1.

PANAS SENSIBLE
Tabel Data Kapasitas Panas pada Gas dan Liquid
Komponen A
NH3(l) -182.157
NH3(g) 33.573
CO2(g) 27.437
CO2(l) -3981.02
H2O(l) 92.053
H2O(g) 33.933
O2(g) 29.526
Urea(l) 965.507
Urea(g) 24.856
(sumber:Yaws,Carl.1999.)

dik:
suhu inlet ke stripper (A9a)
suhu inlet ke stripper (A9b)
suhu inlet CO2 (A4)
suhu outlet ke HPD (A10)
suhu outlet ke CC (A11)
(sumber:material balance pusri)

Stream
Aliran 4
Mol
KOMPONEN
NH2CONH2 0
NH3 0
CO2 1654.85767825494
H2O 0
NH2CONHCONH2 0
NH4COONH2 0
Total
 2. PANAS PENGUAPAN
Komponen A T Tc
NH3 31.5230 239.75 405.6500
H2O 52.0530 457 647.1300

Hpenguapan NH3 ###

Hpenguapan H2O ###

###
input

p
Y1
Y
Y2

2262.965011809
758.437656043

output

p
Y1
Y
Y2

704.73168
661.448672
 43.0615
238.846
238846

B C D E
3.3618 -0.014398 0.000020371
-0.012581 0.000088906 -7.1783E-08 1.86E-11
0.042315 -1.96E-05 3.9968E-09 -2.99E-13
52.511 -0.22708 0.00032866
-0.03995 -2.11E-04 0.00000053469
-0.0084186 2.99E-05 -1.7825E-08 3.69E-12
-0.0089 3.81E-05 -0.0000000326 8.86E-12
-5.0993 1.00E-02 -0.0000063799
1.44E-01 3.81E-05 -0.00000011 3.92E-11

°C K (+273)
= 185.15 458.15
= 185.15 458.15
= 114.84 387.84
= 180.48 453.48
= 187.83 460.83

INLET
Aliran 4 Aliran 9A (liquid)
CpdT(Kj/Kmol K) H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ)
0 0 2171.111687922 21168.7799109019 45959785.48362
0 0 5950.310983915 24070.7868998503 143228667.6816
3575.14858405113 5916362.0852193 0 0 0
0 0 4876.566626332 12255.5062547076 59764792.79051
0 0 3.281262935299 28813.851685 94545.8235572
0 0 1225.842909014 52912.2904751367 64862156.07864
5916362.0852193 313909947.858
 321989162.379444

n ΔHv (kJ/kmol)
0.3640 22.770
0.3210 35131.1802
 Double Interpolasi
p T H (m)
20 X1 320 m1,1 3068.8
21.25101055 X 323 m1,2 2984.3
25 X2 325 m2,1 3080.2
m2,2 2998.7

jadi 3021.402667852 722.133366032635 kcal/kg

kj/kg

Double Interpolasi
p T H (m)
10 X1 205 m1,1 2839.3
17.52 X 206 m1,2 2851.1
20 X2 210 m2,1 875.06
m2,2 897.69

jadi 1366.180352 326.525301210112 kcal/kg

kj/kg
total 395.6080648225
 0.18028981017057
10285.067029
0.00018028981017057
10285067.029

Berat Molekul
UREA 60.06200
NH3 17.03400
CO2 44.01000
H2O 18.01600
BIURET 103.0900
KARBAMAT 78.0780

DATA MENGGUNAKAN CARBAMAT

Stream 4
Inlet CO2
KOMPONEN Kg
NH2CONH2 0
NH3 0
CO2 72830.28642
H2O 0
NH2CONHCONH2 0
NH4COONH2 0
72830.28642
Total Kg
495662.0314398

Aliran 9B (gas)
Mol CpdT(Kj/Kmol K) H sensible (KJ)
0 0 0
290.951248502994 6097.71184899385 1774136.87547626
41.4033338786639 6536.88650418106 270648.894459541
21.5786435834814 5471.45912397886 118066.666317927
0 0 0
0 0 0
2162852.43625373
4

3. PANAS STEAM
Komponen Tekanan (kg/cm2 G)
Steam (superhated) / input 21.6700
Condensat (saturated) / output 17.5200

massa utk mencari Q steam 86850

ΔH 525.608064822523

Q steam 45649060.4298361
190995668.838434
 p
21.67
2125.101055
2.125101055
21.25101055
752.133366032635

p
17.49
1715.183085
1.715183085
17.15183085
226.525301210112

495.608064822523
 Cp Biuret
x1 33.06
cp
x2 33.27
y1 317.55
suhu
y2 320.52

Inlet
4 9A 9B
Inlet CO2 Reactor Out sol N Reactor Top Gas
kmol Kg kmol Kg
0 130401.3102 2171.11168792248 0
0 101357.5973 5950.31098391452 4956.063567
1654.857678255 0 0 1822.160724
0 87856.22434 4876.56662633215 388.7608428
0 338.265396 3.28126293529925 0
0 95711.36265 1225.84290901406 0
1654.857678255 415664.759886 14227.1134701185 7166.9851338
Kg kmol
495662.0314398 16235.9043743386

