Patent Application

【Application Classification】 patent application

【Applicant】

【Name】 SEO JUNG YUL

【Patent Customer 4-2003-039583-4

Number】

【Agent】

【Organization Name】 DAE YEON PATENT & LAW FIRM

【Agent's Code】 9-2014-100121-5

【Designated Patent Kwon Yi Jong

Attorney】

【Title of Invention】 WATER TREATMENT AGENT AND MANUFACTURING

METHOD THEREOF

【English Title of Invention】 Water treatment and its manufacturing method

【Inventor】

【Name】 SEO JUNG YUL

【Patent Customer 4-2003-039583-4

Number】

【Application Language】 korean language

【Request for Examination】 claimee

【Purport】

Submit it to the Commissioner of the Korean Intellectual Property Office as

above.
【Official Fee】

【Application Fee】 0 page 46,000 won

【Additional Application 28 pages 0 won

Fee】

【Priority Fee】 0 case 0 won

【Examination Fee】 12 terms and 671,000 won

【Total】 717,000 won

【Reason for Reduction】 Secure Information

【Fee after Reduction and 215,100 won

Exemption】

【Attached Documents】

1.Delegation_1 Tong
 【Description of the Invention】

【Title of Invention】

WATER TREATMENT AND ITS MANUFACTURING METHOD

【Technical Field】

【0001】 The present invention relates to a water treatment agent capable of

treating soluble phosphorus contained in water at an ultra-high temperature

while minimizing the amount of sludge generated, and to a manufacturing

method thereof.

【Background Technique】

【0002】 In general, phosphorus (phosphoric acid), which is the main cause

of eutrophication and the limiting substance of algae proliferation, has been

mainly treated by biological treatment methods or chemical treatment methods

using a coagulant. The technology for removing phosphorus by electrolysis/

coagulation, which has been studied a lot recently, is one of the technologies

that can take advantage of the chemical removal technology and solve the

shortcomings of the chemical precipitation method, but has a problem in

maintenance due to problems such as electrode corrosion.

【0003】 Meanwhile, the reuse of shells is used to remove exhaust gas, improve

acidic soil, adsorb heavy metals, and remove high-concentration phosphorus,

but calcium carbonate, which accounts for most of oyster shells, has a large

amount of sludge generated when applied to water treatment, and has a

problem in that it contains a large amount of organic and inorganic materials,

and thus has another problem in that it needs to undergo an appropriate

calcination process.

【0004】 As another alternative, a technique for treating total phosphorus

using talc or a natural coagulant has been developed, but generally, soluble

phosphorus is removed by precipitation with insoluble metal phosphate

 produced by reacting soluble phosphorus with one or more metal ions, for
example, Al (aluminum), Fe (iron) or calcium (Ca), and at this time, excessive

use of chemicals and, as a result, accumulation of a coagulant on the river

bottom and accumulation of residual aluminum and residual iron at a high

concentration adversely affect the aquatic ecosystem, and there have been

considerable difficulties in treating the accumulated sludge.

【0005】 Therefore, in the related art, in order to treat the total phosphorus

concentration at an ultra-high level, there is a problem in that excessive

sludge generation and disposal generated when a liquid inorganic coagulant

is applied, and the water ecosystem is adversely affected due to residual

aluminum and residual iron.

【Citation List】

【Patent Literature】

【0006】 (Patent literature 0001) Korean Patent No. 10-1334861

【Content of Invention】

【Problem to solve】

【0007】 DISCLOSURE Technical Problem Accordingly, the present invention

has been made keeping in mind the above problems occurring in the related

art, and an object of the present invention is to provide a water treatment

agent including a novel inorganic coagulant, which is capable of solving

the problems of excessive sludge generation and disposal, and adversely

affecting the water ecosystem due to residual aluminum and residual iron,

which are generated when a liquid inorganic coagulant is applied, and of

reducing the amount of sludge generated while treating the total phosphorus

concentration at an ultra-high level.

【Solution to the Problem】

 【0008】 To achieve the purpose, the present invention comprises: red mud
having a moisture content of 40-55% and a pH of 11 or more; In other words,

the processed red mud in which the percentage of water content is included

of 5~25%, and pH is 7~11 The first additive consisting of the calcium chloride,

the magnesium chloride, and the dissolution agent class mixing one or two

or greater among the magnesium oxide The second additive consisting of

the acidic chemicals mixing one or two or greater among the sulfuric acid,

hydrochloric acid, phosphoric acid, aluminium sulfate Suggested is a water

treatment agent consisting of a mixture of the above compounds.

