Sec: JR_*CO-SC(MODEL-B) Date: 02-07-23

Time: 3 Hrs Max. Marks: 300

02-07-2023_JR.IIT_STAR CO-SC(MODEL-B)_JEE MAIN_CTM-4
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. A system is pushed by a force F as shown in Fig. All surfaces smooth except between B
and C. Friction coefficient between B and C is  . Minimum value of F to prevent block
B from down ward slipping is

 3   5  5 3
A)   mg B)   mg C)    mg D)    mg
 2   2  2
  2
 

2. A trolley A has a simple pendulum suspended from fixed to its desk. A block B is in
contact on its vertical slide. The trolley is on horizontal rails and accelerates towards the
right such that the block is just prevented from falling. The value of coefficient of
friction between A and B is 0.5. The inclination of the pendulum to the vertical is
Narayana IIT Academy 02-07-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-4_Q’P

1
A) tan 1   B) tan 1  3 C) tan 1  2  D) tan 1  2 
2

3. Two blocks M and m are arranged as shown in the diagram. The coefficient of friction
1
between the blocks is 1 = 0.25 and between the ground and M is  2  If M = 8 kg,
3
then find the value of m so that the system will remain at rest.

A) 4/3 kg B) 8/9 kg C) 1 kg D) 8/5 kg

4. A given object takes n times more time to slide down 45° rough inclined plane as it
takes to slide down a perfectly smooth 45° incline. The coefficient of kinetic friction
between the object and the incline is
1 1 1 1
A) B) 1  C) 1  D)
1  n2 n2 n2 2  n2

5. A horizontal force of 25 N is necessary to just hold a block stationary against a wall. The
coefficient of friction between the block and the wall is 0.4. The weight of the block is

A) 2.5 N B) 20 N C) 10 N D) 5 N

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6. A block of mass m is kept on an inclined plane of a lift moving down with acceleration
of 2 ms 2 . What should be the minimum coefficient of friction to let the block move
down with constant velocity?

1
A)   B)   0.4 C)   0.8 D)   not defined
3

7. Two smooth blocks of masses m and m' connected by a light inextensible strings are
moving on a smooth wedge of mass M. If a force F acts on the wedge the blocks do not
slide relative to the wedge, find the acceleration of the wedge

m' m' m' m

A) g B) g C) g D) g
m M m M m'
8. Blocks A and C start from rest and move to the right with acceleration a A  12t ms 2 and
aC  3 ms 2 . Here t is in seconds. The time when block B again comes to rest is

A) 2 s B) 1 s C) 3/2 s D) 1/2s
9. The acceleration of the block B in Fig, assuming the surfaces and the pulleys P1 and P2
are all smooth, is

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F 3F F 3F
A) B) C) D)
4m 13m 2m 17m
10. If block B moves towards right with acceleration b, find the net acceleration of block A

A) biˆ  4bjˆ B) biˆ  bjˆ C) biˆ  2bjˆ D) None of these

11. Two blocks A and B are separated by some distance and tied by a string as shown in the
figure. The force of friction in both the blocks at t = 2 s is

A) 4 N    ,5 N    B) 2 N    ,5 N   

C) 0 N    ,10 N    D) 1N    ,10 N   

12. Two masses each equal to m are lying on X-axis at (-a, 0) and (+a, 0), respectively, as
shown in fig. They are connected by a light string. A force F is applied at the origin
along vertical direction. As a result, the masses move towards each other without losing
contact with ground. The acceleration of each mass is (Assume the instantaneous
position of the masses as (-x, 0) and (x, 0) respectively)

2F a 2
 x2  2F x F x F X
A) B) C) D)
m x m a 2
 x2  2m a 2
 x2  m a 2
 x2 

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13. The pulley arrangements shown in figure are identical, the mass of the rope being
negligible. In case 1,the mass m is lifted by attaching a mass 2m to the other end of rope
with a constant downward force 2mg. The acceleration of mass m in case 1 is

A) Zero B) more then thet in case II

C) less then thet in case II D) equal to that in case I
14. The string between blocks of masses ‘m’ and ‘2m’ is massless and inextensible. The
system is suspended by a massless spring as shown. If the string is cut, the magnitudes
of accelerations of masses 2m and m (immediately after cutting)

g g g g
A) g , g B) g , C) ,g D) ,
2 2 2 2
15. In the figure shown a3  6m / s 2 (downwards) and a, =4m/s² (upwards). The acceleration
of 1 is

