VGFCD

Sec: JR.
IIT _*CO-SC(MODEL-A) Date: 06-08-23

Time: 3 Hrs Max. Marks: 186
06-08-23_JR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-5_SYLLABUS
PHYSICS: (100% CUMULATIVE)
SYLLABUS COVERED FROM 22-04-23 TO 05-08-23
CHEMISTRY: (100% CUMULATIVE)
MATHEMATICS: (100% CUMULATIVE)

Narayana IIT Academy 05-08-23_JR.STAR CO-SC(MODEL-A)_JEE-ADV_CAT-5_QP
Time: 3 Hrs IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 1 – 6) 3 -1 6 18
Choice
Questions with Multiple Correct
Sec – II(Q.N : 7 – 14) 4 -2 8 32
Choice (Partial Marking +1)
Questions with Comprehension
Sec – III(Q.N : 15 – 18) Type 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62
CHEMISTRY:
Sec – I(Q.N : 19 – 24) 3 -1 6 18
Choice
Sec – II(Q.N : 25 – 32) 4 -2 8 32
Sec – III(Q.N : 33 – 36) Type 3 0 4 12
Total 18 62
MATHS:
Sec – I(Q.N : 37 – 42) 3 -1 6 18
Choice
Sec – II(Q.N : 43 – 50) 4 -2 8 32
Sec – III(Q.N : 51 – 54) Type 3 0 4 12
Total 18 62
JR.IIT_*CO-SC Page. No. 2

MATHEMATICS Max. Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. The number of integers x for which x 2  19 x  92 is a perfect square is
A) 2 B) 3 C) 4 D) 1
2. The number of real values of a such that the equation ax 2  5 x  2  0 has exactly one
solution is
A) 1 B) 2 C) 5 D) 0
1
3. Let a be a given real which is not equal to 0,1, 1, 2 or .Then the number of real roots of
2
x  x  1 a  a  1
2 3 2 3
 is
x 2  x  1 a 2  a  1
2 2
A) 2 B) 4 C) 6 D) 0
4. Let x, y are arbitrary reals and the maximum value of

 x  y 1  xy  is k . Then
1  x 1  y 
2 2
D) 2k   0, 
1
A) 4k   0,1 B) 8k   0,3 C) k 4   0,1
 2
2a  3b  2c  13
a  2b  3d  4

5. Consider the system of equations 
3a  c  7 d  7
2b  3c  4d  0
Then the value of a  b  c  d is equals to
11 17
A)10 B) C) 5 D)
3 3
6. In a 4  4 matrix(not all elements are same) the sum of elements of each row, each
column and both the diagonals is  . Then the sum of four corner elements is equal to
A) 2 B) 4 C) 8 D) None

SECTION-II
(Multiple Correct Answer Type)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
7. Which of the following statements are not incorrect ?
A)If Am n , Bn  m are two matrices such that m  n . Then det  AB   0
B) If An  n is nonsingular matrix and Bn  n , Cn  n are two distinct matrices. Then AB and

AC are also distinct
C) If An  n , Bn  n , Cn  n are 3 matrices such that AB  AC then B  C can be true.
D) If An  n , Bn  n , Cn  n are 3 matrices and if B  C then always AB  AC
8. Which of the following are not incorrect ?
A) If An  n be a matrix n  2 . Then det  adj A   A n 1 only if A  0
B) If An  n be a matrix n  2 . Then det  adj A   A n 1
C) If An  n be a matrix n  2 . Then det  adj A   A n 1 is not necessarily be true.
D) If An  n be a matrix, Bn  n be a non-null matrix such that AB  O  null matrix  . Then
A 0
Let x, y are reals such that 16 x  y  16 x  y  1 . Then

2 2
9.
A) x  y  1 B) x  3 y  2
C)  2 x 2 y is a +ve number D)  8 y 4 x is a prime
10. Let a, b are two fixed given real numbers. Let
E  a 2 cos2 x  b2 sin 2 x  a 2 sin 2 x  b2 cos2 x be an expression in x , x  R(set of reals).
Then
A) Range of E when a  3, b  4 is 7,5 2 
B) Range of E when a  3, b  4 is 1,5 2 
C) Range of E when a  3, b  4 is  1,5 2 
D) Range of E when a  3, b  4 is 7,5 2 

