Sec: SR MPC STAR-30 DATE: 29-04-2023

Time: 03:00 Hrs WEEKEND-3 Max Marks: 300

IMPORTANT INSTRUCTIONS: -
JEE MAINS MODEL
MATHEMATICS:
+Ve - Ve No.of
Section Question Type Total marks
Marks Marks Q’S
Sec – I(Q.N : 1 – 20) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 21 – 30) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Mark Marks Q’S Marks
Sec – I(Q.N : 31 – 50) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 51 – 60) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100
CHEMISTRY:
+Ve - Ve No.of
Section Question Type Total marks
Mark Marks Q’S
Sec – I(Q.N : 61 – 80) Questions with Single Answer Type 4 -1 20 80
Questions with Numerical Answer Type
Sec – II(Q.N : 81 – 90) 4 -1 10 20
(+/ - Decimal Numbers)
Total 30 100

Syllabus:
MATHS : Complex numbers : Algebra of complex numbers, conjugation, polar representation,
properties of modulus & argument of complex numbers
PHYSICS : Ray Optics - Total Chapter
CHEMISTRY : Total Chemical kinetics except Molecular Collision theoram.

QUESTION PAPER ANALYSIS

SUBJECT EASY MODERATE TOUGH

MATHS
PHYSICS
CHEMISTRY
TOTAL

SR MPC ALL MAINS Page 1

 TEST ASSESSMENT AND ANALYSIS SHEET
MATHEMATICS Marks per Total Attempt Unattempted Correct Incorrect Net
Questions Ques. ed Score
Multiple Choice Questions 80 20
Question No. (Incorrect)
Question No. (Unattempted)
Numerical Type Questions 20 10
Question No. (Incorrect)
Question No. (Unattempted)

PHYSICS Marks per Total Attempt Unattempted Correct Incorrect Net

Questions Ques. ed Score
Multiple Choice Questions 80 20
Question No. (Incorrect)
Question No. (Unattempted)
Numerical Type Questions 20 10
Question No. (Incorrect)
Question No. (Unattempted)

CHEMISTRY Marks per Total Attempt Unattempted Correct Incorrect Net

Questions Ques. ed Score
Multiple Choice Questions 80 20

Question No. (Incorrect)

Question No. (Unattempted)
Numerical Type Questions 20 10
Question No. (Incorrect)
Question No. (Unattempted)
TOTAL SCORE

1) Analysis of Wrong Questions:

Reason for wrong Questions No. of Questions
(to be filled after you have attempted wrong questions on your own after the test)
Knew the question and solve after test but did wrong because of calculation mistake (A)
Knew the question and solve after test but did wrong because of confused and applied wrong concept
(B)
Did not knew the question and couldn’t solve even after exam (C)
Total Number of questions attempted wrong
Note: If some of (A) & (B) is high then you need more practice and also read instructions more carefully whereas if (C) is high it
means the coverage of topic is not sufficient and you need to improve on it
2) Analysis of not attempted Questions: Divide the questions not attempted in 3 categories
Reason for unattempted Questions No. of Questions
(fill after you have tried unattempted questions on your own after the test)
Easy Questions (A)
Average Questions (B)

Difficult Questions (C)

Total Number of questions attempted wrong

Sr STAR JEE MAINS WEEKEND -3 Page 2

MATHS Max Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1
1. The conjugate of a complex number is then the complex number is
i 1
1 1 1 1
A) B) C) D)
i 1 i 1 i 1 i 1
lz  z1   z2
2. If 2 is purely imaginary number then is equal to
mz1  z1   z2
l  
A) B) C) D) 1
m  
3. If z1 and z2 are two non-zero complex numbers such that | z1  z2 || z1 |  | z2 | , then arg z1  arg z2
is equal to
 
A) 0 B)  C) D) 
2 2
 
4. If and are arguments of z1 and z2 then the value of arg  z1 z2  is
3 4
5  7 
A) B) C) D)
12 12 12 12
5. The mod - amp form of 1  i 2 is
  2 
A) 3 cis tan 1 
B) cis tan 1  2 
C) 3 cis  tan   2  
1
D) cis  tan 1  2  
  a  ib  
6. tan  i log   
  a  ib  
2ab a 2  b2 2ab
A) ab B) C) D) 2
a  b2
2
ab a  b2
 a  ib   a  ib 
2 2

