/ cnn

DlUl,',aQD[:ül/nE)[r, A i^ilş ,A--^ ^ıa

u ij [r..!lj\lı İ ü.glij^u!\:İ ı:\,lJllUj ij:eı"t|jıj[Zia.,!" iG[',?ltÇle
^

.Sa.,*ii; iatn -ii:eeı

aocording to Regulation (EC) i.io. ,i9C7/2006 iRiACH) wiih iis arneniment Reguiaiicn (EUj 20ı5i830
Dat= oi issue: i2120/201,,! Re,iisiorı ciai.e:4l13i2017 Supersedes: 'i!'iizai7 \./eı,sioi-ı: 3.

Pı-oCuct i'orm substance

Trade name PHOSPHORlC ACiD Feriilizei. Gı,adş
chernical name Crihophospnoi-ic: acic
EC {ndex No
EC No
015_011-00_6
23,i-633-2 ( çJ
CAS No 7664-3B-2
REACH ı,egistıaiion lılo 0 1 -2 1 1 9485 92ı:-7_t: -002i
produci code Prayphos - 006
Formula H3Po4
Synonyms Orthophosphoric acici
Product group acid

ii İ.gi.;ı,ıııi,. ı$*i:tiŞi,-eç-i -saş ş:'' iıı* 5*ıb$ıiıiiüi 'J, ıtıi;ıİi-tr+ at"!!.i ;Jsg; '.[,i\.|ş?ı .a$aiit§ı
,i.i.,i. Reiş,ıaı,ıtidentified !leaa

lntenCed for gdneral public

use of the substanceimixiure : Fei-tilizer

Title use ciescr

lndustrial usas : Phosphoı,ic acici SU3, SU8, SU9, SU10, SU'i4-, SU'l5, SU16, SU17, SU19, SU20, PCO, PC1, PC7, PC6, PC9a,
(ES Ref.: SE2) PCgb, PC13, Pc14, PCi5, PC19, PC20, Pc21, PC23, PC24, PC25, PC26, PC32, Pc3.1, PC35
PC37, PC39, PROC1, PROC2, PROC3, PROC4, PROC5, PROC7, PRCCBa, PROCBb,
PROC9, PROC10, PROC13, PROC14, PROC15, ERC1, ERC2, ERC3. ERCui, ERC5, ERC6a,
ERC6b, ERC6d, ERC7, ERC12a
Professiona| uses - Phosphoric acici SU1, SU14, SU15, SU16, SU17, SU19, SU22, SU24, PCB, PCga, PC9b, PC12, PC14, PC15,
/tra Dai. Qtr'l\
\L9
ı \9l -. vLv/
PC21 , PC31 , PC35, PC37 , PC3B, PROCBa, PROCBb, PROC9, PROC10, PROC11 . PROC,I3,
PROC15, PROC19, AC1, ACZ, AC3, AC7, ERCBa, ERCBb, ERCBc, ERCBe
consumer use :phosnhoric acid I suzı, pc12, pC31, pC35, pc3a, pC39, ERCea, ERC8b, ERCBd, ERCBe
(ES Rei.: SE4) I

Full text of use descriptors: see section 16

,l.?.2. Uses advised agaiı,ıst

Phosphoric acid
i.3, Dştşilg şi ths suppiier ar thş sqfeıy daia sheei
PRAYON S.A.
Rue Joseph Wauiers, 144
B-44B0 Engis - Betgique-Be[gium
T +32 Q}42739211 - F +3z (0]4273 96 35
Reachcustomer@pravon.com - www.pravon.be
,i.4. Emergeııcy teiepiıcıne ııu;nter
eountry Organisation/Company l-ıd^^^
nuuİEşş
^ Errıergenca number Gornment
lreland Nationat poisons lnformation Grosvenor Road 0870 600 6266 (UK
BT12 68A Beliast
Service (Betfast Centre) only),
Royal Mctoria Hospital
Uniied Kingdom National poisons Information Dudley Roac 0344 892 011 1
818 7QH Birmingham
Service (Birmingham Centre)
City Hospital
United l(ingdom ationai poisons Informatioıı
l{ Penarth 0344 B92 011 i
CF64 2XX Caı-ciiii
Seı-vice (Cardiff Centre)
Grvenıvyn Ward, Llandough Hospitat
United l(ingdom National poisons lnformaiion Littte France Cresc:nt 0344 892 01,1i
EH16 4SA ECinburgh
Service Edinburgh
Royal lnfirmary of Edinburgh
Uniieci Kingdom Guy's & Si Thomas' Poisons AvonIey Road aB70 243 224,|
S=14 5ER Lcndcrı
Uni'ı
Medical Toxicoiogy Unit, Guy's & St
Thomas'Hospital Trust
i uniteo Kingdom Naiional Poisons lnfo; ı,nation clai,emont place
Ne\,,, ı,,Stle_uDon-Tyne
0344 B92 il1 1 i
i Service (lJeı,v-.,a stl;. i,erıı ı,e) NE, ,:Li-' Newcastle
l Regiona| Drug: ;.,, ' l i: .:, ıi:,-:utics
Centre,sJıifsot;i ,. .i I

l.i,, ğllnaa Ei.i (English) SDS Ref.: PRAYP'ıiOS-006

 ,, n n a
' ,.=ı li i; 16.ı. 1^ F\ i ij /^\ İA n -^§ ,1 .^\ n i=\
ir,
.-ii\ij,ş fiı !J,.
:,UJ
[F(!ll\=,, ,1aşiÇ tj|!; iF ı--ı İ',İ il ij l Z |3 ıj' ],
,,l
-
,YJ-l:!
|14-!
4,1
t] (yJ
,,.<ti.aır
li il i.a
rVJ \\r,

' §afei1,, liıia ,*qheçi

907/2006 (REACH)
,ıiih iıs arneııciı,i,ıenıl Regulation (EU) 20ı 5/830
accoi-ding tc Regulation (EC) Iılc.
-i

İ;iaı-,-.iiica,iicı^, aşçtııelliie i. Regulaticı iEti i,jc. ,i272lİü3§ ii:İ_ııi

Corrosive io metals, Category

,i H290
Acute ioxiciili (oial). Categoyi H302
Skin corrosion/in,iiation, Caiegory 1B H314
,i6
Full text of H-statements: see section

Aı{rıerse p!^ıysicoci,ıeınica!, huıaan health aııc oniı!rgrınenİaİeİfşcts

No additional information available

2,2, Labeİ eleıt-ışnıs

Lai:eiling accordinç tc Regıılation (Eü} illo. i72l2tt08 [*LPj

,i

A
/,\
Hazard pictograms (CLP) . -J,' !\
,,r \ .+r' \.

-\ ıA
..ı:/ ;,İ'B"x
_. .P,\ *§/;,
.,_"7r:ş\

-,;1.. -1f \. o
t..şel

,{ \.
.,i'
;ii
-.:\ .6/
,ı7 n,{
GHS05 nrao,
Signalword (CLP) : uanger
Hazard statements (CLP) : H290 - May be corrosive io metals
H302 - Harmfut if swallowed
H314 - Causes severe skin bums anci eye damage
Precauti onary statements (CLP) : P234 - Keep onty in original container
P260 - Do noi breathe dust, fume, gas, mis'ı, vapours, spray
p28O - Wear protective gloves, protective clothing, eye protection, face shield
P301+P330+P331 - lF SWALLOWED: rinse mouth. Do NOT induce vomitinE
P303+P361+P353 - lF oN SKlN (or hair): Take off immediately atl contaminated clothing.
Rinse skin with waterlshower
paos+P351+P33B - İF ıN EYES: Rinse cautiousty with water for several minutes. Remove
coniact lenses, if present and easy to do. Continue rinsing
P310 - lmmediately catl a POISON CENTER, a dÖctor

?.3, Otheı: fıazards

-
No additional information available
. , ., '.', .-,'-'
'
'' - ''' a..-

3.,i. §ubstances
Name : PHOSPHORIC ACID Fertilizer Grade
CAS No : 7664-3B-2
EC No : 231-633-2
EC tndex No :015-011-00-6

§lassification according f
Regulation (EC) No.
i.zv2t2aü8
Orthoohosphoric acid (CAS No) 7664-38-2 MeL Corr.1, H290
(EC No) 231-633-2 Acute Tox. 4 (Oral), H302
(EC lndex No) 015-01 1-00-6 Skin Ccn. 1B, H3,14
(REACH-no) 0 1 -21 1 9485924-24-0021

Full text of H-statements: see sectlon 16

[iixiuıes
i.iot apptica'ole

'Şs- §itü_ji ft§" iiu. ,ssi.ğ.,E:l*_

.!.l. Descıipıioıt ,ıf iirst aid meşsurşe
First-aid measures after inhalation lf persistent breathing troubles, immediately see[t medical attention. Remove victim to fres
First-aid measui-es afier sl<in contaci Remove contaminated ciothing and shoes, wash off immediatel5ı 3n6 plentifully with uıateı
ai leasi 20 _ 30 minutes. Take off contamlnaieci clothing and wash before i-euse. Call a dot

.\laolrn1-7 Eiıl (English) SDS Rei.: PRAYPHOS-O06

 -- . .^. a. :. j- _1 /A\ n .A *
/_r,.. , l: lt ıı
-
i=, i=ij
(uı;=>j
lF'' i,=ı
(l:j] -\
i-< [l
iüJ Ei l'__.} ]i iL-}

.i:'.":+ri: l a,iıi İh+ı=.,

_ : i'-.|*- t.

-i907i20l6 iR=.\,]H) wiiir iis amendmen'i Regulaticn (EU) 20'l;,'330

acccıiing io Regulaiion (EC) i.lo.

First-aid measures aflei e,/e rontact : \ıVash iırıi^nediatellı with plentv\i/aiei- (ciuıinE 20 - 30 minutes). also under evelids. Cail a dccioı

Firsi-aid measuies aftei- inEes,tion : lf swalloı,,,ıed, rinse mouth viiih wai.ei- (onilı i;the pei,son is conscious). Do noi inc!uce vomiiiilg.
Catt a physician immediaiely,

,:_j ıi$ıısı iı,ııpı:ı-raı:,i ı.jrı"ı,iFi*i:-iş aııai ,:iı'şGüS., qç.ln acuıe aıd Cç!.ayqe
Sympioms/injuries : The vapour causes slighi irritaiions in eyes, throat anc! sl<in.

