MindTap General Chemistry 4 Terms 24 Months Instant Access 1st Edition Vining Test Bank Download

Chapter 06 - Electromagnetic Radiation and the Electronic Structure of the Atom
Test Bank for MindTap General Chemistry 4 terms 24

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1. Place the following types of electromagnetic radiation in order of decreasing energy:

Ultraviolet radiowaves microwaves
a. Radiowaves > microwaves > ultraviolet
b. Ultraviolet > microwaves > radiowaves
c. Radiowaves > ultraviolet > microwaves
d. Ultraviolet > radiowaves > microwaves
e. Microwaves > radiowaves > ultraviolet
ANSWER: b
POINTS: 1
QUESTION TYPE: Multiple Choice
HAS VARIABLES: False
DATE CREATED: 3/5/2014 6:51 PM
DATE MODIFIED: 12/22/2016 2:07 AM
2. What is the frequency of microwave radiation that has a wavelength of 0.870 m?

a. 7.62 × 108 s−1
b. 3.45 × 108 s−1
c. 2.90 × 10-9 s−1
d. 2.61 × 108 s−1
e. 3.83 × 10-9 s−1
ANSWER: b
POINTS: 1
DATE MODIFIED: 3/5/2014 6:51 PM
3. It takes 513 kJ to remove a mole of electrons from the atoms at the surface of a piece of metal. How much
energy does it take to remove a single electron from an atom at the surface of that metal?
a. 3.09 × 1026 J
Copyright Cengage Learning. Powered by Cognero. Page 1

b. 3.09 × 1029 J
c. 4.29 ×10-17 J
d. 8.52 × 10-19 J
e. 8.52 × 10-22 J
ANSWER: d
POINTS: 1
4. Which of the below shows the emission of the longest wavelength of light?
A. B. C. D.
a. A
b. B
c. C
d. D
ANSWER: b
POINTS: 1
5. Calculate the energy for the transition of an electron from the n = 4 level to the n = 1 level of a hydrogen
atom.
a. −2.178 × 10-18 J
b. −1.361 × 10-19 J
c. −5.445 × 10-19 J
d. −2.042 × 10-18 J
e. −3.165 × 10-19 J
ANSWER: d
POINTS: 1

6. How many sublevels are contained in the second energy level (n = 2) of a given atom?
a. 0
b. 1
c. 2
d. 3
e. 4
ANSWER: c
POINTS: 1
7. How many different values of ml are possible in the 4f sublevel?

a. 1
b. 2
c. 3
d. 5
e. 7
ANSWER: e
POINTS: 1
8. In which orbital below would an electron (on the average) be closest to the nucleus?
a. 2p
b. 4s
c. 2s
d. 5d
e. 3p
ANSWER: c
POINTS: 1

9. Each of the following sets of quantum numbers is supposed to specify an orbital. Choose the one set of
quantum numbers that does not contain an error.
a. n = 2, l = 2, ml = −1
b. n = 2, l = 2, ml = 0
c. n = 3, l = 2, ml = −3
d. n = 4, l = 3, ml = −2
e. n = 4, l = 2, ml = +4
ANSWER: d
POINTS: 1
10. Which of the following designations could be used to describe the orbital below:
a. 2s
b. 1py
c. 4dyz
d. 3px
e. 5fxyz
ANSWER: d
POINTS: 1
11. How many electrons have n = 2, l = 1 as one of their quantum numbers?

a. 0
b. 1
c. 2
d. 3
e. 6
ANSWER: e
POINTS: 1

12. Place the following types of electromagnetic radiation in order of decreasing frequency:
X-ray Gamma ray Radio wave
a. X-ray > Gamma ray > Radiowave
b. X-ray > Radiowave > Gamma ray
c. Gamma ray > X-ray > Radiowave
d. Gamma ray > Radiowave > X-ray
e. Radiowave > X-ray > Gamma ray
ANSWER: c
POINTS: 1
13. Place the following types of electromagnetic radiation in order of decreasing wavelength:
Green light Blue light Red light
a. green light > blue light > red light
b. green light > red light > blue light
c. blue light > green light > red light
d. blue light > red light > green light
e. red light > green light > blue light
ANSWER: e
POINTS: 1
14. A local FM radio station broadcasts at a frequency of 99.0 MHz. Calculate the wavelength at which it is
broadcasting. (1 MHz = 106 Hz)
a. 3.03 m
b. 2.97 ×1016 m
c. 3.37 × 10-17 m
d. 3.30 × 10-13 m
e. 3.03 × 1012 m
ANSWER: a
POINTS: 1

