Sundararaj Et Al. 2022 Groundwater Contaminant Transport Modeling Using VMF-V.4.2

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Arabian Journal of Geosciences (2022) 15: 1538

https://doi.org/10.1007/s12517-022-10804-0

ORIGINAL PAPER

Groundwater contaminant transport modeling using Visual


MODFLOW: a case study of corporation sewage farm in South Madurai,
Tamil Nadu, India
Chandran Sundararaj1   · Kaarmegam Muthukaruppan2 · Dhanasekarapandian Mariappan3   ·
Kumar Veluswamy4 

Received: 22 February 2022 / Accepted: 2 September 2022 / Published online: 16 September 2022
© Saudi Society for Geosciences 2022

Abstract
The groundwater movement and pollutant transport model help study the movement of pollutants in the subsurface environ-
ment. The study area, Avaniyapuram sewage farm (ASF-156 ha), has been receiving wastewater for fodder grass and vegetable
cultivation for the past eight decades from Madurai city. The conceptual groundwater flow modeling was developed for ASF
and simulated for an area of 152 k­ m2 (10,000 m × 15,200 m) in the weathered portion of a three-layered unconfined aquifer
system using Visual MODFLOW v.4.2. Forty pumping wells and ten observation wells were considered for modeling. The
mass transport modeling was performed on contaminant plume for total dissolved solids (TDS) and nitrate (­ NO3) contaminant
plume, with three scenarios and runs for 5, 10, and 15 years for future prediction. The model was calibrated from 2014 to
2018 and validated with 2019 data using steady-state and transient flow conditions. The results showed that the ­NO3 plume
concentration was within the permissible limit (45 mg/l) up to 3 km in the study area. However, after 10 and 15 years, the
­NO3 plume extended up to 4.5 km northeast, and a maximum N ­ O3 concentration of 90 mg/l was observed. The simulation
also showed that the TDS plume concentration ranging from 500 to 1500 mg/l was seen in the study area’s southwest and
northwest direction. The TDS values were high in northeast and southeast zone wells, especially near ASF at a 2.5 km
circle. The TDS concentration of 3000 mg/l was predicted at 5.5 km in 15 years. Our study clearly showed that distance,
direction, and slope played a significant role in the groundwater pollution in and around the corporation sewage farm.

Keywords  Visual MODFLOW · TDS · NO3 · Avaniyapuram sewage farm

Introduction and Knop 2015; Khadri and Pande 2016). Rapidly increas-
ing urbanization will multiply the magnitude of problems,
Urban sprawl has increased over the last three decades and such as groundwater depletion, waterlogging, the vanishing
will continue in the developing countries with an increase of wetlands, water pollution, and increasing salinity levels,
in size and density (Cohen 2006; Seto et al. 2012; Turrini affecting the overall quality of urban life (Tian et al. 2011;
Suhag 2016). Decision-making on sustainable water resource
Responsible Editor Broder J. Merkel management requires knowledge about groundwater–surface
water interaction and its uses within the ecosystem (Abdulla
* Chandran Sundararaj and Al-Assa’d 2006; Zagonari 2010; Zhou and Li 2011).
schandran@tce.edu
Groundwater overexploitation and contaminants of emerging
1
Department of Civil Engineering, Thiagarajar College concern are a menace to ecological services, human health,
of Engineering, Madurai, Tamil Nadu 625015, India and sustainable socio-economic growth (Li 2020; Li and Wu
2
Centre for Water Resources, Anna University, Chennai, 2019). Numerical modeling is helpful for predicting, man-
Tamil Nadu, India aging groundwater resources, and recommending suitable
3
Public Works Department, Environmental Cell Subdivision, groundwater pollution remediation. Groundwater modeling
Tirunelveli, TN, India using MODFLOW can replicate the flow and transport pro-
4
Department of Agricultural Engineering, ACRI – TNAU, cesses with towering effectiveness (Bredehoeft and Kon-
Madurai, India ikow 2012; Chiang 2005; Singhal and Goyal 2011). Based