11. Let n  N ( set of natural numbers) and f (n)  1! 2! 3!   n !be an expression in n such
that f (n  2)  P(n) f (n  1)  Q(n) f (n), n  1 then
A) P(n) has n coefficient as 1 B) P(n) has constant term as 3
C) Q(n) has n coefficient as 1 D) Q(n) has constant as 2
cos   3  sin   3 
12. If   m   0  . Then
cos3  sin 3 
2m 4  9m 2  8 2  m2
A) cos 2  B) cos  
m2 m
2m 4  9m 2  8 2  m2
C) cos 2  D) cos  
m2 m
a
If the least positive angle satisfying sin 3 x  sin 3 2 x  sin 3 3 x   sin x  sin 2 x  sin 3 x  is
3
13.
b
a, b  N  set of naturals  . Then
A) Least value of a  b is 12 B) Least value a  b is 7
C) Least value a  b is 10 D) Least value a  b is 35
14. Let A  1, 2, 3, 4 ,5. Consider the following statements
i) 3, 4  A ii) 3, 4  A iii) 3, 4  A
iv) 1 A v) 1  A vi) 1, 2,5  A
vii) 1, 2,5  A viii) 1, 2,3  A
ix)   A,  where  stands for null set  x)   A  where  stands for null set 
xi)   A  where  stands for null set 
The number of incorrect statements is
A) 6 B) 5 C) 7 D) None of these
SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph for Questions 15 and 16:
Let Ann , Bnn are two square matrices, I nn be identity matrix
15. Consider the following list of statements

i) If A  B  AB then A, B are commutative
ii) If A, B are distinct and A3  B3 , A2 B  B 2 A then A2  B 2  0 . Which of the following
are correct ?
A) (i) is true (ii) is true B) (i) is true (ii) is false
C) (i) is false (ii) is true D) Both (i), (ii) are false
16. If A  I , B  I such that AB  BA , and A10  B10 is invertible also
A12  B12  A11  B11  A10  B10 . Then
A) I  A is nonsingular B) I  B is nonsingular
C) A  B  AB  I D) AB   A  B   I

a1 x  b1 y  c1 z  d1
Consider the system a2 x  b2 y  c2 z  d 2
a x  b y  c z  d in x, y, z
 3 3 3 3
Where ai , bi , ci , di , i  1, 2,3 are given real constants. Also

a1 b1 c1 d1 b1 c1 a1 d1 c1 a1 b1 d1
  a2 b2 c2 , 1  d 2 b2 c2 ,  2  a2 d 2 c2 ,  3  a2 b2 d 2
a3 b3 c3 d3 b3 c3 a3 d3 c3 a3 b3 d3
17. Consider the following statements

1) The system has unique solution if and only if   0
2) The system has infinity many solutions if and only if   0, 1   2   3  0
3) The system has no solutions if and only if   0, and 1   2   3  0
4) The system has non trivial solution if and only if   0
The number of incorrect statements is
A) 3 B) 2 C) 1 D) 0
2 x  py  6 z  8
18. Consider the system  x  2 y  qz  5 . Then
 x  y  3z  4

A) If p  2, q  3 system has solutions

B)If p  2, q  3 system has unique solutions
C) if p  2, q  3 system has no solution
D) None of the above

PHYSICS Max. Marks: 62
SECTION-I
19. Two blocks of masses M = 10 kg and m = 5 kg are kept on a smooth horizontal surface
connected by a massless string. The block of mass M is pulled using another light string.
This string has a light spring balance attached to it. The pull force(as indicated by the
spring balance in steady state) is F = 30 N at an angle   600 to the horizontal. Find the
tension (in N) in the string connecting the two blocks at the given instant.
A) 5 B) 10 C) 15 D) 20
20. A block of mass M = 2 kg is kept on a smooth incline having inclination angle   300 .
Find the vertical force F (in N) that must be applied to prevent the block from
accelerating. (Take g  9.8 m / s 2 )
A) 20.0 B) 9.8 C) 19.6 D) 40.0
21. Particle is moving along path y  x 2 in x  y plane with constant speed of 1 m/s. What
will be its magnitude of acceleration when it is at x  0 . (Assume all the units are in SI)
A) Zero B) 2 m / s 2 C) 20 m / s 2 D) 200 m / s 2