【0009】 And besides. And the manufacturing method of the above-described

water treating agent, is the red mud of the place of business waste state
In other words, the step that dries in the constant temperature and pre-

processed the red mud The step that the first additive consisting of the

calcium chloride in the red mud or the pre-processed red mud, the

magnesium chloride, and the dissolution agent class mixing one or two or

greater among the magnesium oxide is added and mixed The step that the

second additive consisting of the acidity chemicals mixing one or two or

greater with mixture among the sulfuric acid, hydrochloric acid, phosphoric

acid, aluminium sulfate is added and mixed The dry step in the constant

temperature mixture The step of assorting the powder of the constant size it

shatters to pieces building It proposes to manufacture through.

【Effect of Invention】

【0010】 The water treatment agent manufactured by the manufacturing

method of the present invention is a natural mineral such as ferric oxide,

aluminum oxide, silicon dioxide, titanium oxide, calcium oxide, sodium

oxide, etc. included in red mud, and has properties of rapidly adsorbing,

coagulating, substituting, decomposing, and removing pollutants and

soluble phosphorus included in water. In addition, the water treatment agent

 supplements physicochemical properties of red mud by mixing a first additive
composed of a dissolving agent and a second additive composed of acidic

chemicals having a coagulating function, maximizes reaction of minerals,

and improves treatment efficiency, thereby completely removing pollutants

and soluble phosphorus included in water without a secondary problem and

hardly generating sludge.

【Description of Drawings】

【0011】 FIG. 1 is a block diagram showing a manufacturing step of the present

invention.

【Detailed Description for the Implementation of the Invention】

【0012】 Hereinafter, the present invention will be described in detail with

reference to the accompanying drawings.However, the terms and names used

in the description may be implicitly determined by the shape, operation, role,

and the like of the configuration rather than the dictionary meaning, and a

detailed description of the previously registered known technology and the

conventional technology may obscure the gist and thus will be omitted.

【0013】 First, a water treatment agent according to the present invention will

be described as follows.

【0014】 As mentioned in the solution, the water treatment agent according

to the present invention has a water content of 40-55% and a pH of 11 or

more. In other words, the processed red mud in which the percentage of water

content is included of 5~25%, and pH is 7~11 The first additive consisting of

the calcium chloride, the magnesium chloride, and the dissolution agent class

mixing one or two or greater among the magnesium oxide The second additive

consisting of the acidic chemicals mixing one or two or greater among the

sulfuric acid, hydrochloric acid, phosphoric acid, aluminium sulfate It is made

of the mixture mixing. The mixed mixture has a pH of 2 to 9 and a particle size
of 3 to 25 μm.
【0015】 Hereinafter, a method of preparing the water treatment agent will be

described with reference to FIG. 1.

【0016】 FIG. 1 is a block diagram showing a manufacturing step of a water

treatment agent according to the present invention, and as mentioned in the

drawings and solutions, a manufacturing method of a water treatment agent

according to the present invention comprises: red mud in a state of waste in a

workplace; The step that is dry and pre-processed the red mud in the constant

temperature The step that the first additive consisting of the calcium chloride

in the red mud or the pre-processed red mud, the magnesium chloride, and

the dissolution agent class mixing one or two or greater among the magnesium
oxide is added and mixed The step that the second additive consisting of the

acidity chemicals mixing one or two or greater with mixture among the sulfuric

acid, hydrochloric acid, phosphoric acid, aluminium sulfate is added and

mixed The dry step in the constant temperature mixture The step of assorting

the powder of the constant size it shatters to pieces building It is manufactured

after.

【0017】 Hereinafter, each step of the preparation method will be described in

more detail.

【0018】 First, red mud will be described as follows.

【0019】 Red mud is industrial waste generated in the process of refining

bauxite, and red mud in a waste state has a moisture content of 40 to 55% and

a pH of 11 to 13. When such red mud is used as a water treatment agent as

it is, the water quality is basified by strong alkali, which adversely affects it.

More specifically, since red mud injects a large amount of sodium hydroxide

in the process of extracting alumina hydroxide by applying a Bayer process

to bauxite ore during the purification process, red mud itself contains a high

Na2O of 12.4%. Because it contains such high Na2O, it is classified as waste,

and if it is directly injected into the water, it will not only basicize the water
quality but also adversely affect the water quality, such as the destruction of

the ecosystem. Therefore, it is necessary to go through a process of treating

such red mud to be suitable for a water treatment agent.

【0020】 Hereinafter, the pretreatment step will be described as follows.

【0021】 Until the percentage of water content of the red mud makes low the red

mud between 25~300°C between 5~25%, the preprocess phase is proceed the

process of drying.

