NAO Adv Paper-2 (Phase-4)

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FIITJEE –Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS


BATCH – 2224 LOT NAO PAPER (PHASE−4)

Pattern - CPT-1 QP CODE: PAPER - 2


Time Allotted: 3 Hours Maximum Marks: 180

▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.

1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Part.


(i) Part-A (01-04) – Contains Four (04) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and −1 marks for wrong answer.

(ii) PART–A (05–10) contains Six (6) Multiple Choice Questions which have One or More Correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in −1
marks, as a wrong option is also darkened.

(iii) PART–C (01-08) contains (08) Numerical based questions with single digit integer as answer, ranging from
0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
CTY-2224 LOT−NAO-PAPER-2(PH−4)_ADVANCED (PCM)-2

PART – A: (Single Correct Answer Type)


This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. n identical cells, each of emf  and internal resistance r, are joined in series to form a closed circuit. The
potential difference across any one cell is
(A) zero (B) 
 n −1
(C) (D) 
N n

2. Find flux through the given surface.


q q
(A) (B)
20 40
q
3q q
(C) (D)
40 0

3. A magnet is suspended in such a way that it oscillates in the horizontal plane. If it makes 20 oscillations
per minute at a place-1 where dip angle is 30 and 15 oscillations per minute at a
B 
place-2 where dip angle is 60. The ratio of earth’s total magnetic field  1  at the two places is
 B2 
(A) 16 : 93 (B) 163 : 9
(C) 16 : 1 (D) 1 : 16

4. A neutral particle at rest at A decays into two charged particles of different mass. Magnetic field is inside
the paper. Which can be correct paths for two particles if we ignore any gravitational and electrostatic
force?
(A)           (B)          
                   
                   
                   
                   
        collision
           
A A
                   
                   
                   
                   
                   
(C)           (D)          
                   
                   
                   
                   
                   
A A
                   
                   
                   
                   
                   

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PART – A: (Multi Correct Answer Type)

This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

5. The separation between the plates of charged parallel plate capacitor (not connected with battery) is
increased. Which of the following quantities will change?
(A) charge on the capacitor (B) potential difference across the capacitor
(C) energy of the capacitor (D) energy density between the plates

6. A conducting spheres of radius R carrying charge Q lies inside an uncharged conducting shell of radius
2R. if they are joined by a metal wire
(A) Q/3 amount of charge will flow form the sphere to the shell
(B) 2Q/3 amount of charge will flow from the sphere to the shell
(C) Q amount of charge will flow from the sphere to the shell.
(D) kQ2/4R amount of heat will be produced.

7. A conductor AB carries a current I in a magnetic field B . If AB = r and the force on the conductor is
F,
(A) F does not depend on the shape of AB (B) F = i(r  B)
(C) F = i(B  r ) (D) F = i(r  B)

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8. A current passes through a wire of nonuniform cross-section. Which of the following quantities are
independent of the cross-section?
(A) the charge crossing in a given time interval
(B) drift speed
(C) current density
(D) free-electron density

9. A rod of length  having linear charge density  lies parallel to an infinite


B
conducting sheet of surface charge density 0. The line charge is rotated
slowly, such that it becomes vertical as shown in the figure. Neglect gravity
throughout the question. Choose the INCORRECT option(s). (Assume that
there is no change in charge density of sheet during the process) A 
0 2 a 
(A) Work done to rotate the line charge is .
4 0
0
 2
(B) Work done to rotate the line charge is − 0 .
4 0
0 2
(C) Work done to rotate the line charge is .
20

(D) VB − VA = , where V stands for potential at a point.
20

10. A prism is made of wire mesh with each side having equal resistance E
R. A battery of 6 V and zero internal resistance is connected across
E and F as shown in the figure. The current in the branch AD, if R is F
equal to 5 , is A B
(A) 0.6 A (B) 0.8 A
(C) 0.4 A (D) 2 A
D C

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PART – C: (Numerical Based Type)

This section contains 08 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

1. Four wires of current I1 = 2A, I2 = 4A, I3 = 6A and I4 = 8A cut the page


 I3
perpendicularly at the points a, b, c and d respectively. The value of
 B.d for the shown loop is −k0. Find the value of k.  I2

 I4
 I1

2. An electric field is given by E = yiˆ + xjˆ volt/m. The work done in moving slowly a charge of 10 C from
a point r1 = 3iˆ + 4ˆj to another r2 = 2iˆ + 6ˆj is

3. The energy stored in the capacitor in steady state in the 1 6V


given circuit shown is k J. Find the value of k.
2F

2 4

2V
6

3V

4. The diagram shows four identical capacitors each of capacitance 4Q 2Q


C. Now a +2Q and +4Q charges are given simultaneously at the A B
nQ
positions shown in the figure. The value of | VA − VB | is .
2C
Find the value of n.

