrect statement?

A) Acceleration of block w.r.t. car is a  g
B) Net force acting on the block observed from car is ma  mg
C) Net force acting on the block observed from ground is mg
D) None of these
16. The speed of block relative to earth at the moment it hits the wall of the car is:
2   
A) g B) 2g C) g D) g
a  g a  g 2a  g a  g

An automobile drives over some terrain. The motion of the automobile at the top of a
hill is instantaneously similar to circular motion with center of curvature beneath the
road. The motion of the automobile at the bottom of a dip is instantaneously similar to
circular motion with the center of curvature above the road. At any time there are three
  
forces on the car. Weight W , normal N , and f friction of the tires with the road. The
magnitudes of these three forces are given respectively by W,N and f.
17. When the car at the top of a hill, which of the following gives the magnitude of the
centripetal force?
A) N B) W + N C) W – N D) N – W
18. When the car at the bottom of a dip, which of the following gives the magnitude of the
centripetal force?
A) N B) W + N C) W – N D) N – W

CHEMISTRY Max. Marks: 61
SECTION – I
1  P (g) is shown

19. The plot of log kf versus for a reversible reaction A (g) 
T
Pre-exponential factors for the backward and forward reactions are 1011 s−1 and 1019
s−1, respectively. If the value of log K for the reaction at 500 K is 6, the value of
log kb at 250 K is ______.
[K = equilibrium constant of the reaction
kf = rate constant of forward reaction
kb = rate constant of backward reaction]
A) 4 B) 5 C) -4 D) -5
20.  A2(g) has KP = 8×108 atm−1. If initial pressure of A is 1 atm
The process 2A(g) 
pressure, then what should be the equilibrium pressure of ‘A’?

A) 0 B) 2.5 × 10−5 atm C) 4 × 104 atm D) 1.25 × 10−5 atm
21. Phase diagram of a one-component system (S), is shown below
I. Sublimation phase change occur to the components of system S, when it kept in

open container under normal atmospheric condition.
II. The condition under which all the phases are in equilibrium is T = 216.8K and
P = 5.2 atmosphere in closed vessel.
III. If pressure is increased, the melting temperature of solid S will decrease.
IV. To the system S at X4 , if pressure is decreased slowly keeping temperature
Constant, system will turn into liquid phase.
Which of the following statements are correct:
A) II, III, IV only B) I only
C) I, II, III only D) I and II only
22. In the reaction N2(g) + 3H2(g) 
 2NH3(g) + Heat. One mole of N2 reacts with
three moles of H2. If equilibrium ‘x’ moles of N2 combined, then the value of ‘x’ in
terms of KP and the total pressure of gases at equilibrium P is (Given: x << 1).
3P 3.K p 8P 3 3.K p 8 Kp
A) B) C) D)
8 3 3.K p 8P P 3
23. A certain gas ‘A’ polymerizes to a very small extent at a given temperature T as
 An (g). The reaction is started with one mole of ‘A’ in a container of
nA(g) 
capacity V (liters). Kc is equilibrium constant at given temperature T, then which of

PV
the following is the correct value of at equilibrium, where P is pressure at
RT
equilibrium?
A) 1 
 n  1 .K C B)
 n  1 .K C C) 1 
n.K C
D) 1 
n.K C
n 1 n 1
V V V n 1 Vn
24. Two solid compounds X and Y dissociate at a certain temperature as follow:
X  s   A  g   2B g  ;K p1  1.204atm3
Y s   2B g   C g  ;K p2  0.844atm 3
The total pressure (atm) at equilibrium is