【0022】 Although not described in the background art, a conventional method

of treating red mud to be used for water treatment is generally a method

of mixing red mud with an acidic material and neutralizing the mixture by
physical stirring and chemical reaction. However, this method requires not

only a large-scale site but also a large neutralization facility, which increases

the cost and takes a considerable amount of time in the neutralization process,

resulting in a problem in that productivity is lowered.

【0023】 The pretreatment step of performing the drying process can overcome

all the problems of the related art, save space, reduce facility costs, facilitate

mass production, improve production speed, and reduce costs.

【0024】 In the pre-treatment step, the basic component is deodorized together

with the moisture of the red mud during the drying process, so that the pH of

the red mud is lowered to between 7 and 11. Thereafter, pretreated red mud

having a particle size of 3 to 25 μm can be obtained through a grinder or a

screen from the lumped red mud in the drying process.

【0025】 In the pre-treatment step, it is very important to dry the red mud until

the moisture content of the red mud is lowered to 5 to 25% regardless of the

drying time. This is because drying the red mud to 5% or less not only requires

excessive drying costs, but also causes a problem in that the pre-treated

red mud is scattered and blown away during the manufacturing process. On
the other hand, when the water content of the red mud is 25% or more, it is
difficult to homogeneously mix the red mud with the chemicals introduced

into the subsequent step due to the water content of the red mud itself, and

the moisture of the red mud itself and the chemicals react first to lower the

chemical reactivity with the minerals constituting the red mud. This is because

there is a problem that treatment efficiency may be lowered when such a final

product is used as a water treatment agent.

【0026】 The pretreated red mud formed under the above-described conditions

is made of natural minerals including ferric oxide, aluminum oxide, silicon

dioxide, titanium oxide, calcium oxide, and sodium oxide, and thus has

properties of adsorbing, aggregating, substituting, decomposing, and removing

suspended solids in the form of fine particles and soluble phosphorus

contained in water, thereby improving the water quality improvement effect.

【0027】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0028】 Next, the step of mixing the first additive will be described as follows.

【0029】 The first additive is included of the calcium chloride, magnesium

chloride, and the mixture mixing one or two among the magnesium oxide.

The process of mixing after throwing in the first additive in the red mud of the

place of business waste state or the pre-processed red mud is proceed.

【0030】 The first additive group is a solubilizer consisting of chloride and

oxide, and the reason why the solubilizer is added is to increase the removal

efficiency of pollutants including total phosphorus contained in water while

lowering the high alkalinity of red mud itself.

【0031】 Accordingly, when the first additive is added to and mixed with red

mud in the state of industrial waste or pre-treated red mud, moisture of the

red mud is removed through dissolution of the red mud, and an ion exchange
reaction occurs in the process, and through this, the sodium component of
the red mud is substituted with calcium and magnesium to lower the alkalinity,

and at the same time, a new trace mineral material including calcium and

magnesium is formed through an adsorption reaction and a ligand exchange

reaction.

【0032】 When the final water treatment agent including the first additive is

introduced into the water due to the above-described action, a reaction

of rapidly adsorbing, aggregating, decomposing, and removing pollutants

including total phosphorus contained in the water occurs actively, and the

water quality is improved in the reaction process.

【0033】 Meanwhile, in the group of the first additive, for example, a difference
between mixing only one calcium chloride and a mixture of calcium chloride

and magnesium chloride or magnesium oxide will be described. When only

calcium chloride is mixed alone, new trace minerals including only calcium

are formed through an ion exchange reaction, adsorption, and ligand

exchange reaction, but when both calcium chloride and magnesium chloride

or magnesium oxide are mixed, new trace minerals including components

of both calcium and magnesium are formed, thereby further increasing the

efficiency of removing pollutants including total phosphorus.

【0034】 Therefore, as the first additive, any one of the groups may be selected

and applied according to cost reduction, special use, and the environment in

which the first additive is placed. However, if possible, it is more preferable to

mix and apply two or more.

【0035】 It returns. Since the mixing of the first additive reds, 1~5 parts by

weight is put about 100 parts by weight into mixer and the speed of rotation is

***ed to 150rpm 5~10 discrimination and it mixes.

【0036】 When the first additive is added in an amount of 1 part by weight or

less, the chemical reactivity between the red mud and the first additive is weak,
and thus sodium contained in the red mud itself cannot be sufficiently replaced
with calcium or magnesium, thereby lowering the water treatment efficiency.

When the first additive is added in an amount of 5 parts by weight or more,

the red mud itself lowers the activity of minerals such as hematite (Fe2O3),

boehmite, and gibbsite (Al2O3), which are useful minerals used to adsorb total

phosphorus, and thus the characteristics of the red mud itself are lost.