%wt karbamat 23.03 %

T operasi 185.15 °C
cp karbamat 1.01136812671707 cal/gmol `C
cp 4.23156424218422 KJ/kmol K
OUTLET
Aliran 10 (liquid) Aliran 11 (gas)

Mol CpdT(Kj/Kmol K) H sensible (KJ) Mol

2070.5382704539 20606.2131554415 42665952.9474714 0

466.97121744746 22725.8423781705 10612314.2828533 6853.83694963015
0 0 0 2235.27558373097
3678.9834702487 11878.9361727564 43702409.8237099 1121.62195881439
4.7980511310505 27758.823924 133188.256525181 0
784.36817797587 51403.1144 40318967.158503 0
137432832.469063
 201079776.877624

M
ekanan (kg/cm2 G) Temperatur (̊C) Flow(T/hr) Massa(kg/h)
21.6700 323 86.96 86960
17.5200 206 86.85 86850

(kg/h)

(kcal/kg)

kcal
kj
 p
20
1961.33
1.96133
kg/cm2g 19.6133
kpa
mpa
bar

kg/cm2g
kpa
mpa
bar
 Outlet
9B 10 11
Reactor Top Gas Stripper out Sol'N Stripper Top Gas
kmol Kg kmol Kg kmol
0 124360.6696 2070.53827045386 0 0
290.951248502994 7954.387718 466.971217447458 116748.2586 6853.83694963
41.4033338786639 0 0 98374.47844 2235.275583731
21.5786435834814 66280.5662 3678.98347024867 20207.14121 1121.621958814
0 494.6310911 4.79805113105054 0 0
0 61241.8986 784.36817797587 0 0
353.933225965139 260332.1532091 7005.65918725691 235329.87825 10210.73449218
ol Kg kmol
3743386 495662.0314591 17216.3936794324

%wt karbamat 23.52 %

T operasi 180.48 °C
cp karbamat 1.01203269802062 cal/gmol `C
330.392072901259 CpdT 4.23434480851829 KJ/kmol K 330.6092

Aliran 11 (gas)

CpdT(Kj/Kmol K) H sensible (KJ)

0 0
6206.05584434063 42535294.8574099
6652.46436374034 14870091.1639092
5564.76122653643 6241558.38724215
0 0
0 0
63646944.4085612
Enthalpy(kcal/kg) Enthalpy(kj/kg)
752.133366032635 3021.402667852
226.525301210112 1366.180352
kg/cm2g T/P H
kpa y1 20 x1
mpa y 24 x
bar y2 30 x2

4 x-
10 -0.01

-0.04 : 30

10.12 : 30
x 0.337333333333
0.080624690667

Data CP Karbamat 9a
t1 182 y1 1.01
t2 182 y2 1.014
t 182 y

y 1.01136812671707

Data CP Karbamat 10
t1 182 y1 1.01
t2 182 y2 1.014
t 182 y

y 1.01203269802062
 4. PANAS REAKSI
gas
ΔHf NH3
liquid
liquid
ΔHf CO2
gas
liquid
ΔHf H2O
gas
ΔHf Urea liquid
solid
ΔHf Carbamate
liquid
ΔHf Biuret liquid

Reaksi
m
b
s

Panas Pembentukan (∆Hf 298)

∆H Rx.1 =
=
=
=

Qf 298 =

PANAS REAKTAN

Q reaktan RX.1 =
 PANAS PRODUK

Q produk rx.1 =

PANAS REAKSI (Hrx)

Q rx.1 =

Q TOT =

NERACA PANAS
KOMPONEN INPUT (KJ)
Panas Sensibel 321989162.379
Panas Steam 190995668.838
Panas Penguapan 0
Panas Reaksi 0
Panas Terakumulasi 0
Total 512984831.218
 1.016
0
1.006

1.016 :

x 10.16 min

22 x1
25 x2
23.03 x

22 x1
25 x2
23.52 x
REAKSI
-46.19 kj/mol
-67.2 kj/mol
-412.92 kj/mol
-393.51 kj/mol
-285.84 kj/mol
-241.826 kj/mol
-333.6 kj/mol
-645.05 kj/mol
-626.4703 kj/mol
-36.16 kj/mol

Reaksi Dekomposisi Carbamat

NH4COONH2(l) ↔ CO2(g) 2NH3(g)