7. The real and imaginary parts of     are

 a  ib   a  ib 
8ab  a 2  b 2  8ab  a 2  b2  8ab  a 2  b 2  8ab  a 2  b 2 
A) 1, B) 0, C) 0, D) 1,
 a 2  b2   a 2  b2   a 2  b2   a 2  b2 
2 2 2 2

1  i cos 
8. If is purely imaginary then  =
1  2i cos 
   
A) 2n  ,nI B) 2n  ,nI C) 2n  ,nI D) n  ,nI
2 2 2 4
1  i 3  then
2

9. If z  z and arg z are

4i 1  i 3 
1  1  1 
A) 1,  B) , C) , D) ,
2 2 8 2 4 2
   i 
3  i , then arg  z  =
2 4
10. If z 2  2 3i

Sr STAR JEE MAINS WEEKEND -3 Page 3

 5   7
A) B)  C) D)
6 6 6 6
1  i  x  i 1  2i  y  i  1 
11.   x, y  
2i 2i
 7 7  7 7   7 7  7 7 
A)  ,  B)  ,  C)  ,  D)  , 
 3 15   3 15   5 15   5 15 
12. If z1  2 , z2  3 , z3  4 and z1  z2  z3  5 then 4 z2 z3  9 z3 z1  16 z1 z2 =
A) 20 B) 24 C) 48 D) 120
13. The sum of the series i  2i  3i  ... up to 200 terms equals
2 3

A) 100  i 1 B) 100 1  i  C) 200 i D) 100 1  i 

14. Let z1 , z2 be two complex numbers such that z 1  iz 2  0 and arg  z1 z2    then arg  z1  
 3 3 
A) B) C) D)
2 2 4 4
15. The principal mod-amp form of 2  3  i is
5  5 5

A) 6  2 cis
12

B) 2 3cis
12
C) 3 2cis
12
D) 2 2cis
12
16. The square root of 4ab  2i  a  b 2 
2

A)   a  b   i  a  b   B)   a  b   i  a  b  
C)   a  b   i  a  b   D)  a  b   i  a  b  
17. If z1  1  2i and z2  2  3i Then the sum of z1 and additive inverse of z2 is equal to
A) 1  2i B) 3  i C) 3  5i D) 1  i
i i i i i
592 590 588 586 584
18. The value of 582 580 578 576 574  1 is equal to
i i i i i
A)-1 B)-2 C)-3 D)-4
19. Im  a  i a 4  a 2  1  
 
a2  a  1 a2  a  1 1 1
A) B) C) a 2  a  1 D) a2  a  1
2 2 2 2

i
20. If z  6e 3
then eiz 
1 1 1 1
A) 3
B) 2 3
C) 3 3
D) 4 3
e e e e

SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted
questions will be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If
the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer is above 10
and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

The smallest positive integer n for which 1  i   1  i 

2n 2n
21. is
22. The minimum value of z  z  1 is
23. If | z  2i | 2 , then the greatest value of | z  3  i | is

Sr STAR JEE MAINS WEEKEND -3 Page 4

 3  4i
then 169  x 2  y 2  
2
24. If x + iy =
5  12i
then the value of  x  3 x 1  y 2 
3
25. If x  iy 
2  cos   i sin 
Z  3Z 2
26. If Z1 , Z 2 are two complex numbers satisfying 1  1, z1  3 then z2 =
3  Z1 Z 2
27. Let z = x + iy be a complex number where x and y are integers then the area of the rectangle
whose vertices are the roots of the equation z z 3 + z z 3 = 350 is
28. For all complex numbers z1 , z2 such that z1  12 and z2  3  4i  5 the minimum value of
z1  z2 is
29. The number of solutions of the equation z 2  z is
30. If z  2  i 3 then z 4  4 z 2  8 z  35 is