【0037】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0038】 Next, the step of mixing the second additive will be described as

follows.
【0039】 The second additive is included of the mixture mixing one or two

or greater among the sulfuric acid, hydrochloric acid, phosphoric acid,

aluminium sulfate. The process of mixing after throwing in the second additive

in the mixture of pre-phase is proceed.

【0040】 The group of the second additive is acidic chemicals, and the reason

for adding the second additive is to compensate for the chemical properties

insufficient in red mud.

【0041】 Accordingly, when the second additive is added to and mixed with

the mixture of the previous step, an ion exchange reaction with the red mud

occurs, thereby lowering the pH of the red mud to neutral or less. At the same

time, minerals such as hematite (Fe2O3), boehmite, and gibbsite (Al2O3), which

are useful minerals, act as optimal environmental conditions for activation.

【0042】 When the final water treatment agent including the second additive

is introduced into the water due to the above-described action, iron and

aluminum ions of minerals constituting red mud are actively subjected to

ion exchange reaction and adsorption reaction without affecting the pH of

the water, thereby further increasing the efficiency of removing pollutants

including total phosphorus.
【0043】 Meanwhile, among the groups of the second additive, for example, the

difference between mixing only one sulfuric acid and mixing both sulfuric acid

and hydrochloric acid is that when the two are mixed alone, sulfuric acid ions

react with red mud to form new trace minerals, and when the two are mixed

alone, more trace minerals are generated due to the mixed interaction between

sulfuric acid ions, hydrochloric acid ions, and red mud, compared to when the

two are mixed alone, thereby further improving the water quality improvement

effect.

【0044】 Therefore, as the second additive, any one of the groups may be

selected and applied according to cost reduction, special use, and the
environment in which the second additive is placed. However, if possible, it is

more preferable to mix and apply two or more.

【0045】 It throws in 5~35 parts by weight in mixer and it ***s about 100 parts by

weight in the rpm 200 3~10 discrimination and the second additive mixes.

【0046】 When the second additive is added in an amount of 5 parts by weight

or less, a chemical reaction with red mud is weak, and thus minerals such as

hematite, boehmite, and gibbsite constituting red mud may not be activated,

and thus water treatment efficiency may be lowered. When the second additive

is added in an amount of 35 parts by weight or more, severe gas may be

generated due to an intense reaction with moisture contained in red mud itself,

and pH of red mud may be excessively lowered, and useful minerals such as

Fe2O3 and Al2O3 contained in red mud may be lost, and thus water treatment

efficiency may be lowered.

【0047】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0048】 Next, the drying step will be described as follows.

【0049】 Until it puts the mixture of pre-phase into drier and the pH of mixture
makes low between 40~200°C to 2~9 interval, step is proceed the process of

drying for 1~3 hours.

【0050】 The reason for performing the drying step is to sufficiently cause a

chemical reaction between the mixture of the previous step and the second

additive.

【0051】 Accordingly, when the drying step is performed, the sodium

component of red mud is substituted with calcium, magnesium, and aluminum

components to generate new trace minerals, and at the same time, iron and

aluminum are maximally activated to be easily dissociated from red mud

through an ion exchange reaction with minerals such as hematite (Fe2O3),

boehmite, and gibbsite (Al2O3) constituting red mud.

【0052】 The final water treatment agent including the drying step due to the

above action activates ion exchange and adsorption reactions with pollutants

including total phosphorus contained in water, thereby maximizing the water

quality improvement effect.

【0053】 When the drying temperature is 40° C. or lower, the substitution ability

between the sodium component contained in the mineral lattice of red mud

and the second additive added as a chemical agent is weakened, and thus

new trace minerals cannot be formed and useful minerals such as hematite,

boehmite, and gibbsite constituting red mud cannot be activated, thereby

lowering the water treatment efficiency. When the drying temperature is

200° C. or higher, the substitution reaction between the sodium component

contained in the mineral lattice of red mud and the second additive added as

a chemical agent causes the formation of new trace minerals to be very weak,

sulfuric acid, hydrochloric acid, phosphoric acid, and aluminum sulfate to

be quickly volatilized without causing a chemical reaction with red mud and

released as a gas, and thus the chemical reaction with hematite, boehmite, and
gibbsite, which are useful minerals of red mud, cannot occur, and thus iron
and aluminum contained in he

【0054】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0055】 Next, the selection step will be described as follows.

