Nao Ph4 Main PGK 100623 Merg

FIITJEE INTERNAL TEST
PHYSICS, CHEMISTRY & MATHEMATICS

PHASE–4 QP CODE: 000000.0
Time Allotted: 3 Hours Maximum Marks: 300
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
BATCH -
4. Each Section is further divided into Two Parts: Part-A & C in the OMR. Part-B of OMR to be left unused
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each character
of your Enrolment No. and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options each
and only one correct option. Each question carries +4 marks will be awarded for every correct answer and
-1 mark will be deducted for every incorrect answer.
(i) Part-C (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries +4
marks for correct answer and there will be no negative marking.
Name of the Candidate :______________________________________________________
Batch :______________________________ Date of Examination :___________________
Enrolment Number :_________________________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
NAO-(Main)-(Ph-4)-PCM(000000.0)-2
Part A : (Only One Option Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. A long solenoid carrying a current produces a magnetic field B along its axis. If the current is doubled
and the number of turns per cm is halved, the new value of magnetic field will be equal to
(A) B (B) 2B
B
(C) 4B (D)
2
2. Find the magnitude of magnetic field at O (centre of the circular b

part) of the current carrying coil as shown.
b
i
/2
O
a
i
0i  3 2 0i  3 2
(A)  +  (B)  + 
4  a b  2  2a b 
0i   3  0i  3 2
(C)  +  (D)  + 
2  3a 2b  4  2a b 
3. If a charged particle goes un accelerated in a region containing electric and magnetic fields, then which
of the following is true?
(A) E must be parallel to B (B) V must be perpendicular to E .
(C) E must be equal to B (D) V must be perpendicular to B .
Space for rough work
NAO-(Main)-(Ph-4)-PCM(000000.0)-3
4. A nonconducting spherical shell of radius ‘R’ and uniformly charged on its surface with charge ‘Q’ is
rotating about its diametrical axis with a constant angular velocity ‘’. Find the magnetic moment of the
sphere.
QR2  QR2 
(A) (B)
2 3
QR2 
(C) (D) none of these
4
5. A beam of fast moving electrons having cross section area A falls normally on flat surface. The electrons
are absorbed by the surface and the average pressure exerted by the electrons on this surface is found
to be P. If the electrons are moving with a speed v, then the effective current through any cross section
of the electrons beam is
APe APe
(A) (B)
(mv) (mv 2 )
2APe APm
(C) (D)
(mv) (ev)
6. Figure shows a circuit consists of two capacitors C and 2C and C

ideal battery of terminal voltage V. Initially the switch was open for
a long time and capacitors were fully charged. The heat developed
in the circuit after switch is closed.
2C
V
1 1
(A) CV 2 (B) CV 2
4 3
3 2
(C) CV 2 (D) CV 2
4 3
7. In the circuit shown, the reading of the ammeter (ideal) R1 = 100 

A
is the same with both switches open as with both
closed. Find the value of resistance R in .
R3 = 50 
R
E
+ −
R2 = 300 
(A) 600 (B) 800
(C) 400 (D) 300
NAO-(Main)-(Ph-4)-PCM(000000.0)-4
8. The current density (current per unit area) in a solid cylinder of radius R varies
with distance r from its axis as J = kr, where k is a constant. Find the magnetic
J = kr
field at a point P where r > R.
R
0kR2 0kR3
(A) (B)
r r
 kR3  kR3
(C) 0 (D) 0
2r 3r
9. An equilateral triangular loop of wire of side  carries a current i. The magnetic field produced at the
circum centre of the loop is
 3 3i  9i
(A) 0 (B) 0
4 4
0 18i 0 6i
(C) (D)
4 4
10. A point charge ‘q’ is placed at distance ‘a’ from the centre
of an uncharged thin spherical conducting shell of radius
R = 2a. A point ‘P’ is located at a distance ‘4a’ from the R = 2a
centre of the conducting shell as shown. The electric
potential due to induced charge on the inner surface of P O a q
the conducting shell at point ‘P’ is
4a
kq kq
(A) (B) −
5a 5a
kq kq
(C) (D) −
4a 4a
NAO-(Main)-(Ph-4)-PCM(000000.0)-5
11. Three concentric spherical conducting shells A, B and C of radii a, +Q

2a and 4a are initially given charges +Q, −2Q and +Q respectively.
−2Q
The charge on the middle spherical shell ‘B’ after switches S 1 and C
S2 are simultaneously closed, will be
B +Q
Q
(A) −Q (B) − A a S1 S2
2
+3Q
(C) +Q (D)
2 2a
4a
12. In the circuit shown the cell will deliver maximum power to the network if  =6V r = 1
the value of ‘R’ is
2 4
(A)  (B)  R R
3 3
1 5 R R
R
(C)  (D) 
3 3 R
R R
R R
R R
13. Charge Q coulombs is uniformly distributed through out the volume of a solid
hemisphere of radius R meters. Then find the potential at centre O of the R
hemisphere in volts.
O
1 3Q 1 3Q
(A) (B)
40 2R 40 4R
1 Q 1 Q
(C) (D)
40 4R 40 8R
NAO-(Main)-(Ph-4)-PCM(000000.0)-6
14. A graph of the X component of the electric field as a Ex(N/C)

function of x in a region of space is shown. The Y and Z
components of the electric field are zero in this region. If 20
the electric potential is 10V at the origin, then find the
potential at x = 2.0 m. 1 2 3 4 5
0
x(m)
−20
(A) 10 V (B) 40 V
(C) −10 V (D) 30 V
15. A particle of charge ‘q’ and mass ‘m’ enters a y

uniform magnetic field region B = −Bkˆ at origin ‘O’
           
with a velocity v 0 = 6iˆ m/s and after some time it            
exits the magnetic field region with a velocity            
          v =(3iˆ + 3 ˆ
3j) m/s
v = (3iˆ + 3 3ˆj) m/s as shown. The time interval for
           
which the particle has moved in the magnetic field            
region is            
           
           
           