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1538 Page 2 of 15 Arab J Geosci (2022) 15: 1538

on certain simplifying assumptions, including flow direction, contamination levels. The specific objective of this study is
aquifer geometry, and bedrock heterogeneity or anisotropy, (1) to develop a conceptual model in and around the Avani-
groundwater models explain the water flow and contaminant yapuram sewage farm based on the borehole logs, periodic
transport using numerical equations (Koda 2012; Lagudu monitoring of wastewater concentration, and periodic field
et al. 2013; Surinaidu et al. 2014; Rapantova et al. 2017). measurements of water level data, and (2) to perform a mass
Several researchers have used MODFLOW for groundwa- transport modeling on contaminant plume for total dissolved
ter modeling with various hydrogeological conditions and solids (TDS) and nitrate ­(NO3) with three scenarios.
executed groundwater contaminant transport modeling of The novelty of this study is to predict the TDS and ­NO3
surface and subsurface water interaction (Ritter et al. 2002; plume concentration due to the reuse of sewage for agri-
Panagopoulos 2012; Hogeboom et al. 2015; Saleem et al. culture which has been practiced near Madurai city for the
2018). The stages of contaminant transport modeling include past 95 years and to predict the contaminant movement
developing a conceptual model, model calibration and vali- for different management strategies of southern part of
dation, sensitivity analysis, and potential prediction for the Madurai, keeping the Avaniyapuram sewage farm (ASF) as
future (Wagner 1992; Mohamed 2018). the epicenter.
Visual MODFLOW application started in 1994 with
various applications of this software to study and develop
contaminant transport modeling (Dufresne and Drake 1999;
Scanlon et al. 2003; Tait et al. 2004; Mondal and Singh Study area
2005; Abdulla  and Al Assa’d 2006; Liu and Pan 2009;
Sarvarian et al. 2010; Wang et al. 2013; Parameswari and The study area is near Madurai, in the southern part of Tamil
Mudgal 2015; Baharuddin et al. 2016). Visual MODFLOW Nadu and one of the ancient cities of India and has one of
is the most insightful and powerful graphical interface that the oldest, systematic wastewater collection and disposal
combines MODFLOW, MODPATH, and MT3D (modular systems in the world. The city is divided into the north
three-dimensional transport model) and helps in assembling and south zones by the River Vaigai, which is a seasonal
a data set graphically for a three-dimensional groundwater river occasionally carrying fresh water, otherwise only city
flow and contaminant transport model (McDonald and Har- wastewater. The sewerage system was initially established
baugh 1988; Zhou and Li 2011; Anon 2000; Selvakumar as early as in 1924 in South Bank. The collected wastewa-
et al. 2017). The run module within the Visual MODFLOW ter is pumped to Avaniyapuram, where a sewage farm was
helps the user modify the various MODFLOW, MODPATH, established for the reuse of wastewater.
and MT3D parameters and run the model. The output The sewage farm under this investigation (Fig.  1)
module lets the user to exhibit all the simulation outputs is located with the latitude 9°52′29″N and longitude
of MODFLOW, MODPATH, and MT3D (Hariharan and 78°05′52″E. This study area was selected since the treated
Uma Shankar 2017; Mohamed 2018). Nevertheless, another and untreated sewage collected from the villages within a
advantage of this software is that it is user-friendly; ensures 5 km radius converge here. The wastewater irrigated area
good generalization capability; elucidates binary output is in the Ayan Pappakudi village (Saravanan et al. 2011;
files by creating color/contour maps; and helps in analyz- Prabhakaran et al. 2021) functioning from 1924 with 156 ha.
ing and interpreting the model results. Furthermore, with The cultivable land is 88 ha (area of Guinea grass cultiva-
the versatility of the software, the user can evaluate vari- tion 75 ha and vegetables 13 ha), with an annual produc-
ous scenarios that may occur in the future and understand tion of Guinea grass at 7398.17 tons. The farm has two
contaminant movement. With comprehensible visualization lagoons with a capacity of 13.62 million l/d and a size of
methods, complex situations can be effectively simulated 95 m × 95 m × 2.5 m. This farm is an outlet for the waste-
and incite support to do more studies with the Visual MOD- water collected from the Madurai corporation south zone.
FLOW software. Madurai south zone comprises seven sub-pumping stations
Avaniyapuram sewage farm (ASF) has been functioning and the main pumping station at Santhaipettai. These seven
since 1924, and it was constructed for sewage management sub-pumping stations are located at different places in the
in South Madurai. Due to the continuous use of sewage in the city, and the sub-pumping stations collect the sewage gen-
farm, which is rich in organic matters (CWR 2004), ground- erated in the fully and partially sewered wards. The waste-
water is getting polluted in the nearby vicinity (Saravanan water collected through oval-shaped conduit pipes in their
et al. 2011; Natesan and Keerthy 2012; Prabhakaran et al. respective areas is pumped to the central pumping station,
2021), and there have been no simulation studies assessing which was provided with modern gadgets to discharge sew-
groundwater contamination levels. The present case study age efficiently. In addition to this collection, there are many
aimed to assess groundwater contamination and predict sewage-carrying ditches in the Madurai South Zone (Sup-
groundwater quality parameters, temporal variations, and plementary Fig. 1).

