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M Sc-II-Sem III-Safety Material AEPS
M Sc-II-Sem III-Safety Material AEPS
M.Sc. Semester-III
Paper-V: Unit-I
Industrial Safety
(Skill Enhancement Course)
Compiled
By
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C PREFACE
2. Risk Assessment
CLASSIFICATION OF ACCIDENTS
(1) Minor
(2) Moderate
(3) Major
(4) Disaster
Construction work
8. Human-made Accidents.
Sabotage, thefts of critical parts
9 Natural Disasters.
Floods, Lightning, Landslides, Earthquakes, Volcano. Refer Table
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Management’s Responsibility
Objectives include:
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1. Taking care of workers and staff in the event of an accident by
providing fast Treatment and financial assistance and
compensation.
2. 2. Providing environment and surrounding.
3. Welfare.
4. Continuous vigil and improvements.
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PREFACE
To develop the basic understanding and skill about Industrial Safety aspects in
students, “Veer Narmad South Gujarat University (VNSGU)” is introducing
“Industrial Safety & Water Analysis Techniques” topic in syllabus as a part of
Skill Enhancement Course in Master of Science, M. Sc. Chemistry Semester III.
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Syllabus of PDIS is based on the book “Fundamentals of Industrial Safety and
Health”, written by renowned late Shri Dr. K. U. Mistry, Former Chairman of
Gujarat Pollution Control Board and published by Siddharth Prakashan,
Ahmedabad.
The syllabus of PDIS was referred to compile the syllabus for “Industrial Safety”
for M. Sc. Chemistry, 3rd Semester of VNSGU.
We are sure that the contents of this reading material would be useful to
students of the course from academic perspective and enhancing their basic
knowledge on Safety.
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When chemicals are transported by road, by rail, by water (sea, river, channel),
by pipeline, by air, needs to communicate about the hazard to general public and
related authorities, so that in case of any eventuality, concern person can take
appropriate actions.
There are following types of hazards in day to day industrial life needs to
communicate to all concern and control appropriately to prevent from accident:
• Physical Hazard
• Mechanical & Electrical Hazard
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• Chemical Hazard
• Fire & Explosion Hazard
• Heat, Noise, Radiation Hazard
• Ergonomic Hazard
• Biological Hazard
• Environmental Hazard
• Transportation hazard
• Engulfment by liquid or flowing solids Hazard ……….
Other Hazard:
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Biological Hazard Electrical Hazard Asphyxiation / Radiation Hazard
Hazard
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2. Risk Assessment
There is a relation between Hazard & Risk and one must do the detail studies on
Probability, Frequency or likelihood of hazard occurring to estimate the risk.
Accordingly, we should take appropriate control measures. The Risk is the
likelihood or probability of an adverse outcome or event.
There are various types of Risk Assessment and not limited to as explain below:
• Process Safety Risk Assessment
• Static Electricity Risk Assessment
• Chemical Storage Risk Assessment
• Fire & Explosion Risk Assessment
• Industrial Hygiene Risk Assessment (Noise, Illumination, Ventilation,
Ergonomics, Heat Stress,
• Environmental Risk Assessment
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3. Process Safety Management
Employers have a Process Safety Management system in place that follows these
rules and practices for accident prevention:
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• the brief electric shock felt when a person touches a metal object after
walking across a carpeted floor or stepping out of a vehicle
• the crackling and clinging of fabrics as they are removed from a clothes
dryer
The human body is an electrical conductor and can accumulate a static charge if
insulated from ground. To most people, static electricity is simply an annoyance,
but in many industries, particularly those where combustible materials are
handled, static electricity can be quite dangerous as the work environment then
becomes at risk for fires and explosions. For Preventing Fire Hazards, that are
caused by Static Electricity, needs to control by proper earthing / grounding.
For human, Static shock can be unpleasant, but the brief jolt that is felt is
typically not dangerous. However, there may be a situation when the shock
causes a sudden, involuntary reaction that results in a slip, trip or caught-in
injury.
When friction causes a high level of static electricity to build up, the discharge
can cause a fire or explosion if flammable or combustible substances are nearby.
Dry environments are more prone to static build up. Any moisture in the air can
help disperse the static charge on an object.
Ignition hazards from static electricity may be controlled by methods such as:
Static electricity warning and grounding safety signs can alert employees visitors
and remind workers to ensure they are electromagnetically discharged before
handling equipment or entering designated areas. Signs can be placed at points
where static discharge is required.
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5. Industrial Hygiene Risk Assessment
• Repetitive stress injuries: These are caused by performing the same motion
many times throughout the day, which can have a negative impact on joints
and bones.
• Hearing loss: This can occur when employees are exposed to high levels or
high frequencies of noise.
• Poisoning: Toxic chemicals such as pesticides, herbicides, cleaning agents,
and formaldehyde can lead to poisoning when absorbed through the skin.
• Respiratory conditions: Chronic bronchitis, pneumonitis, and asbestosis
can result from exposure to air that contains dust or other contaminants.
• Skin diseases: Rashes, blisters, eczema, and dermatitis may occur when
workers’ skin comes into direct contact with hazardous materials or
chemicals.