           
6 m/s
O            x
m m
(A) (B)
qB 2qB
m m
(C) (D)
3qB 4qB
16. A conducting wire MN carrying a current I is bent y

into the shape as shown and placed in xy plane.
A uniform magnetic field B = −Bkˆ is existing in x
B I
the region. The net magnetic force experienced B
by the conducting wire MN is I I R I
(A) 2BIR M N
60
60
R 2R R R
I I
(B) 3BIR
(C) 4BIR
(D) 6BIR
NAO-(Main)-(Ph-4)-PCM(000000.0)-7
17. Two particles having positive charges +Q and +2Q are fixed at
equal distance x from the centre of a conducting sphere having x r x
zero net charge and radius r as shown. Initially the switch S is +Q +2Q
open. After the switch S is closed, then find the net charge
following out of sphere.
S
Qr Qr
(A) (B) −
x x
3Qr 3Qr
(C) (D) −
x x
18. A cylindrical solid rod of length L and radius ‘a’ is connected across a
a source of emf V and negligible internal resistance as shown in the x P
figure. The resistivity of the rod at point P at a distance ‘x’ from left
end is given by  = bx (where b is a positive constant). Find the L
electric field at point P.
V
2V V
(A) x (B) x
L2 L2
4V 8V
(C) x (D) 2 x
L2 L
19. A conducting wire carrying a current I is bent into the shape as shown.
The net magnetic field at the centre ‘O’ of the circular arc of radius ‘R’
is I
 I  1 + 3   I  1 + 3 
(A) 0   (B) 0  R
4R   
I
2R    I
 I  1 + 3  0I  2 + 3 
(C) 0   (D) R
8R    8R   
O
20. An infinitely long cylindrical wire of radius ‘R’ is carrying a current with current density j = r 3 (where 
R
is constant and ‘r’ is the radial distance from the axis of the wire). If the magnetic field at r = is ‘B1’
2
B2
and at r = 2R is ‘B 2’ then the ratio is
B1
(A) 2 (B) 4
(C) 6 (D) 8
NAO-(Main)-(Ph-4)-PCM(000000.0)-8
PART – C: (Numerical Based Type)

This section contains 05 questions. Numerical based questions, the answer of which maybe positive or
negative numbers or decimals and round off the value of two decimal places. (e.g. 6.25, 7.00, -0.33, -.30, 30.27,
-127.30)
1. The equivalent capacitance between points A and B in below shown figure will be……… F .
8 F 8 F
A B
8 F 8 F 8 F 8 F
2. A meter bridge setup is shown in the figure. It is used to determine an 5V

()
unknown resistance R using a given resistor of 15  . The galvanometer
K
(G) shows null deflection when tapping key is at 43cm mark from end A B
A. If the end correction for end A is 2 cm. Then the value of R is k  .
 k + 1 G
Find the value of  .
 4 
15  R
3. Current measured by the ammeter (A) in the reported circuit when no R 4

x
current flows through 10  resistance is x ampere. Find the value of 10 
5
. 3 6
A
36V
4. The total current supplied to the circuit is shown in figure by the 5

V battery is……….A.
5
5
5V 5
2.5 
5. The election field in a region is given by E = ( Ax + B ) ˆi where E is in NC-1 and x in meters. The values
of constants are A = 20 SI unit and B = 10 SI unit. If the potential at x =1 is V 1 and that at x = – 5 is V2
then V1 – V2 is 90k volt. Find the value of k.
NAO-(Main)-(Ph-4)-PCM(000000.0)-9
Part A : (Only One Option Correct Type)
1. (i) CF CO H Conc. H SO
⎯⎯⎯⎯⎯ 3
(ii) H O
3
⎯
→ A ⎯⎯⎯⎯⎯⎯

2 4
→B
2
A and B are respectively.

(A) OH OH (B) OH
and and
OH
(C) O (D) O
OH OH OH
and and
OH
2. Which of the following statements is correct, when tertiary butyl bromide is allowed to react with sodium
methoxide in a mixture of methanol and water?
With increase in concentration of sodium methoxide:
(A) The rate of formation of methyl ter-butyl ether increases
(B) The rate of formation of methyl ter-butyl alcohol increases
(C) The rate of disappearance of ter-butyl bromide increases
(D) All the above
3. Which of the following phenol has lowest pKa?

(A) OH (B) OH
OCH3 OH
(C) OH (D) OH
F Cl
NAO-(Main)-(Ph-4)-PCM(000000.0)-10
O
i) NH 2 − NH 2
4. ⎯⎯⎯⎯⎯
ii) OH − / 
→Y
Y is:
(A) N (B) Ph
Ph NH2
CH3
(C) Ph (D) NH NH2
NH Ph
HO NH2
HO
5. The molecule which is isomeric with pentan-3-one and also showing positive iodoform test is
(A) pentanal (B) 3-methybutan-2-one
(C) 2,2-dimethylpropanal (D) pent-1-ene-3-ol
6. For the following reaction which of the following statements is correct?

