Introductory Chemistry Atoms First 5th Edition Russo Test Bank Download

Introductory Chemistry Atoms First 5th
Edition Russo Test Bank

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Introductory Chemistry: Atoms First, 5e (Russo/Silver)
Chapter 6 The Shape of Molecules
6.1 Multiple-Choice Questions
1) In a molecule having four pairs of electrons around the central atom and a pyramidal shape,
how many bonding pairs of electrons does the central atom have?
A) 2
B) 1
C) 4
D) 3
Answer: D
Section: Section 6.2
Learning Outcome: 6.2 Explain the principles behind VSEPR theory.
Global Obj: G2 Demonstrate the ability to think critically and employ critical thinking skills.
2) Which of the following pictures best illustrates a tetrahedral shape for the molecule AB4?
A)
B)
1
Copyright © 2015 Pearson Education, Inc.
C)
D)
Answer: A
2
3) Which of the following pictures best illustrates a trigonal planar shape for the molecule AB3?
A)
B)
C)
D)
Answer: D
4) Which compound listed below would you expect to have the greatest H-C-H bond angle?
A) CH2ClF
B) CH2 CI2
C) CH4
D) CH2O
Answer: D
Learning Outcome: 6.3 Draw and name a molecule's shape starting from a dot diagram.
3
5) Which compound listed below has a bond angle of 180° around the central atom?
A) H2O
B) CO2
C) CC14
D) NH3
Answer: B
6) In a molecule having four pairs of electrons around the central atom and a pyramidal shape,
how many lone pairs of electrons does the central atom have?
A) 2
B) 1
C) 4
D) 3
Answer: B
7) In a molecule having four pairs of electrons around the center atom and a bent shape, how
many bonding pairs does the central atom have?
A) 2
B) 1
C) 4
D) 3
Answer: A
8) In a molecule having three pairs of electrons around a central atom and a trigonal planar
shape, how many lone pairs of electrons does the central atom have?
A) 1
B) 0
C) 2
D) 3
Answer: B
4
9) When drawing the three-dimensional structure diagram of a molecule the bold line ________.
A) shows a bond that projects out from the page.
B) shows a bond that goes back behind the page.
C) indicates that the bond is in the plane of the page.
D) One cannot say unless the formula of the molecule is known.
Answer: A
Global Obj: G1 Demonstrate an understanding of the principles of scientific inquiry.
10) When drawing the three-dimensional structure diagram of a molecule the dotted line
________.
B) shows a bond the goes back behind the page.
Answer: B
11) When drawing the three-dimensional structure diagram of a molecule the solid (not bold or
dotted) line ________.
B) shows a bond that goes back behind the page.
Answer: C
12) Which of the following statements is correct about the pyramidal structure?
A) The pyramidal structure is very similar to the tetrahedral structure except one electron pair in
the pyramidal structure replaces a bond in the tetrahedral one.
B) The pyramidal structure is the shape of the ammonia molecule.
C) The bond angles around the central atom very close to the 107°.
D) All above statements are correct.
Answer: D
5
13) Which of the following statements is correct about the bent structure?
A) The bent structure has three bonding electrons pairs with at least one lone pair around the
central atom.
B) The bent structure is the shape of the ammonia molecule.
C) The bent structure has bond angles around the central atom very close to the 105°.
D) All above statements are correct.
Answer: C
14) Which of the following molecules is not linear?

A) hydrogen cyanide
B) beryllium chloride
C) boron trifluoride
D) acetylene, C2H2
Answer: C
15) Which of the following molecules is linear?

A) hydrogen chloride
B) ethane, C2H6
C) ethene, C2H4
D) ammonia
Answer: A
16) Which of the following molecules is not tetrahedral?

A) carbon tetrachloride
B) chloroform, CHCl3
C) methane, CH4
D) boron trifluoride
Answer: D
6
17) Which of the following molecules is tetrahedral?
A) sulfur trioxide
B) sulfur dioxide
C) sulfur dichloride
D) ammonium ion
Answer: D
18) Which of the following molecules is bent?