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Fig. 1  Aerial view of Avani-


yapuram sewage farm

It is estimated that 50 million liters of untreated waste- soil; (ii) deep red soil; (iii) red sterile soil; (iv) laterite soil;
water per day is collected from Madurai city. A portion of (v) black soil; and (vi) red sandy soil. The Vellaikal village
the sewage (around 50%) is sent to Avaniyapuram sewage on the northern side and a chain of tanks on the southern
farm, 8 km away from the central pumping station. Due to side bound the study area. The western side is a continua-
the pumping capacity’s inadequacy, the pumping station tion of the foothills of the Thirupparankundram hills. The
cannot cope with the flow, and the rest of the sewage is let sewage water, after irrigating the farm, can only flow east.
into the ditches. The sewage farm also receives water from Furthermore, sewage effluent flows on shallow soil, as the
Kalamkari, a sewage carrier from the city. The mean annual rock strata are within 3 m of the ground surface. The sewage
average rainfall for 31 years was calculated as 832.76 mm. water flows south in the farm, and its return flow is collected
Geographically, the study area is underlain with hard at the outlet of the French drain system, which is diverted
rock strata and comprises six soil types, viz., (i) thin red east. However, the quality of water wells could represent

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sewage contamination caused by sewage flow from the city Scenario III: continuing irrigation with treated wastewa-
and might not exclusively be because of sewage farming. ter and the tanks are renovated and filled up with rain water.
The shallowly buried pediments are distributed all around
the sewage farm.
Model calibration

