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07 ELEMENTIS Wood Coatings
07 ELEMENTIS Wood Coatings
WOOD COATINGS
May 2020
Aqueous Non-Aqueous
Finish paint
40 2
1.50 1.52
1.5
Lightness L*
30.6
30 29.4 1
28.7
ΔE
27.6
26.3 26.3
Competitor 1 / NUOSPERSE®/ Competitor 2
0.5 FX 7500W
0.10
20 0
Tinting rub out Tinting rub out Tinting rub out • NUOSPERSE® FX 7500W
provides visually the best result
Competitor 1 NUOSPERSE® Competitor 2
FX 7500W regarding rub out.
• Color values confirm the
L* △E excellent performance - the
smallest color difference within
the candidates
NUOSPERSE® FX 7500W Market standard - Polymeric NUOSPERSE® FX 7500W Market standard – P+S
7d @ 50 ℃
Nearly
foam-free !
Tested in pue colorants initially after the mentioned time periods a´nd conditions
Metal Protection
Plastic Coating Coating Wood Coating 100
12 80 84.5 87.4 85.1
10 11.2 78.7
Gloss at 60°
60
Color L*
8
40
6 42.8
4 4.8 20
4.4 4.7 4.5
14.4
2 3.3 0
0 Plastic Coating Metal Protection Wood Coating
Coating
NUOSPERSE® FX 7500W provides the high gloss film
NUOSPERSE® FX 7500W Traditional dispersant
Carbon black based colorant tested in acrylic clear base the mentioned test coatings
• NUOSPERSE® FA 196
• NUOSPERSE® FA 601
• NUOSPERSE® 657RD
• NUOSPERSE® 757
Chemical composition
• Multipurpose phosphate ester
• 100% active substance
Key properties
• HLB 12
with NUOSPERSE FA 196
• Dispersant for solvent based systems
• Improves pigment dispersibility and stability
• Excellent dispersant for carbon blacks
• For organic pigments and iron oxide
• Colour acceptance agent for tint bases
+ + + + + + +
+ + + + + + + +
+
- - - - +
+ - - - - - -
+ - - - + -
- - + - - -
- - - - +
+ - - + -
- - - - + + - - - - + +
Without + + + - - + + -- -
-
- +
+ - - - + - -
compatibilizer + + +
+ + +
+
TiO2 in latex paint Pigment in colorant TiO2 and pigment in tinted latex paint
Stable Stable Stable ?
+ +
+ + + + + + + + +
+
With + - - - - - - - +
+
+ + - - - - - - -
- --
+
- - -- - +
Compatibilizer + -
- - - -
- + +
-
- - - -
- + +
FN 260, 265, + + - - + + -- -
-
-
+ - - - + -
+
-
+
+ +
FA 115 + +
+- Polyacrylate salt (e.g. NUOSPERSE® FX 605) Stabilizer/polymer from base paint Surfactant in colorant Compatibilizer
FA 196
2006
FA 196 / 2006
1:1
Enhanced Performance Through Applied Innovation 24
Color acceptance with 2% universal black
colorant
14
delta E rub-out after 10' shaking
12
10
8
6
4
2
0
0.0% 0.5% 1.0% 1.5% 2.0%
w [%]
NUOSPERSE®2006 / FA 196 1:1 NUOSPERSE® 2006 NUOSPERSE® FA 196
In the test formula a 1% addition of competibelizer showed good results with a delta E value <1.
NUOSPERSE® FA 196 or 2006 could be used alone or in a combination.
Enhanced Performance Through Applied Innovation 25
Summary
Summary
Very effective additive which combines unique substrate wetting with non-stabilizing foam behaviour
Chemical base: alkyl terminated nonionic surfactant with polyether segments
Use in waterborne clear and pigmented systems
In grind stage or as postaddition
Gemini Diol
• Costs $$ Elementis
Multifunctional wetting agent
SUPREAD® 2059
+ 0.1 %
+ 0.3 %
Ranking: SUPREAD® 2059 = Gemini Diol > Siloxane-based Gemini > Polyether-modified Polysiloxane