22. Consider two steamers A and B on a calm sea. Steamer A is moving towards the north
with a constant speed VA  30 km / h and steamer B towards the south with a constant
speed VB  10 km / h . If smoke ejected by steamer A spreads in a straight line from the
steamer (with respect to steamer) towards the west and smoke ejected by steamer B
spreads in another straight line from the steamer(with respect to steamer) towards the
north-west, determine magnitude of the wind velocity.(Ignore upward motion of smoke)
A) 30 kmph B) 40 kmph C) 40 2 kmph D) 50 kmph
23. A ball of mass m is suspended from the ceiling with the help of an elastic cord. An
additional downward force applied on the ball, if increased gradually to a value F0 , the
cord would break. What should be the additional minimum constant force F that will
break the cord ?
1 1
A) F  F0 B) F  F0  mg
2 2
1 1
C) F   F0  mg  D) F   F0  mg 
2 2
24. A block of mass m = 6 kg sits on a plank of mass M = 10 kg which lies on a smooth

surface. The coefficient of friction between the block and the plank is   0.5 . At t = 0,
a time dependent force F = 2t starts to act on the plank (t is in seconds). If the block
starts to slip on the plank at n seconds, then find the value of 'n' ? (Take g  10 m / s 2 )
A) 10 B) 20 C) 30 D) 40

SECTION-II
25. Two swimmers are moving towards each other. First swimmer is going in downstream
while second is going in upstream. The velocity of first swimmer in still water is 2 ms 1
and that of second one in still water is 6 ms 1 . The river flow velocity is 1 ms 1 . When
they are 100m apart, a butterfly which can fly with a speed of 10 ms 1 starts flying
from nose of first swimmer. On reaching over the nose of second swimmer, it flies
directly back to first and so on. Then, which of the following statement(s) is/are
correct?
A) The butterfly makes infinite number of trips, before the swimmers meet.
B) The butterfly travels a distance 125 m during swimmers approach each other.
C) The butterfly travels infinite distance during swimmers approach each other.
D) The butterfly travels a distance of 250m during swimmers approach each other.
26. Two cars are travelling on a straight road. The car C1 is going at a constant speed of
9ms 1 . Ahead of C1 is the car C 2 which is at rest. C 2 starts moving with an
acceleration of 1ms 2 when the separation between the cars is 40m. Four graphs have
been drawn characterizing the motion.
A) The graph correctly representing the speeds of the two cars with time is 1.
B) The graph correctly representing the speeds of the two cars with time is 2.
C) During their motion, the car C1 overtakes the car C 2 , but soon C 2 overtakes C1 .
D) During their motion, the car C1 overtakes the car C 2 , and then C 2 cannot overtake
C1 .

27. The direction of velocity of a particle at time t = 0 is as shown in the figure and
has u  20 ms 1 . The acceleration of particle is always constant and has magnitude
10ms 2 . The angle between its initial velocity and acceleration is 1270
 3
 take sin37   . Then find correct options among the following.
0
 5
A) The instant of time at which acceleration and velocity are perpendicular is 0.6s.
B) The instant of time at which speed of particle is least is 1.2s.
C) The instant of time t at which acceleration of particle is perpendicular to its
displacement(displacement from t = 0 till that instant t) is 2.4s.
D) The instant of time at which acceleration and velocity are perpendicular is 1.2s.
28. The reading given by weighing machine as shown in the figure is half of the weight of
the man. The mass of man is 60 kg, mass of weighing machine is 20 kg and mass of lift
is 30 kg (pulley is smooth and string is massless). (Take g  10 m / s 2 ).
A) The force exerted by the man on the string is 6600 Newton