NO2
A B ⎯⎯⎯⎯⎯
Acidic KMnO4
→ Product
(A) Ring (A) is oxidized (B) Ring (B) is oxidized

(C) Both are oxidized (D) None is oxidized
7. O
H3O+
CH3– C – CCl3 + CH3MgBr(excess) A B
B is
(A) (B) O
OH
CH3 – C – CH3
CH3 – C – CCl3
CH3
(C) (D) None of these
OCH3
CH3 – C – CCl3
CH3
NAO-(Main)-(Ph-4)-PCM(000000.0)-11
8. In a Cannizaro reaction, the intermediate that will be the best hydride donor is:
H
(A) O (B) O
OH O
H H
(C) O (D) O
O O
H3CO O 2N
9. CH2NH2
HNO
⎯⎯⎯⎯
2
→ A, A is
OH
(A) CH2OH (B) CH2NH2
OH NO
(C) NH2 (D) O
10. N2Cl
O O
⎯⎯→ ⎯⎯→ ⎯⎯→
K L M
The reagents/conditions K, L and M are respectively

(A) Ba(OH)2, KCN and CHCl3/NaOH heat, H3O+
(B) H2O (boil), CO2/KOH and Ac2O – AcONa, heat
(C) Steam ; CHCl3/NaOH, heat, H3O+ and Ac2O – AcONa, heat
(D) Cu2Cl2/HCl, NaOH/high P and CO 2|NaOH, heat
NAO-(Main)-(Ph-4)-PCM(000000.0)-12
11. CH2COCl
→ C10H12O3 (P )
(i) Et N
N O + ⎯⎯⎯⎯ 3
(ii) H O
2
CH2COCl
The structure of the product P of the reaction
(A) CH2 O (B) O
C O O
C
C O
C
O
(C) O O (D) None
CH2
CH2
OH
COOMe −
12. ⎯⎯⎯⎯
1. MeO
2. H+
→' A '
COOMe
Compound ‘A’ is [Where MeO- is CH3O-]
(A) COOMe (B) O
MeOOC
O
COOMe
O
(C) COOMe (D) COOCH3
COOCH3
13. Which of the following reaction will yield an amine if their product is hydrolysed?
O O
|| || +
(A) R − C− Cl ⎯⎯⎯
NaN

→ 3
(B) R − C− OR ⎯⎯⎯⎯
N H/H
→ 3
O
|| +
(C) R − C− NH − OH ⎯⎯→
H
(D) Both (A) and (C)
NAO-(Main)-(Ph-4)-PCM(000000.0)-13
14. The rate of SN1 reaction is faster with:

Br Br
(A) (B)
Br
(C) (D)
Br
NO 2
15. Which one of the following compounds will give enantiomeric pair on treatment with aq. KOH?
C2H5 CH3
(A) H5C6 I (B) H3C Br
C2H5 C2 H5
H C2 H5
(C) H5C6 Br (D) H5 C2 Br
D CH3
16. The predominant form of histamine present in human blood is (pKa, Histidine = 6.0)
(A) H (B) H
N N
NH3 NH2
N N
(C) H (D) H
N N
NH3 NH2
N N
H H
17. The structure of glycine at pH 6 is (isoelectric point = 6)

(A) H2N−CH2COOH (B) H2N−CH2−COO−
(C) H3N −CH2COOH
+ (D) H3N+−CH2COO−
NAO-(Main)-(Ph-4)-PCM(000000.0)-14
18. The major product formed in the following reaction is:
O
⎯⎯⎯
HI
Heat
→
O
(A) (B)
I OH
OH OH
(C) (D)
OH
I
I
I
19. Compound (1), C8H9Br, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of (1)
gives an acid (2), C8H6O4. (2) easily forms anhydride on heating. Identify the compound (1).
(A) C2 H5 (B) CH2 Br
Br
CH3
(C) CH2 Br (D) CH2 Br
CH3
CH3
20. The reaction

O O
R C Nu R C X
X Nu
is fastest when X is
(A) Cl (B) NH2
(C) OC2H5 (D) OCOR
NAO-(Main)-(Ph-4)-PCM(000000.0)-15

-127.30)
1. Ratio of ambidient nucleophiles to that of neutral nucleophiles in the given set of species is
CCl4, NH3, PH3, PPh3, NO2−, CN−, CNS−, CNO−, Cl−, OH−, aniline, enamine.
2. 2 − chlorobu tan e ⎯⎯⎯⎯

alc. KOH
→ Number of alkenes formed (N ) ⎯⎯⎯
Br2
CCl4
→ Number of product formed (M)
N
Hence, the value of   is.
M
3. Ph
C O ()
→ Major product ( X )
i conc. OH− , 
⎯⎯⎯⎯⎯⎯
( ii) H+
C O
Ph
Ratio of number of carbon atoms in (X) to that of the degree of unsaturation of ‘X’ is…………. (Round
off the answer upto 2nd place of decimal)
4. O
( )
→ Major product ( Y )
H+ catalyst
H N ⎯⎯⎯⎯⎯

Ratio of degree of unsaturation of ‘Y’ to that of number rings present in ‘Y’ is……………………
N2

⎯⎯ → X + CO2 + N2
5.
COO
The degree of unsaturation in X is.
NAO-(Main)-(Ph-4)-PCM(000000.0)-16
PART – A: (Single Correct Answer Type)
1. A curve in the co-ordinate plane is given by the parametric equation x = t 2 + t + 2 and

y = t2 – t + 2 where t  0. The number of straight lines passing through the point (2, 2) which are tangent
to the curve is/are
(A) 2 (B) 0
(C) 1 (D) 3
x2 − 4
2. If y = , then the domain of y is
cos−1 ( 2 − x )
(A) [ –2, 3] (B) [1, 2]
(C) [2, 3] (D) [–2, 2]
3. Let A = {1, 2, 3}, then the relation R = {(1, 1), (1, 2), (2, 1)} on A is
(A) reflexive (B) transitive
(C) symmetric (D) none of these
4. Which of the following functions is inverse of itself