45
40 38
35
31 31 30
30 29
27 28
Drop surface tension
25
21
20
15
SUPREAD® 2059 Market Ref 1 Market Ref 2 Market Ref 3
®
SUPREAD 2059 Market
'Gemini Ref
Diol 1 Market Ref Gemini
'Siloxane-based 2 Market Ref 3
Polyether-modified
Gemini Diol Siloxane-based Gemini Polyether mod.Polysiloxane
Polysiloxane
30
30
25
25 Market Ref 2
20 Siloxane-based
20
15
Gemini
15
10 Market Ref 3 –
10 Polyether-mod.
5 Polysiloxane
5
0
0 100 1000 10000 100000
100 1000 10000 100000 Drop age [ms]
Drop age [ms]
100 100
90 90
80 80 PP-Blank
ABS-Blank
Contact Angle[°]
Contact Angle[°]
70 70
60 60
50 ABS-SUPREAD 50
PP-SUPREAD
2059 2059
40 40
30 ABS - Market 30
Ref. PP- Market Ref
20 20
10 10
0 0
0 2000 4000 6000 8000 10000 0 2000 4000 6000 8000 10000
Market Ref 3
Market Ref 1 Market Ref 2
SUPREAD® Polyether
Gemini Diol Siloxane- Blank w/o
2059 modified
based Gemini
Polysiloxane
0.2%
1.0%
Blank
Surface imperfections
• Blank and Gemini Diol showed a lot of surface imperfections as shown above.
• SUPREAD® 2059 and Siloxane-based Gemini are free of surface defects and provided improved
surface appearance
Blank
Based on
clear
solution
Based on
white Pigment TiO2
grinding Pigment TiO2
showed poor
base showed good
wetting
wetting
SUPREAD® 2059 showes better wetting effect then Gemini diol during charge in process.
Initial
400μm 350μm
After 6
months
300μm 350μm
9
Blank
8
Hectorite based BENTONE® BENTONE® 34
38 provides the highest. 7 BENTONE® 38
Viscosity at low shear rates in
Viscosity [Pas]
6
comparison to the bentonite 5
based BENTONE® 34.
4
3
2
1
0
0 1 10 100 1000
Shear rate [s-1]
200 210
100
BENTONE® 34 BENTONE® 38
30
0
Blank BENTONE 34® BENTONE® 38
September 2019
To verify test methods developed in LK-IND-CP-19- To evaluate the influence of various coalescing agents
005 on the effectivity of pseudoplastic NiSAT products
– Rotational and oscillatory rheology measurements in To identify rheological measuring method to predict the
relation to practical findings
drying time
To judge the influence of various pseudoplastic NiSAT
To bring the rheological data in a context with the
grades on the sprayability
described practical findings
110
KU Viscosity [units]
80
70
60
24 h 48 h 72 h 1 week 2 weeks
Time [min]
KU viscosity (Krebs-Stormer viscosity) represents the the mid-shear (in-can) viscosity of the paint at a temperature of 23°C; Displayed graphic displays the viscosity developement
of the paint after the NiSAT addition at various conditions; predilutition of NiSAT done by blend of water/butyl diglycol (1:1)
120
KU Viscosity [units]
90
80
70
60
24 h 48 h 72 h 1 week 2 weeks
Time [min]
KU viscosity (Krebs-Stormer viscosity) represents the the mid-shear (in-can) viscosity of the paint at a temperature of 23°C; Displayed graphic displays the viscosity developement
of the paint after the NiSAT addition at various conditions; predilutition of NiSAT done by blend of water/butyl diglycol (1:1)
Samples formulated with acrylic thickener grades often display whitening up on water immersion. This is not the case with NiSAT gades
such as RHEOLATE® 299
test system pure acrylic industrial clear coat
100 1.8
KU viscosity [units]
Concentration [%]
93 93 90
1.5
RHEOLATE®299 80
Market reference 1.0
70
0.5
Viscosity [Pas]
10 0.6 60
0.0 50
1
RHEOLATE® 299 requires much lower loadings to achieve equal
KU
KU viscosity. With RHEOLATE® 299 the low shear viscosity was
much higherand the shear thinning characteristics were much
stronger than with the market reference.