B) The force exerted by the man on the string is 3300 Newton
C) The magnitude of acceleration of man is 50 m / s 2
D) The magnitude of acceleration of lift is 110 m / s 2

29. A uniform rope of length 10m and mass 20 kg lies on a smooth frictionless inclined
plane. A force of F = 200 N is applied as shown in the figure. (Take g  10 m / s 2 )
A) The tension (in N) in the string at 2m from end A is 40
B) The tension (in N) in the string at 2m from end A is 20
C) The acceleration of rope is zero
D) The acceleration of rope is 5m / s 2

30. A particle of mass m is kept on a fixed, smooth sphere of radius R at a position, where
the radius through the particle makes an angle of 300 with the vertical. The particle is
released from this position
3
A) the force exerted by the sphere on the particle just after the release is mg
2
1
B) the force exerted by the sphere on the particle just after the release mg
2
C) angle made by radius vector of the particle with vertical just before it leaves contact
 1 
with the sphere is   cos 1  
 3
D) angle made by radius vector of the particle with vertical just before it leaves contact
2
with the sphere is   cos 1  
3
31. A bead of mass ‘m’ is connected at one end of an inextensible massless string. The other
end of the string is attached to a fixed cylinder as shown in figure The system is kept on
a smooth horizontal surface. An initial speed V is given to the bead perpendicular to the
string. Bead moves on a curve and collides with the cylinder after some time. Then,
before it collides.(Neglect the effect of gravity)

A) Tension in the string remains constant during motion.
B) work done by string on bead is zero
C) acceleration of bead remain constant in magnitude
D) Kinetic energy of bead remains constant
32. In the arrangement shown in the figure end A of the string is being pulled with a
constant horizontal velocity of 6 m/s. The block is free to slide on the horizontal surface
and all string segments are horizontal.
A) Speed of point P on the thread is 2 m/s

B) Acceleration of point P on the thread at the moment shown is 2 m / s 2
C) Velocity of block is 2 m/s
D) Acceleration of block is 2 m / s 2
SECTION-III
(Paragraph Type)
In the Atwood machine shown in the figure, two bars have lengths 2m and 4m. Their
masses are 4kg and 1 kg respectively. (Take g  10 m / s 2 )

33. The bars are held with the lower edge of 4kg bar at the same horizontal level as the
upper edge of the other bar. If the system is released from this position, the time required
for the bars to cross each other will be ____
A) 0.5sec B) 1sec C) 1.5sec D) 2sec
34. The 1 kg bar is being pulled down with a constant speed of 2ms 1 and it is released
when its upper edge is at the same level as the lower edge of 4kg bar. Time after which
the bars cross each other from moment of release will be _____
 10  1   10  1   10  1   10  1 
A)  s B)  s C)  s D)  s
 3   3   2   2 

A man stretches a horizontal spring of spring constant k attached to the front wall of a
railway carriage with uniform velocity v relative to carriage. Carriage is moving in same
direction as stretching with uniform speed ‘u’. In ground’s frame of reference
35. Work done by man on spring in time t is
1 1
A) k v v  u t 2 B) k v v  u t 2
2 2
1 1
C)  k v  v  u  t 2 D)  k u vt 2
2 2
36. Work done by trolley on spring in time t is
1 1
A) k v v  u t 2 B) k v v  u t 2
2 2
1 1
C)  k v  v  u  t 2 D)  k u vt 2
2 2