1− x
(A) f (x) = (B) f(x) = 5log x
1+ x
(C) f(x) = 2x(x-1) (D) None of these
 3cos x − 4 sin x  dy
5. If y = cos-1   , then dx is equal to
 5 
(A) zero (B) 1
(C) − 1 (D) none of these
NAO-(Main)-(Ph-4)-PCM(000000.0)-17

 lim
( )
xn − sin xn
, if x  0, x  1
6. Let f ( x ) = n→ xn + sin xn

( ) , then at x = 1
 1 , if x =1
(A) f is continuous
(B) f has removable discontinuity (i.e. lim f ( x ) exists, but this limit is different from f(1))
x →1
(C) f has finite (jump) discontinuity (i.e., f(1+) and f(−1) both exist finitely, but they are different)
1 
(D) f has infinite or oscillatory discontinuity (for e.g. like sin at x = 0 and tanx at x = )
x 2
7. The tangent to the curve y = x 3 – 2x2 + x – 2 is parallel to x-axis at the point

(A) (1, – 2) (B) (– 1, 2)
2 50   1 50 
(C)  , −  (D)  , 
 3 27   3 27 
1 2 3
8. Let f(x) = x 3 + x 2 + 100x + 7 sin x , then equation + + = 0 has
y − f(1) y − f(2) y − f(3)
(A) no real root (B) one real root
(C) two real roots (D) more than two real roots
1
x 2 sin −x
9. lim x is equal to
x → 1− | x |
(A) 0 (B) 1
(C) –1 (D) none of these
10. The equation of the normal to the curve y = 1 – 2x/2 at the point of intersection with the y-axis is
(A) 2y – x log 2 = 0 (B) 2y + x = 0
(C) 2y + x log 2 = 0 (D) none of these
NAO-(Main)-(Ph-4)-PCM(000000.0)-18
1 − cos x
 ,x  0
11. Let f ( x ) =  x sin x If f (x) is continuous at x = 0, then  is
 1
,x = 0
 2
(A) 1 (B) 0
(C) 2 (D) None of these
x2 + 1
12. The value of integral  x 4 + 1 dx is equal to
1  x2 − 1
(A) tan−1  +c (B) tan−1 x 2 + c
2  2x 
 x2 − 1 1
(C) tan−1  +c (D) tan−1 x 2 + c
 2x  4
2
dx
13. Let the function f(x) satisfies f(x)f(–x) = f(–x)f(x) and f(0) = 1, then  1 + f(x) is equal to
−2
(A) 0 (B) 1
(C) 2 (D) none of these
14. Let a, b, c be non–zero real numbers such that

1 2
 (1 + cos x)(ax + bx + c)dx =  (1 + cos x)(ax + bx + c)dx ,

8 2 8 2
0 0
then the quadratic equation ax 2 + bx + c = 0 has
(A) no root in (0, 2) (B) atleast one root in (0, 2)
(C) both root in (0, 2) (D) imaginary roots
sin8 x − cos8 x
15.  1 − 2sin2 x cos2 x dx is equal to
1
(A) sin 2x + c (B) − sin2x + c
2
1
(C) sin2x + c (D) – sin 2x + c
2
NAO-(Main)-(Ph-4)-PCM(000000.0)-19
2
x
16. The value of  1 + sin
2
dx is equal to
0
(A) 1 (B) 5
(C) 7 (D) 8
17. The area bounded by the curve y = f(x), the x–axis and the ordinates x = 1 and
x = b is (b – 1) sin (3b + 4), then f(x) is equal to
(A) (x – 1) cos (3x + 4) (B) sin (3x + 4)
(C) sin (3x + 4) + 3(x – 1) cos (3x + 4) (D) cos (3x + 4)
2−x
1
18. The value of  ln  2 + x  dx is
−1
(A) 0 (B) 2
(C) ln 2 (D)  ln 2
x 1
19. If  f(t) dt = x +  t f ( t ) dt , then the value of 6f(1) is
0 x
(A) 0 (B) 1
(C) 2 (D) 3
If integrating factor of x(1 – x2)dy + (2x2y – y – ax3) dx = 0 is e 

Pdx
20. , then P is equal to
2x 2 − ax 3
(A) (B) 2x3 – 1
x(1 − x 2 )
2x 2 − a 2x 2 − 1
(C) (D)
ax 3 x(1 − x 2 )
NAO-(Main)-(Ph-4)-PCM(000000.0)-20

-127.30)
h−1 (x) − h−1 (1)

1. If f(x) = x + 1 and g−1(x) = x3 + x + 1, let gof(x) = h(x) then It is ______
x →1 x −1
2. If f: R → R is a function satisfying the property f(2x + 3) + f(2x + 7) = 2  x  R, then the period of f(x)
is _____
27x 2
3. The number of non-zero integral values of ‘a’ for which the function f ( x ) = x 4 + ax 3 + + 1 is
2
concave upward for  x  R
10
[x 2 ] dx
4. If [x] stands for the greatest function then the value of  [x 2 − 28x + 196] + [x 2 ]
is
4
2sin x − sin2x
5. If g(x) =  dx , x  0, then lim g ( x ) is equal to
x3 x →0
NAO-(Main)-(Ph-4)-PCM(000000.0)-21
FIITJEE INTERNAL
TEST
PHYSICS, CHEMISTRY & MATHEMATICS
PHASE–4 CODE: 000000.0
ANSWERS
PHYSICS (SECTION –I)
PART-A
1. A 2. D 3. B 4. B
5. A 6. D 7. A 8. D
9. C 10. B 11. B 12. A
13. A 14. D 15. C 16. D
17. C 18. A 19. C 20. D
PART-C
1. 6.00 2. 5.00 3. 2.00 4. 2.00
5. 2.00
CHEMISTRY (SECTION –II)