0.1
0 1 10 100 1000
Shear rate [s-1]
Rheological data measured with the Anton-Paar MCR 301 rheometer, geometry PP 50, at a temperature of 23°C; KU describes the Krebs-Stormer viscosity; All samples adjusted
to equal KU viscosity of ~93 units; test system clear base coat
KU viscosity [units]
100
3.0 100 100
Concentration [%]
90
2.5
2.0 80
1.5
70
Viscosity [Pas]
10 1.0
60
0.5
RHEOLATE®299 0.5
0.0 50
Market reference
1
RHEOLATE® 299 requires significantly lower loadings to achieve
KU
equal KU viscosity. With RHEOLATE® 299 the low shear viscosity
was much higher and the shear thinning characteristics were
much stronger than with the market reference.
0.1
0 1 10 100 1000
Shear rate [s-1]
Rheological data measured with the Anton-Paar MCR 301 rheometer, geometry PP 50, at a temperature of 23°C; KU describes the Krebs-Stormer viscosity; All samples adjusted
to equal KU viscosity of ~100 units; test system acrylic clear coat
2.9
2.5
2.5
2.3
2.0
1.8 1.8
1.5 1.7
1.3
1.0
1.0 1.0
0.8 0.8
0.5
0.0
Sytem 1; 1c acrylic ; satin System 2; 2c PU; satin System 3; 1c acrylic ; glossy
Concentration of rheological additive (delivery form) to achieve target viscosity of 25-30 sec (DIN 4 cup); the shorter the bar the better the result
RHEOLATE® 350D
Pendulum hardness [swings]
80
72 75 74
70
60
40
All tested samples show comparable film
20
hardness over the relevant testing time.
0
after 24 hours after 1 week after 4 weeks
Tested according to König, DIN EN ISO 1522, applied at a layer thickness of 50 µm; the longer the bar the better the result
3.0 3 105
The use of RHEOLATE®
HX 6008 results in identical DIN 4 cup
and ICI viscosity values at markedly lower product quantities.
100
2.0 2
95
1.4
1.4 1.4 90
1.0 1
High-shear/ICI
High-shear/ICI
DIN 4 cup
DIN 4 cup
RHEOLATE® HX 6008 requires the lowest product 85
loading to achieve a DIN 4 cup viscosity of 100“
0.0
RHEOLATE® HX 6008 Market reference 0 80
RHEOLATE® HX 6008 Market reference
Concentration required to achieve DIN 4 cup viscosity of 100“; ICI viscosity indicates the viscosity at high shear rates of 10000 s-1; Tested in 1c acrylic high gloss woos clear coat
0.1
0.1 1 10 100 1000
Shear rate [s-1]
Rheological data determined using the Anton-Paar MCR 300 rheometer, measuring geometry PP 50, at a temperature of 23°C; ; Tested in 1c acrylic high gloss woos clear coat; All
samples adjusted to equal DIN 4 cup viscosity of 100 seconds
100 110
70 80
80
60 64 70 72
50 60 RHEOLATE® HX 6008 provides enhanced
61
50 57 film hardness after all tested time periods
40
1.4% RHEOLATE®
1.4% RHEOLATE®
1.4% RHEOLATE®
30 40
Samples formulated with RHEOLATE® 30
2.4% Market
20
2.4% Market
2.4% Market
Reference
Reference
HX 6008 display the best gloss results
Reference
HX 6008
20
HX 6008
HX 6008
10
0 10
2.4% Market reference 1.4% RHEOLATE® HX 0
6008 24 hours 1 week 2 weeks
Gloss determined using the Byk Gardner Haze/Gloss tester; Pendulum hardness tested using the Byk Gardner Pendulum hardness tester; In both cases, the larger the bar, the
better the performance; Tested in 1c acrylic high gloss woos clear coat
MATTING MECHANISM
APPLICATION PERFORMANCE
2C PU Matting Coatings
Alkyd Based Wood Coatings
CONCLUSION
Matting effect
Transparency Specific appearance
HYPOMER® MT-2550K
Minimum gloss variation Good adhesion on ABS,
under different DFT PC substrates Specific touch feeling
MATTING MECHANISM
APPLICATION PERFORMANCE
2C PU Matting Coatings
Matting Wood Coatings
Inks application
CONCLUSION
o o o o o o o o o o o o o o o
o o o o o o o o o o o o o o o Wet film
1.Solvent evaporation
Light
Substrate 2.Crosslink and film shrinkage
Scattering
o o oo o o o oo o o o o o o o o o o o oo o o o o o o Dry film
• Solid Resin
Special chemical reaction process
• Liquid resin Solid resin is dispersed and built a uniform
dispersion in liquid resin form.
