Answer 1

2-propanol and 1-propanol T-x-y diagram at 760 Torr

2-propanol and 1-propanol P-x-y diagram at 90oC.
Answer 2

VAN LAAR CONSTANTS FOR CHLOROFORM - ACETONE

It is derivation of Vander Waal equation:

Hex= b1X1b2X2/b1X1+b2X2 (√ a 1/b 1-√ a 2/b 2 ¿2

Here ai and bi are Vander Waal parameters.

Gex/RT= A12X1A21X2/A12X1+A21X2

Here A12 and A21 are Van Laar coefficients.

Putting the values, we get Van Laar coefficients of chloroform as -0.5899 and that of
acetone as -0.864
P-x-y diagram for the system at 64.5oC.
Answer 3
When we begin cooling with 1300C with y1 as 0.75, the mixture contains 70% mol of
benzene and 30% mol of toluidine. To find the temperature of liquefaction the diagram
above has been used and extrapolated such that we reach the ratio of 25/75 using the
inverse lever arm rule. The temperature is found to be 88 0C. To find this we make a vertical
line from point M to point B. Now the ratio of AB to BC is 25/75. The composition of
benzene at this state is equivalent to point A which is 0.65.