A) water
B) sulfur dioxide
C) carbon dioxide
D) both A and B
Answer: D
19) Which of the following molecules is bent and has a bond angle close to 118° around the
central atom?
A) sulfur dioxide
B) boron trifluoride
C) ammonia
D) both A and C
Answer: A
20) Which of the following molecules is pyramidal and has a bond angle close to 107° around
the central atom?
A) sulfur dioxide
B) boron trifluoride
C) ammonia
D) both A and C
Answer: C
7
21) The angle around nitrogen in the ammonium ion is ________.
A) 60°
B) 90°
C) 109.5°
D) 120°
Answer: C
22) The angle around boron in boron trifluoride is ________.

A) 60°
B) 90°
C) 109.5°
D) 120°
Answer: D
23) The angle around carbon in hydrogen cyanide is ________.

A) 105°
B) 109.5°
C) 120°
D) 180°
Answer: D
24) What is the molecular shape of H2S?

A) tetrahedral
B) pyramidal
C) linear
D) bent
Answer: D
8
25) What is the molecular shape of CC14?
A) tetrahedral
B) pyramidal
C) linear
D) bent
Answer: A
26) What is the molecular shape of NO2-

A) tetrahedral
B) pyramidal
C) linear
D) bent
Answer: D
27) What is the molecular shape of CH2O?

A) tetrahedral
B) bent
C) trigonal planar
D) pyramidal
Answer: C
28) What is the steric number of the central atom in CH4?

A) 1
B) 2
C) 3
D) 4
Answer: D
9
29) What is the steric number of the central atom in carbon disulfide?
A) 1
B) 2
C) 3
D) 4
Answer: B
30) What is the steric number of the central atom in boron trichloride?
A) 1
B) 2
C) 3
D) 4
Answer: C
31) Which of the following compounds would be soluble in a nonpolar solvent?

A) H2S
B) NH3
C) CC14
D) SO2
Answer: C
Learning Outcome: 6.7 Explain how molecular polarity leads to intermolecular attraction.
32) Which of the following compounds would you expect to be the most polar molecule?
A) H2S
B) H2Se
C) H2Te
D) H2O
Answer: D
Learning Outcome: 6.6 Predict the relative polarity of a molecule.
10
33) Which of the following compounds contains bonds that are the most polar (greatest
electronegativity difference between hydrogen and the central atom)?
A) H2O
B) H2S
C) H2Se
D) H2Te
Answer: A
34) Which of the following compounds is non-polar?

A) acetylene, C2H2
B) ethene, C2H4
C) methane
D) All of the above are non-polar.
Answer: D
35) Which of the following nitrogen-containing compounds is least polar?

A) NH3
B) CH3 - N = N - CH3
C) (CH3 CH2)3N
D) (CH3)3N
Answer: A
36) Which of the following sulfur-containing compounds or ions is not polar?

A) SO3
B) H2S
C) HS-
D) SOCl2
Answer: A
11
37) Which of the following chlorine-containing compounds is not polar?
A) CHCl3
B) CH2Cl2
C) HCl
D) CCl4
Answer: D
38) Which of the following compounds is polar?

A) SO3
B) CO2
C) CS2
D) H2CO
Answer: D
39) Which of the following compounds is non-polar?

A) SO2
B) CH2O
C) CS2
D) SOCl2
Answer: C
40) Which of the following compounds is pure covalent?

A) H2CO
B) Cl2SO
C) O2
D) CO
Answer: C
12
41) Which of the following compounds is polar?
A) N2
B) O2
C) SOCl2
D) CO2
Answer: C
42) Which of the following compounds will be affected by the presence of an electric field?
A) H2
B) O2
C) HCl
D) N2
Answer: C
43) In which of the three phases of matter would you expect hydrogen bonding between water
molecules to be the strongest?
A) solid phase (H2O Os very close together)
B) liquid phase (H2O Os more separated than solid phase)
C) gas phase (H2O Os much farther apart than liquid phase)
D) It is equally strong in all three phases.
Answer: A
Learning Outcome: 6.9 Describe how intermolecular attractions arise between dipolar
molecules.
44) Dipole dipole forces are an important factor to consider in determining whether or not a
substance will dissolve in water (a molecule which has a dipole). Which of the following
compounds would you expect to be the most soluble in water?
A) CCl4
B) NH3
C) N2
D) CO2
Answer: B
molecules.
13
45) Dipole dipole forces are an important factor to consider in determining whether or not a
substance will dissolve in water (a molecule which has a dipole). Which of the following
compounds would you expect to be the least soluble in water?
A) BF3
B) NH3
C) HF
D) H2S
Answer: A
molecules.
46) Which of the following compounds will be the least soluble in water?
A) CH3OH
B) CH4
C) NH3
D) CH3CH2OH
Answer: B
molecules.
6.2 True/False Questions
1) When drawing the three-dimensional structure diagram of a molecule the bold line goes back
behind the page.
Answer: FALSE
2) The ball-and-stick model emphasizes the bonding pattern.