1225.842909 - -
441.474731 441.474731 882.949462
784.368178 441.474731 882.949462

produk - reaktan
(∆Hf 2(ammonia) + ∆Hf(CO2)) - ∆Hf carbamat
140.58032
140580.32 kj/kmol

62062658.9558939 kj

23359439.2041048 kJ
 8416528.58437186 kJ

47119748.336161 kJ

73533483.5081427

PANAS
OUTPUT (KJ)
201079776.877624
0 Total output selain panas terakumulasi ###
195465770.494464
73533483.5081427 0.9163604892
42905800.3376475 91.636048919 %
512984831.217878
 Reaksi Hidrolisis

Reaksi NH2CONH2(l) H2O(l) ↔

m 2171.11169 4898.14527
b 97.53984065 97.53984065
s 2073.57184935 4800.60542935

Panas Pembentukan (∆Hf 298)

∆H Rx.2 = produk - reaktan
= (∆Hf 2(ammonia) + ∆Hf(CO2)) - (∆Hf urea +∆Hf H2O)
= 133.55
= 133550 kj/kmol

Qf 298 = 26052891.437615 kj

PANAS REAKTAN

Q reaktan RX.2 = 3260199.54643356 kJ

 PANAS PRODUK

Q produk rx.2 = 1859555.71021301 kJ

PANAS REAKSI (Hrx)

Q rx.2 = 24652247.6013945 kJ
 Reaksi Pembentukan Biuret

CO2(g) 2NH3(g) Reaksi 2NH2CONH2(l)

- - m 2073.571847
97.53984 195.0796813 b 3.033576392
97.53984 195.0796813 s 2070.538270608

Panas Pembentukan (∆Hf 298)

∆H Rx.3 = produk - reaktan
urea +∆Hf H2O) = (∆Hf(biuret) + ∆Hf(ammonia)) -
= 584.85
= 584850

Qf 298 = 1774187.1528612

PANAS REAKTAN

Q reaktan RX.3 = 64217.1109851559

 PANAS PRODUK

Q produk rx.3 = 51517.5287111783

PANAS REAKSI (Hrx)

Q rx.3 = 1761487.57058722
Pembentukan Biuret

↔ NH2CONHCONH2(l) NH3(g)
- -
1.516788196 1.516788
1.516788196 1.516788

uret) + ∆Hf(ammonia)) - ∆Hf 2(Urea)

kj/kmol

kj

kJ
kJ
1. PANAS SENSIBLE
Tabel Data Kapasitas Panas pada Gas dan Liquid
Komponen A B
NH3(l) -182.157 3.36E+00
NH3(g) 33.573 -1.26E-02
CO2(g) 27.437 4.23E-02
CO2(l) -3981.02 5.25E+01
H2O(l) 92.053 -4.00E-02
H2O(g) 33.933 -8.42E-03
O2(g) 29.526 -8.90E-03
Urea(l) 965.507 -5.10E+00
Urea(g) 24.856 1.44E-01
(sumber:Yaws,Carl.1999.)

dik:
suhu inlet ke stripper (A9a) =
suhu inlet ke stripper (A9b) =
suhu inlet CO2 (A4) =
suhu outlet ke HPD (A10) =
suhu outlet ke CC (A11) =
(sumber:material balance pusri)

Stream
Aliran 4
Mol CpdT(Kj/Kmol K)
KOMPONEN
NH2CONH2 0 0
NH3 0 0
CO2 1612.4052 3575.97125780573
 H2O 0 0
NH2CONHCONH2 0 0
NH4COONH2 0 0
Total

2. PANAS PENGUAPAN
Komponen A T Tc n
NH3 31.5230 239.75 405.6500 0.3640
H2O 52.0530 457 647.1300 0.3210

Hpenguapan NH3 149134744.63156

Hpenguapan H2O ###

###
input

p
Y1 20
Y 21.2804305
Y2 50

2944.3686
127.74172

output

p
Y1 10
Y 17.19105745
Y2 20

798.20597
632.51535
 43.0615 0.18029
238.846 10285.07
238846 0.00018
10285067
C D E
-1.44E-02 2.04E-05
8.89E-05 -7.18E-08 1.86E-11
-1.96E-05 4.00E-09 -2.99E-13
-2.27E-01 3.29E-04
-2.11E-04 5.35E-07
2.99E-05 -1.78E-08 3.69E-12
3.81E-05 -3.26E-08 8.86E-12
1.00E-02 -6.38E-06
3.81E-05 -1.10E-07 3.92E-11