CHEMISTRY Max. Marks: 62
SECTION-I
37. When certain amount of propane is burned in air 0.1 mol. of CO2 is produced. How
many drops of water will be formed if one drop of water contains 2  1022 molecules of
H 2O . Given reaction yield is 50%. .  N A  6  1023 
A) 3 B) 4 C) 2 D) 6
38. If for a first order reaction t90%  X t1/ 2 , t99%  Y t1/ 2 , t99.9%  Z t1/ 2 . Then calculate value of

 log 2  0.3 .
YX
A) 1 B) 2 C) 3 D) 4
39. The ratio of RMS speed of methane at T, K and SO2 at 300 K is 4 : 1. If total kinetic
energy of 80 g of that CH 4 is X Kcal., then value of X / 6 is
A) 4 B) 2 C) 1 D) 3
t0.875
40. The value of for nth order reaction (n  1) is
t0.5
8n 1  1 4n 1  1
A) 22 n2 B) 22 n1 C) D)
2n 1  1 2n 1  1
41. Wavelength of radiation emitted when an electron jumps from energy level A to energy
level C is 2000 A0 and it is 3000 A0 , when electron jumps from energy level B to energy
level C. Then wavelength ( A0 ) of radiation emitted when an electron jumps from energy
level A to energy level B is 1000 x . What is x.
A) 8 B) 6 C) 9 D) 5
42. In silicate mineral Na2 Fe5 (OH )2 Si8 O22 total number of Fe2  x and total number of
Fe 3  y . Find value of x / y .
A) 0.66 B) 3 C) 1.5 D) 2
SECTION-II
43. Two identical containers each of volume V are joined by a small pipe of negligible
volume. The containers contain identical gases at temperature T and pressure P. One
container is heated upto temperature 2T. While maintaining the other at same
temperature, then identify the correct statements.

A) Final pressure of the gas in each container is 2P
4P
B) Final pressure of the gas in each container is
3
2 PV
C) Final number of moles of gas in container at temperature 2T is
3RT
4 PV
D) Final number of moles of gas in container at temperature T is
3RT
44. Decomposition of Ag follows first order kinetics according to the reactin Ag  2 Bg  Cg .
If initial pressure of Ag is 10 atm and total pressure after 70 sec is 20 atm, then
 n 2  0.7 
A) Rate constant of reaction is 0.01 sec1 M
B) Partial pressure of B at 70 sec is 10 atm
C) Partial pressure of C at 140 sec is 7.5 atm
D) Initial rate of reaction is 0.1 atm/sec
45. Select correct statements from the following
A) For ideal gas in isobaric process dU  nCV dT
B) For real gas in isochoric process dU  nCV dT
C) For the reaction A  Ag at constant T & P, dU  0
D) Heat capacity is a state function
46. Select the correct options.
 f H 0  heat of formation  c H 0  heat of combustion
 a H 0  heat of atomization   Bond dissociation enthalpy
A)   f H 0  H    a H 0  H B)   c H 0 C , graph    f H 0 CO
g 2g 2g
C)   c H 0 C H4 g
 2 f H 0 
H 2O
D)   a H 0  H  H  H
2 2g
47. Based on following diagram select correct statements for ideal gas starting from A in
adiabatic expansion process.
A) AB is adiabatic isothermal and WAB  WAC

B) AD and AE may be irreversible adiabatic process
C) If AD is adiabatic single stage then AF may be two stage adiabatic process
D) WAC  WAE (where AE = irreversible adiabat)
48. In a container Ag and Bg are initially at 1 bar pressure each and following equilibrium is
established Ag  Bg  2Cg . At equilibrium mole fraction of C is 0.25, then identify the
true statements.
A) The equilibrium constant of the reaction is 0.44.
B) The total pressure of the system after 20 sec is 2 bar.
C) Partial pressure A and B together is 1.75 atm
D) Decreasing the volume of container favours the formation of Cg
49. Which of the following orbitals have non-zero value for number of angular nodes.
A) 3 s B) 2 Px C) 3d Z 2 D) 4 Py
50. In which of the following cases the pH is almost independent of dilution.
A) aq NaCl B) aq NH 4 CH 3COO 
C) aq CH 3COOH  aq CH 3COO  Na  D) aq HCl
SECTION-III
(Paragraph Type)
One mole of liquid ‘A’ and two moles of liquid B are mixed at 270 C to form an ideal
binary solution.
 u 2  0.7, n3  1.1
51. The value of  H mixing is ______ k.cal/mole.