PART-A
1. C 2. C 3. D 4. B
5. B 6. A 7. D 8. C
9. D 10. C 11. B 12. C
13. D 14. A 15. C 16. A
17. D 18. A 19. C 20. A
PART-C
1. 1.25 2. 0.60 3. 1.56 4. 1.50
5. 9.00
MATHEMATICS (SECTION –III)

PART-A
1. C 2. C 3. C 4. A
5. B 6. C 7. A 8. C
9. A 10. D 11. A 12. A
13. C 14. B 15. B 16. D
17. C 18. A 19. D 20. D
PART-C
1. 4 2. 16 3. 10 4. 3
5. 1
NAO-(Main)-(Ph-4)-PCM(000000.0)-22
SOLUTIONS
PHYSICS (SECTION –I)
PART-A
1. A
B = 0 I
if I → 2I
→n
2
n
B1 = 0 2I
2
B1 = B
2. D
3 0i
Magnetic field due to circular segment =
4 2a
0i 0i
Due to one straight wire segment = (sin 45 + sin0) =
4b 4 2b
3 i 0i  i  3 2
Net field = 0 + 2  = 0  + 
8a 
4 2b 4  2a b 
3. B
qE = −q(v  B)
E = −(v  B)
 E ⊥ v and E ⊥ B
4. B
M Q
=
L 2m
Q 2
M=  mR2 
2m 3
QR2 
M=
3
5. A
Let n be the average number of electrons per unit volume, present in the beam of electrons, then
impulse momentum theorem gives
(nAv) (mv) = F
P = F/A
P
n=
(mv 2 )
 P  PAe
 current I = nAev =   Aev = mv
 mv 2 
6. D
Ui + WBattery = Uf + Heat
CV 2 4CV 2
+ = CV 2 + Heat
3 3
NAO-(Main)-(Ph-4)-PCM(000000.0)-23
5  2
Heat =  − 1 CV 2 = CV 2
3  3
7. A
E
With both switches open, IA =
R1 + R2 + R3
With both switches closed, there will be no current through R3,
the current through E and R2 is
E
I =
RR1
R2 +
R + R1
Current through the ammeter is
RI RE
IA = =
R + R1 (R + R1 )R2 + RR1
E
=
R2R1
R1 + R2 +
R
As IA = IA
R1R2 100  300
R= = = 600 
R3 50
8. D
We take the ampeiran loop of radius r > R.
Since the loop is outside the cylinder, the current through the loop is
R R
2kR3

0

I = kr  (2rdr) = 2k r 2 dr =
0
3
2kR3 0
 B  2r = 0I =
3
0kR3
B=
3r
9. C
Due to a wire
 i
B= 0 (sin60 + sin60)
4 ( / 2 3 )
0i  3  60i i
= 2   2 3 =

4  2  4
Magnetic field due to three sides
 18i 60 60
Bnet = 3B = 0 r
4
r=
2 3
10. B
The net electric potential due to external charge inside the cavity and the induced charge on the surface
of the cavity at any point outside the cavity is zero. If ‘V’ is the electric potential due to induced charge
on the surface of cavity at point ‘P’.
kq
V+ =0
5a
NAO-(Main)-(Ph-4)-PCM(000000.0)-24
kq
 V=−
5a
11. B
The electric potential of shell B is zero Q+q
−q
VB = 0
q
kq kQ C
+ =0 0
2a 4a B 0
Q A a
 q=−
2
2a
4a
12. A
The cell will deliver maximum power to the network if Req = r
3R
 =r
2
2r 2
 R= = 
3 3
13. A
The potential at centre of sphere in which q charge is uniformly distributed through the volume is
1 3q
VC =
40 2R
By symmetry, the potential at centre due to half sphere will be half of the complete sphere.
V 1 3q / 2 1 3Q
V0 = C = = (since, q/2 = Q)
2 40 2R 40 2R
14. D

VB − VA = − E x dx = −(area under Ex −x curve)
1
VB − 10 = −  2  ( −20) = 20
2
VB = 30 V
15. C
Since the particle exists the magnetic field region with a velocity v = (3iˆ + 3 3ˆj) m/s
3 3
tan  =
3

 =
3

The angular displacement of the particle in the magnetic field region is  =
3
qB
Angular velocity,  =
m
 m
 t= =
 3qB
NAO-(Main)-(Ph-4)-PCM(000000.0)-25
16. D
Since B is constant in the region
The net magnetic force experienced by the conducting wire MN is
(
F = I L eff  B )
Where, Leff = 6Riˆ
F = I 6Riˆ  B( −k)
ˆ 

F = 6BIR( ˆj)
17. C
After the sphere is grounded, potential at centre becomes zero. Let the net charge on the sphere finally
be q.
kq k3Q
+ =0
r x
3Qr
q= −
x
3Qr
The charge following out of sphere is
x
18. A
dx 0
bxdx  b 2
R=  A
=
A
=
2A
V 2VA
I= =
R b 2
I 2V
 j= = 2
A b
 j = E
bx2V 2V
E = j = = 2 x
b 2 L
19. C
The net magnetic field at the centre ‘O’ of the circular arc is
 I 3 I  I
B0 = 0 + 0 − 0
4R 8R 8R
0I 30I
= +
8R 8R
 I  1 + 3 
B0 = = 0 
8R   
20. D
When r  R
j = r
3
r
0

B2r = 0 j2rdr
r
B
 r 5 B
Br = 0
5 R
B
 r 4
B= 0 ,rR
5
when r > R
NAO-(Main)-(Ph-4)-PCM(000000.0)-26
R

B2r = 0 j2rdr
0
R

Br = 0 r 3rdr
0
 0 R 5
Br =
5
 0 R 5
 B= ,r>R
5r
R  R 4
at r = , B1 = 0
2 80
 0 R 4
at r = 2R, B2 =
10
B2
 =8
B1
PART-C
1. 6
24  8
ceq = = 6F 1 1 2
32 A B
2 8F 8F 8F 8F 8F
8F
8F
8F
8F
8F
A 1 8F 2 8F B

