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e-Sankalp2224 S & T-XI-PCM-(100565)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. A sonometer wire has a length of 133 cm between two fixed ends. Two bridges are placed
between the fixed ends so that the wire is divided in three segments whose fundamental
frequencies are in the ratio 1: 3 : 4. The distance between the two bridges is
(A) 28 cm (B) 24 cm
(C) 42 cm (D) 36 cm
2. A plane sound wave is generated in a medium along positive x-axis, whose equation is given as
y = A cos (t kx)
If c is the speed of wave in the medium. There is a reference frame k which is moving with
uniform acceleration ‘a’ in the negative direction of x-axis and at t = 0 both wave and reference
frame k coincide with each other at origin. The equation of wave in reference frame k is
at at
(A) y = A cos t 1 kx (B) y = A sin t 1 kx
2c 2c
at at
(C) y = A cos t 1 kx (D) ) y = A sin t 1 kx
c c
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e-Sankalp2224 S & T-XI-PCM-(100565)-3
4. Two harmonic sound waves are moving in x-direction. Displacement of particles are given by
y1 = A cos (t kx) and y2 = 0.8 A cos (t + kx). The two waves are superimposed. If Bulk
modulus of medium is B0 and atmospheric pressure is P0 then amplitude of pressure variation at
x = 0, will be
(A) 0.2 B0kA (B) 0.4 B0kA
(C) 1.8 B0kA (D) None of these.
5. A string of length 0.4 m and mass 102 kg is tightly clamped at its one end
and other end is free to move as shown in the figure. The tension in the
string is 1.6 N. Identical pulses are produced at one end at equal intervals
of time t. The minimum value of t which allows constructive interference
between the successive pulses is
(A) 0.05 sec (B) 0.10 sec
(C) 0.20 sec (D) 0.40 sec
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e-Sankalp2224 S & T-XI-PCM-(100565)-4
A block of mass 2m is hanging at the lower end of a rope of mass m and length and the
other end is being fixed to the ceiling. A pulse of wavelength 0 is produced at the lower end
m,
of the rope.
2m
6. The wavelength of the pulse when it reaches the other end of the rope is
3
(A) 3 0 (B) 0
2
(C) 0 (D) 0
2
8. The time taken by the pulse to reach the other end of the rope is
(A) 2 ( 3 1) (B) 2 ( 3 2)
g g
(C) 2 (D) 2 ( 3 2)
g g
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e-Sankalp2224 S & T-XI-PCM-(100565)-5
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e-Sankalp2224 S & T-XI-PCM-(100565)-6
11. A transverse wave is traveling in the +ve x-direction according to the equation
y = 2sin[100t x/50], where x and y are in cm.
The ratio of the maximum velocity that a particle can have to the velocity of wave propagation is
K
. Find the value of K.
25
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e-Sankalp2224 S & T-XI-PCM-(100565)-7
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. 1 mole of an ideal gas at 25°C is subjected to expand reversibly ten times of its initial volume.
The change in entropy of expansion is
–1 –1 –1 –1
(A) 19.15 JK mol (B) 16.15 JK mol
–1 –1
(C) 22.15 JK mol (D) 22.12 JK mol–1
–1
2. The equilibrium constant for the reaction, A B was measured over a range of temperature and
can be represented by the equation, ln Kp = 4.814 – (2059/T)
Then G°, H°, S° for the reaction at 298 K will be
(A) G° = 6.25 kJ, H° = 18.29 kJ, S° = 45 Jk–1 mole–1
(B) G° = 7.323 kJ, H° = 19.37 kJ, S° = 48 Jk–1 mole–1
(C) G° = 8.729 kJ, H° = 20.22 kJ, S° = 51.23 Jk–1 mole–1
(D) G° = 5.185 kJ, H° = 17.11 kJ, S° = 40 Jk–1 mole–1
(IV) The Second Law in terms of entropy: The entropy of an isolated system increases in the
course of a spontaneous change: Stot 0.