• Nonfatal and fatal illnesses: Workers can be exposed to a wide variety of
illnesses in settings such as hospitals and laboratories. Additionally, COVID-
19 is a top concern for most companies whose workers spend extended
periods of time close to one another.
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• For cleaning / housekeeping, use vacuum equipment and avoid the use of
brushes or compressed air for removing dust from clothing, surfaces and
machinery, flooring etc.
• AT last resource, when engineering controls are not possible, provide
PPEs), (Personal Protective Equipment) RPE (Respiratory protection
Equipment),
Needs to have proper medical checkup of the employees to verify the control
measures are suitable or further improvement required.
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6. Fire & Explosion Risk Management (FERA)
Oxygen, heat, and fuel are frequently referred to as the "fire triangle." Add in
the fourth element, the chemical reaction, and you actually have a fire
"tetrahedron." The important thing to remember is: take any of these four
things away, and you will not have a fire or the fire will be extinguished.
The 5 main classes of fires are categorized, how to suppress the fire and type of
fire extinguisher to be used are as follows. In industries there is need to calculate
the fire load, accordingly water storage capacity, fire hydrant system, sprinkler
system, requirement of pumps to be provided. Fire NOC is also required to be
taken from authority.
Freely
Water, ABC/powder, water,
Class A burning
Smothering water mist, foam
combustibles
Non-
ABC/powder, CO2,
Class C Electrical fire conductive
water mist, clean agent
chemicals
Dry powder
Class D Metallic fire Powder
agent
Fire behavior can be characterized as the manner in which a fire reacts to the
interaction of fuel, properties of chemicals, Chemical reaction, Temperature,
pressure, Weather and topography.
• rate of spread,
• fire line intensity,
• flame length, and
• flame height.
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FERA required details of process, type of reactions (Exothermic / endothermic/
Run away reaction), MSDS of chemicals involved in the process and plant
structure, Preventive and protective measures, training, Nitrogen Inertisation etc.
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7. Environmental Risk Assessment
Environment is the basic requirement for survival and sustaining life on earth.
For all organizations, government, Environmental Protection is core philosophy,
is concerned with the protection, promotion and preservation of environment.
ERA differs from EIA by focusing first on environmental conditions, then on the
factors causing changes to these conditions. EIA generally focuses on a specific
project and the nature of its impacts on the environment.
In ERA and EIA five “Rs” are important: Reduce, Reuse, Repair, Rot (Kitchen
wastes), Recycle. Carrying out an ERA involves six steps:
a. problem identification;
b. hazard characterization;
c. exposure characterization;
d. risk characterization;
e. documenting the assessment and implementing precautions; and
f. monitoring at regular intervals. Sustainable Living Alternatives
ERA and EIA depends on the Occurrence Probability, Frequency of Detection and
Nature of Consequences. To arrive at the possibility of impact of our activities on
the Environment, requires proper technical and scientific assessment and
appropriate control measure must be planned to protect environment.
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8. Chemical Storage and Bulk Storage Safety
Chemical Segregation
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Bulk storage of Flammable & Explosive chemicals
Bulk storage terminology is used when the chemicals are stored in the tanks.
Following safety measures are necessary to ensure to avoid any eventuality.
a. Appropriate MOC w.r.t. chemical properties (i.e. SS, MS, PP/FRP, HDPE,
Rubber lines, etc.).
b. Design it for pressure / vacuum depending on the properties and storage
conditions.
c. Provision of level Indicator. (in the flied and parallel to control room).
d. Provide breather valve with Nitrogen purging for flammable chemicals.
Otherwise normal breather valve to avoid Explosion or Implosion.
e. Make provision of Hi level and HI-Hi level audio visual alarm. At Hi-Hi level
pump shall stop to avoid overflow from tank. It shall be rest by authorized
person only.
f. Provide proper loading / unloading station with leakage collection system.
g. Loading unloading operation shall be carried out by trained and authorized
person only.
h. Provide Bund wall / Dyke. Dyke should be at least 110% of the storage
capacity of the tank
i. Provide proper scrubber with scrubbing media to control the gaseous
emissions
j. All electrical installation shall be in line with the requirements of chemical
properties.
k. Make provision for Earthing / grounding and check its continuity regularly.
l. Provide cooling facility for low boiling point chemicals. Provide cryogenic
cooling system for the storage of Ammonia, LPG, Nitrogen and such gases.
m. Make provision of %LEL sensor or specific gas sensor to know the leakage of
the gas from storage tank with audio visual alarm.
n. Provide fire hydrant system and automatic sprinkler system.
o. Provide fence surrounding to tanks as directed by authority
p. Declare the area as “Restricted Entry” with CCTV camera, security guards.
q. Provide emergency gate at other side of the tank farm.
r. Tank farm shall be made Part of Preventive Maintenance Program.
s. Cautionary notices and instructions regarding fire, explosion, health hazard,'
unsafe practices, symbols and colour used on labels.
t. Prohibition of smoking and source of ignition. Notice necessary.
u. Hazard Label, NFPA Diamond to be displayed on the storage tank, Drums,
Carboys, Bags.
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