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5. A long straight wire of circular cross-section is made of a non-magnetic material. The radius of cross-
section of the wire is a. The wire carries a current I which is uniformly distributed over its cross-section.
n0I2
The energy stored per unit length in the magnetic field contained with the wire is . Find the value
64
of n.

6. There large conducting plates carrying charges Q, 2Q and Q on them, Q 2Q 3Q


are placed parallel to each other as shown in the figure. If u1 and u2
denote electrostatic potential energy in the space between 1st and 2nd
u
plate and 2nd and 3rd plate respectively as indicated, then 2 equals to
u1

1 2 3

7. Consider a dipole placed in a uniform electric field E as shown. E


The charged particles are connected by a light rigid rod. Under 2m
influence of the uniform electric field, frequency of small oscillations q
1 kqE
of the dipole is . Find the value of k.
2 2m

–q
m

11 A D
8. The voltage across capacitor in steady state is Volts.
k
7 6
Find the value of k. 6V

B E
10C
3 12

F
C

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PART – A: (Single Correct Answer Type)

This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

1. The product(s) of the following reaction sequence is (are)


NH2

i) Aceticanhydride/pyridine
ii)KBrO3/HBr
¾¾¾¾¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾®
iii)H3O+ ,heat
iv) NaNO2 /HCl, 273- 278 K
v)Cu/HBr
Br
Br

(A) (B)

Br Br
Br
Br

Br Br Br Br
(C) (D)

Br

2. KI in acetone, undergoes SN2 reaction with each of P, Q, R and S. The rates of the reaction vary as
O
Cl
H3C-Cl Cl
Cl

P Q
R S
(A) P > Q > R > S (B) S > P > R > Q
(C) P > R > Q > S (D) R > P > S > Q

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3. Among cellulose, polyvinyl chloride, nylon and natural rubber, the polymer in which the intermolecular
force of attraction is weakest is
(A) Nylon (B) Polyvinyl chloride
(C) Cellulose (D) Natural Rubber

4. OH O O

OH / 
H3C CH CH2 C H ⎯⎯⎯ ⎯→ H3C CH CH C H
Expected mechanism is
(A) E1 (B) E1cb
(C) E2 (D) none

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PART – A: (Multiple Correct Answers Type)


This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

5. KMnO4 / H+ , 
Y
OH
⎯⎯⎯⎯⎯
30% H2SO4
→W + X
(major ) (minor )
OH KMnO4 / H+ , 
Z
Of the 4 compounds listed above, more than one will:
(A) exhibit resonance due to conjugation in their structure
(B) show NaHCO3 test
(C) have a cyclic structure
(D) show 2,4-DNPH precipitation

6. Reductive ozonolysis of agathene dicarboxylic acid gives


H3C COOH

, CHO
H2CO and
O COOH
CH3 CH CH COCH
2 2 3
Which of the following structure(s) can not be of agathene dicarboxylic
(A) H C COOH (B) H C COOH
3 3

CH2 CH2

CH3 CH3
COOH COOH
(C) COOH (D) COOH
H3C H3C

CH2 CH2
COOH COOH
CH3 CH3
CH3 C2H5

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7. Which of the following reaction products give haloform test?