Symptoms/injuries aftei- sl<in contact : Burns upon iontact with the skin.
4.J inctitaıioı-ı *! aı:y ima.e,jiart ı;ıecİicşl aitşr}ıioıı and speciai rı,qaımeçi neeıieç
An endoscope or a stomach wash might be considered but might Gause severe stomach or oesophagus damage.

5.1. Extiçguisting rnedİa

Suitable extinguishing media : CO2. Powders, Foam. Wateı, spray.
Unsuitable extinguishing media : Do not use a heary waier stream.

ğ.2 §peciai hazards arising $ıçn-t thç suhstaçce or mixture

Fıre naza[o : Non flammabte.
Exptosion hazard : Contact with metals produces hydrogen gas which may form explosive mixtures with air.

5.3, Ad.ylce ior firefjghters

Firefi g hting instructions : Use water spray/fog for cooling.
Protection during tirefighting : Acid-resistant protecüve clothing, Acid-resistant protective gloves, Acid-resistant boots. Use
,
. self-containedbreaihing,apparatus.(seesection(s):8).

§.]. Feısona! precauiionsı pf§tectit/e equİpment anğ emergeÇcy proceeİures

6.1.1. Fornon-emergencypersennel
No additional information available
6.1.2. Fcr emergency responders
Protective equipment : Spill should be handled by trained cleaning personnel properly equipped ıvith respiratory and
eye protection. + acid-resistant protective clothing.
Emergency procedures : Keep pubiic away from danğer area.

6.Z. Environmentai precautlor.§

Clean up any spills as soon as possible, using an absorbent materiai to collect it. Prevent entry to sewers and public waters. Avoid soil
contamination,
6.3, .Mqhgcis and.malesiai ior çoştainm.ent anci c|ç.açı_i.ng.gp
Methods for cleaning up : Ventilate area. Transfer in an appropriate container properly labetled in order to set up a futu
treatment. Neutralize with :sodium carbonate, Calcium carbonate, Lime. Rinse with plen§ of
water.

6.4. Referenca i9 gther sgctions

See section 8 and 13 for more information.

7.1, Precautignş fçi safe lıandİing

Precautions for safe handting : Good ventitation of ihe workplace required. Foltowthe exposure limits given on ihis material
safety data sheet. Use suitable material. For preference use pumping techniques for unloadir
and discharging. Waterproof retention basin. Avoid any direct contact with the product. Do nc
breathe vapours. Never introduce water or any aqueous agent into tanks or containers.
Ditutions or neutralizations are very highly exothermic. Avoid : Splatters. Always add the
product to the water for dilution/mixture. Do not mix with : lncompatible materials: (see
section(s) :10.5).
Hygiene measutes Wash hands and other exposed areas with mild soap and water beiore eating, drinking or
smol<ing and when leaving work. Do not eat, drink or smoke when using this product. Remoı,
contaminated clothing and shoes.

?.2. ğonciittenş for saie staragğ, incluciing eçy incçIT,patibiiitieş

Storage conditions : Store in a dry, cool and well-ventilated place. Keep av.vay from alka[is, sulfides, cyanides ant
metat powdjı-s. Keep oui of direci suntighi. S'toı,e at i,oom iemperaiure above cı-ystatliİaiion
point. Compatible materials : Stainless sieel. Polyethylene (high density). Glass.

7.3. §şecific +nd use{ş}

No additional information available

§ffi ,ffi §_fo -şış;*.cgl-,#

j{-T-işi.g*g*"s*s§gfuff ı.-
§_,! Gorıtroi peraır:g'ie!"§

l lJ,alr^4,7 EN (Engiish) SDS Ref.: PRAYPHOS-006

 ,i907/2c0e (REACıi) ı,ıiih its amencneni Reguiailion iİU) 20'i51630
accoı_ding io Regulaiicn (EC) i.lc.

İ p1i;,3pllşRlc ACıD i+i'ıiilzeı _G;a*re {?§6ei-38_2}

DNEUDMEL fftiorl<ers)
Acute - locat effecis, inhalaiion
Long-term - svş]ıe!ry9sffe"iı jer[g! ( Not appticable. - Corrosive, - local effects)

10.7
1 mq/m"

0.1
4.57
0.36

8.2. ExposEreöo..nEols
Approprlgte engineering controlşi
of the workplace requ|red. Mon|toİ the atrnosphere ai regutar intervals,
Use in elosed proces,s (for example in close loop system). Good ventiİatİon
pıease refer td ihe annğx (exposure scenarios).

Pbrsonal Protgctfue equipmene

Emegencyeyewashfountainsandsabtyshowersshouldbeavallablelntheimmediaieücinltyofarrypotentialexposure.
Hand'protgctlon:
advice to gloves'manufacturor,"
Use gloves resistant to chemical products correspondİng to EN 374:3". Take
permeation [hickness (mm} penetration
l}rpe tıJlaterial
6 (, +gO minutes) ],11 374
Nitrile rubber (NBR)

Eye protğctlqn:
gccording to EN 166,
chemical goggles or face shield with safety glasses
skln and body protection:
(tests of re§İstance according to EN 36&369), wear impeNious
Wear protective cloİhİng adapted to the risks of acld projection and 8çidProof
rubber safety shoes

Rg§piratoryprotection:'
ıı/ear an approved ,espiratory p,otedion (with filter congspondin|
use onty in wellventılated areas. vvhere excessive aerosoI or vapour may result,
to EN 143).

Envtİonmental expoŞqre cont oİs:

For preference use pumping techniques ior unloading and dischargİng,

9.1. lnformation op.basic phydicaİ and ch.emiöal properties

Physicalstİte Liquid
Molecular mass 98 g/mol
Golour colourless-
Odour Acrid.

odour threshold No data available

pH 0
Relative evaporation rate (butytacetate=1 ) No data available
Metting point No data available
Freezing point Solution 30%: - 11,8 'C
50%:-41,9"C
- 20 "C
75o/o:
80% :4 "C
81,5o/o:7 "C
85%:21"C
Boiling polnt : Soluüon 30%:101,B'C
50%: 108'C
75%: 135'C
80%: 150"C
81,5% : 152 "C
B5%:158 "C
Flash point : Noi flammable
Auto-i g ni'ıion tem pe ratu re : Noi appticabte

Ei.! (Engiish) SDS Rei.: PRAYPHCS-005

4l19l2017
 n..o.,.i.,=

3cccrdinE io Pteguiation (EC) Nc,

,ı90712006 (P.EACH) ,,,ıith iis amşniı-nşn,i Reg,-itatioı (EU) 2C,i51830

Decomposition tem pei,atu ı-e i\lo caia aııaiiable

Flammabilii_v (solid, gas) 1ılot applicable

Vapour pressure Noi applicable

Relative vapour density ai 20 "C No data available

Retative densl§ı No data available

Density 30%: 1,179 giml25'C

50%: 1,33 g/ml30"C
75o/oi 1,576 giml 20'C
B0% : 1,631 glm! 209C
81,5% 1,648 g/m[20"C
85%: 1,689 g/ml20'C

Solubitity Wdteı: 100 %

Log Pow No data avallable

Viscosity, kinematic No data availabte

Viscosity, dynamic 30%-85%: (30 "C) 2.a32 mPa-s

Explosive properties Product is not explosive.

Oxidising properties Not applicable.

Exptosive limits Product is not explosive

§.2.
,. .Ölle, inid-rmatien
Addiiionat information
". Miscible with water

10.1" Reactiv§
wİth metals,
Reacts wİth : Strong bases. Very flammabte gas (hydrogen)rnay be formed on contact

10.2. Chemicat stabİlrty ,:,

Stable under normal conditions (Handling and storage),

Contact with sulfides and cyanides liberates toxic gas,

1P.+. Cont'ttigns:to'avoid
Light (daylight).

atkalis- Causüc products. Non noble metals,

iü.§. Hazardousde.compositionproduçts
May liberate toxic gases

{1.1. infarmation oıı İoxlcqiögical effects

Acute toxici§ Oral: Harmful if swaltowed.

hosphörlc acid (16§İ J§*}

>300 mg/kg bw <= 2000
No data
No data

skin corrosionlinitation corrosive

pH: O

Serious eye damage/irritation corrosive

pH:0
Respiratory or skin sensitisation Not ctassified

Additional information Not relevant

corrosive
Germ cell.mutagenicity : Not mutagenic. OECD 471I473i476
Carcinogenici§ : No carcinogenic effect
Reproduciive toxicity : Reproductive toxicity Not classiiied. DevelopmentaltoxicitY:}lOAEL:> 410 mg/kg bw,rat,
oEcn 4}2.Ferli|ityiııonsı > 500 mg/kg bw/day, rat, oECD 422
STOT-singie exposure : Not classified
STOT-repeated exposure : Nlot classifieC

Elıl (Engiish) SDS Ref.: PRAYPHOS-006

4t19l2017
;=ü n n i=} ili ı5, [ı3 ll ,fl,
.^\.1}
İ-'ı::j ğ iİ iı' ı]'l-:J ii-\|l,L-..^
r.=,}

], .* .i.^.i: ,, İ .ı i..:ı İ' İ-, ,ı -:ı';' Ji :.g.v.l

t_,.:. ]ş;l; ;,,:t(;,

iR.=A.C ırith iis amerıdment P.egulaiicrı {EU) 20i 5/630

accordiıg io Regulaiion (EC) No. 1 907/200c 1-1)

! *ıtlıophoşphoıic açici t766+-}8,2

250 ay OECD zı22
İIOAEL {ora[, rat, 90 da
NOAEL (dermal, rat/rabbit, 90 days) No data availabte
NOAEL (inhalation, ra't, gas, 90 days) No data available

Aspiration hazard : No significant hazards.

