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9.5-9.

6 Review sheet-1 Name_________ Class_________


1. The equation shows the formation of anhydrous copper (II) sulfate from
hydrated copper (II) sulfate.

Statements 1, 2 and 3 refer to this reaction.


1 Hydrated copper (II) sulfate is reduced to anhydrous copper (II) sulfate.
2 The (II) in the name copper (II) sulfate refers to the oxidation state of the
metal.
3 The reaction is reversible.
Which statements are correct?
A. 1 only
B. 1 and 2
C. 2 and 3
D. 3 only

2. Methanol is made by reacting carbon monoxide with hydrogen. The reaction is


reversible.
CO(g) + 2H2(g) CH3OH(g)
The forward reaction is exothermic.
Which combination of temperature and pressure gives the highest equilibrium
yield of methanol?

3. Consider the following reaction at equilibrium


A(g) + B(g) C(g) + D(g)
Which of following cannot change the reaction’s position of equilibrium?
A. Changing temperature.
B. Adding catalyst.
C. Adding product C(g).
D. Adding reactant A(g).
4. Hydrogen is produced when methane reacts with steam.
The equation for the reaction is shown.

The forward reaction is endothermic.


Which conditions produce the highest yield of hydrogen?

5. In the Contact process, sulfur dioxide is converted into sulfur trioxide in a


reversible reaction.
2SO2(g) + O2(g) 2SO3(g)
The forward reaction is exothermic.
Which conditions give the highest yield of sulfur trioxide at equilibrium?

6. The colors of the reactants and products are shown.

The forward reaction is exothermic.


Which statement is correct?
A. An increase in pressure has no effect on the equilibrium position.
B. The purple color fades when the reaction mixture is heated.
C. When equilibrium is reached, both forward and reverse reactions stop.
D. When more hydrogen gas is added, the purple color increases.
7. Chlorine can be manufactured by the following reaction. The reaction is
exothermic.

Which change increases the yield of chlorine at equilibrium?


A. adding more HCl (g)
B. adding more H2O(g)
C. decreasing the pressure
D. increasing the temperature

8. Methanol is prepared by the reversible reaction shown.

9. Sulfur dioxide reacts with oxygen at 2 atmospheres pressure. The forward reaction
is exothermic.
The equation for the reaction is shown.
2SO2(g) + O2(g) 2SO3(g)
The reaction reaches equilibrium. The pressure is then doubled.
How and why does the amount of sulfur trioxide formed change?
10. At 400 °C the reaction between hydrogen and iodine reaches an equilibrium.
The reaction is exothermic.

Which change in conditions would increase the percentage of hydrogen iodide in


the equilibrium mixture?
A. a decrease in pressure
B. a decrease in temperature
C. an increase in pressure
D. an increase in temperature

11. When carbon monoxide reacts with hydrogen, methanol is formed.

The forward reaction is exothermic. Which statements are correct?


1 There are more moles of gas on the left-hand side of the reaction.
2 Increasing the temperature increases the amount of methanol at equilibrium.
3 Increasing the pressure increases the amount of methanol at equilibrium.
4 Increasing the initial amount of hydrogen decreases the amount of methanol at
equilibrium.
A 1 and 2 only
B 1 and 3 only
C 2 and 4 only
D 3 and 4 only

12. When blue copper (II) sulfate is heated, a white solid and water are formed.
The white solid turns blue and gives out heat when water is added to it.
Which terms describe the blue copper (II) sulfate and the reactions?
13. Dinitrogen tetroxide, N2O4, is converted into nitrogen dioxide, NO2, in a reversible
reaction.

14. When pink crystals of cobalt(II) chloride are heated, steam is given off and the
colour of the solid changes to blue.

15. The equation for the effect of heat on hydrated sodium carbonate is as shown.

Statements made by four students about the reaction are given.


P Anhydrous sodium carbonate is formed.
Q Steam is formed.
R There is a colour change from blue to white.
S The reaction is reversible.
Which students’ statements are correct?
A P, Q and R only
B P, Q and S only
C Q, R and S only
D P, Q, R and S

16. Nitrogen, hydrogen and ammonia gases are placed inside a container. The
container is then sealed. After some time, an equilibrium forms.

Which statement describes the equilibrium in this container?


A. The amount of ammonia remains constant from the moment the container is
sealed.
B. The amounts of ammonia, nitrogen and hydrogen in the container are always
equal.
C. The rate of formation of ammonia is equal to the rate of decomposition of
ammonia.
D. The rate of formation of ammonia is faster than the rate of decomposition of
ammonia.

17. When BiCl3 reacts with water, a white precipitate of BiOCl is formed. The
equation for the reaction is shown.

Which statements are correct?


1 The reaction is reversible.
2 When dilute hydrochloric acid is added to the reaction mixture, more of the
white precipitate forms.
3 When aqueous sodium hydroxide is added to the reaction mixture, more of the
white precipitate forms.
A. 1, 2 and 3
B. 1 and 2 only
C. 1 and 3 only
D. 2 and 3 only

18. Methanol is manufactured by reacting carbon monoxide and hydrogen together


in the presence of an aluminium oxide catalyst.
The equation for the reaction is shown.

The reaction is a reversible reaction.


The forward reaction is exothermic.
Which change in conditions increases the yield of methanol?
A. decreasing the concentration of the carbon monoxide
B. increasing the pressure
C. increasing the rate of the reaction
D. increasing the temperature
19. The graph shows how the yield of product in a reversible reaction changes as the
temperature and pressure are changed.
All reactants and products are gases.

Which row is correct for this reversible reaction?

20. Almost all samples of nitrogen dioxide are an equilibrium mixture of nitrogen
dioxide, NO2, and dinitrogen tetroxide, N2O4.

In the forward reaction, a bond forms between the two nitrogen dioxide
molecules.
NO2 + NO2 → O2N – NO2
a) Explain the term equilibrium mixture.
b) The syringe contains a sample of the equilibrium mixture. The plunger was
pulled back reducing the pressure.

i. How would the color of the gas inside the syringe change?

ii. Give an explanation for your answer.

c) If the equilibrium mixture of nitrogen dioxide and dinitrogen tetroxide was


placed in a beaker of ice cold water. The color of the mixture changed from
brown to pale yellow.
i. Is the forward reaction exothermic or endothermic?

ii. Explain your answer in terms of the position of the equilibrium.

d) What other piece of information given in the equation supports your answer to
c)?
NO2 + NO2 → O2N–NO2

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