8F
8F
A 8F 8F 1B

A 8F B
24F
2. 5
At null point :
15 R
=
43 + 2 100 − 43
 R = 19 
3. 2
Using whetstone :
NAO-(Main)-(Ph-4)-PCM(000000.0)-27
R 4
=  R = 2
3 6
54
Requ = 
15
36
i= = 10A
54
15
4. 2
 Re q = 2.5  5
2 2
v 5 2 1
I= = = 2A 5
Re q 2.5 5 5
5v 5 = 2.5
2.5 5
3
2 5v
5. 2
E = (20x + 10)iˆ
1
V1 − V2 = −  (20x + 10)dx
−5
V1 − V2 = −(10x 2 + 10x)1−5
V1 – V2 = 10(25 – 5 – 1 – 1)
V1 – V2 = 180 V
CHEMISTRY (SECTION –II)

PART - A
1. OH OH2
(i) CF3CO3H Conc. H2SO4
⎯⎯⎯⎯⎯
(ii) H2O
⎯
→ ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
, Pinacol −Pinacolone reaction
⎯→
OH OH
-H2O

−H
⎯⎯ ⎯ ⎯⎯
H O
O H O
2. Towards SN reaction, ter-butyl bromide undergo SN1 mechanism which is independent of concentration
of nucleophile. But t-butyl bromide is undergoing E2 reaction as well in presence of strong base like
CH3O–. Hence C.
3. pKa for the compound A, B, C and D are respectively 9.98, 9.48, 8.81 and 8.48.
NAO-(Main)-(Ph-4)-PCM(000000.0)-28
4. O
N N - - N
NH ⎯⎯
→ Ph
NH 2 − NH 2 −
⎯⎯⎯⎯ → Ph NH2 ⎯⎯⎯
OH
→ Ph C NH
Ph H H H H
H2 O
H H
OH −
N ⎯⎯⎯
→ Ph
H
Ph H NH H
5. For a compound to show positive iodoform test the molecule should either have CH 3CO- or
CH3CH(OH)- groups. Out of the options given all of them are isomers of pentan-3-one as they have the
same molecular formula but different structural formula, 3-methybutan-2-one satisfies both the
condition of being an isomer of pentan-3-one and also showing positive iodoform test.
O OH
O O
H3C H3C H3C CH3
CH3
H H
CH3 H3C
CH3 CH2
3-methylbutan-2-one 2,2-dimethylpropanal pent-1-en-3-ol

pentanal
6. The rings containing electron withdrawing (eg. NO2 group) are stable and are not oxidized by acidic
KMnO4. So the ring (A) is oxidized to give the product
NO 2
HOOC
HOOC
7.
O

CH3 – C – CCl3 + CH3MgBr
O OH
1) CH3MgBr
CH3 – C – CCl3 CH3 – C – CH3 CH3 – C – CH3
2) H2O
CH3
CH3
8. The methoxy group being electron-releasing group makes the release of hydride group more easy.
9 Mechanism
H
+
CH2NH2 CH2 N2 CH2 OH O
HNO2
⎯⎯⎯⎯
→ ⎯⎯→ ⎯⎯→ ⎯⎯→
OH OH OH
NAO-(Main)-(Ph-4)-PCM(000000.0)-29
10. N2Cl OH OH
O O
CHO
⎯⎯⎯
steam
→ (i)CHCl3 / NaOH / 
⎯⎯⎯⎯⎯⎯ → ⎯⎯⎯⎯→
(CH3CO)2 O
(ii) H O+ CH3COONa
3

Perkin's reaction
11. O O
O
N O N O C Cl
O C
C −HCl
⎯⎯⎯ →
C CH2 CH2 Cl
Cl O
O O
O O C N O C
C C
HO
⎯⎯
2
⎯
12. O O
CH2 C OCH3 CH C OCH3 COOCH3
COOCH3
CH3 O−
⎯⎯⎯⎯ → ⎯⎯
⎯→
⎯
⎯⎯⎯ ⎯ ⎯⎯
⎯→
⎯
C OCH3 CH3 OH
C OCH3 OCH3
O
O O O
13. (A) is Curtius reaction while (C) is Lossen rearrangement.
14. Carbocation formed is most stable.
15. Compound of option ‘C’ has a symmetric carbon and capable to forms stable carbocation.
16. N
NH3
H N
The N-atoms present in the ring will have same pKa values (6.0), while N atom outside the ring will have
different pKa value (pK a > 7.4)
Therefore, two N-atoms inside the ring will remain in unprotonated form in human blood because their
pKa(6.0) < pH of blood (7.4), while the N-atom outside the ring will remain in protonated form because
its pKa > pH of blood (7.4).
17. At isoelectric pH, compound will be 100% Zwitter ions.
NAO-(Main)-(Ph-4)-PCM(000000.0)-30
18.
O + O − I
⎯⎯→
H
H ⎯⎯⎯⎯→
I
− CH3 − OH
O O O
H+
I I − I
⎯⎯⎯⎯
− CH3 − CH2 −I
⎯
OH O
H
19. +
CH2Br CH2
3( )
AgNO alc.
+ AgBr 
⎯⎯⎯⎯⎯ →
CH3 ( pale yellow )
(A) CH3
O
[O] COOH

⎯⎯⎯
−H O
→ O
2
COOH
(B) O
pthalic anhydride
20. Conjugated acid of Cl- is a stronger acid i.e. HCl.
PART - C
1. Ambident nuclephiles = NO2− , CN− , CNS − , CNO − , Enamine = 5.