A) 2.4 B) 3.4 C) 4.4 D) 5.4
25. Which of the following condition is suitable for forming atomic chlorine from
molecular chlorine in the given equilibrium in a cylinder with movable piston.
 2Cl g 
Cl2 g  
A) Decreasing temperature keeping volume constant.
B) Decreasing volume keeping temperature constant.
C) Increasing temperature keeping volume constant.
D) Increasing pressure keeping temperature constant.
SECTION-II
26. Which of the following are correctly matched, if   1 and initial conc. of X = 1M,
where  is a degree of dissociation.
A) 2X  g  Y g  Z g :  K c B) X  g  Y g  Z g :  K c
1/3
K 
C) 3X g  Y g  Z g :  3 K c D) 2X  g  Y g  2Z g :   c 
 4
27. Making of NH 3 g  by Haber process using suitable catalyst is an exothermic process
N 2 g   3H 2 g   2NH 3 g ; H   ve
Assuming that equilibrium has been established, select the correct statement, on
increasing the pressure on the system at constant temperature.
A) Reaction shifts forward to attain new equilibrium.
B) Average molar mass of gaseous mixture increases.
C) Partial pressure of NH 3 , N 2 ,H 2 will increases.
D) Concentration of NH 3 increase whereas concentration of N 2 &H 2 decreases.
28. The position of equilibrium will shift in the given direction by the addition of inert gas
at constant pressure in which of the following case(s)?
 2NF3(g); forward direction
A) N2(g) + 3F2(g) 
 CO(g) + Cl2(g); forward direction
B) COCl2(g) 
 CH3OH(g); backward direction
C) CO(g) + 2H2(g) 
 2CO(g); backward direction
D) 2C(s) + O2(g) 
29.  Na 2SO 4 s   10H 2O  g  ;

Na 2SO 4 .10H 2O s  
n g
K p  1.024  1017 atm at 350 C
Vapour pressure of water at 350 C is 42.2 torr. At what relative humidity will
Na 2SO 4 .10H 2O s be efflorescent at 350 C ?
A) 10% B) 20% C) 30% D) 40%

30. Following two equilibria are established on mixing two gases A 2 and C.
 A 6  g  , K p  1.6atm 2
(i) 3A 2  g  
 A 2C  g 
(ii) A 2  g   C  g  
Initially A 2 and C are mixed in 2:1 molar ratio in sealed container at a constant
temperature. If the total pressure of the reaction mixture is 1.4 atm and partial pressure
of A 6 is 0.2 atm at equilibrium, then identify the correct statement(s) of the following.
A) Equilibrium partial pressure of A 2  g  is 0.5 atm
B) Equilibrium partial pressure ‘C’ is 0.4 atm

C) Equilibrium partial pressure of A 2C  g  is 0.3 atm
D) K p of reaction (ii) is 1.5 atm 1
31. In a constant pressure calorimeter with heat capacity of 453 J k-1, 200 mL of 0.84 M
HCl and 200 mL of 0.43 M Ba(OH)2 are mixed. (density of solution = 1 g mL-1)
Initially, both solutions are at 20.480C. Then select correct statement(s): (Given:
enthalpy of neutralization of strong acid, strong basics is 57.3 kJ/mole and specific
heat capacity of water 4.2 J k–1g–1)
A)  r H is nearly –9.63 kJ
B) Final temperature of the calorimeter is nearly 250C
C) Some HCI is left unreacted
D) Some Ba(OH)2 is left unreacted
32.  CO( g )  Cl2 ( g ) , K p  8  109 atm, So  30 Cal K 1 at 300 K. At
Given: COCl2 ( g ) 
which of the following temperature, phosgene will be 0.1% dissociated in moles at

2atm equilibrium pressure (Given: R=2 Cal /mol/K, log2 = 0.3)(assume standard
temperature is 300K)

A) 367K B) 413K C) 446K D) 512K
SECTION – III
(PARAGRAPH TYPE)
In a vessel, the equilibria
 2NH3(g) and
N2(g) + 3H2(g) 
 N2H4(g)
N2(g) + 2H2(g) 
are achieved simultaneously. Initially, the vessel contains N2 and H2 in molar ratio of
9 : 13. The equilibrium pressure is 7P0 in which pressure due to ammonia is P0
and pressure due to hydrogen is 2P0.
33.  2NH3(g)is
The value of KP for the reaction N2(g) + 3H2(g) 
20 P0 2 1 3
A) 20 P0 2 B) C) D)
3 20P0 2 20P0 2
 N2H4(g) is
34. The value of KP for the reaction N2(g) + 2H2(g) 
2 20 P0 2 1 3
A) 20 P0 B) C) D)
3 20P0 2 20P0 2
Use the data (all values are in kJ per mole at 25oC) given below to answer the
following.
Enthalpy of formation of CH3CN = +88.0
Enthalpy of formation of C3H8 = −85.0
Enthalpy of sublimation of graphite = 719.0
Enthalpy of dissociation of nitrogen = 948.0
Enthalpy of dissociation of hydrogen = 435.0
Bond enthalpies: C–H = 414.0; C–N = 378.0; N–H = 426.0