12.1, Toxlcitlı

Orth
3 - 3.25 (96h) macrochırus
> 100 mg/I(4 oECD 202
> 100 Desmodesmus subspicatus, OE§D 201
100 ) Desmodesmus , OECD 201

Not relevant.

Bioaccumuiaİive polentiaİ

Nct relevant.

12.4. Mobility in spii

Orthophos acid
No data available

12.5. Reş..q[ts o,f PEt arrd vPvB asşeş_§rnsr_ıt

the PBT criteria of REACH regulaüon, annex Xlll

This substance/mixture does not meet the vPvB criieria of REACH regulaiion, annex
Xlil

12,6. cıher a$verse effects

No additionaı information available

1q.t. Was!ğ treatment methods Calcium

waste treaıment methods Comply with local reğulaüons for disposal. Neutralize with :sodium carbonate,
carbonate, Lime.
containers mus
Additional information : \Mıen totally empty, containers are recyclable like any other packing, Storage with
be free of cİıntam'ı-nation before use. Dİspose in a safe manner in accordance
iocai/national regulations.
Ecology - waste materials : See the european waste catalogue.

[n accordance with ADR / RlD / |MDG / IATA / ADN

t4.{. Ült nuıT_ıber

UN-No. (ADR} 1805
UN-No. (IMDG) 1805
UN-No. ([ATA) t805
UN-No, (ADN) 1B05
UN-No. (RlD) 1805

14.Z, UN prqper shipping ilaffe

Proper Shipping Name (ADR) PHOSPHORIA ACİD, SOLUTİON
Proper Shipping Name ([MDG) Phosphoric acid, solution
Proper Shipping Name (IATA) Phosphoric acid, solution
Proper Shipping Name (ADN) Phosphoric acid,' solution

Proper Shipping Name (RlD) Phosphoric acid, soluüon

Transport document description (ADR) UN 1805 PHosPHoRlc ACID, soLUTloN, B, ııl, (E)
Transport document description (lMDG) UN 18O5 Phosphoric acid, solution, 8, lll
Transpori d ocument description (IATA) UN 1B05 Phosphoric acid, solution, B, lIl

EN (English) SDS Ref.: PRAYPHOS-006

4l19l2017
iP H OşP= FIOP''IG A"3 [ Eu P gliiE ızeı, G ı,a cie
:il ı
v'-;|-'i i.ef i;
I
!_-,, a i:: ;], .-,,-:ış:.

according to Regulaiion (EC) ıılo.

,ı
907i2O0S (REACH) ıı,i'th i',s arnençjmeni Regulation (=U) 20i5/6'jC

Transpon documeni. ciescription (ADi\!) Ui{ 18O5 Phosphoıic acici, solution, B, lli

Transport document description (RtD) UN 'l805 Phosphoric acid, solution, 8, 1ll

-ili.3 Transpon ftazaı,d alassiesj
ADR
Transport hazard class(es) (ADR) 8

Danger labels (ADR) 8

ıMDG
Transport hazard class(es) (lMDG) 8

Danger labeis (tMDG) 8

tATA
Transport hazard ctass(es) ([ATA) :8
Hazard labels (ATA) :8

ADN
.9.
Transport hazard ctass(es} (ADN)
Danger labe[s (ADN) :B

RıD
Transport hazard ctass(es) (RlD) :8
:B

'.A.
Danger labels (RtD)

"§şr,
14.4, Packing grcup
Packing group (ADR) lll
Packing group (IMDG) tıl

Packing'group (IATA) ııı

Packing group (ADN) lll
Phcking group (RtD) lll

j4.5, Enviroıımenıali"tazard*
Dangerous for the environment :No
EN! (English) SDS Ref.: PRAYPHOS-006
4l19l2o17
 .i ı,F J iFr iE i];- -,_ ,ı=) _, * -i ie
E ii] t]+ S r-.' [:.l O,R [,,]r
,^
*l,,.=; ij Ur l--
=. -_-:':P
.= a ıii! lj İ Zİ;,ı-
--,
i.flj-a;.i ll!i

Sş.i.=ıi, liei;, Şie*iı

according to Regula'ıion (l=C) llo iS07/2006 (REACH) v:ith its amencimeı: Regulaticn (EU) ;20,i5/83C

Maıine poliutani : lıio

other infonıation : Nlo supplemeniary information aııailable

j4.6. Specia! precauJions foı- useş

- Overland transpoıt
Classificaüon code (ADR) c1
Limited quantiües (ADR) 5ı

Excepted quantities (ADR) E1

Packing instructions (ADR) P001, ıBc03, LP01, R001

Mixed packing proüsions (ADR) MP19
portable tank and bulk container instructions T4
(ADR)
Portable tank and bulk container special TP1
provisions (ADR)
Tank code (ADR) L4BN
Vehicle for tank caniage AT
Transport category (ADR) 3
.§peciat provisions for carriage: Packages v.12
(ADR)
Hazard identification number (Kemler No-)
Oİange plates

Tunnel restriction code (ADR) : E

EAC code : 2R

- Transpcrt by sea
MFAG-No : 154

- Air transport
No daia available

- tnland waterway transpört

No daia available

- Rail transport
No data avaitabte

14,.7 . Trçnsport in buik aciording to f,çnex İ1.of seıpol and,th§ ıbç co*e
Not appiicable

15.1" S3fety, l-.ıeaith aııd environıl9nial regulationsltegisİaiiqn qp9çi!İ9 İoı thç substa'Şce or mixture

15.1.1. EU-Regulations
No REACH Annex XVll restrictions
Ph{OSPHORIC AC|D Fertilizer Grade is not on the REACH Candidate List
PHOSPHOR|C ACID Fertilizer Grade is not on the REACH Annex XlV List

Other information, restriction and prohibition : Not a Seveso substance. Not an ozone depteting substance. Not a persistant organic Polluta
regulations

15.{.2. i.lational regulations

No additional informaüon available

15.2. Qhemigalş.atelyaşsesşÇeiıt
A Chemical Safety Assessment has been canied out.

lndication of changes:
to Regulation ) No. 1907/2006 (REACH) vıiih its amendment
EN (English) SDS Ref.: PRAYPHOS-006
4|19l2017
F",şj CI iş F,,Fl O R.[c .E ı]; iiD,
. ,'İ ııa,;
^ !.. i., .-..i-^ .ğj İ^,
I i- i İ j j,_.j a: L5',
:^- --
:-l :-i
.|
j i rr.*- ı

accordingicR'egulation(EC)No.,i907/2006(REACH)Witili,(sarnendrnentRegulaiion(EU)20.i5i830

201 5/830.
Section Corrosive to metals, Gategory i
,i
HaI,I-fıTuı ıi
a C.lassmcafon according to Added
swallowed
Regulation (EC) No. 97a2OaB
L

tcLP]
J{tiifr6Tffitormation Added
8
LD50 oratrat Modified
11

Abbrevlations and
ge of nangerous'goods by'lnland waterwaYs
ADR: European agree;.ni ion."*inğ ıniernatıonal caniağe of Danğerous goods by Road
AF : Assessment factor
BCF : Bioconcentration factor
Bw: Bodyweight
CAS: Chemical Abstracts Service
CLP : Classiftcaüon, labelling, packaging
CSR,: Chemical Safety Report
DMEL: Derived maximum effect level
DNEL: Derivative No effeci Level
EC: European Community
ELV : Emission limit values
EN: EuroPean Norm
EUH: European Hazard Statement
'EWC : European Waste catalogue
IATA: lntemationat Air Transport Association
,

ICAO: lnternational Ciül Aviation Organization

İlvlOe : lntemational Maritime Dangerous Goods
LC50: Median. lethal concentration
LD50 : Median lethal dose
llbAel_': No-observed-adverse-effect-level
NOEC : No bbseivöd effect concentration
NOEL: No obsehıed effectlevel
O'EL: Operator exposure level
PBT: Persistent, bioaccumulative, Toxic
pEc : predicted effect levei
PNEC: Predicled No effect Concentration
hinöi_i;R6;"t ;ti;n, Jvaıuation
REAAH :-l-teglsrat]on, aııtorısation of chemicaıs
aııu au!
evaıuauL,ıı and
G iniernational carrlage of dangerous goods by rail
. _-J^-^
-3)^^aı
RlD: Regulations
STEL: S-hortTerm"onJ"*ıng
Exposure Limit
TWA : Time weighted average
vPvB: Very persİstent, very bioaccumulative

Data sources
Training advice
Fulttext of H- and EUH-statements:

corrosive to metals,
§l<ln conosion/inttation, Category 1
P
be corrosive to metals
HarmfuIif swallowed
causes §evere skin bums and
VehTcles
, mechanical el ectıical/electroni c arti cles
Electrical batteries and accumulators
Metal artictes
Manufacture of substances
lndustrial of articles ııııiih abrasive techniques
Formulation of
Formuiaüon in materials
aids in and not becoming part of ariicleş
lndustrialuse
lndustrialuse ın inclusion into or onto a matrix
in.manufaciure of another substance of intermediates
lndustrial use
lndustrial use of reactive
of resins, rubbers,
tndustrial use of
ınctustrial use cf s,ıbstances in closed
ffia; di.$rsire ,ndoor use of processin
systems
W,ddi.p""l"" ln-Ooor use or r*rcti"

EN (English) SDS Ref.:PRAYPH0S-006

4119l2o17
iE,ı,,,J üR Q iD.,{ rfiı ltr) ll ıi^:
u- iı ii i\vj7(Çi i: i; i',§zi_ \["!='
Ş:iıtiij Da,ia Sh,:şt
acccrciing to Reguiaiion (EC) ı!c. 'i 907i2OC6 (REAC'|-i) ,.ıitiı its amencjment Regulaiicn (EU) 20151830