(A) (B) Cl

H O/
HNO ⎯⎯⎯⎯
2
→Q
OH ⎯⎯⎯⎯
2
→P Cl
NH2
(C) O (D) O
+
HO
H3C C OC2H5 ⎯⎯⎯→
3
R
SeO
⎯⎯⎯

2

→S

8.
Cl
⎯⎯⎯⎯⎯
KCN(1 eq.)
→(A) ⎯⎯⎯→
H2 /Pt
B
Cl
Correct statement for product B is
(A) It is gives positive carbyl amine test
(B) It gives coupting reaction with diazonum salt
(C) It gives alcohol on treatment with nitrous acid
(D) It forms dibromo derivative with bromine water

9. CH3
Br CH Ph
(1) Mg, ether
⎯⎯⎯⎯⎯
( 2) Ph − CHO →
( 3 ) H3 O+
N N
H H
The given product cannot be obtained in the above reaction. Identify the correct product obtained.
(A) (B)

N CH Ph N
H HC Ph
OH
OH
(C) OH (D) O
CH C
Ph Ph

N N

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10. NH2
O
+ →P (Product ) . P can not be
⎯⎯
O
H2C
CH3
(A) O O (B) O
HN C CH2 C CH3 HN C CH3

CH3
CH3
(C) NH2 O O (D) NH2 O
C CH2 C CH3

CH3 CH3 O

PART – C: (Numerical Based Type)

This section contains 08 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

P + Br2
1. CH3 CH2 COOH ⎯⎯⎯ → A ⎯⎯⎯
NH3
→ B
( C3H5BrO2 ) C3H8NO2

If dl (  ) mixing of (B) heated then the possible. Number of stereo isomer formed are……….

2. O
C OCH3

HO

⎯⎯⎯⎯⎯
HO
dry HCl( g )
→ ( X )(Major product )

CHO
Degree of unsaturation of ‘X’ is……………..

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3. How many of the following acids are relatively more acidic than acetic acid?
COOH COOH COOH
CH3 OCH3
(A) (B) (C)

Cl
COOH OH
O 2N NO 2
(D) (E) (F) H2CO3

NO 2 NO 2
COOH
OH
I
(G) HCOOH (H) (I)

4. O
C H () i OH−
⎯⎯⎯⎯
(ii) H+ / 
→ ' X'
C CH3
O
Find degree of unsaturation of ‘X’.

Ph O O CH3
| || || |
5. When H − C − C− NH2 , CH3 − C− NH2 and H − C − CONH2 are mixed and reacted with Br2/KOH than
| |
D D
how many 1 amines are obtained.

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6.

N I ⎯⎯⎯
AgOH

→ (A) + tertiary amine
Major hydrocarbon

H+ / H2 O

(D )  + ( C ) ⎯⎯⎯
I /NaOH
2
⎯ (B )

M3 +

Blood red colour


The number of electrons in d-orbitals of M3+ is (where atomic number of M  30 ).

7. How many of the following compounds liberate CO 2 with NaHCO3


OH OH O OH COOH OH
NO2

, , , ,
OH O
OH NO2

8. How many of the following compounds give white precipitate when treated with HIO4 followed by AgNO3
CH2OH H C O H C O H C O CH2OH

CH2 CH2 OH C O CH2 CHOH

CH2OH CH2OH CH3 H C O CH2OH

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PART – A: (Single Correct Answer Type)

This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

x3 + x − 2 x2 + x + 2
1. If f(x) = and g(x) = then (Df represents domain and Rf represents range of f(x))
x3 − 1 x2 + x + 1
 7 4  7
(A) Df = R – { 1 } Rf =  1,  −   (B) Df = R – {1} Rf =  1, 
 3 3   3
 7  7
Dg = R Rg =  1,  Dg = R Rg = 1, 
 3  3
 7  7
(C) Df = R – {1} Rf = 1,  (D) Df = R – {1} Rf =  1, 
 3  3
 7  7
Dg = R Rg = 1,  Dg = R Rg =  1, 
 3  3

2. The value of lim ( x 2 ln ( x cot −1 x ) ) is


x →
1 1
(A) − (B)
3 3
2 2
(C) (D) −
3 3
1
x2 + t2
3. Consider the real valued function y = f ( x ) =  2 − t dt . It represents
0
(A) a parabola with latus rectum ln2 (B) an ellipse with latus rectum ln4
1 1
(C) a parabola with latus rectum (D) an ellipse with latus rectum
ln2 ln2

4. A survey shows that 63% of the Americans like cheese whereas 76% like apples. If x % of the
Americans like both cheese and apples, then
(A) x = 39 (B) x = 63
(C) 39  x  63 (D) none of these

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PART – A: (Multi Correct Answer Type)