35. The bond enthalpy of C−C bond in C3H8 (kJ/ mol) is
A) 250.0 B) 335.0 C) 223.33 D) 248.5

36. The bond enthalpy of C  N bond (kJ/ mol) is
A) 987.5 B) 811.5 C) 899.5 D) 890.
MATHEMATICS Max. Marks: 61

SECTION – I
37.  
If f    cos sin   sin 2   sin 2  where  is constant 0     . Then maximum value of
f   is
A) 1  cos 2  B) 1  cos3  C) 1  sin 2  D) 1  sin 3 

tan 80 3tan 240 9 tan 720 27 tan 2160
38. If     x tan1080  y tan 80 then x + y =
1 3tan 8 1 3 tan 24 1 3 tan 72 1 3 tan 216
2 0 2 0 2 0 2 0
A) 8 B) 10 C) 6 D) 12
4x 7 x 10 x
If k is a fundamental period of cosec  x   2  3  .....  then  tan k 
2015 2017
39.   cot k  
 2 2 2 
A) 2014 B) 4032 C) 1 D) 2
40. The values of x for min(sin x,cos x )  min(  sin x,  cos x) where x   0, 2  equals
3 5 3   7
A) (0, π) B)  
, 2  C)  0,  D)  0,  

, 2 
 4   4   4   4 
x
41. Number of point of intersections of the graphs f  x   sin x , and g  x   is
100
A) 64 B) 63 C) 65 D) 60
x x
42. Let the smallest positive value of x for which the function f ( x)  sin  sin , ( x  R)
3 11
achieves its maximum value be x0 in degrees i.e. , x0   0 .

Then the sum of the digits in  is
A) 15 B) 17 C) 16 D) 18
SECTION-II
43. If a, b, c  R satisfying the relation a 2  b 2  c 2  2a  6b  4c  14  0 and

g ( x )  a cos 2 x  b sec 2 x  2c then
A) a  b  c  0 B) a  c  3
C)The minimum value of g ( x ) is 4  2 3 D) The minimum value of g ( x ) is 8
sec 4  sec 4 
44. The expression  (wherever defined) can take the value
tan 2  tan 2 
A) 4 B) 6 C) 8 D) 10
 
45. Let x, y, z be real numbers with x  y  z  such that x  y  z  and let
12 2
P  cosx .siny.cosz , then
1 2 3
A) Minimum value of ‘P’ is B) Maximum value of ‘P’ is
8 8
2 3 2 3
C) Minimum value of ‘P’ is D) Maximum value of ‘P’ is
8 4
46. In a triangle ABC

3 3 9
A) sinA sinBsinC  B) sin 2 A+sin 2 B+sin 2C 
8 4
C) sinA sinBsinC is always positive D) sin 2 A+sin 2 B 1  cosC

sin x sin x cos x sin x

47. If 0  x  and let a   cos x sin x  , b   sin x cos x  , c   cos x sin x  , d   sin x  sin x 
4
Then which of the following is/are incorrect?
A) a  b  c  d B) b  d  a  c C) c  d  a  b D) a  c  b  d

    
48. Let the function y  sin   x   sin   x   sin   x 
4   4  3
 
3 2
A) The maximum value of the function y 
4
3
B) The maximum value of the function y 
2
1
C) The minimum value of the function y 
2 2
3
D) The minimum value of the function y 
2
49. Which of the following statements is/are correct?

A) Fundamental period of cos  sin x  cos x  is
2

B) Fundamental period of cos  cos x   cos  sin x  is
2
C) Fundamental period of cos x.cos 2 x cos 3x is 
tan x  cot x 
D) Fundamental period of is
sin x  cos x 2
50. Which of the following is periodic ([.] is G.I.F) having fundamental period
 sin 2 x  cos4 x
A) f ( x)  sin  [ x ]  B) h( x) 
2  cos2 x  sin 4 x
C) g ( x )  sin  2 x   cos  2 x  D)  ( x)  sin  [ x]  [ x  1]  x