ERGEc Wide dispersive indoor use resuliing in inclusion into oi, onio a matrix
ERCBd Wde outdoor use of aids in open systems
\Mde outdoor use of ı-eactive substances in open
ARTıOLES, PYROTEOHNIC
Adhesives, seatanis
Fertilizers
Fuels
Metal surface treatment products, including galvanic and electroplaiing products
N on-metal-surface treatment

lntermediate
products such as flocculants, neutralization
Laboratory chemicals
ther dye, finishing, impregnaüon and care products
Lubricants, Greases and Release Products
Metal Fluids
Paper and Board dye, finishing and bleaches and other
Polishes and Wax Blends
and
Textile finishing and impregnaüng bleaches and other processing aids
and solvent based
Water treatment chemicals
and flıx
Cosmeücs, care products
Base
Biocidal Disinfectants, pest control)
and thinners, paint removers
Fillers,
Use in closed process, no likelihood of exposure
Roller
Non industrial
Treatment of articles and pouring
production of or articles extrusion,
Use as laboratory reagent
wtth intimate contact and only ppE available
Use in closed, continuous process with occasional controlled exposure
use in closed batch
Use in batch and other process where for exposure arises
Mixing or blending in batch processes for formulation of preparaüons and articles (multistage and/or
contact)
lndustrial
Transfer of substance or prepatation (charging/discharging) from/to vessels/large containers at non
dedicated facilities
Transfer of substance or preparation (charging/discharging) from/io vessels/large containers at dedicated
facilities
Transfer of substance or into small containers line,

FormuIation of preparations and/or

Manufacture of basic metals,
Manufacture of fabricated metal , except machinery and
,,
Manufacture of electronic and , electrical
General manufacturing, e.g. machinery, equipment, vehicles, other transport
and construetion work
Health services
Consumer uses: Private househoids (= general public = consumers),
Professional uses: Public domain (administration, education, entertainmen'ı, services,
scientific research and
lndustrial uses: Uses of substances as such or in prepaıations* at industrial sites
Manufacture of bullt, Iarge scale chernicals
Manı-ıfacture of fine clıemicıiı;

4l19l2017 EN (English) SDS Rei.: PRAYPHOS-006

,D|-,=_jlıli;,§DitİrinlEjİf=:
:: ,V' '::ı li ll ll ,:_-j' il + ı,a|iİF,i
't:a, :....-_
E,a.5ii[!n=,aı"
\Y. il ,-=,. ' t=u J .', J J .: "-- i
,,:?i.ş,,^Li.:.,
a>.,/ |.j l!'.r 'İi
L i.i ",. ..j ..1
\ü- _!

İa.i=,ii; İai:: Ş i,= _+,,

,i907/2006 (R=ACH) ı.viih iis amendment Regulaticn (EU) 20J5/830

acccı,ding to Regulaiion (EC) No.

sDs EU (REAcH Annex lı)

iatoinaüon ıüy not be appflcabla.

4l19na17 EN (English) SDS Ref.: PRAYPHOS-006

'ıl' i]OS ş iıj O lFJ,l C AÇ [ Dl trış =,ıti]
i i=,eı" i3 iı,a,lle
.S;ai'ei:lç iat;: Şı*çı
accci-ciing,io Regulation (EC) i,!o. 1907/2006 (R=ACH) u.ıith iis ameninıeni Regulation (EU) 20151830

trşadııci s)ipo§§üıi s ceı-ıaı,io(sl

lndustrial uses - Phosphoric acid

Consumer use :Phosphoric acid

EN (English) SDS Ref.: PRAYPHOS-006

h ı:='..iı i.,=..ı:, e,
.:' \t b
ii_ll i Aı iD ,,,a ııi . . /,.i f_ İ F., E
..-
_.=ı
J,,
.;.,l, İ:l İ,ili 3:,__..
.l .! {
-"
. /..a
l:
.""ş.. .oij .^.
:. /_.ı.l |. ii
-.l .!,J.\-j
,, :l :i i-ly./,i.:=.jü .l ij l'=./|l':i\J 'tlj!,:::. ..',-**--'.i _-j ! :::l!'.'Ji! 't| iii;l'=ri 'j:ir!'s_.1

iafe,ii; ial:a Şı*eı

according io Regulaiicn (EC) iılo. 1907/2006 (P.=ACH)uviih its amenciment Regulaiion (EU) 2015/830

iş,ıcitıstnEa§ q.!seş - Fttos,phonıc aGaC Date of issue: 03l03/201ı

Su3, SUB, SUg, sU10, Su14, sU15, su16, sU17, Su19, SU20
PROC1, PROG2, PROC3, PROC4, PROC5, PROC7, PROCBa, PROC8b, PROC9, PROC10,
PRoc13, PRocl4, PRoc15
PC0, PC1, PC7, PC8, PG9a, PC9b, PG13, PG14, PC15, PC19, PC20, PC21, PG23, PA24,
Pc25, Pc26, Pc32, Pc34, Pc35, Pc37, Pc39
ERC1, ERC2, ERCS, ERC4, ERC5, ERC6a, ERC6b, ERC6d, ERC7, ERCl2a
lndustrialuse
Tier 1 MEASE 1.02.01
Tier2 ART (Avanced Reach Tool)
Concentraüon - Exposure scenario : 5 - 100%
Concentration - Contributihg Scenario : Worst case assumption

Use in closed process, no llkellhood of exposure

Concentration of substance in product

OpÖrational conditionş

conditions and measures at process level

Emergency eye wash fountains and safety showers
should be available in the immediate vicinity of any

Use in semi-automated and predominanüy enclosed

Organisationa| measures to prevent /limit releases, Familiarize personnel with

dispersion and exposure proper use of protection

Conditions and measures related to personal Breathing'equipment lf the verıtilation is suitable, it

proteciion; hygiene and health evaluation .
is not essenüalto wear.
respiratory equipment. ln cas,
of insufficient ventilation, wea
suitable respiratory
141 / EN
Wear chemical protecüve

or
shield with glasses

protective
elasücated cııfis and closed
neck). lmpervious footwear
must bewom
2-1.2 cotitributing ğcğna.io cont.oltirg workg. ğxFo6uir (PRoci) ourstioni > 4 Hour6;codcentiation; i İ6 %;lndooi u8giwtthoqt
PRE;wiitt LE\o .

Use in closed, continuous process with occasional

..--
exposure
p rod uct characıeristic§

Concentration of substance in product

4l19l2o17 EN (English) SDS Ref.: PRAYPHOS-006

P Fil OS iP li e},R.[,C A,.Ç İ D, Fe rt:ı ız,.şı" G ı"ar"İ ı=
.,*'
ll

Ş a.tel,., ü1'i,a } li*,:a

according to Regulaiion (EC) No.
,i
9c7/2006 (REACH) v;itiı its amendment Regulai,ion (EU) 20151830

ffi measures atprocess level See Contributing Scenario 2.1.,i

(source) to prevent release
Locat exhaust ventilaiion - efficienclı of ai teast [%]: 90%
Technicaü conditions and measures to control
diİpersion from source towards ttİe wort<er
See Contributing Scenario 2.1,1
@anjaetional measures to prevent llimit releases,
dispersion and exposure
Cond'|tions;ndmeasures related io persona[ See Contributing Scenario 2.1-1
protection, hygiene and health evaluation
su,e{Pdoö3}iDuratıon:>aiHoı,ıݧ;Conceniıation:>İ5%;fıtoooıus*;!ifi(iı
PRE;$Jith LEV;
Use in closed baich process

Concentration of substance in product

ffind measures atprocess level See Contributing Scenar|o 2.1.1

(source) to preveni release
Local exhaust ventilation - efficiency of atJeast 90%
Tecrııical conoltions and measures to control [%]:

dispersion from source towards the worker _

See Contributing Scenario 2.1.1
@res to prevent /timit releases,
dispersion and exposure
C'onditlons and measures related to personal See Conüibuting Scenario 2.1.1
protection, hygiene and heatth evaluation g aratus - effiçıQ4çy_ glglle ast [%]i 75%
_2.1.ı"
B re athin a pp
z5 ğ/,:İndoor use;lYİth
Contributing seenario *o.,trotııng *rirrı,er exposur§'lrn6c+1 (Durİtion: > 4 Hçİjrs;öÖnc'entrationi '
PRE;with LEV}
Use in batch and other process where opportuniŞ for exposure arises

Concentratlon ot substance in product

> 4 hiciay

recrınlcat condltions and measures at process level See Contribuüng Scenario 2.1.1
(source) to prevent release
90%
ffil condiüons and measures to controt Local exhaust ventilation - efficieney of at least [%]:
dispersion ftom source towards the worker
Organ'ısational measures to prevent iimii releases, See Contributing Scenario 2.1.1
dispersion and exposure
ConOltionyand measures related to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation Breathinq abparatus - efficienc,y of at !e§|[ğ1_ 75 o/o

Physical form of product

Concentration of substance in product

Frequency and duration of use

Techn'rcal conditions and measures at process level See Contributing Scenario 2.1.1
(source) to prevent release
Local exhaust ventitation - efficiency of ai least 90%
Technicat conditions and measures to control [%]:

dispersion from source towards the worker

Orgenlsational measures to prevent /limit releases, See Contributing Scerıario 2.1.1
dispersion and exposure
ConOitions and measures related to personal See Coniributing Scenario 2.1.1
EN (English) SDS Ref.: PRAYPHOS-006
4l1912017
==.!. E,:^ j.nF=\fi i.,^.aı,/^\ ı,a\_ni-. ı: 4c:'iE ,. ,
|i' ir-ıi {,.t -j iF' i-i ıi=jl l.,n i' .,ş
aI

Ş 1
(i=_. ;':i ,i-"
[i |!-_i; i:: ls i'ii i li ii Z,i3 !ı"..';r1 ı0! ,..*

.3r ı:fei,.,J
üata *' ıı e,ş,l

accoıding to Regulation (EC) No. 1907/2006 (REACH) rı,ith its amendmen'ı Regulaiion (EU) 2015/830

proiection, h5rgiene and health eııaluation 75%

,3 Ccınrril:ıııiing sceııaric ıı-ü!ıijıöiling wcı.,kğı ğxp(ı§uıe iPnşşZiiEuratioıı;
i.-i > 4 iloı-ırs:Coııceştraiiorı: ,iötı
9t;lndoor use:Wifhoıiı:
FRE;ıJiiith LEVi
industrial spraying
p rod uct characteristics