Answer: TRUE
3) In the VSEPR model the multiple bond is treated as a single electron group, just the way a
single bond is treated.
Answer: TRUE
14
4) The angle around the central atom in the pyramidal structure is very close to that of the
tetrahedral one.
Answer: TRUE
5) Any molecule of the form AX3 is tetrahedral.

Answer: FALSE
6) SO2, HCN and CO2 are linear.

Answer: FALSE
7) NH3, CH3-, and PCl3 are pyramidal.

Answer: TRUE
8) When determining the shape of a molecule, count all electron groups around the central atom.
Answer: TRUE
9) When naming the shape of a molecule count only the lone pairs.
Answer: FALSE
10) The pyramidal structure is the tetrahedral arrangement minus a bond but with a lone pair.
Answer: TRUE
15
11) Sulfur dioxide is linear.
Answer: FALSE
12) The bond angle in carbon tetrachloride is 109.5°.

Answer: TRUE
13) The bond angle in ammonia is 109.5°.

Answer: FALSE
14) Bonds are regions of negative charge and therefore repel each other.
Answer: TRUE
Learning Outcome: 6.5 Explain polarity in terms of individual bonds and an entire molecule.
15) Carbon tetrachloride is polar.

Answer: FALSE
16) SO3, CO2, and CS2 are all non-polar.

Answer: TRUE
17) Carbon dioxide contains polar bonds and is a nonpolar molecule.

Answer: TRUE
18) Carbon tetrachloride contains polar bonds and is a polar molecule.

Answer: FALSE
16
19) Compounds with polar bonds may be nonpolar.
Answer: TRUE
20) A polar covalent compound is unaffected by the presence of an electric field.

Answer: FALSE
21) The difference in electronegativity between H and in HF is higher than that between H and
Cl in HCl.
Answer: TRUE
6.3 Short Answer Questions
Use VSEPR theory to predict the shape of the molecule or complex ion shown. Draw a Lewis dot
structure to assist you in determining these shapes.
1) CO32-
Answer:

2) PH3
Answer:

17
3) NO3-
Answer:

4) CHC13
Answer:

5) CS2
Answer:

6) CN-
Answer:

18
7) O3 (ozone)
Answer:

8) SCN-
Answer:

9) H2S
Answer:

10) SO2
Answer:

19
11) PO43-
Answer:

Judge whether or not the molecule or polyatomic ion shown is polar or non-polar. Draw a
dipole vector to indicate the direction of any net polarity.
12) SO3
Answer: non-polar
13) NO+
Answer: polar

14) CBr4
Answer: non-polar
15) BF3
Answer: non-polar
20
16) NO2-
Answer: polar

17) CSe2
Answer: non-polar
21
6.4 Matching Questions
Match each molecule in the left column with the shape of the central atom that appears in the
right column.
A) linear
B) trigonal plamar
C) tetrahedral
D) bent
E) trigonal planar
F) pyramidal
1) hydrogen sulfide
2) water
3) ammonia
4) boron trifluoride
5) acetylene, C2H2
6) sulfur dioxide
7) sulfur trioxide
22
8) ammonium ion
9) ethylene, C2H4
10) carbon tetrachloride

11) hydrogen cyanide

12) phosphorus trihydride

13) nitrogen trifluoride

14) carbon disulfide

Answers: 1) D 2) D 3) F 4) E 5) A 6) D 7) B 8) C 9) E 10) C 11) A 12) F 13) F 14) A
23
Match each molecule in the left column with an angle around the central atom that appears in
the right column.
A) 105°
B) 107°
C) 120°
D) 118°
E) 109.5°
F) 180°
15) hydrogen sulfide

Learning Outcome: 6.4 Draw a molecule's shape for molecules possessing multiple bonds.
16) water
17) ammonia
18) boron trifluoride