15. Place the following forms of electromagnetic radiation in order of decreasing energy:
Gamma ray Infrared Microwave
a. Gamma ray > Infrared > Microwave
b. Gamma ray > Microwave > Infrared
c. Infrared > Microwave > Gamma ray
d. Infrared > Gamma ray > Microwave
e. Microwave > Infrared > Gamma ray
ANSWER: a
POINTS: 1
16. A local AM radio station broadcasts at a wavelength of 349 m. Calculate the energy of the wavelength at
which it is broadcasting.
a. 5.69 × 10-28 J
b. 8.59 × 105 J
c. 6.33 ×10-45 J
d. 7.71 × 10-40 J
e. 6.93 × 10-39 J
ANSWER: a
POINTS: 1
The following information is available to answer questions 17-22.
The diagram below depicts the energy states and transitions in a hydrogen atom.
17. Which transition depicts the emission line with the shortest wavelength?
a. A

b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1
PREFACE NAME: Hydrogen
18. Which transition depicts the absorption line with the longest wavelength?
a. A
b. B
c. C
d. D
e. E
ANSWER: a
POINTS: 1
19. Which transition depicts the emission line with the highest energy?
a. A
b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1
20. Which transition depicts the absorption line with the highest energy?
a. A
b. B
c. C
d. D
e. E
ANSWER: c
POINTS: 1
21. Which transition depicts the emission line with the highest frequency?
a. A
b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1
22. Which transition depicts the line corresponding to the ionization energy of hydrogen?
a. A
b. B
c. C
d. D
e. E
ANSWER: c
POINTS: 1
The following information is available to answer questions 23-28.
The diagram below depicts the energy states and transitions in a hydrogen atom.

23. Which transition depicts the emission line with the shortest wavelength?
a. A
b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1
PREFACE NAME: Hydrogen2
24. Which transition depicts the absorption line with the longest wavelength?
a. A
b. B
c. C
d. D
e. E
ANSWER: b
POINTS: 1
25. Which transition depicts the emission line with the highest energy?
a. A
b. B
c. C
d. D

e. E
ANSWER: d
POINTS: 1
26. Which transition depicts the absorption line with the highest energy?
a. A
b. B
c. C
d. D
e. E
ANSWER: a
POINTS: 1
27. Which transition depicts the emission line with the highest frequency?
a. A
b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1
28. Which transition depicts the line corresponding to the ionization energy of hydrogen?
a. A
b. B
c. C
d. D
e. E
ANSWER: a
POINTS: 1
29. The energy of a particular color of green light is 3.89 × 10−22 kJ. What is the wavelength of this light?
a. 511 nm
b. 773 nm
c. 860 nm
d. 696 nm
e. 437 nm
ANSWER: a
POINTS: 1
30. In the Bohr model of the hydrogen atom, the electron occupies distinct energy states. One transition between
energy states of the hydrogen atom is represented by the picture to the right. In this transition,
a. The electron moves further from the nucleus and energy is absorbed
b. The electron moves closer to the nucleus and energy is absorbed
c. The electron moves further from the nucleus and energy is emitted
d. The electron moves closer to the nucleus and energy is emitted
ANSWER: d
POINTS: 1

31. What would be the wavelength of radiation emitted from a hydrogen atom when an electron moves from the
n = 4 to the n = 2 energy level?
a. 486 nm
b. 365 nm
c. 760 nm
d. 219 nm
e. 197 nm
ANSWER: a
POINTS: 1
32. Calculate the de Broglie wavelength of an alpha particle (mass = 6.64 x 10-27 kg) moving at a speed of 1.52
x 107 m/s.
a. 1.97 x 10-6 m
b. 8.68 x 10-59 m
c. 4.55 x 108 m
d. 5.06 x 10-9 m
e. 5.08 x 105 m
ANSWER: a
POINTS: 1
33. n is known as the:

a. principal quantum number, and it specifies the size and energy of the shell in which the orbital
resides
b. principal quantum number, and it specifies the orbital orientation
c. angular momentum quantum number, and it specifies the orbital orientation
d. angular momentum quantum number, and it specifies the orbital shape
e. magnetic quantum number, and it specifies the size and energy of the shell in which the orbital
resides
ANSWER: a
POINTS: 1