This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

5. Let f be a polynomial function satisfying f(x2) – xf(x) = x4(x2 – 1) = 0  x  R+. Then, which of the following
is correct
(A) f is an even function
(B) f is an odd function
f (x)
(C) lim 3 = 1
x → x

 f (x) 
(D) lim  2 − x  exists and is equal to a non-zero quantity
x →
 x 

n2 1! 2! ..... n!
6. If lim =  , where  is a non-zero real number, then
n→ n

3 1
(A)  = (B)  =
4 2
(C)  = e−3/4 (D)  = e−1/2

7. If f(x) is a non-increasing function such that f ( x ) + f '' ( x )  0 x  R & f ( 0 ) = f ' ( 0 ) = 0 then f(x) is not
strictly decreasing in
(A)  −4, −2 (B)  −2,2
(C) 3,4 (D)  2,4

  
8. Let f(x) = 5x tan x + 8 sin(tan x) + 5 ln(cos x), then in the interval  − , 0 
 4 
(A) f(x) is increasing (B) f(x) has a point of local maxima
(C) f(x) has a root (D) f(x) is always negative

Space for rough work

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3n −1 3n

r 
rn rn
9. Tn = , Sn = , then  n  {1, 2, 3, …}
r = 2n
2
+n 2
r = 2n +1 r
2
+ n2
1 1
(A) Tn > ln2 (B) Sn < ln2
2 2
1 1
(C) Tn < ln2 (D) Sn > ln2
2 2

 sec (2)d is equal to


3
10. I=
1
(A) (sec  tan ) + loge sec  + tan  + c
2
1 1
(B) (sec 2  tan 2 ) + loge sec 2  + tan 2  + c
4 2
1
(C) (sec 2  sin 2 ) + loge 4 sec 2  + tan 2  + c
4
(D) none of these

Space for rough work

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SECTION – C (Integer Answer Type)


This section contains 08 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.

1. Let A and B have 3 and 6 elements respectively. What can be the minimum number of elements in
A  B?

x2
(sin t ) dt
2. Lim
x →0  x3
is equal to k, then the value of 3k is _____
0


x3 + 1 x5 − x3
1
3. I1 =  5 dx and I2 =  5 dx , then I1 + 2I2 is equal to ____________
− x + 1 −1 x + 1

1 1  1
4. If f(x) = 3x2 sin − xcos , x  0, f(0) = 0 then the value of f   is _____
x x 

Let f be a continuous and differentiable function in (x1, x2). If f(x) . f(x)  x 1 − ( f ( x ) )


4
5. and
1
lim + ( f ( x ) ) = 1 and lim − ( f ( x ) ) =
2 2
. Then minimum value of  x12 − x 22  is ____________ (where [.]
x → x1 x → x2 2
denotes the greatest integer function)

f  (101)  k 
6. If f(x) = (x – 1)100 (x – 2)2(99) (x – 3)3(98) … (x – n)100, let k = , then  − 97  is ____________
(
f 101 )  50 

 2 2 
7. If k = lim sec −1  −  exist, then the minimum value of [||] is ____________ (where [.] denotes
x →1  ln x x − 1 
the greatest integer function)

8. Let f: A → B be an onto function where A = {1, 2, 3, 4}, B = {x, y, z} also f(1) = x. Let M be total such
M
functions then the value of is ____
2

Space for rough work

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FIITJEE INTERNAL
TEST
PHYSICS, CHEMISTRY & MATHEMATICS
CPT–1 QP CODE: PAPER–2

ANSWERS
PHYSICS (SECTION –I)
PART – A
1. A 2. C 3. A 4. A
5. B, C 6. C, D 7. A, B 8. A, D
9. A, C, D 10. C
PART – C
1. 2 2. 0 3. 9 4. 5
5. 4 6. 0 7. 3 8. 5

CHEMISTRY (SECTION –II)


PART – A
1. B 2. B 3. D 4. B
5. A, C, D 6. A, B, D 7. A, C 8. A, C
9. B 10. B, C, D
PART – C
1. 3 2. 6 3. 7 4. 3
5. 3 6. 5 7. 3 8. 3

MATHEMATICS (SECTION –III)


PART – A
1. D 2. A 3. C 4. C
5. B, C 6. B, C 7. B, C, D 8. A, D
9. A, B 10. B, C
PART – C
1. 6 2. 2 3. 4 4. 0
5. 1 6. 4 7. 1 8. 6