PHYSICS Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

31. In the arrangement shown below, the image of the extended object as seen by the observer is

(A) real and inverted (B) real and erect

(C) virtual and inverted (D) virtual and erect

32. A particle revolves in clockwise direction (as seen from point A) in a circle C of radius 1 cm and
completes one revolution in 2 sec. The axis of the circle and the principal axis of the mirror M
coincide, call it AB. The radius of curvature of the mirror is 20 cm. Then, the direction of revolution
(as seen from A) of the image of the particle and its speed is

(A) clockwise, 1.57 ms–1 (B) clockwise, 3.14 ms–1

(C) anti clockwise, 1.57 ms–1 (D) anti clockwise, 3.14 ms–1
33. Choose the correct statement(s) related to the motion of object on the principal axis and its image in
the case of mirrors
(A) Object and its image always move along normal w.r.t. mirror in opposite directions

Sr STAR JEE MAINS WEEKEND -3 Page 5

 (B) Only in the case of convex mirror, it may happen that the object and its image move in the same
direction

(C) Only in the case of concave mirror, it may happen that the object and its image move in the same
direction

(D) Only in case of plane mirrors, object and its image move in opposite directions

34. A point object is between the Pole and Focus of a concave mirror, and moving away from the mirror
with a constant speed. Then, the velocity of the image is :

(A) away from mirror and increasing in magnitude

(B) towards mirror and increasing in magnitude

(C) away from mirror and decreasing in magnitude

(D) towards mirror and decreasing in magnitude

35. A beam of light of width t is incident on an air-water boundary at an angle of incidence 450. The
width of the beam in water is (Refractive index of water = )

22  1   1
.t .t
(A)  1 t (B) t (C)  (D) 

36. A swimmer is swimming inside a tank of water. He looks up at the sky through the water surface.
The surface is calm and sky is bright due to day-light. He can see : -

(A) a small illuminated patch directly above his head whose angular size is independent of his depth

(B) a small illuminated patch above his head whose angular size depends upon the depth of the
swimmer

(C) nothing but darkness outside the tank

(D) the entire top surface of the water

37. A small object is embedded in a glass sphere ( = 1.5) of radius 5.0 cm at a distance 1.5 cm left to
the centre. Locate the image of the object as seen by an observer standing to the right of the sphere.

(A) 2.65 cm left of the centre (B) 2.65 cm right of the centre

(C) 3.65 cm left of the centre (D) 3.65 cm right of the centre

38. A parallel beam of light from a laser falls on a crystal-ball of radius R as shown in figure. (a) What is
the refractive index of the ball?

3
(A) 2 (B) 3 (C) 2 (D) 1

Sr STAR JEE MAINS WEEKEND -3 Page 6

39. A liquid of refractive index 1.6 is contained in the cavity of a glass specimen of refractive index 1.5
as shown, If each of the curved surfaces has a radius of curvature of 0.20 m, the arrangement
behaves as a

(A) converging lens of focal length 0.25 m

(B) diverging lens of focal length 0.25 m

(C) diverging lens of focal length 0.17 m

(D) None of these

40. Light is incident normally on face AB of a prism as shown in figure. A liquid of refractive index  is
placed on face AC of the prism. The prism is made of glass of refractive index 3/2. The limits of  for
which total internal reflection takes place on face AC is
Liquid
A 60 C
o
90
o
B

3 3 3
(A)   (B)   3 (C)   3 (D)  
2 4 2

41. When a beam of white light passes through a prism it splits up into different colours, violet is bent
most because

(A)  of glass of violet rays is smaller than for other rays

(B)  of glass for violet rays is greater than for other rays

(C)  is same for all colours but violet rays have smaller wavelength

(D)  is same for all colours but violet rays have longer wavelength

42. Two thin prisms of crown glass have refracting angles of 10 degrees and 20 degrees. The dispersive
powers of these prisms are:

(A) 1 : 1 (B) 2 : 1 (C) 1 : 2 (D) 4 : 1

43. In a simple microscope, if the final image is located at 25 cm from the eye placed closed to the lens,
then magnifying power is