34. l is known as the:

a. principal quantum number, and it specifies the average distance from the nucleus
b. magnetic quantum number, and it specifies the orbital orientation
e. magnetic quantum number, and it specifies the average distance from the nucleus
ANSWER: d
POINTS: 1
35. ml is known as the:

a. principal quantum number, and it specifies the average distance from the nucleus
b. magnetic quantum number, and it specifies the orbital orientation
e. magnetic quantum number, and it specifies the average distance from the nucleus
ANSWER: b
POINTS: 1
36. How many orbitals are possible when n = 3?

a. 0
b. 1
c. 4
d. 9
e. 16
ANSWER: d
POINTS: 1
37. How many orbitals are possible when l = 0?

a. 0
b. 1
c. 4
d. 9
e. 16
ANSWER: b
POINTS: 1
38. Based on the shape and number of nodes in the picture of an orbital below, what are the values for n and l ?
a. n = 1, l = 0
b. n = 2, l = 0
c. n = 3, l = 0
d. n = 2, l = 1
e. n = 3, l = 1
ANSWER: c
POINTS: 1
39. Based on the shape and number of nodes in the picture of an orbital below, what are the values for n and l ?
a. n = 2, l = 0
b. n = 2, l = 1
c. n = 3, l = 0
d. n = 3, l = 1
e. n = 3, l = 2
ANSWER: d
POINTS: 1
Use the pictures of the electron orbitals below to answer question 40-44.
A B C D
... ... ...
E The quantum number given are not allowed.

40. Which orbital can be described by the quantum numbers n = 2, l = 0, ml = 0?
a. A
b. B
c. C
d. D
e. E
ANSWER: b
POINTS: 1
PREFACE NAME: orbitals

a. A
b. B
c. C
d. D
e. E
ANSWER: a
POINTS: 1

42. Which orbital can be described by the quantum numbers n = 3, l = 1, ml = −1?

a. A
b. B
c. C
d. D
e. E
ANSWER: c
POINTS: 1

a. A
b. B
c. C
d. D
e. E
ANSWER: d
POINTS: 1

a. A
b. B
c. C
d. D
e. E
ANSWER: e
POINTS: 1
45. How many electrons can be described by the quantum numbers n = 3, l = 2, ml = −2?
a. 0
b. 2
c. 6
d. 10
e. 14
ANSWER: b
POINTS: 1
46. How many electrons can be described by the quantum numbers n = 4, l = 1?

a. 0
b. 2
c. 3
d. 6
e. 18
ANSWER: d
POINTS: 1
47. How many electrons can be described by the quantum numbers n = 4, l = 3?

a. 0
b. 2
c. 7
d. 14
e. 32
ANSWER: d
POINTS: 1
48. How many electrons can be described by the quantum numbers n = 3, l = 3, ml = −2?
a. 0
b. 2
c. 7
d. 10
e. 14
ANSWER: a
POINTS: 1
49. In a discharge tube, neon atoms emit light as they undergo transitions from one energy level to another that
is 3.313 x 10-19 J lower in energy. From this information, predict the color of the line in the discharge spectrum
you would see from this
transition:
a. red
b. orange
c. yellow
d. green
e. blue
ANSWER: b
POINTS: 1

50. In Bohr's atomic theory, when an electron moves from one energy level to another energy level more distant
from the nucleus:
a. Energy is emitted.
b. Energy is absorbed.
c. No change in energy occurs.
d. Light is emitted.
e. none of these.
ANSWER: b
POINTS: 1
51. What is the frequency (s−1) of electromagnetic radiation that has a wavelength of 1.2 m?
a. 0.82 s−1
b.
s−1
c.
s−1
d.
s−1
e.
s−1
ANSWER: c
POINTS: 1
52. Which of the following ranks regions of the electromagnetic spectrum in proper order from highest to lowest
energy.
a. radio > ultraviolet> x-rays > visible > microwaves
b. x-rays > ultraviolet > visible > microwaves> radio
c. microwaves > x-rays > ultraviolet > visible > radio
d. ultraviolet > x-rays > microwaves > visible > radio
e. visible > microwaves > radio > ultraviolet > x-rays
ANSWER: b
POINTS: 1
HAS VARIABLES: True