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A) 1m / s 2 upwards B) 2m / s 2 upwards C) 1m / s 2 downwards D) 2m / s 2 downwards

16. Block is attached to system of springs. The equivalent spring constant is

A) K B) 2K C) 3K D) 4K
17. If ‘O’ is at equilibrium then the values of the tension T1 and T2 respectively

A) 20N, 30N B) 20 3N , 20 N C) 20 3N , 20 3 N D) 10N, 30N

18. A cart of mass M has a block of mass m in contact with it as shown in the figure. The
coefficient of friction between the block and the cart is  . What is the minimum
acceleration of the cart so that the block m does not fall

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A)  g B) g /  C)  / g D) M  g / m
19. Find the reading of spring balance as shown in figure. Assume that mass M is in
equilibrium (All surfaces are smooth)

A) 8 N B) 9 N C) 12 N D) Zero
20. A string of negligible mass going over a clamped pulley of mass m supports a block of
mass M as shown in the figure. The force on the pulley by the clamp is given

2 2
A) 2Mg B) 2mg C)  M  m   m 2 g D)  M  m   M 2 g

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

21. A system is shown ib fig. Assume that the cylinder remains in contact with the two
wedges.Then the velocity of cylinder is x ms 1 find x

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1
22. A block of mass m is lying on a having inclination angle   tan 1   wedge is moving
5

with a constant acceleration a  2 ms 2 . The minimum value of coefficient of friction  so

x
that m remains stationary w.r.t. wedge is . Find x  y
y

23. Mass of block A is 5 kg. Neglect the mass of the pulley and cords. The block B has a
mass of 10 kg. The coefficient of kinetic friction between block B and the surface is
2
 k  0.1.(Take g  10m / s 2 ) . If the acceleration of block A is Find y
y

24. A bead C can move freely on a horizontal rod. The bead is connected by blocks B and D
bya string as shown in the figure. If the velocity of B is  . The velocity of block D is
4v / x, then the value of x is

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25. Two blocks A and B having masses 1kg and 4 kg respectivley are arranged as shown in
the figure. The pulleys P and Q are light and frictionless. All the blocks are resting on a
horizontal floor and the pulleys are held such that strings remains just taut. At moment
t  0 a force F  30t ( N ) starts acting on the pulley P along vertically upward direction as

shown in the figure. The time when the blocks A and B loose contact with ground is 4/x
sec then x is

26. A 6kg block is kept over a rough surface with coefficients of friction
 s  0.6 and k  0.4 as shown in fig. A time varying force F=4t(F in newton and t in

second) is applied on the block as shown. Find the acceleration of block at t= 5sec.
 g  10m / s 
2

27. A block of mass 5kg is lying on a rough horizontal surface. The coefficient of static and
kinetic friction are 0.3 and 0.1 and g  10ms 1. The frictional force on the block is (in N)
28. A heavy uniform chain lies on horizontal table top. If the coefficient of friction between
the chain and the table surface is 0.25, the maximum percentage of the lengh of the
chain that can hang over the edge of the table is

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29. A given object taken 3 times as much time to slide down a 450 rough incline as it takes to
slide down a perfectly smooth 450 incline. The coefficient of friction between the object
Y
and the incline is . Find Y
9
30. A block slides down a rough inclined plane of slope angle  with a constant velocity. It
is then projected up the same plane with an initial velocity v. The distance travelled by
pv 2
the block up the plane before coming to rest is . Find p  q
qg sin 

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

31. The difference between enthalpies of reaction at constant pressure and constant volume
for the reaction 2C6 H 6  l   15O2  g   12CO2  g   6 H 2O  l  at 298K in kJ is

A) -7.43 B) +3.72 C) -3.72 D) +7.43

32. When 0.18g of glucose was burnt in a bomb calorimeter, the temperature rose by 4K. The
heat capacity of the calorimeter system is  C H 0  2.8 106 J / mol glucose 

A) 700J/K B) 700kJ/K C) 126 J/K D) 7.0 kJ/K

33. The heat evolved in the combustion of glucose C6 H12O6 is -680 kcal/mol. The mass of CO2
produced, when 170 kcal of heat is evolved in the combustion of glucose is
A) 45g B) 66g C) 11g D) 44g
34. Heat evolved in the complete combustion of 1.026 kg sucrose at constant pressure will
be C12 H 22O11  s   12O2  g   12CO2  g   11H 2O  l  ; H  5.65 103 kJ

A) 1.695 104 kJ B) 5.65 103 kJ C) 1.883 103 kJ D) 3.22 104 kJ

35. A solution of 500ml of 2M KOH is added to 500ml of 2M HCl and the mixture is well
shaken. The rise in temperature T1 is noted. The experiment is again performed using
250ml of KOH solution and 500ml of HCl solution and rise in temperature T2 is again
noted. Which of the following is correct?

