Avogadro Chem Point

Organic chemistry Test 2 11th Class Total marks 46

Q1) Why is trichloroacetic acid stronger acid than acetic acid? 1 Mark
Q2) Arrange the following in increasing order of acidic strength: 1 Mark
ClC H 2 COOH , C H 3 C H 2 COOH , ClC H 2 C H 2 COOH ,C H 3 COOH .
Q3) What is the state of hybridization of carbocation? 1 Mark
Q4) What is the effect of introducing an alky group on the stability of carbocation? 1 Mark
Q5) Define chain isomerism with example? 1 Mark
Q6) Define position isomerism with example? 1 Mark
Q7) Define functional isomerism with example? 1 Mark
Q8) Define Metamerism with example? 1 Mark
Q9) Explain why alkyl groups act as electron donors when attached to a π system. 1 Mark
Q10) Which out of two NO2 – CH2 – O - or CH3 CH2 O- is expected to more stable and why. 1 Mark
Q11) Define nucleophile and electrophile with example? 2 Mark
Q12) What is Carbanion? How is it formed? Compare the relativities of ѳ 2 Mark
¿
Q13) What is relationship between the member the following pair of structure are they structure or geometrical
isomer or resonating structure? 3 Mark

Q14) a) Which of the following are position isomers 3 Mark

b) Write the IUPAC name of the functional isomer of CH 3 CH 2 CH 2 CH 2 CHO

c) Write type of structural isomerism is shown by the following pairs of compound?

Q15) Which structural isomerism is exhibited by the following pairs: 3 Mark

Q16) Draw the resonating structure of 4 Mark

−¿ ,¿
C 6 H 5 OH , C6 H 5 NO 2 ,C 6 H 5−CH 3 CH 3 COO
Q17) What are hybridization states of each carbon atom in the following compound?
CH 2 ¿ C ¿ O ( CH 3 ) 2 CO , CH 3=CHCN ,C 6 H 6 4 Mark
Q18) Indicate the 6,Ω bond in the following molecular C 6 H 6 C 6 H 12,CH 3 NO 2, HCON HC H 3 4 Mark
Q19) For the following bond Cleavage use curved arrow to show the electron flow and classify each as
homolysis or heterolysis, identify reactive intermediate produced as free radical, carbocation and
Carbanion. 4 Mark

WZ-186, Central Market, Near Bank of India, Bodella, Vikaspuri, ND-18 M No 9911395433 Page 1
 Avogadro Chem Point

Q20) Define the following term a) Carbonium ion b) Carbanion c) Inductive effect d) Electromeric effect e)
Hyper conjugation 5 Mark

WZ-186, Central Market, Near Bank of India, Bodella, Vikaspuri, ND-18 M No 9911395433 Page 2