mee Sodium chloride (NaC + CL ions have cep oF foo arrangement (ie. CF ions occupy all the corners and all tho face centros of the cube) + Na’ ions occupy all octahedral sites (ie. Na’ ions ary prevent at the body centre ‘und edge centivs) + CN. of Nav = 6 + CN of Cha 6 ‘Scone Sodium chloride (NCH) Cosium chloride (CC) * Oh ions have simple cubic arrangement (i.e. present nt all the corners of the cube) + Cs" ions occupy cubic rites ma : A ceria cent tne castes OE ses cub) en oe : (a) by 8 Cs" jana * CN, of Ch = 8 f 7 Cesium chloride (CaCl Zine wulphide Zn) + St ions have cep or fee arrangement (i.e, S* ions occupy all the corners ‘and all the face centres of the cube) st bn ‘surrounded by 8 @ Gr cris} Gat se + tat a we Z| ss Za ions occupy half ofthe tetrahedral soe + GN of Zn® =4 tou Stone eh Sion + CN of = 4 ‘otraexaly Te may be noted that ZnS exists in two ony forms: zine blende and wurtzite, In 21¥* jons of sean, fee fone, zine blende, 8 ions have cep or fee neal ‘arrangement (as shown) but in wurtaite S* ions have hep arrangement. Th ‘arrangement of7Zn* ions issame in both Calehian isorid (CaF) i.e. occupy half the toteahedral site + Ca!" iona in cep arvangement (ie. Ca** ions occupy all the corners oe fand all the face centres of the cube) + F-ions occupy all tetrahedral nites + GNof Ca + GN off =4 (© This structure i called fluorite wivucture Sodium oxide (Na,O) has structure reverve of fluorite atructie, Oona are arranged in top arrangement and Nations occupy all thtateahedrl eta, Tis called antiftuorite stracture.‘Table 4, Summary of the structures of ionic solids, Effect of Temperature and Pressure on Crystal Structures ‘At ordinary ampaenbirs and peers, chlorides, bromides and iodides of of silver possess the nodivin chloride type atructure. In this, the nn 5, Gta pein Lh resree,co sac 1 OCT ‘bocome 8 : 8, Therefore, the high oy coordination) Similarly, Aijct, Nir NH! rm fam Ca tare oh Nl een ATK, A an 268 Pa. JES) / a emer ted below: ting 18), 0 atom et fan (each conteting 1) of the ce 5 40 (at feo) 4 + Aa tena toe) 1