【0056】 The screening step is proceed the process of sieving the crushed

material which is pulverized after shattering to pieces the building uniting

through the step of drying of the previous to the lumpy type to the original

powdered form by using the pulverizing device and assorting the powder of

3~25μm through the fine screen and obtaining.

【0057】 The reason for performing the selection step is that since the powder

obtained through the drying step has various sizes, the powder is pulverized

and selected to obtain powder having a predetermined size, so that the

reaction of the water treatment agent in water occurs uniformly and uniformly

and the amount of the water treatment agent is easily controlled.

【0058】 Accordingly, when the selection step is performed, as described above,

the reaction of the water treatment agent occurs uniformly and uniformly in

the water, and in particular, since contaminants contained in the water are

adsorbed in the form of fine particles, the coagulation and precipitation rates

occur rapidly.

【0059】 Due to the above action, the final water treatment agent including the

selection step not only maximizes the water quality improvement effect but also

minimizes the amount of sludge generated.

【0060】 The reason for this is that when the size of the powder is 3 μm or less,

contaminants in water cannot be aggregated and the precipitation rate is slow,

resulting in a decrease in water treatment efficiency, and when the size of

the powder is 25 μm or more, precipitation occurs too quickly due to gravity

precipitation before a reaction with contaminants in water occurs, resulting in
a decrease in water treatment efficiency.

【0061】 Therefore, the above-described conditions play a very important role

in the action of the finally completed water treatment agent, and if the above-

described conditions are not satisfied, the effect cannot be ensured.

【0062】 Hereinafter, a water treatment agent according to various

embodiments will be prepared by applying the above-described preparation

method, and the results of experiments performed thereon will be described as

follows.

【Embodiment 1】

【0063】 In Example 1, a water treatment agent was prepared by mixing only

sulfuric acid with red mud in the state of waste in the workplace. More

specifically, 10 g of red mud having a water content of 48% and a pH of

12.5 and 1.6 ml of sulfuric acid were added to a mixer, stirred at rpm150

for 5 minutes, dried in a dryer set at 105° C. for 2 hours, and then a water

treatment agent having a size of 3 to 25 μm was prepared using a mortar and

a sieve. In this case, the pH of the water treatment agent was measured to be

4.5.

【Embodiment 2】

【0064】 In Example 2, a water treatment agent was prepared by mixing

magnesium chloride, calcium chloride, and sulfuric acid with red mud in

the state of waste in the workplace. The preparation process was the same

as that of Example 1, except that 0.25 g of magnesium chloride and 0.1 g of

calcium chloride were further added to prepare a water treatment agent, and

in this case, the pH of the water treatment agent was measured to be 4.2.

【Embodiment 3】

【0065】 In Example 3, a water treatment agent in which only sulfuric acid

 was mixed with the pretreated red mud was prepared. More specifically, 10
g of pre-treated red mud having a moisture content of 15% and a pH of 9.5

and 1.6 ml of sulfuric acid were added to a mixer by drying the red mud at

250° C., stirred at rpm 150 for 5 minutes, dried in a dryer set at 105° C. for

40 minutes, and then a water treatment agent having a size of 3 to 25 μm

was prepared using a mortar and a sieve. In this case, the pH of the water

treatment agent was measured to be 4.0.

【Embodiment 4】

【0066】 In Example 4, a water treatment agent was prepared by mixing

magnesium chloride, calcium chloride, and sulfuric acid with the pretreated
red mud. The preparation process was the same as that of Example 3, except

that 0.25 g of magnesium chloride and 0.1 g of calcium chloride were further

added to prepare a water treatment agent, and in this case, the pH of the

water treatment agent was measured to be 3.9.

【0067】 Hereinafter, experiments and results thereof will be described with

reference to the above-described embodiments.

【0068】 The following experiment was conducted to find out the results of

phosphate removal using the above examples.

【0069】 [Test 1]

【0070】 As for the experimental conditions, 1.4325 g of potassium dihydrogen

phosphate (KH2PO4) was dissolved in distilled water to make the solution

exactly 1000 ml, and a phosphate (PO4-3) standard solution having a

concentration of 1,000 ppm was prepared. A predetermined amount was

taken from the standard solution and diluted with distilled water to prepare

a comparison target (Blank), and an artificial sewage sample solution having

a pH of 7 and a concentration of 1.10 mg/L was prepared in a 1 L beaker.

In addition, 0.05 g to 0.25 g of each of the water treatment agents prepared

in the examples was added to 1 L of each of the artificial sewage sample

solutions, stirred at 150 rpm for 12 minutes using a stirrer, and then the
artificial sewage sample solution was allowed to stand for 30 minutes.

