Professional Documents
Culture Documents
Salt Analysis
Salt Analysis
Salt Analysis
PRELIMINARY TESTS:
S.No Experiment Observation Inference
4. Ash test
salt + few drops of conc. HNO3 + Blue ash May be the presence
Cobalt nitrate and boiled. Dipped a Green ash of Al 3+
filter paper into the boiled mixture Pink ash Zn2+
& burnt to ash. Mg2+
2. A little of the salt is heated with Evolution of white fumes Cl - may be present.
Conc. H2SO4. Show a glass rod with pungent irritating
dipped in NH4OH on to the mouth smell, becomes a dense
of the test tube. white fumes.
1
NaCl + H2SO4 → NaHSO4 + HCl ,
HCl +NH4OH → NH4Cl + H2O
Dense white fumes
3. Salt is heated with Conc. H2SO4 & Evolution of brown fumes NO3- may be
add a small paper ball present.
For Carbonate:
1. Salt solution + BaCl2 solution White precipitate soluble in CO32- confirmed.
dilute HCl
Na2CO3+BaCl2→BaCO3+2NaCl
White ppt
BaCO3+2HCl BaCl2 +CO2 + H2O
For Chloride ion:
2. Salt solution + Silver nitrate Curdy white precipitate Cl- confirmed.
Soluble in NH4OH
NaCl+AgNO3→AgCl+NaNO3
White ppt
AgCl+2NH4OH→[Ag(NH3)2]Cl+ 2H2O
Soluble complex
For Nitrate ion
1. Brown ring test: Brown ring at the junction NO3- confirmed
of two liquids
2
Salt solution. + Freshly prepared
FeSO4 Solution . Add con. H2SO4
Through sides of test tube
3
1 Salt solution + sodium carbonate solution Clear solution May be the presence
of ammonium salt
(zero group)
2 Salt solution + dilute HCl A white Presence of Gr 1
(Pb2+)
Pb(NO3)2 + 2HCl→PbCl2 (White ppt)+2HNO3
3 Salt solution + dilute HCl + H2S Black precipitate Presence of Gr 2
Yellow precipitate Cu2+ present
Cd2+ present
CuSO4+H2S→CuS+H2SO4
Black
CdCl2+H2S→CdS+2HCl
Yellow
4. Salt solution + solid NH4Cl + NH4OH(till (i)White gelatinous Presence of Gr3
alkaline) precipitate Al3+ Present
(ii)Reddish Brown Fe3+ Presenct
precipitate
AlCl3+3NH4OH→Al(OH)3+3NH4Cl
White gelatinous ppt
FeCl3+3NH4OH→Fe(OH)3+3NH4Cl
Reddish brown ppt
5. Salt solution + solid NH4Cl + NH4OH(till (i)Black precipitate Presence of Gr 4
alkaline) + H2S (ii)White precipitate Co2+ or Ni2+
(iii)Buff precipitate present
Zn2+ present
Mn2+ present
Co (OH)2 +H2S 2H2O + CoS (black)
Ni (OH)2 +H2S 2H2O + NiS (black)
Zn (OH)2 +H2S 2H2O + ZnS (white)
Mn (OH)2 +H2S 2H2O + MnS (Buff coloured.
6. Salt solution + Solid NH4Cl +NH4OH(till White precipitate Presence of group 5
alkaline)+(NH4)2CO3
BaCl2 + (NH4)2CO3 BaCO3 (White ppt) + 2NH4Cl
SrCl2 + (NH4)2CO3 SrCO3 (White ppt) + 2NH4Cl
CaCl2 + (NH4)2CO3 CaCO3 (White ppt) + 2NH4Cl
7. Salt solution+NH4Cl+NH4OH+Na2HPO4 White precipitate Presence of group 6
4
Confirmatory Test for NH4+
1. Salt solution is heated with NaOH. Smell of ammonia. NH4+ confirmed
∆
NH4Cl+ NaOH NH3 + NaCl + H2O
2K2[HgI4] + NH3+3KOH→ 7KI+2H2O+ H2N.HgO.HgI
Brown ppt
Confirmatory Test for Pb2+
CuSO4+4NH4OH→[Cu(NH3)4]SO4+4H2O
Deep blue colour
6
∆
Co (NO3)2 CoO + 2NO2
ZnO + CoO ZnO . CoO
green ash
If the ppt is Buff
2. Flame test
A paste of salt with Con.HCl is brought Brick red flame Ca2+ confirmed
to the flame using a glass rod.
1. Confirmatory Test for Sr2+
7
salt + few drops of conc. HNO3 + Cobalt Pink ash Mg2+ confirmed
nitrate and boiled. Dipped a filter paper
into the boiled mixture & burnt to ashes
∆
Co (NO3)2 CoO + 2NO2
MgO + CoO MgO . CoO
pink ash