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A) T1  T2 B) T1 is 2 times as larger as T2

C) T2 is twice larger as T1 D) T1 is 1.5 times as larger as T2

36. Given that C  s   O2  g   CO2  g  ; H 0   XkJ

2CO  g   O2  g   2CO2  g  ; H 0  YkJ

The enthalpy of formation of carbon monoxide will be

A)
2X  Y  B)
Y  2 X  C) 2X  Y D) Y  2 X
2 2

37. Enthalpy of neutralization of H 3 PO3 by NaOH is 106.68kJ / mol . If the enthalpy of

neutralization of HCl by NaOH is -55.84 kJ/mol, then the H ionization of H 3 PO3 into its ions is

A) 50.84kJ/mol B) 5kJ/mol C) 10kJ/mo l D) 2.5kJ/mol

38. Calculate  f H for ZnSO4  s  from the following data

ZnS  s   Zn  s   S  rhombic  , H1  44kcal / mol

2ZnS  s   3O2  g   2ZnO  s   2SO2  g  , H 2  221.88kcal / mol

2SO2  s   O2  g   2 SO3  g  , H 3  46.88kcal / mol

ZnSO4  s   ZnO  s   SO3  g  , H 4  55.1kcal / mol

A) 233.48kcal / mol B) 343.48kcal / mol

C) 434.84kcal / mol D) 311.53kcal / mol
39. The value of H sol of anhydrous copper (II) sulphate is -66.11kJ. Dissolution of 1mole of
blue vitriol. [Copper(II) sulphate pentahydrate] is followed by the absorption of 11.5kJ of
heat. The enthalpy of dehydration of blue vitriol is
A) -77.61kJ B) +77.61kJ C) -54.61kJ D) +54.61kJ
40. Study the following thermochemical data
S  O2  SO2 H  298.2kJ

1
SO2  O2  SO3 H  98.2kJ
2
SO3  H 2O  H 2 SO4 H  130.2kJ

1
H 2  O2  H 2O H  287.3kJ
2

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The enthalpy of formation of H 2 SO4 at 298K will be

A) -433.7Kj B) -650.3kJ C) +320.5kJ D) -813.9kJ

41. Calculate the free energy change for the reaction: H 2  g   Cl2  g   HCl  g  by using the

following data at the reaction temperature of 270 C .

Bond enthalpies (kJ/mol) H-H = 435; Cl-Cl = 240; H-Cl = 430
Entropies (J/K-mol) H 2  130; Cl2  222; HCl  186

A) -185kJ B2) -20kJ C) -179kJ D) -191kJ

42.  f H 0 for NF3  g  is -113 kJ/mol. Bond energy for the N-F bond is 273.5kJ/mol. The bond

energies of N 2 and F2 , if their magnitudes are in the ratio 6:1 are respectively,

A) 822.6, 137.1 kJ/mol B) 979.8, 163.3 kJ/mol

C) 943.33, 157.22 kJ/mol D) 762.6, 127.1 kJ/mol
43. Two moles of an ideal monoatomic gas is heated from 270 C to 6270 C , reversibly and
isochorically. The entropy of gas
A) increases by 2R ln3 B) increases by 3R ln3
C) decreases by 2R ln3 D) decreases by 3R ln3
44. One mole of an ideal monoatomic gas undergoes adiabatic free expansion from 2 to
20dm3 , 300K. The value of S from the gas is

A) 0 B) +R ln10 C) -R ln10 D) +1.5R ln10

45. A spontaneous reaction is impossible if
A) both H and S are negative
B) H and S are positive
C) H is negative and S is positive
D) H is positive and S is negative
46. The enthalpy and entropy change for a chemical reaction are -2500cal and +7.4cal/K,
respectively. The nature of reaction at 298 K is
A) spontaneous A) reversible
B) never occurring D) non- spontaneous