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SOLUTION
PHYSICS
PART – A

1. A
n 
i= =
nr r
Voltage across one cell =  −ir

=  − r = 0
r

2. C
q q 3 q
− =
 0 4 0 4  0

3. A
60 60
T1 = , T2 =
20 15
I
T = 2 ,  = dip angle
MBcos 
60 I
= 2 …(i)
20 MB1 cos30
60 I
= 2 …(ii)
15 MB2 cos 60
From (i) and (ii)
B1 16
=
B2 9 3

4. A
Momentum of both particles are same and in opposite direction as well as they have equal and
opposite charges
mv P
r= =
qB qB
So, r is same for both particles also force on moving charge particle = q(V  B)

5. B, C
0 A
C=
d
If d, C and V
1 Q2
Energy = , so energy 
2 C
2
1 1  Q 
Energy density =  0E 2 =  0   = constant
2 2  A 0 

6. C, D
If inner sphere and outer sphere are connected charge flows to outermost surface of outer sphere.
1 Q2 1 Q2 KQ2
Loss = Ui − Uf = −  =
2 40R 2 40 (2R) 4R

7. A, B
F = i(r  B)  independent of shape of AB if B field is uniform

8. A, D
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i
Current density (J) =
A
eE
and drift speed
m
Also J = E
If A, J and hence E
So, drift speed 

9. A, C, D
W.D. = P.E. due to field
   
= − 0   ( ) = − 0  2
20  2  4 0
A, C are wrong

VB − VA = −
A 0

D is wrong

10. C
The voltage at D and C are equal also voltage at A C B
and B are equal
Current in D A
 6 2
AD = = = = 0.4A F E
3R 3  5 5

PART – C
1. 2

B  d = (8 − 4 − 6)0 = −20

2. 0
2,6

 q(yiˆ + xj)ˆ  (dxiˆ + dyj)ˆ = q(xy)


2,6
W= 3,4
=0
3,4

3. 9
1
U=  2  32 = 9 J
2

4. 5
2Q1 Q2 Q3 Q1 −Q1 Q1 −Q1 Q2 −Q2 Q3 −Q3
+ + =0
C C C
Q2 − Q1 = 4Q and Q3 – Q2 = 2Q
5Q
Solving Q1 = −
2
5Q
 VA − VB = .
2C

5. 4

Consider an elementary cylindrical shell:


 I dr
B = 0 2 r.
2 a
dv = 2rdr . r
1 B2 1   I  r2
2 q
 du = dv =  0 2  ( 2rdr )
2 0 2  2 a   0

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u 0I2
 =
16

6. 0
charge distribution on 3 plates
u2 = 0
(since E is zero between 2nd and 3rd plate) 3Q −2Q 0 3Q
2Q 0

1 2 3

7. 3
 = − qE
qE
= − 
I
qE
=
I
 1 3qE
 f= =
2 2 2m
2 2
  2  2m 2
Here I = 2m   + m   =
3  3  3
Dipole rotates about its center of mass

8. 5
Figure shows potential distribution in steady state A D
VA − VB = 4.2V
6R
VD − VE = 2V 6V (7×6)/10 7R 6×6/18
From the above equation we get –+
VE − VB = 2.2V B
10C
(3×6)/10 3 12
6×12/18

F
C

CHEMISTRY

PART – A

1. O O
NH2 HN C CH3 HN C CH3 NH2 N2 Cl Br

( CH − CO ) O +
⎯⎯⎯ →
⎯⎯⎯⎯⎯ → ⎯⎯⎯⎯ →
Cu
⎯⎯⎯⎯⎯ → ⎯⎯⎯ →
3 2
KBrO3 /HBr H3 O NaNO2
C5H5N  HCl HBr

Br Br Br Br

2. Due to CH2 = CH − stabilization

S  P  R  Q
More steric hindrance
Less hindrance
O
Due to − I of H5C6 C group

4. Its E1cb mechanism

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5. O
O O
C O
H3C CH3
W O
X Y
O O
Z