(A) I and II (B) II and III
(C) I, II and III (D) I, II, III and IV
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e-Sankalp2224 S & T-XI-PCM-(100565)-8
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e-Sankalp2224 S & T-XI-PCM-(100565)-9
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions and
2 multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
Adiabatic
D
C
Isotherm: T = 200 K
V
6. How much heat is released at the lower temperature, 200 K, during the isothermal compression?
(A) 150 kJ
(B) 30 kJ
(C) 120 kJ
(D) data are not sufficient to calculate exact value
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e-Sankalp2224 S & T-XI-PCM-(100565)-10
The contributions of both heat (enthalpy) and randomness (entropy) shall be considered to the overall
spontaneity of a process. When deciding about the spontaneity of a chemical reaction or other process,
we define a quantity called the Gibb’s energy.
G H T S
Where H = Enthalpy change, S = entropy change.
If G 0, process is spontaneous;
G 0, process is at equilibrium,
G 0, process is non-spontaneous.
10. The standard state Gibbs free energies of formation of C(graphite) and C(diamond) at T = 298 K
are
f G 0 C graphite 0 kJmol 1
f G 0 C diamond 2.9 kJmol 1
The standard state means that the pressure should be 1 bar, and substance should be pure at a
given temperature. The conversion of graphite [C(graphite)] to diamond [C(diamond)] reduces its
volume by 2 106 m3 mol1. If C(graphite) is converted to C(diamond) isothermally at T = 298 K,
the pressure at which C(graphite) is in equilibrium with C(diamond), is
[Useful information: 1 J = 1 kg m 2s2; 1 Pa = 1 kg m 1s2; 1 bar = 105 Pa]
(A) 14501 bar (B) 58001 bar
(C) 14500 bar (D) 29001 bar
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e-Sankalp2224 S & T-XI-PCM-(100565)-11
This section contains 2 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
V
12. 4.48 lit. of an ideal gas at S.T.P. requires 18 calorie heat to raise the temperature by 15oC at
constant pressure. The CV of the gas is…………cal mol-1k-1.
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e-Sankalp2224 S & T-XI-PCM-(100565)-12
This section contains 5 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
n
2n n
2. Cr P and ( Ci n C j ) Q is equal to
r 0 0 i jn
(A) P Q (B) P Q
(C) P Q (D) none of these
3. The value of the expression nC0 4nCn – nC1 4n – 3Cn + nC2 4n – 6Cn – nC3 4n – 9Cn + … to n terms is
(A) 1 (B) 4n
n
(C) 3 (D) 0
3n 1
1r 1 r
4. The sum of the series
r 1
3n
Cr
is (where n is an even natural number)
3n
(A) 0 (B)
3n 1
3n 1 3n
(C) (D)
3n 2 3n 2
p
5 If p is a prime number (p 2), then the difference 2 5 2p 1 is always divisible by (where
[.] denotes the greatest integer function)
(A) p + 1 (B) p
(C) 2p (D) 5p
Space for rough work
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e-Sankalp2224 S & T-XI-PCM-(100565)-13
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions and
2 multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
8. The sum of the difference between the coefficients equidistant from the first and last is
(A) 105 (B) 210
(C) 0 (D) 315
n
4
Let r 1 n1Cr 1 216 where n = 19, then
r 0
9. The number of 3 elements sets of positive integers {x, y, z} such that xyz = p is equal to (where p
is product of all prime factors of )
(A) 30 (B) 41
(C) 35 (D) 53
10. Number of ordered pair of (, ) such that = and where and are relatively prime is
equal to
(A) 31 (B) 32
(C) 16 (D) 63
Space for rough work
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e-Sankalp2224 S & T-XI-PCM-(100565)-14
This section contains 2 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
24
100 100
r 0
C4r C4r 2
11. 25
is equal to _________.