Operationat condltions

Risk Management Measures

Technical conditions and measures at process level See Contribı-rting Scenarto 2.1,1
(source) to prevent release
Technical conditions and measures to control Handle in a fume cupboard oo o/^

dispersion fıom source towards the worker

Organisational measures to prevent /limit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Contribuüng Scenaria 2.1 ,1
protection, hygiene and health evaluation

2,,r.7 cor*ributing §cğflerio conholting workeı exposu* 1ıhocsi'1 1ouraiton: i 4 H6urs;Conc,iıntration: löti %;indoot ıse;l/üi6oit
PRE;İrVİthLEy}' ' .
substance or preparation (charging/discharging) from/to vessels,{arge containers at non

product characteristics

Concentraüon of substance in product

Öperatiohal çondition6

Risk Management Measureğ

Technical conditions and measures at proeess level See Contributing Scenario 2.t.1
(source) to prevent release
Technical conditions and measures to control Local exhaust ventilation - efficiency of at least [%]: 50%
dispersion from source towards the worker
Organisational measures to prevent iimit ı"eleases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to persona[ See Contributing Scenario 2,1.1
protection, hygiene and health evaluaüon

2.1,a cdİtributing sceüiio cbntıolling v,,oiker expo§uiö (PRÖdö^b} fblıraİion: > 4 }iourıi;Cond;ııtdtion: iöo,"/"ındooi üse;wiihouı
PRE;lMth LEy)
l PRoc8b l Transfer of §ubstance or preparation (charuİng/discharging) frorrı/to ve§selsİarge container§ at dedicated facilitie!
product characteristics
Liquid
Concentration of substance in product 100 %
Operational condİtions

Technical conditions and measures at process level See Gontribuüng Scenario 2.1.1
(source) to prevent release
Technical conditions and measures to control Local exhausi ventilation - efficiency of ai least [%]: 50%
dispersion from source towards the worker
Organisational measures to prevent /timit releases, See Contributing Scenario 2.1.1
dispersion and exposure
'See
Conditions and measures related to personal Contributing Scenario 2,1.1
protection, hygiene and hea|th evaluation

2.1.9 Öontributinğ seenario eoiıt.ol|lnğ wo*ei exoo§uıe 1FHöĞib) i6uration: j 4 Houıs;öonceniraıio'ıi: lbb *n1ndoct usejrliftiort
PRE;whh LEv)

produc1 ctiaricterlstit$
-
4l1sl2o17 EN (English) SDS Ref.: PRAYPH0S-006
,-nı i ı- ri^\ tG rŞ iİ n ı.=\ 5=il ['l rF) .;. ial n fF\
.ı'i:',! ir Jı_\19 i.:! ,, )j j=r ll !! ." ,=:,ii .-il ıi jı
.. ll |i !-/ 1Y.i ti ll u -=1 t|
,+
u 1=; .,; l .9. {l .:.

,__ı.;a,l-i., İ ıi.ı § i^**+,i,

acccrding io Regulaiion (EC) iı!c. 1307/2000 (P.EACH) ııiilı iis ainen,iment. Regulaiion (EU) 20i5/e3o

Technical conditlons and measures at process level See Contributing Scenario 2.1.1
(source) to prevent release
Technical condltions and measures to control Local exhaust veniilation - efficiency of at teast [%o]: 5a o/"

dispersion from source towards the wor[<er

Organisational measures to prevent /limit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures relaied io personal Şee Contributing §cenario 2.,1.1
protection, hygiene and hea[th evaluation

2.]Jb___._ coİtribıiting g6en8iio ço.İt c|liıg ,Jori<eı ex,posuıe ğRÖci d} iEğration: > 4 Hours;concentEiion: l0tı %Jİ,doö, u§ğiüithoüt
PRElwitho..qt L.EV)
Treatment of artic[es by dipping and pouring
charaiteristics

Concentration of substance in product

Risk Management Measures

Technical condltions and measures at process level See Contributing Scenario 2.1.1
(source) to prevent release
Organisatlonal measures to preveni /limit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Gontribuüng Scenaçio 2-1.1
protecüon, hygiene and health evaluation

2.]Jf_.___ contrtbutlng scenaİio iontfollİng wori<dt exptisure (iıdÖÖü+1 1ouraıioıi: > ,i ııoırciĞönceıitrdıioıi: > 2s ou"lınaro, ,i"lıjith
PRE;with LEl4

pioduit charaaterlstlis

Technical conditions and measures at process level See Contributing Scenario 2.1.1
(source) to prevent reiease
Technical conditions and measures to control Local exhaust ventilation - efficiency of at least [%]:
on o/^

dispersion from source towards the worker

Organisational measures to prevent iimit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures reIated to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation
Breathingqpparatus _ efficiency of at least [%l: 75 o^

?.1.12 Contribuİİng scenario +ontrolling,.vbrker e,-.po§ure 1İjnOC,i$ {§uratio*: > 4 Hours;Cbncentration: > İ3 7o;lndoor use;With
PRğ;Wlth LEV}

Physical form of product

Concentration of substance in product

Technical conditions and measures at process level See Contributing Scenario 2.1.1
(source) to prevent release
Technical conditions and measures to control Locai exhausi ventilation - e_fficiency of at least [%] 90%
dispersion from source towards the worker
Organisational measures to preveni /iirnit releases, See Contributing Scenario 2.1.1
4l19l2017 EN (English) SDS Ref.: PRAYPH0S-006
Dil-_üliünQDi.:[I-iiEij,f'
ı ! ii lY,j rY); [l l; ü v, .t lşr-, z..\ ıFiiF;,
:=i, (!i. ıjlj., E,^.._Xi[lŞo,oıa
,ş ıt .r1_,.Ş iJ
;.,n-,.o -il -_-
'g: Lı €i{ i,_ii (ş
ıj i.j !- l ij ü] üj

;İ=,i+,i,i: ı]ı,lıı .İ:iı,ırı,l,

according ic Regu{aticn (EC) i.{o. i907/2006 (P.Lı.CH) ı,.;i.ılı its amendment Regulation (Eu) 2015/830

dispeısion and exDosure

Conditions and measures related to personal See Coniributing Scenario 2.i.1
protection, hygiene and health evaluation
Breathing apparjıtus - efficlency ot aİ least t"/"l:
l.2 Aoniributi;,tg scenari* cöiltı,alllng en,ııiı,onrnğtıtai exşiösuıe {ERC-i.
ERG,ıZai
Manufacture of substances
Formulaiion of preparations
Formuiation in materials
lndustrial use of processing aids in procesa
lndustrial use resu
lndustrial use resultlng in manufactu
lndustrial use of reactive processing aidİ
lndusirial use of process regulators toi@ production of resins, rubbers, potymers
use of substances in c[osed systems
lndustrial processing ot artlc
p rod uct characteristics

Concentration of subsiance in product

Organisation measures to prevenVlimit release from P revent environ mental discharg e cons istent with-
p9 q|.ato
ry requirements (Co uncil Directive 96/6 1 /EC)

onsite conditions and measures to İeduce soi[: lnstalla ıetention iank

or limit discharges, air emiss[ons and reteases to soil
Provide regular control of speClmens l pn
Neutralize contaminated cleaning water prior to

conditions and measures related to extemattreatment

of waste for dİsposal

3.{. Heaftlı

Long-term - systemic effects

10.7 mglt

dermal exposure Assessment method

mg/kg bodyweighilday
PRoC1 lnhalation: OEL (B Hours ref; (,l
(Duration: > 4 mgim},ART tool
Hours,Concentraiion: >
Dermal: Highly conoslve to skin
25 %,lndoor use,Wthout
PRE,Without LEV)

lnhalation: OEL (S Hours reQ (1

(Duration: > 4 mg/m'),ART tool
Hours,Concentration: > Dermal: Highly corrosive to skin
25 o/o,1ndoor use,Wthout
PRE,Wth LE!)

PRoc3 : OEL (B Hours ref; (1

(Duration: > 4 mg/m3),Tier 1 MEASE
Hours,Concentration: >
Dermal: Highty corrosive to skin
25 0z6,lndoor use,\Mth
PRE,With LE\4

PRoc4 lnhalation: OEL (8 Hours re| (1

(Duration: > 4 mg/m),ier 1 MEASE
Hours,Concentration: >
Derma!: Highly corrosiiıe to skin
25 %,lndoor use,Wth
PRE.With LElc

4l19l2o17 EN (English) SDS Ref.:PRAYPHOS-006

eii=! ,.,;:iSP,:ie:;F<[ı;: s,ii]-;İ,-:ir ıtr,c,.,-uİilEze.' ,G[".i,,,*,,.i
Şai*ii; ;ı;.t:: Ş;ıetİ
acccrdİng to Regulaiicn (EC) i.lo. 1907i2006 (REACH) ıvith iis amencjrneni Regulaiion (EU) 20i5/s30

PRoC5 0.50i 0.50,i 0.501 lnhalation: OEL (8 Hours ref; (1

(Duration: > 4 mglm'),Tier 1 MEASE
Hours,Concentration: >
Dermal: Highly corrosive to sl<in
25 %,lndoor use,Wlth
PRE,With LEV)

PRoC7 0.6B 0.6B 0.6B inhalation: OEL (B Hours ref) (1

(Duration: > 4 mg/m3),Ter 2 ART (Avanced Reach
Hours,Concentration: Tool)
100 %,lndoor Dermal: Highly corıosive to sl<in
use,WTthout PRE,With
LEVj
PROCBa a.77 o.77 0.77 lnhalation: OEL (8 Hours ref) (1
(Duration: 4 > mg/m3),Tier 2 ART (Avanced Reach
Hours,Concentration: Tool)
100 %,lndoor
Dermal: Highlyı corrosive to sl<in
use,Wthout PRE,Wth
LEV)

PRoc8b 0.77 o.77 0.77 lnhalation: OEL (8 Hours ref) (1

(Duration: 4 > mgim3),Tier 2 ART (Avanced Reach
Hours,Conçentration: Tool)
100 Yo,lndoor Dermal: Highly corroslve to skin
use,Without PRE,Wth
LEV)