53. What is the energy of a photon of electromagnetic radiation with a wavelength of 383.5 nm? (c = 2.998 × 108 m/s, h =
6.626 × 10-34 J·s)
a. J
b. J
c. J
d. J
e. J
ANSWER: a
POINTS: 1
HAS VARIABLES: True
DATE CREATED: 8/13/2014 7:55 AM
54. What is the wavelength of a photon that has an energy of J? (c = 2.998 × 108 m/s, h = 6.626 × 10-34 J·s)
a. nm
b. nm
c. 0.866 nm
d. nm
e. nm
ANSWER: c
POINTS: 1
HAS VARIABLES: True
55. What is the wavelength of light emitted when the electron in a hydrogen atom undergoes a transition from level n =
6 to level n = 3? (c = 2.998 × 108 m/s, h = 6.626 × 10-34 J·s, constant in the Bohr Equation = 2.179 × 10-18 J)
a. 1.09 × 10–6 m
b. 6.06 × 10–28 m
c. 9.14 × 105 m
d. 1.82 × 10–19 m
e. 2.74 × 1014 m
ANSWER: a
POINTS: 1
HAS VARIABLES: True

56. What is the wavelength of a 144-g baseball traveling at 98.7 mph?

( )
a. 3.45×10 m37
b. 1.04×10–34m
c. 1.04×10–37m
d. 9.59×1033m
e. 2.90×10–38m
ANSWER: b
POINTS: 1
HAS VARIABLES: True
57. What is the wavelength of an electron traveling at 5.54% of the speed of light?
(me = 9.109 × 10-31 kg, c = 2.998 × 108 m/s, h = 6.626 × 10-34 J·s)
a. 2.28 × 1010 m
b. 2.43 × 10–12 m
c. 4.38 × 10–11 m
d. 2.28 × 1012 m
e. 4.38 × 10–13 m
ANSWER: c
POINTS: 1
HAS VARIABLES: True
58. What is the value of the angular momentum quantum number for an electron in a 4p orbital?
a. 3
b. 4
c. 0
d. 1
e. 2
ANSWER: d
POINTS: 1
HAS VARIABLES: True
59. A possible value of the magnetic quantum number ml for a 5d electron is

a. 2.
b. 4.
c. 5.
d. –6.
e. –3.
ANSWER: a
POINTS: 1
HAS VARIABLES: True
60. How many values are there for the magnetic quantum number when the value of the angular momentum
quantum number is 4?
a. 11
b. 9
c. 2
d. 3
e. 17
ANSWER: b
POINTS: 1
HAS VARIABLES: True
61. Which of the following is a representation of a orbital?

a.
b.
c.

d.
e.
ANSWER: c
POINTS: 1
–3
62. Consider an atom traveling at 1% of the speed of light. The de Broglie wavelength is found to be 1.39 × 10
pm. Which element is this?
a. H
b. Mo
c. Hg
d. Ti
e. P
ANSWER: b
POINTS: 1
HAS VARIABLES: True
63. In the hydrogen spectrum, what is the wavelength of light associated with the n = 3 to n = 1 electron
transition?
a. 3.97 × 10–25 nm
b. 8.21 × 102 nm
c. 9.75 × 106 cm
d. 1.94 × 10–18 m
e. 1.03 × 10–7 m
ANSWER: e
POINTS: 1
REFERENCES: 6.3.1
HAS VARIABLES: True

64. How many electrons in an atom can have the quantum numbers n = 3, l = 2?
a. 2
b. 5
c. 6
d. 10
e. 18
ANSWER: d
POINTS: 1
65. Which of the following is an incorrect designation for an atomic orbital?

a. 1s
b. 3d
c. 1p
d. 4f
e. 6s
ANSWER: c
POINTS: 1
66. When n = 4, how many d orbitals are present ?

