Termodinamika

Teknik Kimia Lanjut

Sifat-sifat Termodinamika Fluida
Nyata
 Outline
In practice, we have to deal with not only gases removed
from ideal gas state, but also with liquids and solids. In
addition, mixtures rather than pure components are far
more common in chemical process plants. Therefore,
computation of work and heat interactions for system
comprised of real fluids requires more complex
thermodynamic formulations. This lecture is devoted to
development of such relations that can help calculate
energy requirements for given changes of state for real
systems. As in the case of ideal gases the goal is to
correlate the energy and entropy changes for real fluids in
terms of their volumetric and other easily measurable
macroscopic properties.
1. Thermodynamic Properties Relation for Single Phase System
2. Maxwell Relations
3. Relations for Enthalpy, Entropy and Internal Energy
Example 1
4. Residual Property Relations

M → V, U, H, S, G
Example 2
5. Residual Property Calculation from EOS
Example 3
6. Generalized Correlations for compiting dH
and dS for a real gas

5.55
7. Computation of H and S for a Gas using
Generalized Departure Functions
 c
a

b
Example 4
Example 5
8. Extension to Gas Mixture

The generalized equations developed for H and S may be

extended to compute corresponding changes for a real gaseous
mixture. The method used is through the definition of pseudo-
critical mixture properties using linear mixing rules:
Example 6
Pelajari latihan soal: 6.4; 6.8; 6.9 buku Smith,
van Ness dan Abbott bab 6.
Latihan Soal
Hitunglah Z, HR dan SR dengan menggunakan persamaan
Redlich/Kwong, Soave/Redlich/Kwong dan
Peng/Robinson untuk senyawa berikut ini:
• Acetylene at 300 K and 40 bar.
• Argon at 175 K and 75 bar.
• Benzene at 575 K and 30 bar.
• n-Butane at 500 K and 50 bar.
• Carbon dioxide at 325 K and 60 bar.
• Carbon monoxide at 175 K and 60 bar.
• Carbon tetrachloride at 575 K and 35 bar.
• Cyclohexane at 650 K and 50 bar.
Persamaan Cubic: Faktor kompresibilitas