This task discusses modifying the model input parameters to


Methodology
matchup with the field conditions regarding observed head
and concentration. Model parameters were changed until the
Data collection
simulation results correlate with observed data within a pre-
established error range.
Data on borehole details, well details, hydraulic conduc-
The necessity to calibrate the model originates from the
tivity, porosity, lithology, storability, and transmissibility
uncertainty in parameter values because of assumptions and
values were collected from the Public Works Department
simplifications of conceptual and mathematical models.
(PWD), Central Groundwater Board (CGWB), and Madurai
Before using a model for any projections or decision valida-
Corporation. The time series rainfall and groundwater level
tion, it should be calibrated to demonstrate that it stimulates
data were obtained from 2000 to 2019 from PWD. The
the groundwater behavior acceptably. In MODFLOW, aqui-
toposheets of Madurai districts, Google Maps, and water-
fer properties, boundary conditions, recharge, and hydrau-
shed maps were used for preparing a base map. The maps
lic conductivity are the major parameters to be modified to
were scanned and given as input into the MapInfo software,
obtain a realistic fit with the monitored hydraulic head and
which was digitized into boundary, river, and well locations.
flow rate values at the outlet streams.
Land-use patterns, soil type, and geology of the study area
Both steady-state and transient state calibration was
layer were determined using remote sensing IRS, LISS III,
attempted in our study. The January 2014 water level was
with a 1:50,000 scale. The monthly rainfall data were col-
taken as the initial condition for the steady-state model cali-
lected from 2000 to 2019 from PWD to calculate annual
bration. Many test runs were conducted by changing the
recharge. The groundwater quality was analyzed for the
hydraulic conductivity values within some range until the
major ions, pH, EC, and TDS following standard methods
simulated vs. observed heads correlate well.
(APHA 1998).
Transient calibration was performed from 2014 to 2018.
The conceptual model was developed in and around
The steady-state model calibration values of boundary con-
ASF based on the borehole logs (Supplementary Fig. 2)
ditions, hydraulic conductivity, and water levels were set as
and a methodology flowchart (Fig. 2). GIS software, Map-
the initial state of condition for the transient model calibra-
Info, was used to develop the conceptual model and cre-
tion. The impact of wastewater irrigation from the sewage
ate grids, which was further imported into the numerical
farm into the groundwater was simulated using modular
model. A three-layer groundwater model covering 152 k­ m2
three-dimensional transport model (MT3D). As the farm and
(10,000 m × 15,200 m) was developed (Fig. 3), simulating
tanks are continuous sources of pollution, it was assumed
the groundwater flow and transport in the weathered parts of
that all pollutants at the farm remain at a constant concentra-
an unconfined aquifer system. A simulation was performed
tion. Therefore, the same values of specific storage, specific
on monthly time step periods using Visual MODFLOW v.
yield, time variable recharge, and pumping discharge were
4.2.
used for the transient simulation.
Mass transport modeling was conducted on contaminant
plumes for TDS and N ­ O3 since nitrate contamination is often
associated with domestic (septic) wastewater treatment and Model validation
disposal. To control contaminant plume (TDS and ­NO3)
movement in the wastewater irrigation region, appropriate The term model validation is an annex of the calibration
management techniques should be considered. The follow- process that must ensure that the calibrated model accurately
ing three scenarios were considered in this study after a evaluates all the variables that could influence simulation
detailed discussion with the farmers, corporation officials, results. While several approaches to validate a model exist,
and local government engineers. The prediction of contam- the most effective procedure is to only use a portion of the
inant plumes for the different management strategies was available record of the observed data for calibration (Abdulla
made for 5, 10, and 15 years from 2019. and Al-Assa’d 2006). Once the final parameter values are
Scenario I: continuing irrigation with the same wastewa- acquired through calibration, simulation is continued for the
ter and all other constraints as of 2019. remaining period of the observed data, and goodness-of-fit
Scenario II: continuing irrigation with fresh water and the between observed and simulated values is reevaluated. This
tanks are rehabilitated with fresh water. split-sample calibration/validation procedure is employed in

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Fig. 2  Flow chart of groundwa-


ter flow and contaminant model

several groundwater flow and transport simulation investiga- conditions. The information on different layers was used
tions (Donigian 2002; Duda et al. 2012). to interpolate from point value to the spatial value for
the multilayer aquifer system. Table 1 shows the details.
The groundwater model analyzed different scenarios of
Results and discussions groundwater withdrawal rate, concentration rate, and
recharge conditions using both steady-state and transient
The study region was conceptualized as a three-layer aqui- flow conditions. Supplementary Fig. 3a and 3b shows the
fer system (Fig. 3) with a size of 10,000 m × 15,200 m. longitudinal and transverse direction cross-sections of the
Three layers were taken as unconfined aquifers, but model, respectively.
the aquifer properties were varied to represent the field

