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แบบทดสอบ
เรื่อง คำนวณหำค่ำคงที่สมดุลของปฏิกิริยำ
คำชี้แจง ให้นักเรียนแสดงวิธีกำรหำค่ำคงที่สมดุล (15 คะแนน)
1. ใส่แก๊สไนโตรเจน และแก๊สไฮโดรเจนในภำชนะ 5 dm3 ที่อุณหภูมิ 500◦C เมื่อสมดุลจะมีแก็สไนโตรเจน
3.01 mol แก๊สไฮโดรเจน 2.10 mol และแก๊สแอมโมเนีย 0.656 mol จงหำค่ำ K
จำกปฏิกิริยำสมดุลที่อุณหภูมิ 500๐C (5 คะแนน)
N2(g) + 3H2(g) 2NH3(g)
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เกณฑ์กำรให้คะแนน
5 4 3 2 1
1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร
2)เขียนควำม 2)เขียนควำม 2)เขียนควำม 2)เขียนควำม
เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล
3)เขียนสูตร 3)เขียนสูตร 3)เขียนสูตร
4)แทนค่ำ 4)แทนค่ำ
5)คำนวณได้ 5)คำนวณได้
คำตอบถูกต้อง คำตอบไม่ถูกต้อง
2. ในกำรทดลองเพื่อศึกษำสมดุลในปฏิกิริยำของ N2O4(g) 2NO(g) ใช้ N2O4
จำนวน 0.125 mol ใส่ในภำชนะ 500 cm3 และระบบเข้ำสูส่ มดุลที่อณ
ุ หภูมิหนึ่งพบว่ำ
ควำมเข้มข้นของ N2O4 เท่ำกับ 0.075 mol/dm3 จงคำนวณหำค่ำ K
ก. 1.63 ข. 0.13 ค. 2.33 ง. 1.0
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เกณฑ์กำรให้คะแนน
5 4 3 2 1
1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร
2)เขียนควำม 2)เขียนควำม 2)เขียนควำม 2)เขียนควำม
เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล
3)เขียนสูตร 3)เขียนสูตร 3)เขียนสูตร
4)แทนค่ำ 4)แทนค่ำ
5)คำนวณได้ 5)คำนวณได้
คำตอบถูกต้อง คำตอบไม่ถูกต้อง
3. ปฏิกิริยำ H2(g) + I2(g) 2HI(g) มีค่ำคงที่สมดุลของปฏิกิริยำเท่ำกับ 9 ที่
อุณหภูมิ 60◦C ถ้ำนำ H2(g) 1 mol และ I2(g) 1 mol มำผสมกันในภำชนะ 2 dm3 ที่
อุณหภูมิดังกล่ำว จงหำควำมเข้มข้นของ HI ณ ภำวะสมดุล (7 คะแนน)
ให้ควำมเข้มข้นของ HI ณ ภำวะสมดุล เท่ำกับ 2x mol/ dm3
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เกณฑ์กำรให้คะแนน
5 4 3 2 1
1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร 1)เขียนสมกำร
2)เขียนควำม 2)เขียนควำม 2)เขียนควำม 2)เขียนควำม
เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล เข้มข้นภำวะสมดุล
3)เขียนสูตร 3)เขียนสูตร 3)เขียนสูตร
4)แทนค่ำ 4)แทนค่ำ
5)คำนวณได้ 5)คำนวณได้
คำตอบถูกต้อง คำตอบไม่ถูกต้อง
4. ปฏิกิริยำที่ภำวะสมดุลของ A และ B เป็นดังสมกำร A(g) 2B (g) ถ้ำบรรจุ
แก๊ส A และแก๊ส B ในภำชนะ 1 dm3 ที่สมดุลควำมเข้มข้นของ A เท่ำกับ 1
mol/dm3 และควำมเข้มข้นของ B เท่ำกับ 2 mol/dm3 เมื่อทำกำรรบกวนสมดุลโดย
กำรเพิ่มปริมำตรของภำชนะเป็น 2 dm3 ที่ภำวะสมดุลใหม่ จะมี B กี่ mol/dm3
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5. กลูโคสมีสูตรโครงสร้ำงได้ 2 แบบ คือ กลูโคส A และกลูโคส B เมื่อนำกลูโคส A มำ
ละลำยน้ำ จะเปลีย่ นเป็นกลูโคส B ที่ภำวะสมดุล พบกลูโคส B ร้อยละ 36.4 จงหำ
ค่ำคงที่สมดุล โดยกำหนดสมกำรให้ดังนี้ กลูโคส A ⇋ กลูโคส B
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