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2a
47. Inversion temperature  Ti   is defined as the temperature above which of a gas is
Rb  

expanded adiabatically it gets warmed up but if temperature of gas is lower than Ti then it
will cool down. What will happen to a gas if it adiabatically expanded at 600K if its
Boyle’s temperature is 290K?
A) Heating B) Cooling C) Constant D) None
48. The compressibility of a gas is greater than unity at 1atm and 273K. Therefore
A) Vm  22.4 L B) Vm  22.4 L C) Vm  22.4 L D) Vm  44.8L
N
49. When 2.5g of a sample of Mohr’s salt reacts completely with 50ml of KMnO4 solution.
10
The % purity of the sample of Mohr’s salt is
A) 78.4 B) 70 C) 37 D) 40
50. 4 mole of a mixture of Mohr’s salt and Fe2  SO4 3 requires 500ml. of 1M K 2Cr2O7 for

complete oxidation in acidic medium. The mole % of the Mohr’s salt in the mixture is
A) 25 B) 50 C) 60 D) 75
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

51. Volumes of 50ml if 1M NaOH and 50ml of 1M HCl both at the same temperature were
mixed in a calorimeter of very small heat capacity. A temperature rise of 411K was
recorded. In a second experiment, the HCl was replaced by 50ml of 1M HCOOH. The
temperature rise was 321K. The enthalpy of ionization ( in kcal/mol) of HCOOH is
52. Given C2 H 2  g   H 2  g   C2 H 4  g  : H 0  175kJ / mol

H 0f  C2 H 4  g   50kJ / mol ; H 0f  H 2Ol    280kJ / mol ; H 0f  CO2  g    390kJ / mol

If H 0 is enthalpy of combustion (in kJ/mol) of C2 H 2  g  , then calculate the value of

H 0
257

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53. The integral enthalpies of solution of anhydrous CuSO4  s  and hydrated CuSO4 .5 H 2O  s 

are -70kJ per mol and 10kJ per mol respectively. Determine the magnitude of enthalpy
of hydration of 0.1 mole anhydrous CuSO4  s  as

CuSO4  s   5 H 2O  CuSo4 .5 H 2O  s  1

54. If enthalpy of neutralisation of HCl by NaOH is -57kJ/mol and with NH 4OH is

50kJ / mol . Calculate enthalpy of ionisation of NH 4 OH  aq  .

55. Lattice energy of NaCl  s  is -790 kJ/mol and enthalpy of hydration is -785 kJ/mol.

Calculate enthalpy of solution of NaCl  s  .

56. A perfect gas undergoes a reversible adiabatic expansion from (300K, 200atm) to (90K,
10atm). Find the atomicity of gas.
57. Calculate work done in chemical reaction (in kcal)
A  s   3B  g   C  l  at 2270 C at 1 atm in closed vessel.

58. Find out the difference in number of angular nodes and number of radial nodes in the
orbital to which last electron of chromium present.
59. Infrared lamps are used in restaurants to keep the food warm. The infrared radiation is
strongly absorbed by water, raising its temperature of the food. If the wavelength of
infrared radiation is assumed to be 1500nm, and the number of quanta of infrared
radiation produced per second by and infrared lamp (that consumes energy at the rate of
100W and is 12% efficient only) is  x 1019  , then the value of ‘x’ is

(Given : h  6.625 1034 J  s )

60. A sample of 28mL of H 2O2  aq  solution required 10mL of KMnO4  aq  solution for

complete reaction in acidic medium. What is the volume strength of H 2O2 ?

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MATHEMATICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

890
1
61. Let f    x
and s   f   then 2s-8=
1   cot    1

a) 9 b) 18 c) 81 d) 0
 5 9 13
62. The value of tan  tan  tan  tan 
16 16 16 16

a) -4 b) 4 c) 0 d) 8
2 4 6
63. Let the sum of the series  4  4  .....  19 terms is
1  1  1 2  2  1 3  32  1
2 2 2 2 2

19 38 380 570
a) b) c) d)
20 381 381 571
2 9
64. The product of 9 G.M’s inserted between the numbers and is
9 2

99 29
a) 9 b) 1 c) d)
29 99

cos 2 10  cos 2 2 0
65. The value of is equal to
2sin 30 sin10
1 1 1
a) 1 b) c) d)
3 2 5

66. 
sin 200 4  sec200  
1
a) b) 2 c) 3 d) 1
2
0 6
 
67. If 4cos360  cot  7 1   n1  n2  n3  n4  n5  n6 Then  ni2
 2  i 1

a) 91 b) 20 c) 9 d) 0
sin x.sin 2 x  sin 3 x.sin 6 x  sin 4 x.sin13 x
68. Let y  ,then:
sin .x cos 2 x  sin 3 x.cos 6 x  sin 4 x.sin13 x
 
a) f  x   , then y  2  1 b) f  x   , then y  2  1
72 20

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 5
c) f  x   , then y  2  3 d) f  x   , then y  2  3
108 108