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with a 150 m × 150 m grid. The study area benefits from


the Vaigai River, and hence, the northeastern boundary was
fixed as the river flow boundary. The other sides of the study
were taken as a no-flow boundary because of inadequate
data availability and two hills north and west of the study
area. The aquifer condition of January 2014 was assumed as
the initial condition of the simulation. The study region was
hypothesized as three-layer strata. The top layer represents
shallow topsoil, the mid layer represents weathered rocks,
and the bottom layer represents rock with joints and frac-
tures. Different hydraulic conductivity, specific yield, and
specific storage were apportioned to each layer. The above
aquifer parameters were collected from CGWB and PWD
offices at Madurai (Table 2).
The primary and secondary data collected from PWD
Fig. 3  Three-layer aquifer system of Avaniyapuram region from January 2014 to December 2018 were taken for model
calibration. Most wells in the study area are contaminated
with wastewater that is used to water crops. The pumping
Pumping and observation wells rate was calculated as 16 M ­m3 per year after considering
number of wells and per day pumping in the study area.
This study considered 40 representative pumping wells A dispersion coefficient was used to assign the lateral and
to extract groundwater. Figure  4 shows the locations of longitudinal dispersion coefficients. The urban wastewater
these pumping wells. These pumping wells supply the total was characterized, and the dispersion coefficient of these
groundwater demand of the basin. The monthly pumping characteristics with laterite soil was taken and provided for
rate is given as the input to all the pumping wells and could model input (Freeze and Cherry 1979; Vasanthi et al. 2008).
vary from zone to zone. Ten observation wells were identi- Also, the lateral dispersion coefficient was taken as one-
fied and taken as the regional groundwater model develop- tenth of the longitudinal dispersion.
ment regarding the water level and concentration of water
quality parameters. Figure 5 shows the observation wells Estimation of recharge
locations.
Generally, recharge depends on the rainfall duration and rate,
Model construction and initial boundary condition antecedent soil moisture conditions, soil type, upper bound-
ary conditions, and the water table depth (Kumar 1993;
The digitized map of the area around ASF was selected NIH 2020). A report published by the CGWB revealed that
as input for numerical groundwater flow modeling. The the natural recharge was assumed to be 20% of the annual
numerical model was discretized into 66 rows × 100 columns rainfall. MODFLOW can accommodate the estimated

Table 1  Details of the well logs and layer elevation (TWAD 2012)


S. No Well ID MModelX (m) MmodelY (m) Elevation (m) 1st layer bottom 2nd layer bottom 3rd layer bottom

1 21001D 4628 5650 129.6 127.6 109.6 81.6


2 21014D 92 9891 132.6 130.6 126.6 112.6
3 21005D 4024 31 129.4 127.4 123.4 73.4
4 82,013 10,897 6300 124.8 119.8 115.8 104.8
5 82,014 11,331 8544 125.0 122.0 119.0 105.0
6 82,015 9984 7770 124.9 122.9 117.9 104.9
7 82,016 15,015 5185 124.9 122.9 114.9 104.9
8 21009D 61 510 131.9 129.9 124.9 91.9
9 21004D 4651.5 0 129.5 127.5 126.5 81.5
10 21002D 132 1441 132.9 129.9 126.9 84.9

MModelX, X coordinate
MModelY, Y coordinate

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Fig. 4  Locations of pumping wells

Fig. 5  Locations of observation
wells

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Table 2  Aquifer characteristics Layers Kx (m/s) Ky (m/s) Kz (m/s) Ss (l/m) Sy Effective Total porosity
in and around Avaniyapuram porosity
sewage farm (TWAD 2012)
I, top soil 3.2 × ­10−5 3.2 × ­10−5 1 × ­10−6 5 × ­10−4 1 × ­10−4 20% 32%
II, weathered rocks 1 × ­10−7 1 × ­10−7 1 × ­10−8 5 × ­10−5 1 × ­10−3 15% 22%
III, rock with joints 1 × ­10−6 1 × ­10−6 1 × ­10−7 5 × ­10−2 1 × ­10−2 20% 28%
and fractures