6. Only (C) justifies the formations of above compounds on reductive ozonolysis.

7. O

P=

Q=
O


R= CH3 COOH + C2H5 OH ; C2H5 OH ⎯⎯⎯⎯⎯⎯⎯
Oxidation by XO
→ CH3CHO
O
O

S=

8.
Cl ⎯⎯⎯
KCN
→ Cl ⎯⎯⎯
H2Pt
→ Cl
Cl CN NH2

9. Br MgBr
⎯⎯⎯⎯⎯→
Mg/ dry ether
()1 Ph − CHO
⎯⎯
→ ⎯⎯⎯⎯⎯
( 2 ) H O+

3

N N N N
H H HC Ph
OH

10. O OH
HN C CH2 C CH2
O
H3C NH2
O
H2C Tautomerise
CH3
O O
HN C CH2 C CH3

CH3

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PART – C

1. CH3
CH3 CH2 COOH ⎯⎯⎯
→ H3C CH HVZ
COOH HC COOH
Br NH2
O H
N 
H3C CH3
N
OH
3 isomer possible

2. O O

C O CH3 C OH

⎯⎯⎯
HCl
→ O CH2
O CH2
HC HC
O CH2 O CH2
(X), degree of unsaturation = 6

3. Except (F) and (I) all are relatively more acidic than acetic acid.

4. O O
C CH3 C CH3
O O
OH
C H CH H − OH +
⎯⎯⎯
OH−
→ ⎯⎯⎯ → H /
⎯⎯⎯ →
C CH3 C CH3

O O
H

5. It is Hofmann’s Bromamide reaction and in this reaction cross over products are not obtained.

6. OH
CH3 CH = CH2 H3C CH CH3 CH3 COO− CHI3 
(A)
(B ) (C) (D )
→ Fe ( CH3 COO )3
3CH3 COO ⎯⎯⎯ − Fe3+

Blood red colour

Fe3+ has 5 unpaired e-.

7. OH O OH COOH
NO2
,
and
OH O
NO2

8. HC O HC O CH2OH

CH2OH , C O , CHOH

CH2OH CH3 CH2OH

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MATHEMATICS

Part − A

1. D
x3 + x − 2  x − 1  x + x + 2  x + x + 2
2 2
f(x) =  f (x) =     = , when x  1
x3 − 1  x − 1   x 2 + x + 1  x 2 + x + 1
 7
Hence range is  1,  .
 3

2. A
 1/ h2 
 tan−1 h 
lim x 2
ln ( x cot −1 x ) 
= lim ln   


x → h →0   h  
 h3 h5 
 h − + − .....  − h
1  tan h  −1
− 1 = lim  
3 5 1
= lim 2  =−
h →0 h  h  h →0 h3 3

3. C
1
x2
y = f (x) = 2−t +c  y = x
2
ln2 + c .
0

4. C
Let A denotes the set of Americans who like cheese and B denote who like apples. Let the population
of Americans is 100. Then,
n(A) = 63 and n(B) = 76.
Now, n(A  B) = n(A) + n(B) − n(A  B)
 n(A  B) = 139 − n(A  B).
But n(A  B)  100, so that n(A  B)  39.
Further, A  B  A and A  B  B imply that n (A  B)  n(A) and n(A B)  n(B) that is
n(A  B)  63 and n(A  B)  76]
Hence, 39  n(A  B)  63  39  x  63.

5. B, C
( ) ( )
f x 2 − xf ( x ) = x 4 x 2 − 1

xf ( x ) − x f ( x ) = x  x  ( x ) − x 
2
2 2 2 2 2
 
f (x ) f (x)
2

= (x ) − x
2
2
− 2 2

x x
f (x )
2
f (x) f (x ) 4

− (x ) = − (x )
2 2
2
2
−x = 2
4
4
.....
x x x
f (x)
 − x 2 = k (has infinite solutions)
x
 f(x) – x3 – kx = 0 has infinite roots
 f(x) = x3 + kx
f (x) f (x)  k 
Hence f is odd, lim 3 = 1 , lim 2 − x = lim  x + − x  = 0
x → x x → x x →  x 

6. B, C
1
ln  = lim [ln 1 + (ln 1 + ln 2) + (ln 1 + ln 2 + ln 3) + .....] –  ln n
n → n2

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1 2 n n ( n + 1)
nln + ( n − 1) ln + ..... + ln + lnn
n + 1 − 2n 1 n n + 1− r r
= lim
n→
n n
n2
n 2 −  lnn = lim
n→ 2n
lnn + 
n r =1 n
ln
n
1
1 3
 =
2
and ln  =  (1 − x ) ln x dx = − 4
0