Thereafter, each sample solution was filtered through a glass fiber filter and

phosphate was analyzed.

【0071】 Table 1 below is a table showing the results of experiments with

different input amounts of Example 1.

【0072】

【table 1】

WATER T input a influent INFLOW WA treated treated wa

REATMEN mount pH TER PO4-P water ter PO4-P

T AGENT (g) concentration pH concentration
MANUFA

CTURING

METHOD

embodi 0.05 7.0 1.10mg/L 6.98 0.43mg/L

ment 1-1

embodi 0.10 7.0 1.10mg/L 6.95 0.21 mg/L

ment 1-2

embodi 0.15 7.0 1.10mg/L 6.89 0.09mg/L

ment 1-3

working ex 0.20 7.0 1.10mg/L 6.84 0.03mg/L

amples 1-4

EXAMP 0.25 7.0 1.10mg/L 6.76 0.02mg/L

LES 1-5

【0073】 From the above table, it can be seen that there is no change in pH

as the concentration of the phosphate to be treated is rapidly lowered in all

Examples 1-1 to 1-5. That is, it can be seen that the treatment of phosphate

is efficiently performed without affecting the pH of the water quality.

【0074】 Table 2 below is a table showing the results of experiments with
different input amounts of Example 2.

【0075】

【table 2】

WATER T input a influent INFLOW WA treated treated wa

REATMEN mount pH TER PO4-P water ter PO4-P

T AGENT (g) concentration pH concentration

MANUFA

CTURING

METHOD

embodi 0.05 7.0 1.10mg/L 6.99 0.40mg/L

ment 2-1

embodi 0.10 7.0 1.10mg/L 6.89 0.19 mg/L

ment 2-2

EXAMP 0.15 7.0 1.10mg/L 6.80 0.06mg/L

LES 2-3

working ex 0.20 7.0 1.10mg/L 6.77 0.02mg/L

amples 2-4

EXAMP 0.25 7.0 1.10mg/L 6.74 0.02mg/L

LES 2-5

【0076】 From the above table, it can be seen that the concentration of
phosphate is lowered more rapidly than in Table 1, and the change in pH

is smaller. In other words, it can be seen that there is a difference between

adding only sulfuric acid to red teeth and adding chemicals together.

Therefore, it can be seen that the treatment efficiency of Example 2 is better

than that of Example 1 when the same amount of input is used.

【0077】 Table 3 below is a table showing the results of experiments with

different input amounts of Example 3.

【0078】
【table 3】

WATER TREAT input a influent INFLOW WA treated treated wa

MENT AGENT mount pH TER PO4-P water ter PO4-P

MANUFACTU (g) concen pH concentration

RING METHOD tration

embodi 0.05 7.0 1.10mg/L 6.96 0.40mg/L

ment 3-1

embodi 0.10 7.0 1.10mg/L 6.82 0.16mg/L

ment 3-2

EXAMPLES 3-3 0.15 7.0 1.10mg/L 6.78 0.05mg/L

working ex 0.20 7.0 1.10mg/L 6.72 0.01mg/L

amples 3-4

working ex 0.25 7.0 1.10mg/L 6.70 0.01mg/L

amples 3-5

【0079】 From the above table, it can be seen that the concentration of

phosphate is lowered more rapidly than in Table 2, and the change in pH

is smaller. In other words, it can be seen that there is a difference between

pretreating red mud and not pretreating it. Therefore, it can be seen that the

treatment efficiency of Example 3 is better than that of Example 2 when the

same amount of input is used.

【0080】 Table 4 below is a table showing the results of the experiment by

varying the input amount of Example 4.

【0081】

【table 4】

WATER T input a influent INFLOW WA treated treated wa

REATMEN mount pH TER PO4-P water ter PO4-P

 T AGENT (g) concentration pH concentration
MANUFA

CTURING

METHOD

embodi 0.05 7.0 1.10mg/L 6.93 0.30mg/L

ment 4-1

EXAMP 0.10 7.0 1.10mg/L 6.80 0.10mg/L

LE 4-2

EXAMP 0.15 7.0 1.10mg/L 6.75 0.01mg/L

LES 4-3

working ex 0.20 7.0 1.10mg/L 6.73 0.01mg/L

amples 4-4

EXAMP 0.25 7.0 1.10mg/L 6.68 0.01mg/L

LES 4-5

【0082】 From the above table, it can be seen that the concentration of

phosphate is lowered more rapidly than in Table 3, and the change in pH

is smaller. That is, it can be seen that there is a difference between adding

only sulfuric acid to the pretreated red mud and adding chemicals together.