SECTION – III
(PARAGRAPH TYPE)
Let y  f ( x ) and y  g ( x ) are two functions then the number of solutions of f ( x)  g ( x ) is same
as number of point of intersections of the graphs y  f ( x ) and y  g ( x )
51. The number of solutions of the equation x  cos x is
A)4 B)1 C)2 D) 3
52. The number of solutions of the equation sin  x  log e x is
A) 0 B) 6 C) 4 D) 8
If f ( x ) and g ( x ) are two periodic functions with fundamental period T1 and T2 respectively,
f ( x)
then the fundamental period of f ( x)  g ( x ), f ( x ) g ( x), may be the LCM of T1 and T2
g ( x)
or the submultiple of the LCM or does not exists.

x    x  
53. If the fundamental period of the function f ( x)  4 cos 4  2 
 2 cos  2 
is equal to
 4   2 
k 3 then the value of k is
A) 2 B) 4 C) 8 D) 3
54. If f  x   sin x  cos 

  
4  a 2 x  then set of all integral values of a for which f  x  is a

periodic function
A) 1,1 B) 2, 1,1, 2 C) 2, 0, 2 D) 4, 4

09-07-23 JR - Iit Star Co-Sc (Model-A) Jee Adv 2017 (P-II) Wat-11 QP Final

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09-07-23 JR - Iit Star Co-Sc (Model-A) Jee Adv 2017 (P-II) Wat-11 QP Final

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Sec: JR.

*CO SC(MODE-A) Date: 09-07-23

Name of the Student: ___________________ H.T. NO:

Jr.IIT_*CO SC Page No: 2

s  0.8 ,  k  0.5 and g  10 m / s 2 .

Jr.IIT_*CO SC Page No: 3

For F1  75N and F2  30N then the force of friction is

A) zero B) 0.1 rad/s C) 0.4 rad/s D) 0.7 rad/s

Jr.IIT_*CO SC Page No: 4

g  s  tan   g  s  tan     s  tan    s  tan  

Jr.IIT_*CO SC Page No: 5

Jr.IIT_*CO SC Page No: 6

Jr.IIT_*CO SC Page No: 7

15. According to paragraph which of the following is incorrect statement?

Jr.IIT_*CO SC Page No: 9

Jr.IIT_*CO SC Page No: 10

1  P (g) is shown

pressure, then what should be the equilibrium pressure of ‘A’?

I. Sublimation phase change occur to the components of system S, when it kept in

capacity V (liters). Kc is equilibrium constant at given temperature T, then which of

The total pressure (atm) at equilibrium is

29.  Na 2SO 4 s   10H 2O  g  ;

A) 10% B) 20% C) 30% D) 40%

A) Equilibrium partial pressure of A 2  g  is 0.5 atm

B) Equilibrium partial pressure ‘C’ is 0.4 atm

D) K p of reaction (ii) is 1.5 atm 1

which of the following temperature, phosgene will be 0.1% dissociated in moles at

Jr.IIT_*CO SC Page No: 14

Paragraph for Questions 35 and 36:

Jr.IIT_*CO SC Page No: 15

A) 250.0 B) 335.0 C) 223.33 D) 248.5

MATHEMATICS Max. Marks: 61

A) 1  cos 2  B) 1  cos3  C) 1  sin 2  D) 1  sin 3 

achieves its maximum value be x0 in degrees i.e. , x0   0 .

43. If a, b, c  R satisfying the relation a 2  b 2  c 2  2a  6b  4c  14  0 and

46. In a triangle ABC

C) sinA sinBsinC is always positive D) sin 2 A+sin 2 B 1  cosC

Then which of the following is/are incorrect?

Jr.IIT_*CO SC Page No: 17

49. Which of the following statements is/are correct?

C) Fundamental period of cos x.cos 2 x cos 3x is 

C) g ( x )  sin  2 x   cos  2 x  D)  ( x)  sin  [ x]  [ x  1]  x

Jr.IIT_*CO SC Page No: 18

51. The number of solutions of the equation x  cos x is

A)4 B)1 C)2 D) 3

52. The number of solutions of the equation sin  x  log e x is

Paragraph for Questions 53 and 54:

or the submultiple of the LCM or does not exists.

k 3 then the value of k is

54. If f  x   sin x  cos 

A) 1,1 B) 2, 1,1, 2 C) 2, 0, 2 D) 4, 4

Jr.IIT_*CO SC Page No: 19

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