200
r 1
C8r 6
n+5
12. The coefficients of three consecutive terms of (1 + x) are in the ratio 5 : 10 : 14. Then n =
_______
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e-Sankalp2224 S & T-XI-PCM-(100565)-15
1. A 2. A 3. A 4. A
5. C 6. B 7. A 8. D
9. B 10. B 11. 1 12. 3
CHEMISTRY (PART-II)
1. A 2. D 3. D 4. A
5. C 6. B 7. C 8. B
9. B 10. A 11. 6 12. 4
MATHEMATICS (PART-III)
1. B 2. A 3. C 4. D
5. B 6. B 7. C 8. C
9. B 10. B 11. 1 12. 6
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e-Sankalp2224 S & T-XI-PCM-(100565)-16
1 1 1 A
1. f 1 : f 2 : f3 :: : : B
1 2 3
1 : 2 : 3 : : 1 : 1/3 : 1/4
: : 12 : 4 : 3
4
2 = 133 = 28 cm
19
(x, y)
2. y = y = y k y (x, y)
y = f(x) . . . (1) y y P
(x, y)
1 2
x = at + x
2 ½ at2
O
O O2 x,
at 2 x
x = x x
2
Replace x by (x (at2/2)) from main equation
kat 2
y = A cos t kx
2
at
y = A cos t 1 kx [here c = /k]
2c
Let velocity of pulse in the string is v and time take by pulse to travel distance from P to Q is t0.
Then at time t0, F = 0, 0 = F0 kt0
F
Hence, t0 = 0
k
T
Now v =
m
dx F kt
0
dt m
L t0
1 12
dx
0
m F
0
0 kt dt
1 2 t
32 0
L= F0 kt
m 3k 0
2
L= 0 F03 2
3k m
32
2 F0 2 F03
k= ,k=
3L m 3L m
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e-Sankalp2224 S & T-XI-PCM-(100565)-17
0
6.
( 3mg) /(m / ) 2mg /(m / )
3
0
2
m
2m g 5
2
7. v = g
m/ 2
m
2m y g
dy
8.
dt m/ y
dy t
1/ 2
g dt 2m
0 y 0
2
t2 ( 3 2)
g
9.
O 2L
L
3 3
10 dy
dx
t
O T 2T
12. T Mg Ma
T M g a 120N.
Let P1 & P2 be the number of loops in left & right parts. For B to be node,
P1 T P2 T P 1 A1 2
1
2 1 2 2 P2 2 A 2 1
Hence, minimum number of loops in string is 3.
MATHEMATICS (PART-III)
1. B
nx(x + 1)n1 = nC1x + 2nC2x2 + ……. + n nCnxn …(1)
nx(x 1)n1 = nnCnxn (n 1)nCn1xn1 + ……. + (1)n1nC1x …(2)
Again differentiating with respect to x both (1) and (2) and subtracting, we get the required result.
2. A
2n 2n 2n
Given c0 c1 ..... cn P
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e-Sankalp2224 S & T-XI-PCM-(100565)-18
2n 2n 2n
c0 c1 ..... c 2n 22n
2n 22n 2ncn 2
Here 2P cn 22n P
c 0 c1 ..... cn c 2
i c c
2 i j
2
2n
2 2 2ncn
2n 2ncn 2Q Q
2
Hence P = Q
3. C
n
C0 4nCn – nC1 4n – 3Cn + nC2 4n – 6Cn – ……+ (–1)n nCn 4n – 3nCn
= coefficient of x n in [nC0 (1 + x)4n + nC1 (1 + x)4n – 3 + nC2(1 + x)4n – 6 – …(–1)n nCn(1 + x)n]
= coefficient of x n in (1 + x)n [nC0 (1 + x)3n – nC1 (1 + x)3n – 3 + nC2(1 + x)3n – 6 – …(–1)n nCn]
= coefficient of xn in (1 + x)n [(1 + x)3 – 1]n
n n 3 2 n n
= coefficient of x in (1 + x) [x + 3x + 3x] = 3 .
4. D
1 3n r ! r ! 3n 1 3n 1 r r 1 3n r ! r !
We have
3n
Cr 3n ! 3n 2
3n 1 !