(A) 25/f (B) [1 + (25/f)] (C) f/25 (D) [(f/25) + 1]

44. To increase the angular magnification of a simple microscope, one should increase

(A) the focal length of the lens (B) the power of the lens

(C) the aperture of the lens (D) the object size

Sr STAR JEE MAINS WEEKEND -3 Page 7

45. An object is placed at a distance u from a simple microscope of focal length f. The angular
magnification obtained depends

(A) on f but not on u (B) on u but not on f (C) on f as well as u (D) neither on f nor on u
46. A refracting astronomical telescope has several interchangeable eye pieces. In order to increases the
instrument’s magnifying power, the operator should replace the eye piece with another of

(A) shorter focal length, moving in closer to the objective lens

(B) shorter focal length, moving it further from the objective lens

(C) shorter focal length, without changing its distance from the objective lens

(D) longer focal length, moving it closer to the objective lens

47. The refracting angle of a prism is A and refractive index of the material of the prism is cot (A / 2)
Then the angle of minimum deviation will be –

A) 180 - 2A B) 90 A C) 180 2A D) 180 -3A

48. An object is placed against the centre of a concave mirror and then moved away from the mirror along
the central axis until it is 5.0 m from the mirror. During the motion, the distance i between the mirror
and the image it produces is measured. The procedure is then repeated with a convex mirror and a
plane mirror. Figure gives the results versus object distance p. Which curve corresponds to which
mirror? (Curve I has two segments.)

c
(A) Concave mirror – 1, convex mirror – 2, plane mirror – 3

(B) Concave mirror – 2, convex mirror – 1, plane mirror – 3

(C) Concave mirror – 1, convex mirror – 3, plane mirror – 2

(D) Concave mirror – 2, convex mirror – 3, plane mirror – 1

49. What is the greatest magnifying power of a convex lens of power 40 dioptre when used when used as
magnifying glass?

(A) 101 (B) 10 (C) 11 (D) 161

50. An object is placed in front of a concave minor of focal length f as shown in figure. Choose the correct
shape of the image:

Sr STAR JEE MAINS WEEKEND -3 Page 8

 (A) (B) (C) (D)

SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions
will be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If the Answer is in
Decimal then round off to the nearest Integer value (Example i,e. If answer is above 10 and less than 10.5 round off
is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

51. The circular boundary of the concave mirror subtends a cone of half angle  at its centre of
curvature. The minimum value of  for which ray incident on this mirror parallel to the principle axis
suffers reflection more than one is 15α°. Find the value of α

52. A concave mirror has a focal length 20 cm. The distance between the two positions of the object for
which the image size is double of the object size is _________ cm

53. In case of concave mirror of focal length f, the minimum distance between a real object and its real
image is nf. Find the value of n
54. An astronomical telescope consists of an objective of focal length 60cm and an eye piece of focal
length 5cm. It is focused on a distant object such that the rays emerging from the eye-lens are
parallel. The object subtends an angle of 20 at the objective. The angular width of the image is
______ degrees.

55. A rod made of glass ( = 1.5) and of square cross-section is bent into the shape shown in figure. A
parallel beam of light falls perpendicularly on the plane flat surface A. Referring to the diagram, d is
d
the width of a side & R is the radius of inner semicircle. If the maximum value of ratio R so that all

Sr STAR JEE MAINS WEEKEND -3 Page 9

 light entering the glass through surface A emerge from the glass through surface B is n/14, find n.

A B

56. A convex spherical surface forms an inverted image of an object. The object is placed in air and
image is formed in glass (μ = 1.5). If the object and image distances from the spherical surface are
0.2 m and 0.3 m respectively, the magnification is x/9, find x.