PRoc10 0.86 0.B6 0.86 lnhalation: OEL (B Hours ref) (1

(Duration: 4 > mg/m),Tier 2 ART (Avanced Reach
Hours,Concentration: TooI)
100 %,lndoor Dermal: Highty corrosive to skin
use,Without PRE,With
La4
PROC13 0.017 0.017 0.o17 lnhaiaüon: OEL (B Hours ref) (1
(Duration: 4
> mg/ms),Tier 2 ART (Avanced Reach
Hours,Concentration:' Tool)
100 %,lndoor Dermal: Highly corrosive to skin
use,\ffithout
PRE,\Mthout LEV]

PRoc14 0.501 0.501 trn,'

[nhalation: OEL (8 Hours reQ (i
^
(Duration: 4 > mg/m),Tier 1 MEASE
Hours,Concentration: >
Dermal: Highly corrosive to skin
25 %,lndoor use,Wth
PRE,Wth LEV)
PRoc 15 0.501 0.501 0,501 lnhaiation: OEL (B Hours ref) (1
(Duration:> 4 mğ/m),Tier 1 MEASE
Hours,Concentration: >
Dermal: Highly corrosive to skin
25 %,lndoor use,Wth
PRE,Wıth LEV)

.).z. Eçiyironr.nent
contributing exposure scenario
No exposure assessment presented for the envirorıment,MEyTauş at very concentration

4.{. Heafttı
Guidance is based on assumedoperating cond
scaling maY be necessafy to define appropriate site-specific risk management measures. Consult
an
exPert. \Mıere other Rİsk Management Measures/Operational Conditio-ns are adopted, then users
should
ensure that risks are managed to at least equivalent tevels

4,2. Eşvirol;ı-ıqı-ıt
Guidan,;e - Eııııironmeni Prevent environmentat discharge coı,sisterıt wlth re l
National regulations, Technical onsite conditions ano meaİureİ to reduce br limit discharges, aıı
emİssions and releases to şoil. Neutralize contaminaied cteaning water prior to disposal
ğH'o to s;
4119l2017 Ei.l (English) SDS Ref.: PRAYPHOS-OO6
Ş CIŞ ii_i,ıiPiiı[: aıC D
Fij F, i=] ıı Fi* ı"tİ [ [z,eı,,G ı,adış
-..
:;TG ı.'ı,' ;-rai.İ ş n.=.= i
according tc Regulation (EC) No. $a712005 (REACH) ı,vith iis amendmeni Regulation (EU) 2Oj5/830

Additional gocd practice advice [so[ate, drain, wash alP qurgg ihe
accordance with good industrial hygiene and safeÇ practice

4l19l2o17 EN (English) SDS Ref.: PP.AYPHOS-006

ş.ı iJi ja,Qi6j ttJ r,n iE ll,ıa Iı, ı,^ ı iF,ı
li ,:-J,t".J1 u _ı \9ı[! i1|]*=.: _.;iv..,j[-'
it !.:

Şaiei,ı; ı]aj:a Sheet

accoıding to Regulaiion (EC) iılc. l907i2006 (REACH),,,ıith its amencjmen,i Regu{aüon (EU)20,i5is3o

: . ıi.6 §Fışıi {s şsı.*i* ıi]sı §ffi:

Fg,oiessioı]ai Lıse§ - Fhcsio[ıon[a acid ES Ref.: SE3 | bat of issue: Oy05l2o14

ES Type: Worker
Version: 1

Use descripiors Su1, SU14, SU15, sU16, Su17, sU19, SU22, sU24
PRoC8a, PRoc8b, PRocg, PRoc10, PRoc11, PRoc13, PRoc15, PRoclg
PC8, PCga, PCgb, PC12, PC14, PC15, PC21, PC31, PC35, PC37, PC38
Ac1, Ac2, AC3, Ac7
ERC8a, ERC8b, ERC8o, ERCBe
processes, tasks, activities covered lndustrialuse
Assessment meihod Tier 1 MEASE 1.02.01
Tier2: UKPOEM
ARTtooi

t.J.1 ğçntributing §cenario conıroiting rııorker exposure {trROCSa} {Duration: >4 Hours;Go.ncentratton:
PRE;ı,ıVİthout L.ÇV)
PROC8a Transferofsubstanceoipreparation(chargİngldischarging)from/tovesie
facilities
p roduçt characteristics
Physical form of product Liquid
Concentration of substance in product 5 -25o/o
peratio na condltlöns

Technical conditions and measures at process Avoid mist, vapours and spray production.
(source) to prevdnt release
eye wash fountains and safety §howers
shouid be available in the immediate vicinity of any

Use in semi-automated and predominantly enclosed

Organisational measures to prevent /limit releases, Pei,sonal protecüve equipment Familiarize personnel with
dispersion and exposure proper use of protection

and measures related to persona[ lf the ventilation is suitable, it

protection, hygiene and health evaiuation is not essential to wear
respiratory equipment. ln case
of insufficient ventilation, wear
suiiable respiratory
141 / EN
Wear protecüve

goggles or tace
shield lüth safety glasses
to EN 166.
Skin and body protection Protective clothing
elasticated cuffs and closed
neck). lmpervious footwear
must be wom
2.].2___ Cğiirübğijng scenaıio cöıüoi!İng worker öxposüre 1ijii6iita} {Euidtioiıi > 4 Hoğış:Ğonceıiraiio-n: > is %ilndöor use;W-lt*ıout
PRE;wlth LEvı
_

Transferofsubstanceorpreparation(charging/discharging)from/tovess
facilities
pioduct characte ristics

Concentration of substance in pioduct

4l19l2o17 EN (Engtish) SDS Ref.: PRAYPHOS-006

 .6.
jP iı+i
iUŞ
A ı ı ,.=\,a iriı;]
i=, Hj
l}
i=_ı,
İ=-.] |i
iıtıl iJ,r\
.i=: j;I ,.i:, ş;
i:
ii:.i i ii_} F .3ıtİ
[İ [.z,+ ı, G i,i;iıi_ilıi+
Sı,iaı,ı.,
JÇilui|' İiı;lı :ti.c,,=,i
: :.*r!fi
-'|-\i*.'*

,."orCtng to Regulaiion (EC) No. 19O7/2O05 (REACH) vıith iis amendmeni Reguiaiion (EU) 20i5/s30

(source) to prevent release

Technical conditions and measures to conirol Local exhaust veniilaiion - efficiency of ai least 50%
[7o]:
dispersion from source towards the worker
Organisational measures to prevent /limii ı,eleases, See Contributing Scenana 2.1.1
dispersion and exposure
Conditions and measures related io personal See Gontributing Scenario 2.1.1
proiection, hygiene and health evaluation

2.'1.3 8ontrikıuşiı,ıg scenario coııırcıiting wşrİ<er ğxposure

İlnoeÜİıi {Buraiion: > ı! Hours;ü<incenıraşion: 5 Z§' %:İnşoor useılliJiihout
P RŞ; ljlJitho.ut.
^

!E\ı)

product characteıisticş
Physicat form of product Liquid
Conce.ntration of substance in product 5 -25%
Operational conditions

Technical conditions and measures ai process level See Contributing Scenano 2.1.1
(source) to prevent release
Organisational measures io prevent İlimit releases, See Contribuiing Scenario 2.1,1
dispersion and exposure
Conditions and measures related to'persona| See Contribuüng Scenano 2.1.1
protection, hygiene and heatth evaluation

2:1.4 Contributing,scenerie cantroliinğ wotker exposure 1lİİoc'so; {buration: > a *burİ;Ğoncentratidın: > Z5'%;ln'door use:With
PRE;With i.EY}
of substance or preparation ( fromlto vessels/targe at dedicated
p roduct characteristics

Technical conditions and measures at process leııel See Contributing Scenario 2.1.1
(source) to prevent release
Technical conditions and measures to control Local exhausi ventilation - efficiency ot af leasq.Z"1 97 o/o

dispersion from source towards the worker

Organisational measures to prevent /linıit releases, See Coniributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal Breathing apparatus - efficiency of at least tYol: o/o
protection, hygiene and health evaluation See Contributin§ Scenario 2.1.1
Z,1.5 Gorıtributiııg scenaı.iocontı"oİlingwsrkerexpcsuiĞ1rRo*§ı{ÖuHtıön:>iHours;Conce,.,i;jiıon.s.2§.ffi
P$E;Without !.ÇV1

Concentraüon of substance in product

Technical conditions and measures at process level See Contribuüng Scenario 2.1.1
(source) to prevent release
Organisational measures to preveni /timit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation

2J.€.__ contfibutilıg seğnario coEtİolliİg worköı exposı.ııe 1FRo§9} (Öğrjti9nl > 4 Hçıır§;Concenıradion: > 25 %riıdoor use;wıth
PRE;with LEV}
I PRuL;g l Transfer of sub§tance or preparation into small containers (oeaıcatea tııng ılrıeİnduongGi6tlinEi--
lıoOue c
4l1912017 EN (English) SDS Ref.: PRAYPHOS-006 21l28
 ii i,i^i ia: i?iı il_;l ,'f}.iDı İ ı;^. .i-', ,ia, il |F, iE o. ^=:ii n;:,^ -,. ıF, ^.,..- _r] -.
'.'.r.ı
ı:',;=,iii_ııi.İ)i-''r=iUiF(ıı|r-; i.lii-:ıj!U; i=ieL-]iİijii,4,eıi-,:,Jii,:;:iiiı.ş
iıi'at,ıı *ı,ı;i Şheşi
accoı,ding io Regulatİon (EC) Nlo. 1907/2006 (REACH) ı,"riih its amendment Regulation (EU) 2015i 830

Physical form of prociuct

Concentration of subsiance in produci
Operational conditions

Technical condltions and measures at process level See Contributing Scenario ?.1.1
(source) to prevent release
Technicalconditiöns and measures to contro| Local exhaust ventilation - efficiency of at least [%]: 90%
dispersion ftom source towards the worlçer
Organisaiional measures to prevent /limit releases, See Coniributing Scenario 2.1 .1
dispersion and exposure
Conditions and measures relaied to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation
Breathinq apparatus - efficienctr, of at least [%I: B0%
i.l.7 Coülfibuiing sceıüerio cortirof$iıg üroffrğr ğxposure ğH6Ciöi iöuratioıi: > 4 höurs;ooneenııaİon; d- f5 %;iııdoor use;iıfiihoırt
PRE;withoü LEV)

product chııacieristics
Physicat form of product Liquid
Concentration of substance in product tr -?troL
Operationai conditİoiığ