3n 1 3n 1 r ! r ! 3n r ! r 1 !
=
3n 2 3n 1 !
1 1 3n 1
= 3n1
3n1
.
Cr Cr 1 3n 2
3n 1
1r 1 r 3n 1
r 1 1 1 3n 1
So, r 1
3n
Cr
1
r 1
r
3n 1
Cr
3n 1
Cr 1 3n 2
1 1 1 1 1 1 1 1 3n 1
= 2 3 ... 3n 1
C
1 C 2 2C C 3 C
3 C 4 C
3n1 C3n 3n 2
3n + 1
[where Cr = Cr]
3n 1 1 1 1 1 1 1 3n
= ...
3n 2 C1 C2 C3 C4 C3n1 C3n C3n
3n 1 3n 3n
= . .
3n 2 3n 1 3n 2
5. B
p p
We have 2 5 2 5 = 2[2p + pC2 2p – 2 5 + pC4 2p – 4 52 + … + pCp – 1 2 . 5(p – 1)/2] …(1)
p p p
From (1), 2 5 2 5 is an integer and – 1 < 2 5 < 0
p p p
(as p is odd), so 2 5 2 5 2 5
= 2p + 1 + pC2 2p – 1 5 + … + pCp – 1 22 5(p –1)/2
p
2 5 2p 1 = 2[pC2 2p – 2 5 + pC4 2p – 4 52 + … + pCp – 1 2 . 5(p –1 )/2].
p p 1 p p p 1p 2 p 3
Now all the binomial coefficients pC2 = , C4 = , …, pCp – 1 = p
1 2 1 2 3 4
are divisible by the prime p. Thus R.H.S is divisible by p.
6. B
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e-Sankalp2224 S & T-XI-PCM-(100565)-19
7. C
8. C
1 + 2 + … + 20 210
Clearly highest power of x = x =x
Number of distinct terms = 210 + 1 = 211
Let (1 + x)(1 + x + x2) … (1 + x + x2 + … + x20) = a0 + a1x + a2x2 + … + a210x210 …(1)
Putting x = 1; we have a0 + a1 + a2 + … + a210 = 21!
Again putting x = –1; a0 a1 + a2 – … + a210 = 0
21!
On adding we have a0 + a2 + … + a210 =
2
1
Again on replacing x by in (1); we get
x
a0 + a1x + a2x2 + … + a210 x210 = a0 x210 + a1x209+ … + a210
a0 = a210; a1 = a209; …
Required sum of differences = 0.
9. B
10. B
3
9.-10. r 1 n 1 nCr
= (n + 1)(n2(n + 3)2n – 3 + 2n + 3·n(n + 1)2n – 2 + 3·n·2n – 1)
Put n = 19
16
209160
2
2 32 5 7 83
3
9. x y z = 2 3 5 7 83
Hence, required answer is 41
10. 25
11. 1
S = 100C0 100C2 + 100C4 100C6 + … + 100C96 100C98
100
100 1 x 1 x 100 1 x 100 1 x 100 1 x 100
= Coefficient of x0 in 1 x ...
x2 x4 x6 x 96 x 98
1 x 200 1 x 200
= Coefficient of x0 in
x194 1 x8
194 200 8 –1
= Coefficient of x in (1 + x) (1 – x )
200 200 200
= C2 + C10 + …+ C194.
12. 6
Let Tr – 1, Tr, Tr + 1 are three consecutive terms of (1 + x)n + 5
r 2
Tr 1 n+5 Cr 2 x , Tr n+5 Cr 1x r 1, Tr+1 n+5 Cr x r
Where, n+5Cr–2 : n+5Cr–1 : n+5Cr = 5 : 10 : 14.
n5
Cr 2 n 5 Cr 1 n 5 Cr
So
5 10 14
n5
Cr 2 n 5 Cr 1
So from n – 3r = –3 ….. (1)
5 10
n5
Cr 1 n 5 Cr
5n – 12r = –30 ….. (2)
10 14
From equation (1) and (2) n = 6
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