Therefore, it can be seen that the treatment efficiency of Example 4 is better

than that of Example 3 when the same amount of input is used.

【0083】 [Experiment 2]
【0084】 Based on the above Experiment 1, the experiment was conducted

on the supernatant that passed through the bioreactor of the 00 sewage

treatment plant in Daegu Metropolitan City, and the experimental conditions

were the same as in Experiment 1, with the supernatant that passed through

the bioreactor instead of the artificial sewage sample solution.

【0085】 Table 5 below is a table showing the results of Experiment 2.

【0086】
【table 5】

WATER T input a influent treated wa treated treated wa

REATMEN mount pH ter PO4-P water ter PO4-P

T AGENT (g) concentration pH concentration

MANUFA

CTURING

METHOD

embodi 0.1 6.54 0.74mg/L 6.54 0.09mg/L

ment 1

embodi 0.1 6.54 0.74mg/L 6.53 0.07mg/L

ment 2

embodi 0.1 6.54 0.74mg/L 6.50 0.04mg/L

ment 3

embodi 0.1 6.54 0.74mg/L 6.47 0.01mg/L

ment 4

【0087】 From the above table, it can be seen that even though 0.1 g of all

of the input amounts of Examples 1 to 4 were added to 1 L, high phosphate

treatment efficiency was exhibited without a change in pH as a whole.

Accordingly, in the case of the water treatment agents prepared by the

methods of Examples 1 to 4, it can be seen that the treatment efficiency of

phosphate is very excellent not only for artificially prepared phosphate but
also for supernatant water passing through the bioreactor of the sewage

treatment plant even when 0.1 g of the water treatment agent is added.

【0088】 Hereinafter, parts that have been tested but have not been described

will be described as follows.

【0089】 In the case of Example 1, hydrochloric acid, phosphoric acid, and

aluminum sulfate were added instead of sulfuric acid, and the results were

similar to those in Tables 1 to 4 and 5. In the case of Example 2, magnesium

oxide was added instead of calcium chloride and magnesium chloride, and
the results were similar to those in Tables 1 to 4 and 5.

【0090】 In addition, as a result of the experiment while excluding one step

in the reverse order from the final completion step of the above-described

manufacturing process, it can be seen that the removal efficiency is

sequentially lowered, but the water quality is improved without significantly

adversely affecting the water quality.

【0091】 Therefore, in the present invention, it is preferable to complete

the water treatment agent through all the steps of the above-described

preparation method, but it is also possible to complete the water treatment

agent by selecting only some of the steps described above according to cost
reduction, manufacturing convenience, or needs.

【0092】 That is, the water treatment agent is red mud or pretreated red mud

in the state of waste in the workplace; The first additive consisting of the

dissolution agent class The second additive consisting of the acidic chemicals

It is most preferable to be made of the mixture in which a is mixed

【0093】 Red mud in the waste state of the workplace; In other words, the pre-

processed red mud The first additive consisting of the dissolution agent class

in the red mud of the place of business waste state described in the above or

the pre-processed red mud In other words, the second additive consisting of

the acidity chemicals It can be included of one or the mixture mixing two.

【0094】 And besides. And the manufacturing method of the above-described

water treating agent, is the red mud of the place of business waste state

In other words, the step that dries and pre-processes the red mud of the

place of business waste state The step that the first additive consisting of

the dissolution agent class is added in the red mud and mixed The step that

the second additive consisting of the acidic chemicals is added in mixture

and mixed The dry step in the constant temperature mixture The step of
assorting the powder of the constant size it shatters to pieces building It most
preferables to manufacture after

【0095】 Jeokni; In other words, the step drying and pre-processes the red

mud The step that the first additive consisting of the dissolution agent class

is added in the red mud or the pre-processed red mud it to the basis and

mixed In other words, the step that the second additive consisting of the

acidity chemicals is added and mixed The step of being dry in the constant

temperature mixture it selectively applies any one of middle or two In other

words, the step of assorting the powder of the constant size it shatters to

pieces building Any one or both of them may be selectively applied, or all of

them may be excluded and manufactured.

【0096】 The step of assorting the powder of the constant size it pulverizes the

curing material the mixture which may not pass through the drying step in

the screening step cures with the natural dry It can advance.

【0097】 In addition, each step described above may be independently applied

to other technical fields other than the technical field in consideration of use,

function, role, action, and the like. Based on this, the present invention will

be able to variously specify the claims as follows.

【0098】 As described above, the description of the present invention is

completed.It is expected that those skilled in the art will be able to fully

understand the gist to be pursued in the present invention through the

above-described details, and various applications and changes will be

possible based on this.