• Solvent
Crosslinking particle
Solvent Butylacetate(nBAc)
Propylene Glycol Monomethyl Ether
Acetate(PMAc)
Methylcyclohexane(MCH)
OH number / OH % as 41.3 mg KOH / g // 1.25 %
supplied
Proposed applications
Car interior coatings
Car bumper coatings
Plastic coatings
Wood coatings
Inks application
High transparency matting baking coatings
MATTING MECHANISM
APPLICATION PERFORMANCE
2C PU Matting Coatings
Study with Acematt TS 100
Study with Acematt OK 412
Alkyd Based Wood Coatings
CONCLUSION
BENTONE® SD-2 1.0 1.0 1.0 Dispersing agent Elementis Dry Thickness - 60 µm
Add under stirring 100 60 ° 85 °
96 98
Setalux D A 160
40.0 -- 38.5 2c PU resin Nuplex
80
SN
60
HYPOMER® MT- -- 64
51.3 -- Matting resin Elementis
2550K 40
-- -- 20
Acematt TS 100 5.0 Silica matting agent Evonik
12 23 28
0
Solvesso 100 13.0 -- 2.50 solvent ExxonMobil Blank 100 % 5 %
Hypomer® MT TS 100
Total 100.0 100.0 100.0 2550 K
MATTING MECHANISM
APPLICATION PERFORMANCE
2C PU Matting Coatings
Study with Acematt TS 100
Study with Acematt OK 412
Alkyd Based Wood Coatings
CONCLUSION
Resins & Matting Acrylic Resin + Acrylic Resin + Acrylic Resin + HYPOMER® MT-
agent Acematt® OK-412 HYPOMER® MT-2550K HYPOMER® MT-2550K 2550K
Acrylic Resin 43.0 16.0 7.8 0 Resin Elementis
OH% 1.0 / OH# 33.0 / TG 61 °C
Composition of PU thinner:Xylene (50%), n-butyl acetate (37.5%), Ethyl acetate (4.5%) and Ethylene glycol monoethyl ether acetate (8%).
Resins & Matting Acrylic Resin + Acrylic Resin + Acrylic Resin + HYPOMER® MT-
agent Acematt® OK-412 HYPOMER® MT-2550K HYPOMER® MT-2550K 2550K
60゚ 1.8 30.5 10.2 2.3
85゚ 5.2 58.5 25.2 10.5
Intercoat adhesion
1st layer : MT-2550K ,
Pass Pass Pass Pass
80℃ for 1hr
nd
2 layer : MT-2550K
Tests performed after spray application on acrylonitrile butadiene styrene based substrate; Film thickness 30-40µm; Gloss measured by Byk Gardner Haze/gloss.