Neutral nucleophiles = NH3, PH3, PPh3, Aniline = 4
Ratio = 5/4 = 1.25
2. Cl Br
H3C CH2 CH CH3 ⎯⎯⎯⎯
alc. KOH
→ H3C CH CH CH3 ⎯⎯⎯⎯ Br2 /CCl4
→ H3C CH2 CH CH2 Br
( cis + trans ) ( + )
d
H3C CH2 CH CH2 Br

N=3 H3C CH CH CH3
Br
( d + + meso )
=5
N 3
= = = 0.60
M 5
NAO-(Main)-(Ph-4)-PCM(000000.0)-31
3. O O OH O
−
Ph C C Ph ⎯⎯⎯
oH
+ → Ph C C O H
H
Ph
(X)
Atoms of 'C' in ' X' 14
= = = 1.56
Degree of unsaturation 9
4.
+
O H N ⎯⎯→
H
 N
(Y)
Degree of unsaturation in ' Y ' 3
= = = 1.5
Number of rings 2
5. ' X' is
MATHEMATICS (SECTION–III)
PART − A
1. Equation of tangent y – (t2 – t + 2) =
2t − 1
2t + 1
( (
x − t2 + t + 2 ))
Putting x = 2, y = 2, we get t = 0
2. x2 – 4  0  x  2 or x  –2
–1  2 – x < 1  x  3 and x > 1
 x  [2, 3].
3. R is not reflexive as (2, 2)  R, (3, 3)  R. Also, R is not transitive as (2, 1)  R and

(1, 2)  R but (2, 2)  R.
However, R is symmetric.
1− x
1−
 1− x  1 + x = x, x
4. Since fof(x) = f(f(x)) = f  =
 1 + x  1+ 1− x
1+ x
 fof = I  f is the inverse of itself.
5. y = cos−1 (cos ( + x))

4
=+x where  = tan−1
3
6. 0 < x < 1  xn → 0 as n →   f(x) = 0 and x > 1  xn → + as n →  f(x) = 1

 f has a jump (finite) discontinuity at x = 1
7. y = x3 − 2x2 + x − 2
dy
= 3x2 − 4x + 1
dx
NAO-(Main)-(Ph-4)-PCM(000000.0)-32
dy
For horizontal tangent, =0
dx
 3x2 − 4x + 1 = 0
 3x2 − 3x − x + 1 = 0
3x(x − 1) − 1(x − 1) = 0
(3x − 1) (x − 1) = 0
1
x= ,1
3
8. Q f(x) = x 3 + x 2 + 100x + 7 sin x

f (x) = 3x 2 + 2x + 100 + 7 cos x = 3x2 + 2x + 93 + 7 (1 + cos x)
2
 1  
2
278
 3  x +   + + 7(1 + cos x)  0
 3   3
 f(x) is increasing function
f(1) < f(2) < f(3)
Let f(1) = a, f(2) = b and f(3) = c
a<b<c
1 2 3
Now given equation is + + =0
y −a y −b y −c
Or (y−b)(y−c) + 2(y−c)(y−a)+3(y−a)(y−b) = 0
 g(a) > 0, g(b) < 0 and g(c) > 0
Hence, one real root between a and b other between b and c
1  1   sin t 
x 2 sin −x x  x sin − 1  − 1
x  x   t  1− 1
9. lim = lim = lim = =0
x → 1− | x | x → 1− x t →0 t −1 0 −1
10. y = 1 – 2x/2 y-axis  x = 0  y = 0

dy x/2 1 dy 1
= −2 log2  = − log2
dx 2 dx 2
2
y= x  2x – y log 2 = 0.
log2
1 − cos x 1
11. lim f ( x ) = f ( 0 )  lim =
x →0 x →0 x sin x 2
x
2sin2 .
2     = 1   = 1 .
2 2
 2 x x sin x 4 2 2
2 2
x2 + 1 1 + 1/ x 2 1 + 1/ x 2
12. I= x 4
+1
dx = x 2
+ 1/ x 2
dx =  (x − 1/ x)2
+2
dx
dt 1 t 1  x2 − 1
= 2+t 2
=
2
tan−1
2
+c =
2
tan−1 
 2x 
+c
13. f(–x)f(x) – f(x)f(–x) = 0

d
 (f(x)f( − x)) = 0
dx
 f(x)f(–x) = k
NAO-(Main)-(Ph-4)-PCM(000000.0)-33
Put x = 0, k = 1 ( f(0) = 1 given)

 f(x)f(–x) = 1 ….. (i)
2 2 b b
dx dx
I=
−2
 1 + f(x) =  1 + f(−x) −2
(using  f(x)dx =  f(a + b − x)dx )
a a
2
f(x)dx
 I=  1 + f(x)
−2
2
 2I =
−2
 dx = 4  I = 2
1 2
14. 
0

(1 + cos8 x)(ax 2 + bx + c)dx = (1 + cos8 x)(ax 2 + bx + c)dx
0
1 2
= 
0

(1 + cos8 x)(ax 2 + bx + c)dx + (1 + cos8 x)(ax 2 + bx + c)dx
1
2
  (1 + cos x)(ax 2 + bx + c)dx = 0
8
1
Now since 1 + cos8x  0, thus ax2 + bx + c must be positive somewhere and negative somewhere in
(1, 2)
Hence ax2 + bx + c = 0 has one root in (1, 2) and thus in (0, 2)
sin8 x − cos8 x (sin4 x + cos4 x)(sin4 x − cos4 x)

15.  1 − 2sin 2
x cos2 x
dx =  1 − 2sin2 x cos2 x
dx
[(sin2 x + cos2 x)2 − 2sin2 x cos2 x](sin2 x − cos2 x)(sin2 x + cos2 x)