Risk Management Measures

Technical conditions and measures at process level See Contributing Scenario 2.1.,1
(source) to prevent release
Technical conditions and measures to control
dispersion from source towards the worker
Organisational measures to prevent /limit releases, See Contribuüng Scenaria 2.1.1
dispersion and exposure
Conditions and measures related to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation

2.1,B Contribuiirtg scenario controtİing worker expö§iırş (PROCt t} {Duration:

:.
PRE;Vüithout LEV}

Concentration of substance in product

O§eratio nal conditions

Technica[ conditions and measures at process level See Contributing Scenario 2.1,1
(source) to prevent release
Organisational measures to prevent /iimit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Aontributing Scenario 2.1.1
protection, hygiene and health evaluation Breathing apparatus - efficiency of at least 95%
[%]:

2.t,9 contrıbuiing scanario cöntıoiiiıg ı,gorieı exposuıi @EöEı3i |oüraİlönı > i Houtş;GoıceiıaiŞ6n: ğ - 2'Ş %;iıidooi uie;liiiıtiioı
PRE;wthout LEV)
Treatment of articles by dipping and pouring
product chaıacterisiics

Concentration of subslance in product

A;^_4:^*^i -^_jiı:^-^
L,rPğı d LlUı ıdı L;Ur ıLııLıLrı ıŞ

Frequency and duration of use

Technical conditions and measures ai process level See Çontributing Scenario 2.1.1
(source) to prevent release
Organisational measures to prevent /timit releases, See Contributing Scenario 2.1.1
dispersion and exposure
4119l2017 EN (English) SDS Ref.: PRAYPHOS-006
 fi .:ir,fiiF1 fi [l .F:rl]İ.'lı:=i j:
_.,.=)..aF\ i: _ --.,--.E:_ ^ ^. .:i:_...^ -!'! ^
r" :İ| i!=],.> l_r' ijii üU iİ( ll lü,=,. :\
=,;r ^ li..., j ı_
.- ,= ;-',: !j ll i Z;.,_Ş* İ" ,,,ş ı'E] reı t*
,ı
;.

Sa,ery i*ıa Şnş,:i

aecording io Regulaiion (EC) No_ 1907/2006 (REACir) ıvith iis anencjment Regulation (EU) 2015/s3o

Concjitions and measuı-es related to personal See Coniributing Scenario 2.i.1

protection, hygiene and health evaluation

?, l. t0 Ğontributiırg scerıarlo çonir+İiiııs üi,.,oi.!(+r exposı{re fnrjÜt6l {ğuraticn:

PRE;'tjıJİthout LEV}
Use as laboratory reagent

Frequency anci duration of use

Risiı Management liiJeasures
Technical conditions and measures at pi,ocess level See Contributing Scenario 2,1.1
(source) to prevent relea§e
Organisational measures to prevent /limit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Contributing Scenario 2.1.1
protection, hygiene and health evaluation

2,'1-11 Co*tribuiinğ sceııariö cerıtşailing wori<ar ğxpo§urs,{PRğCt5} {buration: > 4 Hours;Coıcşntıation: > İş %;indoor use;Witl.ı
PRşwİth İ*FV}

Concentration of substance in produci

Technicai conditions and measures at process leve[ See Contributing Scenario 2.1.1
(source) to prevent release
Technical conditions and measures io control Locai exhaust ventilation - efficiency of at least [o/o]: 90 o/o

dispersion from source towards the worker

Organisational measures to prevent /limit releases, See Contributing Scenario 2.1.1
dispersion and exposure
Conditions and measures related to personal See Gontributing Scenario 2.1.1
protection, hygiene and health evaluation
Breathing apparatus - efficiency of at ieast [%J: 75

Concentration of substance in product

Technical conditions and measures at process leve| See Contributing Scenario 2.1.1
(source) to prevent release
Organisational measures to preveni /limit releases, Scenario 2.1.1
dispersion and exposure
Conditions and measures relaied to personal See Contributing Scenario 2.1.1
protection, hygiene and heaith evaluaiion

Coniributing scer:aric controiting environmen'.a! exposuıe İERcBa, İRcgb, ERüBc, ERGBe}

Wde dispersive indoor use of processing aids in open systems
Wide dispersive indoor use oi reactive substances in open systems
\Mde dispersive indoor use resulting into or onto a mairix
Wide dispersive outcioor use of reaciive substances in open systems
product characteristics

Concentration of substance in product

4l19l2o17 EN (English) SDS Rei.: PRAYPH05-006

,FJ ıFİ Ot§ ı-E' ıql,ı3) Rl Ç A q:; ıi Di Fe ıtİ [ tze ı, t3 :.3,iİ ı.3
.t
=.ı:e.ii; ia=ıa _t:ı,ı,t i
.""oraİng to Regulaiion (EC) iilc. isO7i2O0§ (R.EACH) \.,,iih iis amendmeni Regulation (EU) 2015/e30

Operationai şgnditioıs
No additional iniormation
Risk Management Measures
Organisation measures to preventllimit release from Prevent snvlronmental discharge consistent ı,vith
site regutatory requirements (Council Directive 96/611EC)

Technical onsite conditions and measures to reduce lnstall a retention tanli

or limit discharges, air emissions and ıeleases to soil
Provide regular control of specimens / pH
Neutralize çontaminated cleanlng waier prior to

conditions and measureş related to externa| treatment Liquid. Solid. Packaging

of waste for disposal contaminated by tlıe

3.t. Hçalth

Long-term - systemic effects

DNEL lnhalation: 10.7 mg/l
Dermal:
Contributing Scenario inhalation exposure RcR dermal exposure RCR Sum Assessment method
mg/m" mg/kg boöyweighVday RcR
DDı.\ı'aQa
ı l \vvug 0.03 0.03 0.03 lnhalation: OEL (8 Hours ref) (1
(Duration: > 4 mg/m3),ART tool
Hours,Concentration: 5 - Dermal: Hlghly corrosive to sldn
25 o/o,lndoor use,\Mthou t
PRE,\Mthout LE\0

PROC8a Q.77 0.77 a.77 lnhalation: OEL (B Hours ref) (1

(Duration: > 4 mg/m"),ART too[
Hours,Concentration: > Dermal: Highly corrosive to skin
25 %,lndoor use,Without
PRE,Wth Lry)
PRoC8b 0.03 0.03 0.03 lnhalation: OEL (B Hours ref; (1
(Duration: 4 > mg/ms),ART tool
Hours,Concentration: 5 - Dermal: Highly corrosive to skin
25 %,lndoor use,Wthoui
PRE,Without LE\4

PRoC8b 0.301 0.301 0.301 lnha[ation: OEL (B Hours reQ (1

(Duration: 4 > mg/m3),Tier 1 MEASE
Hours,Concenkation: >
Dermal: High|y conosive to skin
25 %,lndoor use,\Mth
PRE,Wth La4
PRocg 0.03 0.03 0.03 lnhalation: OEL (8 Hours ref; (1
(Duration: > 4 mg/mt),ART tool
Hours,Concentration: 5 - Dermal: Highly corrosive to skin
25 %,Indoor use,Withoui
PRE,Without LEV}

PRoC9 0.802 0.802 0.B02 lnhalation: (1

(Duration: 4 > mg/m3),Tier 1 MEASE
Hours,Concentrati on: >
Dermal: Highty corrosive to sl<in
25 %,lndoor use,Wth
PRE,Wth LE\4

PRoc10 0.03 0.03 0.03 lnhalation: OEL (B Houıs ref1 (1

(Duraiion: > 4 mg/m3),ART tool
Hours,Concentration: 5 - Dermal: Highly conosive to skin
25 0ı6,indooı use,Wihout
PRE,\Mthout LE\4

PRoc11 0.6 0.6 0-6 inhalation: OEL (B Hours ref) (1

(Duration: > 4 mg/m3),Tier 1 MEASE
Hours,Concentration: 5 - Dermal: Highly corrosive te sl<in
25 %,lndoor use,Wth
PRE,\Mthout LE\|

4l19l2o17 EN (English) SDS Rei.: PRAYPH0S-006

F. tjoş F nop.uç A fJ] [ D., tr eı.ı.İ ii İz,gı.,i3 [?ii[ı}
§ a,iet1, i,ai;ı -:;h*,*i
accorciing i,o Regulaiion (EC) l{o. i9O7i2006 (REACH) ıvith i;;s amendment ReEulaiion (iU) 20-i5/83r
DDr\a.l e Cı.03 0.03
l l\vv ıç' 0.03 inhalation: OEL (B Hours i-ef) ('i
(Duration: > 4 mg/m'),ART tool
Hours,Conceniration: 5 - Dermal: Highly corrosive to skin
25 %,lndoor use,Without
PRE,\Mthout LE\4

PRoc15 0.006 0.006 0.006 lnhalation: OEL (B Hours ref) (1

(Duration: > 4 mg/m"),ART tool
Hours,Concentraiion: 5 - Dermal: Highty corrosive to skin
25 b/o,lndoor use,Without
PRE,Wthout LEV)

PROC15 0.501 0.501 0.501 lnhalation: OEL (B Hours ref) (1

(Duration:> 4 mg/m'),Tieı 1 MEASE
Hours,Concentraiion: >
Dermal: Highty corrosive to si<[n
25 %,lndoor use,With
PRE,Wth LEV)
PRoc19 nE 0.5 0.5 lnhalation: OEL (8 Hours ref) (1
(Duration: > 4 mgim3),Tier 1 MEASE
Hours,Concentration: > Dermal: Highly corrosive to skin
25 %,lndoor use,Without
PRE,\Mthout LEV)

Environrnent
l nformation for contributing exposure
NoexposureassesSmenipresentedfortheenvironmen.,