Kx, Ky, and Kz, hydraulic conductivity in X, Y, and Z direction

groundwater recharge rate using the recharge package. The 2011). Aquifer parameters, such as hydraulic conductivity
recharge values were fed into the top layer because actual and storage properties for each layer, were based on the
recharge goes through the ground surface. data collected from PWD and other governmental sources.
The termination criteria considered for residual error were
Simulation results of groundwater model 0.001.
On examining the steady-state calibration, there is a slight
The groundwater model area of 152 ­k m 2 was divided deviation in the groundwater level (Hani et al. 2007). The
into cells containing 100 columns and 66 rows. The water level contours and velocity vectors show that the flow
vertical discretization consisted of three layers of an was primarily toward the northeastern side of the study area
unconfined aquifer. The 2014 January water level and (Chandran et al. 2017). Based on the observed water level
water quality were identified as the initial head and con- measurements in 11 observational wells, calibration of the
centration, respectively. This initial condition was veri- transient flow model at a monthly time step with varying
fied using steady-state simulation, and each month esti- recharge and pumping rates was attempted for 5 years (60
mated groundwater recharge was quantified based on the stress periods). Many trial runs were conducted by appro-
observed monthly rainfall. The pumping details of wells priately varying the hydraulic and storage coefficient values
in the study area from 2014 to 2018 were derived based until a reasonably good correlation between the simulated
on irrigation and domestic demand (Grant Thornton India and observed water levels was obtained.

Fig. 6  Calibration curve
between calculated and
observed heads

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Figure 6 shows the scatter plot at the end of the transient Supplementary Figs. 4 and 5 show the simulated water
model calibration for observed and simulated water levels. level contours and the velocity vector profiles at the bot-
From this transient simulation, the residual mean head and tom layer after the calibration period of December 2019.
absolute residual mean head were 1.78 and 3.56 m, respectively. The water table elevation was decreased from the south-
Similarly, the normalized root mean square error was 28.26%. western (130 m) to the northeastern side (124 m) of the
A linear regression analysis of the simulated and observed model domain (Supplementary Fig. 6). The cells in the
hydraulic head values for ten observational wells yielded a coef- most parts of the upper layer and small portions in the
ficient correlation of 0.485. The good matching of computed middle aquifer dried up during the model run because
and observed water levels in the study area indicates that the the water table level was lower than the bottom of the
model realistically represents the true subsurface system. upper and middle aquifers because of the thin topsoil in
Similarly, the residual mean concentration and absolute resid- the upper layer. Also, the dry cell indicates that the water
ual mean concentration were 111.58 and 164.03 mg/l, respec- table was deeper than the bottom of the first layer. Higher
tively (Fig. 7). The normalized root indicates that the square pumping rates and low water table might have induced dry
error was 6.39%. A linear regression analysis of the simulated cells in the middle. The plume movement was from west
and observed concentration values yielded an R2 of 0.963, which to east. It was inferred that the overall groundwater flow
indicates that the model replicated the aquifer system well. Fig- gradient is easterly, whereas the contaminant particles fol-
ure 8 shows the correlation between computed and observed lowed the same gradient, and the magnitude depends on
concentrations for TDS and ­NO3 water quality parameters. the distribution coefficient values.

