MS EDUCATION ACADEMY

Corporate office, Masabtank, Hyderabad-500028; 040-67684422

SENIOR NEET CHEMISTRY ASSIGNMENT (14-08- 2023)

TRACK – I (ETHER , ALDEHYDES AND KETONES

1. The final product obtained when toluene is subjected to side chain chlorination followed
by hydrolysis at 737 K is
a) Phenol b) Benzaldehyde c) Acetophenone d) Chlorobeneze
2. The product formed in Gattermann-Koch benzal chloride reaction from benzene is
a) Chlorobenzene b) Benzol chloridie c) Benzaldehyde d) Acetophenone
3. Preparatoin of benzaldehyde by Etard’s reaction is not from
a) Toluene b) Ethylbenzene c) Benzoyl chloride d) Sodium benzoate
4. Which of the following compound will give positive Tollen’s test?

O
||
a) CH 3  C  H b) c) d)
5. Which of the following compounds undergo Aldol condensation?
a) CH3CHO b) (CH3)3C - HO c) CCl3CHO d) HCHO
6. “Aldol condensation” can be answered by
A) HCHO B) CH3CHO C) CCl3CHO D) C6H5CHO
a) All A, B, C, D b) A, C, D only c) B only d) A and D only
7. Which of the following do not give Cannizzaro reaction?

O
||
a) Cl3C  C  H b) H  C  H
||
O

c) Ph  C  H d)
||
O
8. Column – 1 (Reaction ) Column – II (Type of reactions)
A) R  CH 2  OH 
CrO3
 p) Dehydrogenation
CH3
|
B) CH 3  C  OH 
Cu
3000 c
 q) Oxidation
|
CH3
C) CH 2  CH  CH 2  OH 
MnO2
 r) Dehydration
CH3
|
D) CH 3  C  OH 
20% H 3 PO4
358 K
 s) Elimination reaction
|
CH3

9. Cannizaro’s reaction is:

a) Reduction b) Disproportionation reaction
c) Oxidation d) Ion – exchange reaction

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10.

a) b) c) d)

11. The reaction, RX+R-ONa  R-O-R+NaX is called

a) Wurtz reaction b) Williamson’s synthesis
c) Kolbe’s reaction d) Hofmann bromamide reaction
12. Find out correctt product of the following reaction : CH 3CH 2 Br 
Ag 2Odry



a) b) CH2=CH2 c) d) CH3CH2OH
13. The order of solubility of

(I) (II) (III)

In water is :
a) I > II> III b) I < II < III c) II > III > I d) II > I > III
14. In which of the following reactions, ethyl chloride is not formed?
 AlCl3
a) C5H5OC5H5+PCl5   b) C5H5OC5H5+CH5COCl  
h
c) C5 H5OC5 H5  Cl2  d) C5 H 5OH  PCl3 
15. C-O-C bond in ethers can be cleaved by
a) H2SO4 b) LiAlH4 c) KOH d) HI

16. In the reaction : Me3C-O-CH2CH3 + HI  
(1Mole )
a) Me3C-OH+CH3CH2I b) Me3C-I+CH3CH2OH
c) Me3C-I+CH3CH2I d) Me3C-OH+CH3CH4OH
17.

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18. Column –I (Reaction) Column – II (Mole of HI consumed)

CHEMITRY : TRACK –I KEY

1) b 2) c 3)bcd 4) abc 5) a 6) c 7) d 8) A-q,p B-s,r 9) b 10) a

C-q, D-s,r
11) b 12) c 13) c 14) c 15) d 16) b 17) b 18) A-q, B-r,
C-p, D-s

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 TRACK -11 (ELECTROCHEMISTRY )

1. The charge required for the reduction of 0.4 mol of K2Cr2O7 to Cr3+ ions is
a) 0.6 F b) 2.4×96500C c) 2.4 F d) 12.4×96500F
2. Column I Column –II
A) 1 mole of MnO 4 to Mn2+ p) 193000 C
B) 1 mole of Cr2O72 to Cr3+ p) 289500 C
4+ 2+
C) 1 mole of Sn to Sn p) 482500 C
3+
D) 1 mole of Al to Al p) 579000 C
3. The ionic conductance of following cations in a given conc. Aq. Solution is in the order
a) Li < Na+ < K+ < Rb+ b) Li+ > Na+ > K+ > Rb+
c) Li+ < Na+ > K+ > Rb+ d) Li+ = Na+ < K+ < Rb+
4. Which of the following statements is correct w.r.t. both electrolytic cell and Galvanic cell
a) in both cells, anode is shown by +ve sign
b) in both cells, cathode is shown by –ve sign
c) in both cells, reduction reaction takes place at the cathode
d) in both cells, oxidation reaction takes place at the cathode
5. The resistance of 0.01 N solution of an electrolyte is 210 ohm at 298K, its conductance is :
a) 4.76×10-3 mho b) 4.76 mho c) 210 mho d) none of these
6. Given Cu + e  Cu E° = 0.15 volt ;Cu + e  CuE° =0.5 volt. E for Cu 2++ 2e-  Cu
2+ - + + -

a) 0.65 V b) 0.325 V c) 0.45 V d) 1.2 V

7. For the cell Zn Zn2  C1  Zn2  C2  Zn.G is negative if:

a) C1 = C2 b) C1 > C2 c) C2 > C1 d) None of these
8. When lead storage battery is charged
a) PbO2 dissolves b) Pb rod coated by PbSO4
c) H2SO4 is regenerated d) The amount of acid decreases
9. During the charging of lead strage battery, the reaction occuring at cathode is represented
by
a) Pb  Pb2+ +2e- b) Pb2+ +2e-  Pb
c) Pb2+ + SO42-  PbSO4 d) PbSO4+ 2H2O  PbO2+4H++SO42-+2e-
10. An aqueous solution containing one mole per litre of each dil H2SO4, AgNO3, Hg(NO3) 2,
Au(NO3)3 is being elctrolysed using inter electrodes, then the sequence of deposition of
elements at cathode will be
a) Ag >Hg>H2>Au b) H2>Au >Hg >Ag c) Au>Ag>Hg> H2 d) H2>Hg>Ag>Au
11. The E° at 25°C for the following reaction at the indicated concentrations is 1.50 V.
Calculate the ∆G in kJ at 25°C; Cr(s)+3Ag+ (aq,0.1M)  Ag(s) +Cr3+ (aq,0.1M)
a) -140.94 b) -295 c) -212 d) -422.83kJ
12. A fuel cell develops an electrical potential from the combustion of butane at 1 bar and 298 K
C4H10(g) + 6.5O2(g)  4CO2(g)+5H2O(l);∆G° = -2746kJ/ mol
a) 4.74 V b) 0.547 V c) 4.37 V d) 1.07 V
13. The nernst equation giving dependence of electrode potential on concentration is

a) E  E  
2.303RT
log
M  b) E  E  
2.303RT  M 
log 
n

nF  M n   nF M 
2.303RT  M n   2.303RT
c) E  E   log d) E  E   log  M n  
nF M  nF

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14. If a salt bridge is removed from the half – cells, the voltage:
a) drops to zero b) does not change c) increases gradually d) increases rapidly

TRACK –II KEY :

1) bc 2) A-r, B-s, 3) a 4) a 5) a 6) b 7) c 8) c 9) d 10) c

C-p, D-q
11) d 12) d 13) b 14) a