10
Clarity value
8.7 9 20
20.3
5
10
Tested in a non-aqueous 2K PU coating system; Film uniformity tested using the Dino-Lite Plus digital microscope – AM 313 Plus
fingernail
fingernail
38 um 44 um 43 um
36 um
62 um 60 um
26 um
23 um
HYPOMER® MT-2550K gives excellent gloss stability over a wide range of film thickness
Tested in a non-aqueous 2K PU coating system; Gloss measured using the Byk Gardner Haze/gloss; Tests performed after application on acrylonitrile butadiene styrene substrate
A B C D
Formulation No. (Pure silica matting agent) (68% Matting resin of total (84% Matting resin of total (100 %
binder components) binder components) Pure matting resin)
Resins & Matting Acrylic Resin + Acrylic Resin + Acrylic Resin + HYPOMER® MT-
agent Acematt® OK-412 HYPOMER® MT-2550K HYPOMER® MT-2550K 2550K
500g Pass* Pass Pass Pass
Alcohol
1Kg Pass Pass Pass Pass
500g Damaged (95 cycles) Pass Damaged (496 cycles) Damaged (217 cycles)
MEK
1Kg Damaged (92 cycles) Damaged (970 cycles) Damaged (484 cycles) Damaged (201 cycles)
Remark Fully matt Gloss(60˚)=25-30 Gloss(60˚)=10-12 Fully matt
Test formulation non-aqueous 2K PU based coating; Tested using the Abrasion tester model 339
APPLICATION PERFORMANCE
2C PU Matting Coatings
Study with Acematt TS 100
Study with Acematt OK 412
Alkyd Based Wood Coatings
CONCLUSION
Sample formulated with HYPOMER® MT-2550K shows better transparancy at equal gloss compared with silica based matting agent
Tested in a non-aqueous alkyd based wood coating; Gloss measured using the Byk Gardner Haze/gloss;
10
Enhanced Performance Through Applied Innovation
0
Film Appearance By Microscope
MATTING WOOD COATINGS
A1 A2
B1 B2
10
Enhanced Performance Through Applied Innovation
1
Outline
MATTING MECHANISM OF HYPOMER
MATTING RESIN
APPLICATION PERFORMANCE
2C PU Matting Coatings
Alkyd Based Wood Coatings
CONCLUSION
10
Enhanced Performance Through Applied Innovation
2
Conclusion – HYPOMER® MT-2550K
10
Enhanced Performance Through Applied Innovation
3
DAPRO® DF 21 & DF 51
Deafoamers for clear aqueous
wood coating systems
TECHNICAL OVERVIEW
April 2018
10
Enhanced Performance Through Applied Innovation
5
DAPRO® DF 21
Chemistry/Technical details
• Blend of hydrophobic silica, emulsifiers and mineral oil
• Useable in letdown stage
Market/Application
• For paints, adhesives and resins
• Useful for gloss paints
Strength
• Letdown defoamer for sensitive coating systems
• Product readily dispersed in water
• Minor influence on optical properties
10
Enhanced Performance Through Applied Innovation
6
DAPRO® DF 52
Chemistry/Technical details
• Blend of esters, hydrophobic silica and emulsifiers
• Suitable for let-down addition
Market/Application
• Flexo inks
• Screen printing inks
• Paper coatings
• Clear coatings
Strength
• Minor influence on optical properties
• Excellent compatibility
10
Enhanced Performance Through Applied Innovation
7
System 1
High viscosus acrylic coating
10
Enhanced Performance Through Applied Innovation
8
Head of foam -
HIGH VISCOUS ACRYLIC CLEAR COAT
160
100
80
60
40
37.1
20 28.6
14.3
0
Blank DAPRO® DF 21 DAPRO® DF 52 Market reference 3
All defoamers added at a concentration of 0.5%; Immediate volume increase after 5 minutes mixing with tooth bladed dissolver (Ø3cm) at 5000 rpm; The lower the bar, the
better the result
10
Enhanced Performance Through Applied Innovation
9
Density
HIGH VISCOUS ACRYLIC CLEAR COAT
1.2
Both, DAPRO® DF 21 and DAPRO® DF 52
1.0 outperform the market reference
Density [g/cm3]
0.919
0.8
0.813
0.763
0.6
0.4
0.428
0.2
0.0
Blank DAPRO® DF 21 DAPRO® DF 52 Market reference 3
All defoamers added at a concentration of 0.5%; Density measured Immediately after 5 minutes mixing with tooth bladed dissolver (Ø3cm) at 5000 rpm; Density of the
unstirred sample 1.047 g/cm3; the larger the bar, the better the result
11
Enhanced Performance Through Applied Innovation
0
Gloss at 85°
HIGH VISCOUS ACRYLIC CLEAR COAT
95
93
93
92
92
90
Gloss at 85°
85
Neither, DAPRO® DF 21 nor DAPRO® DF 52
affect the gloss negatively
80
Blank DAPRO® DF 21 DAPRO® DF 52 Market reference 3
All defoamers added at a concentration of 0.5%; the larger the bar, the better the result; Gloss was measured at an angle of 85° using the Byk Gardner Haze/Gloss tester;
Material applied at 250 µm
11
Enhanced Performance Through Applied Innovation
1
Thank you
ADDITIVES FOR WOOD COATINGS
INDOOR OUTDOOR