 【Claims】

【Claim 1】

Jeokni; In other words, the pre-processed red mud The first additive consisting

of the dissolution agent class in the red mud described in the above or the pre-

processed red mud In other words, the second additive consisting of the acidity

chemicals 1. A water treatment agent comprising a mixture of any one or both

of the above compounds.

【Claim 2】

The method according to claim 1, wherein:

1. A water treatment agent comprising red mud having a water content of 40 to

55% and a pH of 11 or more.

【Claim 3】

The method according to claim 1, wherein:

A water treatment agent characterized in that the pretreated red mud has a

water content of 5 to 25% and a pH of 7 to 11.

【Claim 4】

The method according to claim 1, wherein:

The water treatment agent of claim 1, wherein the first additive is any one

or a mixture of two or more of calcium chloride, magnesium chloride, and

magnesium oxide.

【Claim 5】

The method according to claim 1, wherein:

The water treatment agent of claim 1, wherein the second additive is any one

or a mixture of two or more of sulfuric acid, hydrochloric acid, phosphoric

acid, and aluminum sulfate.

【Claim 6】
 The method according to claim 1, wherein:
1. A water treatment agent comprising dried powder having a pH of 2 to 9 and

a particle size of 3 to 25 μm.

【Claim 7】

The red mud of claim 1, wherein the water treatment agent is in a waste state

of the workplace; In other words, the step drying and pre-processes the red

mud The step that the first additive consisting of the dissolution agent class

is added in the red mud or the pre-processed red mud and mixed In other

words, the step that the second additive consisting of the acidity chemicals

is added and mixed The step of being dry in the constant temperature the
mixture it selectively applies any one of middle or two In other words, the step

of assorting the powder of the constant size it shatters to pieces building A

method for producing a water treatment agent, characterized in that any one

or both of them are selectively applied or all of them are excluded.

【Claim 8】

The method according to claim 7, wherein:

The present invention relates to a method for manufacturing a water treatment

agent, wherein the pretreatment step is dried at 25-300°C until the moisture

content of red mud is lowered to 5-25%.

【Claim 9】

The method according to claim 7, wherein:

1. A method of preparing a water treatment agent, wherein the first additive

comprises any one or a mixture of two or more of calcium chloride,

magnesium chloride, and magnesium oxide.

【Claim 10】

The method according to claim 7, wherein:

 A method of preparing a water treatment agent, wherein the second additive
comprises any one or a mixture of two or more of sulfuric acid, hydrochloric

acid, phosphoric acid, and aluminum sulfate.

【Claim 11】

The method according to claim 7, wherein:

The present invention relates to a method for manufacturing a water treatment

agent, wherein the drying step comprises a step of putting the mixture of the

previous step into a dryer and drying the mixture at 40-200°C until the pH of

the mixture is lowered to 2-9.

【Claim 12】

The method according to claim 7, wherein:

A method of preparing a water treatment agent, wherein the selecting step

comprises drying a mixture of the previous step, pulverizing the dried mixture,

and selecting and obtaining powder having a particle size of 3 to 25 μm through

a screen treatment.
 【Abstract】

【Summary】

The present invention relates to a water treatment agent capable of treating

soluble phosphorus contained in water at an ultra-high temperature while

minimizing the amount of sludge generated, and to a manufacturing method

thereof.

The water treatment agent according to the present invention is red mud;

In other words, the processed red mud in which the percentage of water

content is included of 5~25%, and pH is 7~11 The first additive consisting

of the calcium chloride, the magnesium chloride, and the dissolution agent
class mixing one or two or greater among the magnesium oxide The second

additive consisting of the acidic chemicals mixing one or two or greater among

the sulfuric acid, hydrochloric acid, phosphoric acid, aluminium sulfate It

characterizes to be made of the mixture mixing.

the manufacturing method of the above-described water treating agent, is

the red mud of the place of business waste state In other words, the step that

dries in the constant temperature and pre-processed the red mud The red

mud of the place of business waste state; In other words, the step that the

first additive consisting of the calcium chloride in the processed red mud,

magnesium chloride, and the dissolution agent class mixing one or two or

greater among the magnesium oxide is added and mixed The step that adds
the second additive consisting of the acidity chemicals mixing one or two

or greater with the mixture in which the first additive is mixed among the

sulfuric acid, hydrochloric acid, phosphoric acid, aluminium sulfate and mixed

The step of being dry in the constant temperature the mixture in which the

second additive is mixed The step of assorting the powder of the constant size

it shatters to pieces building It characterizes to manufacture after.

【Representative Drawing】

Figure1
 【Drawings】

【Figure 1】