7. B, C, D
f '(x)  0
 f ( x ) f ' ( x ) + f ' ( x ) f '' ( x )  0
d
dx
( (
f ( x )) + ( f ' ( x ))  0
2 2
)
( )
 f 2 ( x ) + ( f ' ( x ) )  f 2 ( 0 ) + ( f ( 0 ) ) x  0
2 2

 f ( x ) = 0 x  0

8. A, D
  
f(x) = 5x tan x + 8 sin(tan x) + 5 ln (cos x), x   − , 0   f(x) = sec2 x·(5x + 8 cos (tan x))
 4 
  
Now let g(x) = 5x + 8 cos(tan x). So, g(x) = 5 – 8 sin(tan x) sec2 x > 0 in  − , 0 
 4 
   5 5 1 16 − 5
So, g(x) is increasing. So, for x > − , g(x) > g  −  = − + 8cos1  − + 8 = 0
4  4 4 4 2 4
     
So, f(x) > 0. So, f(x) is increasing in  − , 0  . Also at x = 0, LHL = 0. So, f(x) < 0  x   − , 0  .
 4   4 

9. A, B
3
x
Sn <  1+ x
2
2
dx  Tn  n  N.

10. B, C
tan 2 2 tan2 2 sec 2
I=  sec 3 2d =  sec 2 2 sec 2 d =
2
sec 2 −  2
d

tan 2 1
 2I = sec 2 + ln  sec 2 + tan 2 + c
2 2
tan 2 1
I= sec 2 + ln  sec 2 + tan 2 + c
4 4
Part − C
1. 6
A  B will contain minimum number of elements if A  B and in this case n(A  B) = n(B) = 6.

2. 2
d  
x
We know   f(t) dt  = f(x)
dx  0 
x2
(sin t ) dt
Hence Lim  . Let t = u then dt = 2u du
x →0
0 x3
2x sin x 2 sin x 2
 Lim = Lim =
x →0 3x 2 3 x →0 x 3

3. 4
1
(x 5
) (
+ 1 − x3 + 1 ) dx 1 1
x3 + 1
I2 =  x +1 5
=  dx −  x5 + 1 dx
−1 −1 −1

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−1 
x3 + 1 x3 + 1 x3 + 1
1
Again I1 =  5 dx +  5 dx +  x5 + 1 dx
− x + 1 −1 x + 1 1

x3 + 1
1
1
Putting x = in first and third part in I1, we get I1 = 2  5 dx
−1 x + 1
t
I1
 I2 = 2 −
2
 I1 + 2I2 = 4

4. 0
1 1
f(x) = 3x2 sin − x cos
x x
1 1
 f(x) = (3x2 sin − xcos ) dx
x x
1 3 1 1 3  1
f(x) = sin .x −  cos  − 2 x  dx −  x cos dx
x x x  x
1
f(x) = x3 sin + c
x
f(0) = 0 + c = 0  c = 0
1
 f(1/) = 3 . sin + 0 = 0.

5. 1
2f ( x )  f  ( x )
− 2x  0 
d
( )
sin−1 ( f ( x ) ) − x 2  0
2

1− ( f ( x ))
4 dx
Let g(x) = sin–1((f(x))2) – x2 is a non-decreasing function.
 lim + g ( x )  lim − g ( x )
x → x1 x → x2

 
 − x12  − x 22
2 6

 x12 − x 22    x12 − x 22   1.
3

6. 4
100

 ( x − i)
i(101−i )
f(x) =
i=1
100
ln(f(x)) =  i (101 − i) ln ( x − i)
i=1

i (101 − i )
100


1
  f(x) =
(
f x) i=1
( x − i)

f  (101)
100
101 − i
k=
f (101)
=  i  101 − i  = 5050
i=1
 k 
  − 97  = 4.
 50 

7. 1
 2 2 
lim sec −1  − 
x →1  ln x x − 1 
let x – 1 = t  x = t + 1  as x → 1, t → 0
 2 2  −1   
2
t 
lim sec −1  −  = lim sec   − 1 
t →0  ln ( t + 1) t  t →0  t  ln ( t + 1)  
 2 
= lim sec −1  
t →0  2 

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2
  1 |  | 2
2
Hence minimum value of [||] = 1.

8. 6
M
M = 3C1  2! + 3C2  2 = 12  = 6.
2

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