a. 2
b. 5
c. 10
d. 7
e. 18
ANSWER: b
POINTS: 1

67. How many f orbitals have the value n = 2?

a. 0
b. 3
c. 5
d. 7
e. 1
ANSWER: a
POINTS: 1
68. How many sublevels are there with n = 2 in an atom?

a. 1
b. 2
c. 3
d. 5
e. 7
ANSWER: b
POINTS: 1
69. How many orbitals are there with n = 2 in an atom?

a. 1
b. 2
c. 3
d. 4
e. 6
ANSWER: d
POINTS: 1
70. Which of the following sets of quantum numbers could be describing the electrons in the orbital depicted
below?

a. n = 2, l = 2, ml = −1, ms = − ½
b. n = 2, l = 1, ml = 1, ms = + ½
c. n = 3, l = 2, ml = −2, ms = 1
d. n = 3, l = 1, ml = −1, ms = + ½
e. n = 2, l = 0, ml = 0, ms = + ½
ANSWER: b
POINTS: 1
71. Which of the following sets of quantum numbers could be describing the electrons in the orbital depicted
below?
a. n = 3, l = 2, ml= 0, ms = + ½
b. n = 3, l = 3, ml = −3, ms = + ½
c. n = 2, l = 2, ml = 1, ms = − ½
d. n = 4, l = 2, ml = −2, ms = − ½
e. n = 4, l = 3, ml = 2, ms = + ½
ANSWER: a
POINTS: 1
72. A photon of light has a frequency of 3.26 × 1015 hertz. What is its wavelength? The speed of light is 2.998 ×
108 m/s.
a. 109 nm
b. 9.78 × 1014 nm
c. 978 nm
d. 1.09 × 107 nm
e. 92.0 nm
ANSWER: e
POINTS: 1
73. Place the following regions of the electromagnetic spectrum in order from highest to lowest energy.
a. infrared > gamma rays > x-rays > visible > radio
b. gamma rays > x-rays > visible > infrared > radio
c. x-rays > gamma rays > infrared > visible > radio
d. radio > x-rays > gamma rays > visible > infrared
e. visible > infrared > radio > x-rays > gamma rays
ANSWER: b
POINTS: 1
74. What is the phenomenon that occurs when certain metals emit electrons when illuminated by particular
wavelengths of light?
a. electromagnetic spectrum
b. Planck's constant
c. emission spectrum
d. quantum theory
e. photoelectric effect
ANSWER: e
POINTS: 1
75. Determine the energy of a photon that has a frequency of 5.23 × 1014 Hz. Given: h = 6.626 × 10−34 J·s.
a. 1.27 × 10−48 J
b. 3.47 × 10−19 J
c. 1.16 × 10−27 J
d. 1.04 × 10−10 J
e. 7.87 × 1047 J
ANSWER: b
POINTS: 1
76. Calculate the wavelength of light emitted when an electron in a He+ ion goes from the n = 5 shell to the n =
2 shell.
a. 2.30 × 106 m
b. 4.34 × 10−7 m
c. 1.08 × 10−7 m
d. 1.52 × 10−7 m
e. none of these
ANSWER: c
POINTS: 1
77. For a proton (mass = 1.673 × 10–27 kg) moving with a velocity of 2.83 × 104 m/s, what is the de Broglie
wavelength (in pm)?
a. 0.356 pm
b. 3.56 pm
c. 14.0 pm
d. 7.15 pm
e. 28.5 pm
ANSWER: c
POINTS: 1
78. What quantum number(s) provide(s) information with respect to the spatial orientation of an atomic orbital?
a. Principal quantum number, "n"
b. Angular Momentum quantum number, "l"
c. Magnetic quantum number, "ml"

d. Electron spin quantum number, "ms"
e. Principle and Angular Momentum quantum numbers
ANSWER: c
POINTS: 1
79. What is the total number of orbitals having n = 4 and = 2?

a. 3
b. 5
c. 7
d. 9
e. 10
ANSWER: b
POINTS: 1
80. Which of the following diagrams represent d-orbitals?
a. 1 only
b. 2 only
c. 3 only
d. 4 only
e. 1 and 4
ANSWER: e
POINTS: 1
81. A 3p orbital has ?

