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Thermodynamics: Kumar Shishir
Thermodynamics: Kumar Shishir
KUMAR SHISHIR
CHEMISTRY THERMODYNAMICS
ONE OR MORE THAN ONE CORRECT TYPE
1. Which of the following statement(s) is/are correct :
Statement(a) : In any closed system with P, V work only, G is always minimized at equilibrium.
Statement(b) : G is always zero for a reversible process in a closed system.
Statemnent(c) : Gº for an ideal gas reaction is a function of pressure.
Statement(d) : For an irreversible, isothermal, isobaric process in a closed system with P, V work only G must
be negative.
(A) Statement a, b, d (B) Statement b, c, d
(C) Statement c, d (D) Only statement d
9.
Statement–1 : When process H2O(s)
H2O(), reaches equilibrium in a closed system at constant
temperature and pressure, Gibb’s function of H2O(s) & H2O() become same.
Statement–2 : For reversible phase change at constant temperature & pressure, change in Gibb’s free energy will
be zero.
(A) Statement–1 is true, statement–2 is true; statement–2 is correct explanation for statement–1.
(B) Statement–1 is true, statement–2 is true; statement–2 is NOT correct explanation for statement–1.
(C) Statement–1 is true, statement–2 is false.
(D) Statement–1 is false, statement–2 is true.
11. For incomplete combustion of C(s) into CO(g)-pick out correct statement(s) from following:
1
C(s) + O (g)
CO(g) : H° is negative
2 2
(A) G° decreases as temperature is increased
(B) As temperature is increased, tendency of reaction to proceed in forward direction decreases
(C) At low temperature Stotal is less compared to it's value at higher temperature
(D) The equilibrium between reactant and product is not possible because G° is negative at all temperature,
12.
The enthalpy and entropy of trimerizatbo of gas A in gas phase [3A (g)
A3(g)] are –100 kJ/mol and –400
J/K mol respectively. The enthalpy of vapourisation for liquids A and A3 are respectively 25 kJ/raol and 50 kJ/rnol
respectively. If the boiling points of A and A3 are 300 K and 400 K respectively, then select correct statement(s):
(A) Enthalpy for trimerization of liquid is –75 kJ /mol
(B) Enthalpy for trimerization of liquid is –125 kJ /mol
(C) Entropy for trimerization of liquid is –775 J /K. mol
(D) G for trimerization of liquid is 7.5 kJ /mol
13. Statement-1 : Under identical conditions, moist air diffuses faster than dry air.
Statement-2 : The rate of diffusion of gases increases with the decrease in molar mass of the gas and moist air
is lighter than dry air under identical condition.
(A) Statement-1( is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1
(C) Statement-1 is true, statement-2 is false
(D) Statement-1 is false, statement-2 is true
CHEMISTRY 2
14. Select the correct option(s).
(A) Entropy change will be same for the adiabatic reversible and irreversible process if carried out from same
initial states tosame final volume
(B) A closed system having all adiabatic boundaries must be isolated system
(C) Work done in a cyclic process may be zero
(D) Area enclosed by a cyclic process on PV diagram is same as that of TS diagram.
15. Which of the following is frue for reversible adiabatic process involving an ideal gas?
(A) Gas with higher has high magnitude of slope in a P (y-axis) v/s T (x-axis) curve
(B) Gas with higher has high magnitude of slope in a V (y-axis) v/s T (x-axis) curve
(C) Gas with higher has high magnitude of slope in a P (y-axis) v/s V (x-axis) curve
(D) Gas with higher has low magnitude of slope in a P (y-axis) v/s T (x-axis) curve
17. Statement-1: Absolute entropy of an ion in aqueous solution at 298 K may be negative.
Statement-2: Absolute entropy at 298 K of any substance can never be negative.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
V
(D) In an adiabatic process, the internal energy increases at the expense of work done on the gas.
CHEMISTRY 3
20. Which of the following is/are correct?
(A) Spherically symmetric complex of the type MX4 is generally, having low enthalpy than MX2 Y2
(B) More the value of ‘’ lesser will be the work done by gas in an adiabatic expansion process.
(C) Ideal gases produce more work in an isothermal reversible expansion as compared to Vanderwaal's gases,
assunring (V>>nb)
(D) Extensive properties are additive in nature but intensive are not.
22. Statement-1: There is no change in enthalpy of an ideal gas during compression at constant temperature
Statement -2 : Enthalpy of an ideal gas is a function of temperature and pressure.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement- 1 .
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement- 1 .
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
CHEMISTRY 4
27. Which is/are correct statement.
(A) wadiabatic> wisothetmal in anideal gas compression from same initial state to same final volume
Cp
(B) The value of remains constant for diatomic gas at all temperature
C
v
CHEMISTRY 5
34. Statement-1: For adiabatic free expansion of a real gas H = 0.
Statement-2: In adiabatic free expansion W = 0, Q = 0, U = 0 for ideal as well as real gas.
(A) Statement- 1 is true, statement-2 is true and statement-2 is correct explanation for statement-1
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
39. For the process : H2O (l,TK, P bar) H2O (g, TK, P; bar)
(A) G = 0, if P = vapour pressure of H2O(l) at TK
(B) G = +ve, if P = vapour pressure of H2O (l) at a temperature above TK
(C) G =+ve ; if P > vapour pressure of H2O (l) at TK
(D) G = –ve ; if P < vapour pressure of H2O (l) at TK
40. In the P & V diagram shown for an ideal gas undergoing ABCDA process. Choose the correct option(s)
P
A
D
B
Pvx = const & x=1
V
(A) The area enclosed by ABCDA curve gives the net work done on the system,
(B) Area under the curve CDA gives the work involved in CDA process.
(C) In process CDA first the temperature of the process increases and then decreases.
(D) The temperatures at point A, B & C is same.
CHEMISTRY 6
41. Select the incorrect statement(s).
(A) dG = Vdp - SdT is applicable for all process involving both ‘PV’ and ‘non-PV’ work in a closed system.
(B) Ssys can not be negative in any adiabatic process in a closed system.
(C) U=0 for the combustion of C6H6 (g) in asealed rigid diathermic container.
(D) In the presence of 'non-PV' work if (Gsay)T, P < 0, process must be spontaneous in a closed system.
42. Super cooled rain water (–1°C) strikes the wind screen of a car and converts to ice in winter season.
With reference to second law of thermodynamics which statement is correct for above process.
(A) Randomness of universe decreases as ice possess less disorder than liquid water.
(B) Randomness of surrounding decreases
(C) Water to ice conversion is equilibrium process thus increase in randomness is surrounding is equal to
decrease in randomness of system.
(D) Increase in randomness of surrounding is greater than decrease in randomness of system.
45. Sratement-1: For a definite amount of an ideal gas, the internal energy of gas increases in isothermal expansion.
Statement-2 : There areno intermolecular forces among the molecules of an ideal gas.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is hue, statement-2 i s true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
q
(B) T 0 for all cyclic processes.
(C) Adiabatic reversible process is isoentropic
(D) Heat exchange at constant volume condition will be independent of path.
*****
CHEMISTRY 7
CHEMISTRY THERMODYNAMICS
11. (ACD) 12. (AD) 13. (A) 14. (CD) 15. (CD)
28. (ABD) 29. (BCD) 30. (ABC) 31. (BCD) 32. (A)
41. (ACD) 42. (D) 43. (ABCD) 44. (ABD) 45. (D)