Fig. 7  Calibration curve between calculated and observed concentrations

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Fig. 8  Calibration curve between calculated and observed concentrations, a TDS and b ­NO3

Fig. 9  Validation graph for


observed and calculated
concentrations of water quality
parameters: a nitrate and b total
dissolved solids

Model prediction as ­NO3 and TDS (Fig. 9). The standard deviation and cor-
relation coefficient between the observed and calculated
Once the model was calibrated, validation was conducted concentrations for all parameters were calculated and pre-
for future prediction, and 2019 was taken for the model sented in Table 3.
validation to validate the water quality parameters, such

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Table 3  Standard deviation and S. No Parameters Standard deviation of Standard deviation of Correlation


correlation coefficient between observed conc. (mg/l) calculated conc. (mg/l) coefficient
observed and calculated
concentrations 1 TDS 1243.64 1263.27 0.97
2 NO3 23.99 28.90 0.99

TDS, total dissolved solids


NO3, nitrate

A groundwater contaminant transport model is applied to Also, the pumping quantities and head boundary condi-
either conceptualize or understand the hydrological system tions were the same as in Scenario I. However, the con-
or predict the outcome of the system changes. The waste- centration in the entire region was taken as negligible. The
water is an added source of irrigation in this region, and the wastewater irrigation in the entire area was stopped, and
farmers accept the practices that support their livelihood. the tanks available in the study area were rejuvenated and
However, the water quality test results indicate that the used as a storage structure for irrigation and recharge. The
region is highly polluted for most parameters. If this practice concentration values were predicted for the parameters N­ O3
continues, the contaminant could spread further and contam- and TDS.
inate the downstream areas. Once the groundwater aquifer is
contaminated, it is challenging to remediate. Under these cir-
Scenario III: continuing irrigation with treated
cumstances, different management strategies were evolved to
wastewater and the tanks are renovated and filled
minimize the environmental impacts of wastewater irrigation
up with rain water
in the study area. The agricultural activities were assumed
to be the same; hence, the head boundary conditions were
Treated sewage (according to the Bureau of Indian (BIS)
unchanged. However, the concentration values were changed
irrigation standards) is used for irrigation on farms, and the
according to the different management strategies.
study area with the existing tanks renovated and filled with
rainwater. In this scenario, the entire treated wastewater from
Scenario I: irrigation using the untreated urban
the sewage treatment plant is supplied for agriculture and
sewage in the farm and the tanks are filled
used for irrigation. The tanks in the study area function as
with wastewater
recharge structures using fresh rainwater.
The quality of the treated wastewater was assumed to be
In this scenario (current situation in the study area), reus-
equal to the irrigation water quality of BIS standards. The
ing wastewater for irrigation has been practiced for the
pumping quantities and head boundary conditions were the
last eight decades, and the same trend could be continued.
same as in Scenario I. However, the concentration in the
Therefore, Scenario I was framed, and the model was run to
entire region was within the BIS standard. The irrigation
simulate the plume’s movement. The analysis was conducted
tanks available in the study area were rejuvenated and used
by assuming the same head and concentration rate for the
as storage structures for irrigation and recharge. The con-
remaining period of the model prediction. The concentration
centration values were predicted for the parameters N ­ O3 and
plume values were predicted for the parameters N ­ O3 and
TDS for this scenario. The prediction was done for 15 years
TDS for the next 5, 10, and 15 years.
from 2019 to 2034 for the above three scenarios.
Scenario II: continuing irrigation with fresh water
and the tanks are rehabilitated with fresh water Nitrate

No further sewage irrigation is practiced in the study area, The plume concentration was within the permissible limit
and the existing tanks are renovated and filled with rainwa- in the entire study area in Scenario I, except in Zone I of the
ter. In this scenario, the practice of untreated urban wastewa- farm and up to 3 km east. The maximum concentration of
ter irrigation has significantly influenced the environment, 90 mg/l was noticed on the farm, and it increased further
especially the groundwater system. An alternative manage- after 10 and 15 years. In the 15th year, the concentration
ment strategy was attempted to remediate the contaminated of 55 mg/l reached 4.5 km along the plume northeasterly
aquifer, and the model was run. The assumptions taken for (Fig. 10a). Paddy-growing farmers’ application of nitrogen
this scenario are (i) wastewater irrigation must be stopped, fertilizers could be the reason for this higher concentration.
and (ii) the tanks in the study area must be reclaimed and Research studies by Eltarabily et al. (2017) and Bijay‑Singh
used as freshwater recharge storage structures. and Craswell (2021) corroborated our above inference.

