SAC/MSDS/2020/01

DCM SHRIRAM LTD.

(Unit: Shriram Alkali & Chemicals)

MATERIAL SAFETY DATA SHEET

SODIUM HYDROXIDE

SECTION 1: CHEMICAL PRODUCT AND COMPANY INFORMATION

Supplier : DCM Shriram Ltd.

(Unit: Shriram Alkali & Chemicals)
749, GIDC, Jhagadia-393110,
Dist- Bharuch, Gujarat.
Phone No: (+91 2645)226021/23
Fax No: (+91 2645)226037

Substance : Sodium Hydroxide

Trade Name/Synonyms : Caustic soda Lye /Flakes

CAS number : 1310-73-2

Application : It is used in many industries, mostly as a strong chemical base in

the manufacture of pulp and paper, textiles, drinking water, soaps
and detergents and as a drain cleaner.

SECTION 2: HAZARDS IDENTIFICATION

HAZARD PICTOGRAM:

NFPA RATING:
Health Rating : 3 - Severe (Poison)
Flammability Rating : 0 - None
Reactivity Rating : 1 - Low
Special : None

RISK PHRASES:
35 : Causes severe burns.
SAFETY PHRASES:
1/2 : Keep locked up and out of the reach of children.
26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37/39 : Wear suitable gloves and eye/face protection.
45 : In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).

SECTION 3: COMPOSITION INFORMATION ON INGREDIENTS

Component Substance : Sodium hydroxide

Plot No. 749, GIDC Industrial Estate, Jhagadia, Dist. Bharuch, Gujarat-393110, Ph: +91- 2645-226021/23, Fax: +91- 2645-226037
 SAC/MSDS/2020/01

DCM SHRIRAM LTD.

(Unit: Shriram Alkali & Chemicals)

Component Percent : 47 – 50 % by weight (Lye), Min. 97 % by weight (Flakes)

CAS Registry Number : 1310-73-2

SECTION 4: FIRST AID MEASURES

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call
physician.
Ingestion:
DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Call a physician, immediately. Wash clothing before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.
Note to Physician:
Perform endoscopy in all cases of suspected sodium hydroxide ingestion. In cases of severe esophageal
corrosion, the use of therapeutic doses of steroids should be considered. General supportive measures
with continual monitoring of gas exchange, acid-base balance, electrolytes, and fluid intake are also
required.
SECTION 5: FIRE FIGHTING MEASURES
Fire: Not considered to be a fire hazard. Hot or molten material can react violently with water. Can react
with certain metals, such as aluminum, to generate flammable hydrogen gas.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Adding water to
caustic solution generates large amounts of heat.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus
with full face piece operated in the pressure demand or other positive pressure mode.
SECTION 6: ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into
storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in
the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Do not get water
on spilled substances or inside containers.

SECTION 7: HANDLING AND STORAGE

Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away
from sources of heat, moisture and incompatibilities. Always add the caustic to water while stirring; never
the reverse. Containers of this material may be hazardous when empty since they retain product residues
(dust, solids); observe all warnings and precautions listed for the product. Do not store with aluminum or
magnesium. Do not mix with acids or organic materials.

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

Ventilation System:

Plot No. 749, GIDC Industrial Estate, Jhagadia, Dist. Bharuch, Gujarat-393110, Ph: +91- 2645-226021/23, Fax: +91- 2645-226037
 SAC/MSDS/2020/01

DCM SHRIRAM LTD.

(Unit: Shriram Alkali & Chemicals)

A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area.

Personal Respirators:
If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the
exposure limit or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times
the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or
respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not
known, use a full-face piece positive-pressure, air-supplied respirator.
WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to
prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash
fountain and quick-drench facilities in work area.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquid / solid

Appearance : Colorless liquid / White coloured solid
Odour : odourless
Solubility : 111 g/100 g of water.
Specific Gravity : 2.13
pH : 13 - 14 (0.5% soln.)
Boiling Point : 1390°C
Solidifies at : 05°C
Melting Point : 318° C
Vapour Density (Air=1) : > 1.0
Vapor Pressure (mm Hg) : Negligible.
LEL : Not applicable
UEL : Not applicable
Flash Point : Not applicable

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability: Stable at room temperature in closed containers under normal storage and handling
conditions.
Conditions to Avoid: Moisture, contact with water, exposure to moist air or water, prolonged exposure to
air.
Incompatibilities with Other Materials: Acids, water, flammable liquids, organic halogens, metals,
aluminum, zinc, tin, leather, wool, nitro methane.
Hazardous Decomposition Products: Toxic fumes of sodium oxide. Decomposition by reaction with certain
metals releases flammable and explosive hydrogen gas.
Hazardous Polymerization: Will not occur.

SECTION 11: TOXICOLOGICAL INFORMATION

Toxicity Data : LD 50 – 2000 mg/kg (rat)
STEL : Not listed

Plot No. 749, GIDC Industrial Estate, Jhagadia, Dist. Bharuch, Gujarat-393110, Ph: +91- 2645-226021/23, Fax: +91- 2645-226037
 SAC/MSDS/2020/01

DCM SHRIRAM LTD.

(Unit: Shriram Alkali & Chemicals)

SECTION 12: ECOLOGICAL INFORMATION

Ecological Overview
Toxicity to fishes : 40 mg/l

Toxicity to bacteria : Not listed

Harmful to aquatic animals, so do not discharge into drains.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste generators must consult state and local hazardous waste regulations to ensure complete and
accurate classification.

SECTION 14: TRANSPORT INFORMATION

Shipping Name : Sodium Hydroxide
UN No. : 1823/1824
Hazard Class : Class 8-Corrosive
Hazardous waste Id No. : 16
Hazchem Code : 2R
Packaging : Lye in tanker & Flakes in bags.

SECTION 15: REGULATORY INFORMATION

 Refer Section-2
 As per National / State regulations

SECTION 16: OTHER INFORMATION

Name of the firm Mailing Address Contact Person in Telephone no.

Emergency
Shriram Alkali & 749, GIDC Estate Head of Production Telephone NOS : +91 2645-
Chemicals (SAC) Jhagadia. Pin-393110 226021/23
Dist: Bharuch Fax No : +91 2645-226037

Chlor –Alkali Emergency response network Toll free No. : 1800-11-1735

Disclaimer:
Shriram Alkali and Chemicals (SAC) provides this information which is commonly known and generally
available in respect of this product; but makes no representation as to its comprehensiveness or accuracy.
This information is given only as a guide to the appropriate precautionary handling of the material by a
trained person. Persons receiving the information must use their judgment in determining its
appropriateness for a particular purpose. SAC makes no representations or warranties, either express or
implied, including without limitations any warranties of merchantability, fitness for a particular purpose
with respect to the information given herein or the product to which the information refers. Accordingly,
SAC will not be responsible for damages resulting from use of or reliance upon this information.

Plot No. 749, GIDC Industrial Estate, Jhagadia, Dist. Bharuch, Gujarat-393110, Ph: +91- 2645-226021/23, Fax: +91- 2645-226037