a. 0 planar nodes and 1 spherical node.
b. 1 planar node and 0 spherical nodes.

c. 1 planar node and 1 spherical node.
d. 1 planar node and 2 spherical nodes.
e. 2 planar nodes and 1 spherical node.
ANSWER: c
POINTS: 1
82. From the restrictions on the three quantum numbers that define an orbital, which set of three quantum
numbers listed below is forbidden?
a. n = 3, = 3, ml = 3
b. n = 3, = 2, ml = −2
c. n = 3, = 2, ml = +2
d. n = 3, = 1, ml = +1
e. n = 3, = 0, ml = 0
ANSWER: a
POINTS: 1
83. What type of orbital is designated by n = 5, = 2, ml = +1?

a. 5d
b. 2f
c. 5p
d. 2s
e. 5p
ANSWER: a
POINTS: 1
84. If l = 2, what value/s can ml have?

a. ml = +1
b. ml = 0, +1, +2
c. ml= +2
d. ml = −1, 0, +1
e. ml = −2, −1, 0, +1, +2
ANSWER: e
POINTS: 1
Use the shapes of atomic orbitals below to answer questions 85-86.
I. II. III. IV. V.

85. Which of the shapes would represent one of seven possible 4f atomic orbitals?
a. I
b. II
c. III
d. IV
e. V
ANSWER: c
POINTS: 1
PREFACE NAME: exhibit 7-1
86. Which of the shapes would represent one of three possible 2p atomic orbitals?
a. I
b. II
c. III
d. IV
e. V
ANSWER: a
POINTS: 1
PREFACE NAME: exhibit 7-1

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Chapter 06 - Electromagnetic Radiation and the Electronic Structure of the Atom

Test Bank for MindTap General Chemistry 4 terms 24

1. Place the following types of electromagnetic radiation in order of decreasing energy:

2. What is the frequency of microwave radiation that has a wavelength of 0.870 m?

Copyright Cengage Learning. Powered by Cognero. Page 1

HAS VARIABLES: False

7. How many different values of ml are possible in the 4f sublevel?

Copyright Cengage Learning. Powered by Cognero. Page 3

11. How many electrons have n = 2, l = 1 as one of their quantum numbers?

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The following information is available to answer questions 17-22.

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The following information is available to answer questions 23-28.

Copyright Cengage Learning. Powered by Cognero. Page 8

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33. n is known as the:

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DATE MODIFIED: 3/5/2014 6:51 PM

34. l is known as the:

35. ml is known as the:

36. How many orbitals are possible when n = 3?

37. How many orbitals are possible when l = 0?

... ... ...

E The quantum number given are not allowed.

41. Which orbital can be described by the quantum numbers n = 3, l = 0, ml = 0?

DATE CREATED: 3/5/2014 6:51 PM

42. Which orbital can be described by the quantum numbers n = 3, l = 1, ml = −1?

43. Which orbital can be described by the quantum numbers n = 3, l = 2, ml = 1?

44. Which orbital can be described by the quantum numbers n = 3, l = 1, ml = 2?

DATE MODIFIED: 12/22/2016 8:09 AM

46. How many electrons can be described by the quantum numbers n = 4, l = 1?

47. How many electrons can be described by the quantum numbers n = 4, l = 3?

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56. What is the wavelength of a 144-g baseball traveling at 98.7 mph?

59. A possible value of the magnetic quantum number ml for a 5d electron is

61. Which of the following is a representation of a orbital?

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HAS VARIABLES: True

65. Which of the following is an incorrect designation for an atomic orbital?

66. When n = 4, how many d orbitals are present ?

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67. How many f orbitals have the value n = 2?

68. How many sublevels are there with n = 2 in an atom?

69. How many orbitals are there with n = 2 in an atom?

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c. Magnetic quantum number, "ml"

79. What is the total number of orbitals having n = 4 and = 2?

80. Which of the following diagrams represent d-orbitals?

81. A 3p orbital has ?

b. 1 planar node and 0 spherical nodes.

83. What type of orbital is designated by n = 5, = 2, ml = +1?

84. If l = 2, what value/s can ml have?

Use the shapes of atomic orbitals below to answer questions 85-86.

I. II. III. IV. V.

DATE MODIFIED: 3/5/2014 6:52 PM