57. A right-angled prism of apex angle 40 and refractive index 1.5 is located in front of a vertical plane
mirror as shown in figure. A horizontal ray of light is falling on the prism. If the total deviation
produced in the light ray as it emerges 2nd time from the prism is x degrees clockwise, then x = ___

58. What is the magnifying power of a simple microscope of focal length 3 cm? (Take least distance of
distinct vision to be 24 cm. The image is formed at distance 25 cm)

59. If the ratio of magnifications produced by a simple microscope in near point adjustment and far point
adjustment is 6/5, then the focal length of the lens is ________ cm. (take D = 25 cm)
60. In a compound microscope the focal length of the objective is 0.5 cm and the focal length of eye-
piece is 5 cm. The real image of the object is formed at a distance of 15.5 cm from the objective. If
the final image is formed at a distance of 25 cm from the eye-piece, what is the magnifying power of
the microscope? (Round off to the nearest multiple of 10)

CHEMISTRY Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of
which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
3
2 A  3B  C  3P
61 . For the reaction 2 which statement is correct?
dnA 3 dnB 3 dnC dnA dnB dnC
   
a ) dt 2 dt 4 dt 2) dt dt dt
dnA 2 dnB 4 dnC dnA 2 dnB 3 dnC
   
c) dt 3 dt 3 dt d) dt 3 dt 4 dt

Sr STAR JEE MAINS WEEKEND -3 Page 10

62. In the following reaction: xA  yB
 d  A   d  B 
log10     log10    0.3010
 dt   dt 
‘A’ and ‘B’ respectively can be
a) n  Butane and Iso-butane b) C2 H 2 and C6 H 6
C H and C4 H8
c) 2 4
N O and NO2
d) 2 4
63. NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation
2 N2O5  g   4NO2  g   O2  g 

The initial concentration of

N 2O5 is 3.00 mol L1 and it is 2.75 mol L1 after 30 minutes. The rate of

formation of
NO2 is :
3 1 1 2 1 1
a ) 4.167x10 mol L min b) 1.667x10 mol L min
3 1 1 3 1 1
c) 8.333x10 mol L min d) 2.083x10 mol L min

64. The given plots represent the variation of the concentration of a reaction R with time for two
different reactions (i) and (ii). The respective orders of the reactions are:

a)1,0 b)1,1 c)0,1 d)0,2

65. For the reaction 2 A  B  C , the values of initial rate at different reaction concentration are given in
the table below The rate law for the reaction is :

 k  A B  Rate  k  A  B  Rate  k  A B Rate  k  A  B 

2 2 2 2

a)Rate b) c) d)
66. The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a
two step process shown below
O3  g   Cl *  g   O2  g   CIO*  g   K i  5.2x109 L mol 1s 1 
…(i)
CIO  g   O  g   O2  g   CI  g   K ii  2.6x10 Lmol s 
* * *
 10 1 1

…(ii)
O  g   O  g   2O2  g 
*
The closest rate constant for the overall reaction 3 is :
20 1 1 10 1 1
a ) 1.4x10 L mol s b) 3.1x10 L mol s
9 1 1 10 1 1
c) 5.2x10 L mol s c) 2.6x10 L mol s
k  A B
67. The rate of law for the reaction below is given by the expression
A  B  product
If the concentration of B is increased from 0.1 to 0.3 mole, keeping the value of A at 0.1 mole, the
rate constant will be
a)3k b)9k c)k/3 d)k
68. Consider the following reactions A  P1; B  P 2; C  P 3; D  P 4,
The order of the above reactions are (i),(ii),(iii) and (iv) respectively. The following graph is
obtained when log [rate]vs log[conc] are plotted:

Sr STAR JEE MAINS WEEKEND -3 Page 11

 Among the following, the correct sequence for the order of the reactions is :
a)         b)        
iv  i  ii  iii i  ii  iii  iv

c)         d)        
iii  i  ii  iv iv  ii  i  iii
69. A flask contains a mixture of compounds A and B. Both compounds decompose by first order
kinetics. The half lives for A and B are 300s and 180s, respectively. If the concentrations of A and B
are equal initially, the time required for the concentration of A to be four times that of B (in s) is:
(Use In2=0.693)
a) 180 b)900 c)300 d)120