=  1 − 2sin2 x cos2 x
dx
1
 (sin x − cos2 x) dx =  − cos 2x dx = − sin2x + c
2
=
2
2 2
x x x x x
16. 
0
1 + sin
2
dx = 
0
sin2
4
+ cos2 + 2sin cos dx
4 4 4
2 /2
x x x
= 
0
sin
4
+ cos dx = 4
4 
0
sin t + cos t dt (putting
4
= t)
/2
/2
= 4  (sin t + cos t) dt = 4 − cos t + sin t 
0
0 =8
b
17. We have  f(x) dx = (b − 1)sin(3b + 4)
1
Differentiate both sides w.r.t b, we get
f(b) = 3(b – 1) cos (3b + 4) + sin (3b + 4)
 f(x) = 3(x – 1) cos (3x + 4) + sin (3x + 4)
−1
2−x 2+x 2−x 2−x
18. Let f(x) = loge   dx , f( − x) = ln   = ln   = − ln   = −f(x)
2+x 2−x 2+x 2+x
1
Hence, f(x) is an odd function   f(x) dx = 0 .
−1
NAO-(Main)-(Ph-4)-PCM(000000.0)-34
x 1
19. 
0
f(t)dt = x + t f ( t ) dt
x
Differentiating w.r.t x, we get
f(x) = 1 – x f(x)
1 1
 f(x) =  f(1) =  6 f(1) = 3
1+ x 2
dy dy (2x 2 − 1) ax 3 dy
20. x(1 − x 2 ) + y(2x 2 − 1) = ax 3 , + · y = which is of the form + Py = Q
dx dx x(1 − x )
2
x(1 − x )
2 dx
2x 2 − 1
So IF = e 
Pdx
, P= .
x(1 − x 2 )
PART − C
−1
1. f (x) = x − 1 then h (x) = ( g  f(x) )
−1 −1
= x3 + x

d −1
dx
(
h (x) = 3x 2 + 1 )
(h −1
)
(1) ' = 3 + 1 = 4
2. f(2x + 3) + f(2x + 7) = 2 …(1)

x→x+1
f(2x + 5) + f(2x + 9) = 2 …(2)
x→x+2
f(2x + 7) + f(2x + 11) = 2 …(3)
(1) – (3)
f(2x + 3) = f(2x + 11)
 f(2x + 3) = f(2x + 3 + 8)  T = 16.
3. f(x) = 12x2 + 6ax + 27  0  a  (–6, 6)
b b
4. Applying the property  f(x) dx =  f(a + b − x) dx
a a
10 2
[x ] dx
Hence I =  [(14 − x)2 ] + [x 2 ] …(1)
4
[14 − x 2 ] dx
10
 I=  [x 2 ] + [14 − x 2 ]
…(2)
4
10
 2I =  dx  2I = (10 − 4)  2I = 6  I = 3
4
2sin x − sin2x 0
5. lim g ( x ) = lim = form
x →0 x3x →0 0
2cos x − 2cos 2x 0
g(x) = = form
3x 2 0
−2sin x + 4 sin2x 0
g(x) = = form
6x 0
−2cos x + 8cos 2x
g(x) = = 1.
6

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FIITJEE INTERNAL TEST

PHYSICS, CHEMISTRY & MATHEMATICS

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :______________________________________________________

Batch :______________________________ Date of Examination :___________________

Enrolment Number :_________________________________________________________

Part A : (Only One Option Correct Type)

2. Find the magnitude of magnetic field at O (centre of the circular b

Space for rough work

6. Figure shows a circuit consists of two capacitors C and 2C and C

7. In the circuit shown, the reading of the ammeter (ideal) R1 = 100 

Space for rough work

Space for rough work

11. Three concentric spherical conducting shells A, B and C of radii a, +Q

Space for rough work

14. A graph of the X component of the electric field as a Ex(N/C)

15. A particle of charge ‘q’ and mass ‘m’ enters a y

16. A conducting wire MN carrying a current I is bent y

Space for rough work

Space for rough work

PART – C: (Numerical Based Type)

2. A meter bridge setup is shown in the figure. It is used to determine an 5V

3. Current measured by the ammeter (A) in the reported circuit when no R 4

4. The total current supplied to the circuit is shown in figure by the 5

Space for rough work

Part A : (Only One Option Correct Type)

A and B are respectively.

3. Which of the following phenol has lowest pKa?

Space for rough work

6. For the following reaction which of the following statements is correct?

(A) Ring (A) is oxidized (B) Ring (B) is oxidized

Space for rough work

The reagents/conditions K, L and M are respectively

Space for rough work

(C) O O (D) None

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14. The rate of SN1 reaction is faster with:

17. The structure of glycine at pH 6 is (isoelectric point = 6)

Space for rough work

18. The major product formed in the following reaction is:

20. The reaction

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PART – C: (Numerical Based Type)

2. 2 − chlorobu tan e ⎯⎯⎯⎯

Space for rough work

PART – A: (Single Correct Answer Type)

1. A curve in the co-ordinate plane is given by the parametric equation x = t 2 + t + 2 and

4. Which of the following functions is inverse of itself

Space for rough work

7. The tangent to the curve y = x 3 – 2x2 + x – 2 is parallel to x-axis at the point

Space for rough work

14. Let a, b, c be non–zero real numbers such that

 (1 + cos x)(ax + bx + c)dx =  (1 + cos x)(ax + bx + c)dx ,

Space for rough work

If integrating factor of x(1 – x2)dy + (2x2y – y – ax3) dx = 0 is e 

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PART – C: (Numerical Based Type)

h−1 (x) − h−1 (1)

Space for rough work

CHEMISTRY (SECTION –II)

MATHEMATICS (SECTION –III)

CHEMISTRY (SECTION –II)

Batch :____________ Date of Examination :_