4.1. Hqaith
Guidance - Health WhereotherRiskManagementMeasures1operationatcono
that risks are managed to at least equivalent levels. Guidance is based on assumed operating conditions
which_may not be applicable to all sites; thus, scaling may be necessary to define appropriatj site-
specific risk management measures. Consult an expert
Website

Environment
Guidance - Environmeni Preventenvironmentaldischargeconsistentwithregulat
National reguİations. Technical onsite conditions and measures to reduce or limit discharges, air
emissions and releases to soi[. Neutralize contaminated cleaning water prior to disposal ğH o to s;

Handleinaccordancewithgoodindustrialhygieneandsafetypra
the RMMs in place are being used correcily and OCs followed

4/19l2o17 EN (EngIish) SDS Ref.: PRAYPHOS-006

 t
ır.ıil ,l =.i,,Q n)|ı_ii l,,aüiD !r,=:.
j'- !İj ',.ul'.J i- iİ! 'L-JJ lı-- jr. il ,+=::
(. ,i' --.i.^.i, . i-ı
^,.i_
'İ, i^
^
. ..'.

iccordingic,Regulaiİon{iC)i.jo. i9C7lzaae (REACH)ı,viihiisai,neni.jin3niRegulai,ion(EU)20i51630

Şoıtsıııııer use :Piıospü,ıerrt aeıd Date oi issue: 03/03/20,i4

SU21
Pc12,Pc31, Pc35, Pc38, PC39
ERCBa, ERC8b, ERCBd, ERCBe
processes, iasi<s, actirıities covered consumer use
ConsExpo (RIVM 2006)
UK POEM

üorıtrihuti*g scenario consu$lğr qnci-use (PÇ,i?} (Qpnçgilıf#ii.o_ç: < 2ğY.g;Wqişı qqsg eşşulll.ipiıo.ii
Fertillzers
prod uct characteriğtics

'
Operational condition's
Frequency and duration of use Exposure duration 30 minutes / days
condıtıons:
Spraying outside industrial settings and/or applications
- Fertilizer (Liquid)
Risk Management Measures
conditions and measures related to infonnation and Prescribed phrase on labet / Packaging
behavioural advice to consumers
The product should not be used for purposes other
than those shown above without first refening to the
suppliel and obtaining written handlinq instructions
Pacl<aging with child-resistant fastening. Give >=10%
warninq of danger
Keep children away
Conditions and measures related to personal Ensure that splashes and spills are avoided by
protection, hygiene and health evaluation produci design
Wear suitable protective clothing, gloves and > 10 o/o
in mixiure
eyeiface protection
Wear long sleeves
L. l-a C.oı'ıiribuiing Scerıarlo so.rısurtlei- encf-use iPC.3'ı, PC^3.Ş, PC3Şi (Concefitratıgı; < Z5?L;i,ıVorst ca.§e assuınption;
polishes and wax Blends
washing and c[eaning products 1ıncıüoın@
Welding and soldering products, flux products
product characteristics

Concentration of substance ln product

Amounts used 110 g

prodııct i
Frequency and duration of use Appticaüon duration 20 minutes
Use frequency 4 x /years
Baihroom

Washing and cleaning products Bathroom cleaning (liquid),WATER SOFTENERS

conditions and measures related to information and See Contributing Scenario 2.1.1
behavioural advice to consumers
Conditions and measures related to personal See Contributing Scenario 2.1.1
proteciion, hygiene and health evaluation

Sor:iribııti n g scena ric- Aoı,tS LııTıer *nrt-usş {P C 3'ı,

polishes and wax Blends

4l19l2017 EN (Fng1151; SDS Ref.: PRAYPH0S-006

Çi in ı|].iS İF, Fil iar,R.l C; eiÇ D, [
tri} l,i|İ İ İze ı",.ğ r"aaİ e
i--,i.^.i,,
, a,, i-: lt
l',.*.,ia i'i^a.^.',
: l_:

u""orOlng io Regulaiİon (EC) iıto. 1907[aaa(REACH),"_.ıiih iis anıencji.nent Regutation (EU) 20.i5/s3o

.Çt:ııs u"gııt eE, [*§e : Fııospüışriç aeEd Date oı issue: 03/03/20l4

descriptors SLJ2'i
Pc12, PC31, PC35, PC38, PC39
ERCBa, ERCBb, ERCBd, ERCBe
processes, iasl<s, actirıities covered consumer use
Assessment meihod ConsExpo (RIVM 2006)
UK PoEM

F- ,şğğii§d ;tiiiığ,ı reıı *:* ı n:ı.S,ııaç

2.i.,i :.*o*ı:ibutiş:gscenerio conşur*grqnci-use
tPÇ.t?}

Liquid
Concentration of substance in product Max 10 o/o.

coıditions

Spraying outside industrial settings and/or applications

Risk Management Measures

conditions and measures related to information and Prescribed phrase on label / Packaging
behavioural advice to consumers
The product should not be used for purpoıas otrıer
than those shown above wiihout first refening to the
supplier and obtaining written handlinq instruciions
Pacl<agin g with child-resistant fastenİn g- Cive >= 10%
waming of danger
Keep children away
Condiiions and measures related to personal Ensure thai splashes and spills are avoided 6y
protection, hygiene and heaith evaluation product design
Wear suitable protective clothing, gtoves and > 10 o/o
in mixiure
eveiface protection
Wear long sieeves
1.İ-L Corıtıibuting sceııario coJ]sumg.r e.nçf-üse iPÇ31, PQ3ğ Pc3pj (Gcncentrat!.qç; <.!.şy"_;lııigrsi ca_§* q§şuıqption1
polishes and wax Blends
Washing and cleaning proOuc
Welding and soldering products, flux produİts
product characteristlcs

Concentration of substance in product

,110
g
Product /
Frequency and duration of use 20 minutes

Bathroom cleaning (liquid),WATER SOFTENERS

Tabs) for consumer use
Rİsk flffİnagemeni ffieasures
concjitions ancj measures relaied to information and See Contributing Scenario 2.1.1
behavioural advice to consumers
Conditions and measures related to personal See Contributing Scenaria 2.1.1
protection, hygiene and health evaluaiion

:.'!.3 CÇnİıli:ııting sc*paric cc}i}su]Tıer epı:-usa.{PC3,i, Pğ5_b, PÇݧ) iCqçca*lyaiiorı; < 257o;.Jfoı.s.i.q3.sç asstrr,ption}
polishes and wax Blends
4l19lzai7 EN 1çnn1l.n, SDS Rei.: PP,AYPHOS-006
 ,

fi UŞ
F ;1 ,.-a\\ ,-^\ iFl !r n /r\\ :=ş\ - :=. a .-=._ i F_
i,-' L=' ı=l iU u=iliu :=il.,,; il iU;
' ;'' ' Saı'e,ii; Daia Snee,l
acccrding to Regulation (EC) ,i907/2006 (REACii) ,,ıiih
i,Jo. its amendmeni Regulaiion (EU) 2015/630

Washing and cleaning nroducts (including solrren.r basec! products)

vVeiding and soldering products, flux producis
pşoduct cha.racteristics
Physical form of produci
Concentration of substance in product

Frequency and duration of use

Washing and cleaning producis

Management llfleasures
conditions and measures related to information and See Contributing Scenario 2.1.1
behavioural advice to consumers
Conditions and measures related to personai See Contributing Scenarto 2,1,1
protection, hygiene and health evaluation

.Go*iribuıing scenario çonı!cıilng gnyironrnentd!.e;posure İŞ_Rcga. ERC8-b, ERcq§, EE§9e}

Wide dispersive indoor use of proces.sing aids in open systems
\Mde dispersive indooruse of reactlve@
Wde dispersive outdoor use of processing aids in open sysiems
Wide dispersive outdoor use of reactive substances in open
'ysiems
Liquid, Solid
Concentration of substance in product < 25 o/o

Operational c.onditions
No additionai information
Risk Management Measures
conditions and measures related to externaltreatment Household solid waste (e.g, product packaging) is
of waste for disposal
battery : Reeycling is preferred to disposal or
incineration, External recovery and recycling of
waste should comp[y rvith applicable local and/oı-

3.1. Health
Information for exposure scenario
Contributing scenario consumer end-use=Worst case asstımption
Contribuiing scenarlo consumer end-use=Woi.st case assumption
Contributing scenario consumer end-use=Worst case assumption

Long-term - systemic effects

DNEL tnhaIation:4.57
Dermai:
Oral: 0.1 mg/kg bodyweighUday
Contributing Scenario inhalation DaD derma[exposure Dr.D oral exposure RCR Sum Assessment
eXpoSure mg/kg rng/kg RcR method
mglm3 bodyweigh't/day bodyweighVday
Pc12 0.01 0.014 0.014 tnhalation: uk
PoEM
Dermal: Covered
by: Personal
protective
equipment
Di'aei
l v9 lt lD^etr lD/^eo
vJJt UJu 0.0687 0.094 0.094 lnhalation:
ConsExpo (RIVM
2cc6)
Dermal: Coverec
by: Personal

4li9tzo17 EN (EngIish) SDS Ref.: PRA.YPHOS-006

 CŞiP' iii O FiilG ni,e D Feu-uı izie ı" G ı",?,ici,3
F,'}--i il
"'1
i]

§aıeiı; Üe':a Shş*i

accorciing i,o Regulaiion (EC) lıio. ,i907,'2006 (REACH) with ii,s amandment Regulation (EU) 2015is30

equipmenı
Pc31, PC35, PC3B lnhaIation:
ConsExpo (Rl\4U
2006)
Dermal: Covereo'
by: Personal
protecüve
equipment

3.2. Enırircnrnenı
lnformati on for coniributing exposure scenarlo
N!o exposure assessment presented for the environmenİ

Guidance - Health Predicted exposures are noi expected io exce

SDS) when the operational conditions/risl< managemeni measures given in sectİÖn 2 are implemented

4.2. Enııiıonmeni
No specific measures are necbssary

Wear suitable gloves and eye/face prote-c@

4l19l2o17 Eiıl (English) SDS Ref.: PRAYPll0S_006