70.
H 2 gas is adsorbed on the metal surface like tungsten. This follows ____ order reaction
a)3 b)2 c)0 d)1
71. Decomposition of X exhibits a rate constant of 0.05  g / year . How many years are required for the
decomposition of 5 g of X into 25 g ?
a)50 b)25 d)20 d)40
0
72. At 518 C , the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of at
1 1
a pressure of 363Torr, was 1.00Torr s when 5% has reacted and 0.5Torr s when 33% has reacted.
The order of the reaction is :
a)2 b)3 c)1 d)0
th
1
For a first order reaction, A  P , 1/2 (half-life) is 10days .The time required for 4 conversion of A
73.
t

(in days) is :
 In 2  0.693, In 3  1.1
a)3.2 b)2.5 c)4.1 d)5
74. The rate constant (k) of a reaction is measured at different temperature (T), and the data are plotted in
the given figure. The activation energy of the reaction is kJ mol-1 is :

a) 2/R b)1/R c)R d)2R

For following reactions : A   Pr oduct
700 K
75.
A 
500 K
catalyst
 Pr oduct
E
It was found that the a is decrease by 30kJ/moI in the presence of catalyst. If the rate remains
unchanged, the activation energy for catalysed reaction is (Assume pre exponential factor is same)
a)75 kJ / mol b)105 kJ / mol c)135 kJ / mol d)198 kJ / mol

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76. A sample of milk splits after 60mins at 300K and after 40min, at 400K when the population of
lactobacillus acidophilus in it doubles. The activation energy (in kJ / mol ) for this process is closest
to ______
2
R  8.3 J mol 1 K 1 , In    0.4, e 3  4.0)
(Given, 3
a) -4 b)-8 c)-10 d)+10
E E E E
77. The activation energies of two reactions are a1 and a 2 with a1 a2
If the temperature of the
reacting systems is increased from T to T´, which of the following is correct ?
K1' K '2 K1' K '2 K1' K '2 K1' K '2
(A) K1
= K2 (B) <2K1 K2
(C) > K1 K2(D) < K1 K2

78. For a Ist order reaction nA  B whose concentration Vs time curve as shown below

B
Conc.

A
48 time (min) 

If half life for the reaction is 24 mins the value of n is

(A) 1 (B) 2 (C) 3 (D) 4
1
79. The reaction, N2O5 (g) 2 NO2 (g) + 2 O2 (g), is started with initial pressure of N2O5 (g) equal
to 600 torr. What fraction of N2O5 (g) decomposed when total pressure of the system is 960 torr ?
(A) 0.05 (B) 0.1 (C) 0.2 (D) 0.4
80. The reaction, X+2Y+Z  N occurs by the following mechanism
(i) X + Y M (very rapid equilibrium) (ii)M + Z O (slow)
(iii) O+Y N (very fast)
What is the rate law for this reaction
(A) Rate = k[Z] (B) Rate = k[X] [Y]2 [Z] (C) Rate = k[N] (D) Rate = k [X] [Y] [Z]
SECTION-II
(Numerical Value Answer Type)
This section contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted
questions will be considered if more than 5 questions attempted. The Answer should be within 0 to 9999. If
the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer is above 10
and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

81. If 75% of a first order reaction was completed in 90 minutes, 60% of the same reaction would be
completed in approximately ( in minutes)__________ (Take :log2=0.30; log2.5=0.40)
0
82. The rate of a reaction decreased by 3.555 times when the temperature was changed from 40 C to
1
30 0 C . The activation energy ( in kJ mol ) of the reaction is
83. A reaction has a half line of 1 min. The time required for 99.9% completion of the reaction is _____
min(Round off to the nearest integer) [Use: In 2=0.69, In 10=2.3]

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84. Gaseous cyclobutene isomerizes to butadiene in a first order process which has a ‘k’ value of
3.3x10 4 s 1 at 1530 C .The time in minutes it takes for the isomerization to proceed 40% to
completion at this temperature is (Rounded off to the nearest integer)
85. Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a

half-life of 3.33h and 25 C . After 9h , the fraction of sucrose remaining is f . The value of
0

1
log10   2
 f  is X x10 then x is (Rounded off to the nearest integer)
1
86. For the reaction , aA  bB  cC  dD, the plot of log k vs V is given below :