A) 0 B) + 0.7 C) 1.1 D) 1.8
52. The value of  Gmixing is ______ cal/mole (approx)
A) 0 B) + 1140 C) 1140 D) 380
The solubility product of AgCN is 1016 and the formation constant of Ag (CN )2 is
1.5  1017 .
53. The solubility of AgCN in 0.02 M-KCN solution assuming no complex formation is
A) 108 M B) 5  1015 M C) 0.02 M D) 5  1014 M
54. The solubility of AgCN in 0.02 M KCN solution assuming complex formation to happen
is
A) 0.3 M B) 0.02 M C) 1.33  1019 M D) 1.87  102 M

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Sec: JR.

IIT _*CO-SC(MODEL-A) Date: 06-08-23

PHYSICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 05-08-23

CHEMISTRY: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 05-08-23

MATHEMATICS: (100% CUMULATIVE)

SYLLABUS COVERED FROM 22-04-23 TO 05-08-23

JR.IIT_*CO-SC Page. No. 2

4. Let x, y are arbitrary reals and the maximum value of

Then the value of a  b  c  d is equals to

JR.IIT_*CO-SC Page. No. 3

B) If An  n is nonsingular matrix and Bn  n , Cn  n are two distinct matrices. Then AB and

C) If An  n , Bn  n , Cn  n are 3 matrices such that AB  AC then B  C can be true.

D) If An  n , Bn  n , Cn  n are 3 matrices and if B  C then always AB  AC

8. Which of the following are not incorrect ?

A) If An  n be a matrix n  2 . Then det  adj A   A n 1 only if A  0

B) If An  n be a matrix n  2 . Then det  adj A   A n 1

C) If An  n be a matrix n  2 . Then det  adj A   A n 1 is not necessarily be true.

D) If An  n be a matrix, Bn  n be a non-null matrix such that AB  O  null matrix  . Then

Let x, y are reals such that 16 x  y  16 x  y  1 . Then

C)  2 x 2 y is a +ve number D)  8 y 4 x is a prime

10. Let a, b are two fixed given real numbers. Let

E  a 2 cos2 x  b2 sin 2 x  a 2 sin 2 x  b2 cos2 x be an expression in x , x  R(set of reals).

B) Range of E when a  3, b  4 is 1,5 2 

C) Range of E when a  3, b  4 is  1,5 2 

D) Range of E when a  3, b  4 is 7,5 2 

JR.IIT_*CO-SC Page. No. 4

15. Consider the following list of statements

Paragraph for Questions 17 and 18:

Where ai , bi , ci , di , i  1, 2,3 are given real constants. Also

17. Consider the following statements

A) If p  2, q  3 system has solutions

JR.IIT_*CO-SC Page. No. 6

A) 20.0 B) 9.8 C) 19.6 D) 40.0

JR.IIT_*CO-SC Page. No. 7

A) 30 kmph B) 40 kmph C) 40 2 kmph D) 50 kmph

24. A block of mass m = 6 kg sits on a plank of mass M = 10 kg which lies on a smooth

JR.IIT_*CO-SC Page. No. 8

9ms 1 . Ahead of C1 is the car C 2 which is at rest. C 2 starts moving with an

JR.IIT_*CO-SC Page. No. 9

A) The force exerted by the man on the string is 6600 Newton

JR.IIT_*CO-SC Page. No. 10

A) The tension (in N) in the string at 2m from end A is 40

B) The tension (in N) in the string at 2m from end A is 20

C) The acceleration of rope is zero

D) The acceleration of rope is 5m / s 2

JR.IIT_*CO-SC Page. No. 11

A) Speed of point P on the thread is 2 m/s

JR.IIT_*CO-SC Page. No. 12

A) 0.5sec B) 1sec C) 1.5sec D) 2sec

Paragraph for Questions 35 and 36:

35. Work done by man on spring in time t is

36. Work done by trolley on spring in time t is

JR.IIT_*CO-SC Page. No. 13

JR.IIT_*CO-SC Page. No. 14

A) AB is adiabatic isothermal and WAB  WAC

51. The value of  H mixing is ______ k.cal/mole.

JR.IIT_*CO-SC Page. No. 16

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