19) acetylene, C2H2

20) sulfur dioxide

21) sulfur trioxide

24
22) ammonium ion
23) ethylene, C2H4

24) carbon tetrachloride

25) hydrogen cyanide

26) phosphorus trihydride

27) carbon disulfide

28) nitrogen trifluoride

Answers: 15) A 16) A 17) B 18) C 19) F 20) D 21) C 22) E 23) C 24) E 25) F 26) B 27) F 28) B
25
Match the shape and number of electron groups at the central atom on the left column with the
number of bonding pairs of electrons on the central atom on the right column.
A) 4
B) 3
C) 2
29) tetrahedral, four

30) pyramidal, four

31) bent, four

32) trigonal planar, three

33) linear, two

Answers: 29) A 30) B 31) C 32) B 33) C
26
Match each of the ions that appears in the left column with the corresponding shape on the right
column.
A) bent
B) trigonal planar
C) linear
D) pyramidal
E) tetrahedral
34) CH3+
35) CH3-
36) NO3-
37) HC2-
38) HCO3-
39) NH4+
40) CO2
27
41) NH2-
Answers: 34) B 35) D 36) B 37) C 38) B 39) E 40) C 41) A
28
Identify each of the molecules in the left column as polar or non-polar.
A) non-polar
B) polar
42) CH4
43) HC1
44) PCl3
45) NH3
46) H2O
47) H2S
48) H2C CH2

49) CH2Cl2
29
50) SO3
51) CH3Cl
52) Br2
53) CCl4
54) CS2
55) CH3CH3
56) C2H2
57) CO2
Answers: 42) A 43) B 44) B 45) B 46) B 47) B 48) A 49) B 50) A 51) B 52) A 53) A 54) A
55) A 56) A 57) A
30
Identify whether each of the compounds in the left column has intermolecular dipole-dipole
forces.
A) no dipole-dipole forces
B) dipole-dipole forces
58) NH3
59) CH4
60) CH3OH
61) NH2OH
62) CH3SH
63) CH3OCH3
64) H2C O
65) C2H6
31
66) C3H8
Answers: 58) B 59) A 60) B 61) B 62) B 63) B 64) B 65) A 66) A
32

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Introductory Chemistry Atoms First 5th

Edition Russo Test Bank

Test Bank: https://testbankpack.com/p/test-bank-for-introductory-

Solution Manual: https://testbankpack.com/p/solution-manual-for-

6.1 Multiple-Choice Questions

14) Which of the following molecules is not linear?

15) Which of the following molecules is linear?

16) Which of the following molecules is not tetrahedral?

18) Which of the following molecules is bent?

22) The angle around boron in boron trifluoride is ________.

23) The angle around carbon in hydrogen cyanide is ________.

24) What is the molecular shape of H2S?

26) What is the molecular shape of NO2-

27) What is the molecular shape of CH2O?

28) What is the steric number of the central atom in CH4?

31) Which of the following compounds would be soluble in a nonpolar solvent?

34) Which of the following compounds is non-polar?

35) Which of the following nitrogen-containing compounds is least polar?

36) Which of the following sulfur-containing compounds or ions is not polar?

38) Which of the following compounds is polar?

39) Which of the following compounds is non-polar?

40) Which of the following compounds is pure covalent?

6.2 True/False Questions

2) The ball-and-stick model emphasizes the bonding pattern.

5) Any molecule of the form AX3 is tetrahedral.

6) SO2, HCN and CO2 are linear.

7) NH3, CH3-, and PCl3 are pyramidal.

12) The bond angle in carbon tetrachloride is 109.5°.

13) The bond angle in ammonia is 109.5°.

15) Carbon tetrachloride is polar.

16) SO3, CO2, and CS2 are all non-polar.

17) Carbon dioxide contains polar bonds and is a nonpolar molecule.

18) Carbon tetrachloride contains polar bonds and is a polar molecule.

20) A polar covalent compound is unaffected by the presence of an electric field.

6.3 Short Answer Questions

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.2

Section: Section 6.3

Section: Section 6.3

10) carbon tetrachloride

11) hydrogen cyanide

12) phosphorus trihydride

13) nitrogen trifluoride

14) carbon disulfide

Answers: 1) D 2) D 3) F 4) E 5) A 6) D 7) B 8) C 9) E 10) C 11) A 12) F 13) F 14) A

15) hydrogen sulfide

18) boron trifluoride

19) acetylene, C2H2

20) sulfur dioxide

21) sulfur trioxide