4 1
The temperature at which the rate constant of the reaction is 10 s is _____________ K
(Rounded- off to the nearest integer)
5  1
[Given : The rate constant of the reaction is 10 s at 500K]
0
87. The rate constant of a reaction increases by five times on increase in temperature from 27 C to
52 0 C . The value of activation energy in kJ mol 1 is
1 1
(Rounded – off to the nearest integer)[ R  8.314 J K mol ]
1
88. An exothermic reaction X  Y has an activation energy 30 kJ mol . If energy change E during
the reaction is 20kJ , then the activation energy for the reverse reaction in kJ is
1
89. If the activation energy of a reaction is 80.9kJ mol , the fraction of molecules of 700K, having
x
enough energy to react to form product is e , The value of x is
1 1
(Rounded – off to the nearest integer) [Use R  8.31 J K mol ]
2 A  B3  2 AB
90. The reaction is an elementary reaction
For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of 3, the
rate of the reaction increases by a factor of
(Rounded – off to the nearest integer)

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============================================================================
SR STAR JEE MAINS WEEKEND -3 KEY SHEET

DATE: 29 – 04 – 2023

MATHEMATICS KEY:

1) C 2) D 3) A 4) B 5) C 6) B 7) C 8) D 9) B 10) B

11) A 12) D 13) B 14) C 15) A 16) A 17) D 18) B 19) B 20) C

21) 2 22) 1 23) 4 24) 25 25) 0 26) 1 27) 48 28) 2 29) 4 30) 0

PHYSICS KEY:

31) D 32) A 33) A 34) A 35) C 36) A 37) A 38) A 39) B 40) B

41) B 42) A 43) B 44) B 45) C 46) A 47) A 48) A 49) C 50) B

51) 3 52) 20 53) 0 54) 24 55) 7 56) 9 57) 174 58) 9 59) 5 60) 180

CHEMISTRY KEY:
61) C 62) C 63) B 64) A 65) A 66) A 67) D 68) D 69) B 70) C

71) A 72) A 73) C 74) D 75) A 76) A 77) C 78) C 79) D 80) D

81) 60 82) 100 83) 10 84) 26 85) 81 86) 526 87) 52 88) 50 89) 14 90) 27

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1.

2.

3.

4.

6.

7.

8.

9.

10.

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11.

12.

13.

14. arg  z1 z2   arg  z1   arg  z2 

15.

16.

17. Additive inverse of z is -z

18. i 4 n  1
19.

20.

21

22

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23

24

25

26

27

28

29

30
31 Theoritical

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32
33 Conceptual

34

35
36 Conceptual

37

38

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39

40
41 Conceptual
42 Dispersive power is independent of A

43

44
45 Conceptual

46
47 Conceptual
48 Conceptual

49
50 Conceptual

51

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52

53

54

55

56

57

58

Sr STAR JEE MAINS WEEKEND -3 Page 21

59

60

61

62

63

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64

65

66
67

68

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69
70 conceptual

71

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72

73

74

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75

76

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 K´ Ea  1 1  Ea T
ln =   = ×
K R  T T´  R TT '
K´
T is positive, therefore greater the Ea value, greater will be value of
K
K1´ K ´2
 >
K1 K2

77
nA  B
initially a0 0
At time t a0 – nx x
when t =48 min, a0 –nx = x
or a0 = (n +1) x
3a 0
At t = 48 min, nx =
4
3a 0
or a0 = nx + x = +x
4
a0
or x =
4
a0
 a0 = (n + 1) ×
4
or n + 1 = 4
78 or n = 3
1
N2O5 (g) 2 NO2 (g) + O2 (g)
2
Initially : 600 torr — —
p
At equilibrium: (600 – p) torr 2p torr torr
2
 3p 
Total press is  600   torr
 2 

3p
 600 + = 960
2
3p
or = 360
2
or p = 240 torr
240
 fraction of N2O5 (g) decomposed = = 0.4
600
79
80 conceptual

81

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82

83

84

85

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86

87

88

89

90

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