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a) Scenario I

b) Scenario II

c) Scenario III

Fig. 10   Predicted nitrate concentration for a) Scenario I, b) Scenario II, and c) Scenario III

The effect of recharge using freshwater was observed movement was higher in the eastern direction and low
in Zone I of the farm, and the concentration of nitrate had near the sources. The concentration of 3000 mg/l reached
reduced to a permissible limit in Scenario II (Fig. 10b). In 5.5 km at 15 years compared to 3.5 km at 5 years. Fig-
Scenario III, a higher nitrate accumulation was observed ure 11a shows the status of Scenario I.
for ~ 2.5 km in 5 years, ~ 3 km in 10 years, and ~ 3.5 km in In the case of Scenario II, a change in concentration was
15 years. The rest of the regions in Zone I fell within the observed around the sewage farm and in the study area,
permissible limit (Fig. 10c). except for some places. The concentration of 2000 mg/l
at 3 km (5 years) decreased to 1800 mg/l after 15 years
Total dissolved solids (Fig. 11b). The overall groundwater quality improved after
15 years, compared to Scenario I.
In Scenario I, the study had a high total dissolved solid The area affected by TDS concentration decreased with
(TDS) concentration around the farm. The concentration space and time (15 years) in Scenario III (Fig. 11c). The
exceeded the drinking water standards of 500 mg/l in part decrease in TDS concentration might be due to the dilution
of Zone I and part of Zone II. The plume concentration effect of treated wastewater along with recharge potential
of existing irrigation tanks filled with rainwater.

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Arab J Geosci (2022) 15: 1538 Page 13 of 15 1538

a) Scenario I

b) Scenario II

c) Scenario III

Fig. 11   Predicted TDS concentration for a) Scenario I, b) Scenario II, and c) Scenario III

Conclusions the parameters will increase concentration levels, and


remediation would be challenging.
Groundwater modeling was performed using the finite dif- • The result of Scenario II favored the reclamation of
ference method to simulate and forecast the contaminant this study area toward a normal level, which could be
plume for different management strategies: achieved by stopping the wastewater disposal through
irrigation and renovating the tanks to hold fresh water for
• Our calibrated model had a correlation coefficient of recharge. All the parameters around the farm are within
0.861 for flow and of 0.963 for contaminant transport. the limits after 5 years, and this extends to the entire
• Out of three managements (scenarios) considered for study area in 15 years. But it has some difficulty in practi-
the disposal system in the study area, the result of Sce- cal implementation. A new disposal site has to be identi-
nario I indicated that if this disposal system continues, fied in some parts of the city as well as a systematic treat-
the contaminants will spread in 2.5 km radius (Zone ment should be implemented in the new site. Therefore,
I) and reach the river within 15 years. Moreover, all suggestion of an alternate site may not be appropriate.

13
1538 Page 14 of 15 Arab J Geosci (2022) 15: 1538

Instead, a proper disposal system may be developed as Bijay-Singh CE (2021) Fertilizers and nitrate pollution of surface and
suggested in Scenario III. ground water: an increasingly pervasive global problem. SN Appl
Sci 3:518. https://​doi.​org/​10.​1007/​s42452-​021-​04521-8
• Therefore, Scenario III was considered with wastewater Bredehoeft JD, Konikow LF (2012) Ground-water models: validate or
treated to the Bureau of Indian Standards and tanks filled invalidate. Ground Water 50(4):493–495
with fresh water for recharge. The TDS and ­NO3 are Chandran S, Karmegam M, Kumar V, Dhanasekarapandian M (2017)
within limits around the farm after 5 years. The decline Evaluation of groundwater quality in an untreated wastewater
irrigated region and mapping—a case study of Avaniyapuram
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