69. If a1 , a2 , a3 ..............a10 are A.M. ’s between 5 and 35 then the maximum value of

 a1.a2 .a3 ........a10  is:

10 10 10 10
a) 10  b)  20  c)  30  d)  40 

70. If a1  2a2  3a3  4a4  1000 where ai  0  i  1, 2,3, 4 and maximum value of
a1  a22  a33  a44  p q , p, q  N ,then least value of (p+q) is :

a) 30 b) 50 c) 90 d) 100
71. If x,y,z are positive reals satisfying xyz=32 then the minimum value of
x 2  4 xy  4 y 2  2 z 2 is :

a) 92 b) 96 c) 48 d) 44
72. If x 3  px 2  qx  27  0 has three positive roots where p, q  0 and p  k  l 2  4l  10 where
k , l  R , then the greatest value of k is :

a) 1 b) 5 c) 6 d) 7
73. Four geometric means are inserted between the numbers 211  1 and 211  1 . The product of
these geometric means is :
44 23 44 22 22 11 22 12
a) 2  2  1 b) 2  2  1 c) 2  2  1 d) 2  2  1

74. If 4a 2  9b 2  16c 2  2  3ab  6bc  4ca  , then a, b, c are in (where a,b,c c  R  0 )
a) A.P. b) G.P. c) H.P. d) A.G.P.
 2n  1  2n 2  2n  1 n
75. If Tn  2 2 2
, n  N , n  2, then Lim  Tr is equal to :
 n  1 n 2  n  1  n  2  n 
r 2

1 1 1 1
a) b) c) d)
3 4 6 9

76. For a,b>0, let g1 , g 2 , g 3 and g 4 be geometric means between a and b, then the roots of the
 g2 
equation  g 2 g 3  x 2    x  g1 g 4  0 are:
g
 1  g 3 

a) both negative b) both positive

c) one negative and one positive d) imaginary

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Narayana IIT Academy 02-07-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-4_Q’P
77. If n arithmetic means a1 , a2 , a3..............an are inserted between 50 and 200 and n Harmonic
means h1 , h2 , h3............hn are inserted between the same two numbers ,then a2 hn 1 is equal to
:
10000 250
a) 500 b) c) 10000 d)
n n
3 5 7 9
78. The sum of infinity of the series     ....... is :
4 36 144 400
3 1
a) 1 b) c) d) 2
4 2
1 1 1
79. The sum to infinite terms of the series    ......... is:
1 1 1
1 1  3  1  3  5  
4 4 4
1
a) 1 b) 2 c) d) 3
2
1 1   1 1  1 
80. The sum to infinity of the series 1   1  
    1   2  2   ......... is:
2 3  2 2 3
    
12 9 9
a) b) c) d) 3
5 5 10

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.


81. If cot     , 3cot  , cot     , are in A.P and  is not an integral multiple of ,then find
2

2 sin 2 
the value of
sin 2 

 4r  5  1 16
82. If Tr  r r  1   , then find the value of
  r  2  r 2 1  68
T
r 1
r .
 

83. Let T  n   cos 2  300  n 0   cos  300  n 0  cos  300  n0   cos 2  300  n 0  let
30
K  4 nT  n  then last digit of k is________
n 1

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Narayana IIT Academy 02-07-23_JR.IIT_*CO-SC(MODEL-B)_JEE-MAIN_CTM-4_Q’P
84. Let S be infinite sum of the series 2  3cos x  4 cos 2 x  5 cos ³ x  .......... where x satisfies
a
the equation 5cos x  4  5cos x  2  6 If the least value of S is equal to   where a and
b  

b are numbers, then sum of digits of (a + b) =

2 4 
sin 2
sin 2 sin 2
85. The value of the expression 7  7  7 is equal to:
2  2 2 2 4
sin sin sin
7 7 7
86. If cos x  cos 2 x  1. Let E  sin12 x  3sin10 x  3sin 8 x  3sin 6 x  2 , then the value of
log  E is
tan
3

87. If sin   sin   sin   3, ,  ,    0, 2  then cos 2  cos 4   cos 6 is equal to
 2 3 4 5 6 7
88. cos cos cos cos cos cos cos  S then 27 S is______
15 15 15 15 15 15 15
2 4 8 14
89. cos cos cos cos  T then 16T is_____
15 15 15 15

90. If A,B and C are the angles of a triangle, then the value of
tan(A/2)tan(B/2)+tan(B/2)tan(C/2)+tan(C/2)tan(A/2) is

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