°C K (+273)
185.17 458.17
185.17 458.17
114.86 387.86
180.47 453.47
187.91 460.91

INLET
Aliran 4 Aliran 9A (liquid) Aliran 9B
H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ) Mol
0 2202.984965536 21171.1923764506 46639818.5077828 0
0 5421.757039451 24076.6854078929 130537938.596879 273.7491
5765914.626598 0 0 0 41.94029
 0 4627.206138988 12257.1237471628 56716238.2492019 20.47523
0 1.998593549326 28818.400411695 57596.2691647025 0
0 1241.740679961 52948.1701131202 65747896.75896 0
5765914.626598 299699488.381988
307521105.881532

ΔHv (kJ/kmol)
22770
35131.1802
 Double Interpolasi
T H (m)
X1 320 m1,1 3068.8
X 323 m1,2 3080.2
X2 325 m2,1 2984.3
m2,2 2998.7

jadi 3072.110279922 734.252789562958 kcal/kg 764.2528

kj/kg

Double Interpolasi
T H (m)
X1 205 m1,1 2839.3
X 206 m1,2 2851.1
X2 210 m2,1 875.06
m2,2 897.69

jadi 1430.721314485 341.950978489771 kcal/kg 241.951

kj/kg
total 392.3018110732 492.3018
 Cp Biuret
Berat Molekul
cp
UREA 60.06200
NH3 17.03400
suhu
CO2 44.01000
H2O 18.01600
BIURET 103.0900
KARBAMAT 78.0780

DATA MENGGUNAKAN CARBAMAT

Inlet
Stream 4 9A
Inlet CO2 Reactor Out sol N
KOMPONEN Kg kmol Kg
NH2CONH2 0 0 132315.683
NH3 0 0 92354.20941
CO2 70961.95255 1612.405193138 0
H2O 0 0 83363.7458
NH2CONHCONH2 0 0 206.035009
NH4COONH2 0 0 96952.62881
70961.95255 1612.405193138 405192.302029
Total Kg
483031.9704121

%wt karbamat
T operasi
cp karbamat
Cp
OUTLET
Aliran 9B (gas) Aliran 10 (liquid)
CpdT(Kj/Kmol K) H sensible (KJ) Mol CpdT(Kj/Kmol K)

0 0 2044.0290966 20605.0100097586
6098.51956569569 1669464.18394105 481.7429774569 22723.0305639783
6537.74831336795 274195.043586758 0 0
 5472.15516364417 112043.645418508 3626.18620393 11878.1321559227
0 0 3.199322746144 27756.586625257
0 0 730.9692808474 51321.7384178333
2055702.87294632
194676571.04526

3. PANAS STEAM
Komponen Tekanan (kg/cm2 G) Temperatur (̊C)
Steam (superhated) / input 21.7000 323
Condensat (saturatead) / output 17.5300 206

massa utk mencari Q steam 86660 (kg/h)

ΔH 522.301811073187 (kcal/kg)

Q steam 45262674.9476024 kcal

189379031.980768 kj
p
21.7 kg/cm2g
2128.04305 kpa
2.12804305 mpa
21.2804305 bar

p
17.53 kg/cm2g
1719.105745 kpa
1.719105745 mpa
17.19105745 bar
 Cp Biuret
x1 33.06
x2 33.27
y1 317.55
y2 320.52

Inlet Outlet
9A 9B 10
Reactor Out sol N Reactor Top Gas Stripper out Sol'N
kmol Kg kmol Kg kmol
2202.98496553561 0 0 122768.4756 2044.02909660018
5421.75703945051 4663.042006 273.74909040742 8206.009878 481.742977456851
0 1845.792051 41.940287457396 0 0
4627.20613898757 368.8817761 20.4752317995115 65329.37065 3626.18620392984
1.99859354932583 0 0 329.8181819 3.19932274614415
1241.74067996106 0 0 57072.61951 730.969280847358
13495.6874174841 6877.7158331 336.164609664328 253706.2938199 6886.12688158037
kmol Kg
15444.2572202863 483031.9699699

23.93 % %wt karbamat 22.50

185.17 °C T operasi 180.47
1.01192755941426 cal/gmol `C cp karbamat 1.01049554737121
4.23390490858927 KJ/kmol K 330.574827452833 cp 4.22791337020115
OUTLET
10 (liquid) Aliran 11 (gas)

H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ)

42117239.9956845 0 0 0
10946660.4007339 6549.615486674 6209.29340187545 40668484.2262244
0 2321.671283799 6655.91740189464 15452852.2993178
43072318.9522624 864.9407609902 5567.54738146826 4815598.66897632
88802.2789455051 0 0 0
37514614.2231198 0 0 0
133739635.850746 60936935.1945185
194676571.045265

Flow(T/hr) Massa(kg/h) Enthalpy(kcal/kg) Enthalpy(kj/kg)

84.53 84530 764.252789562958 3072.11027992167
86.66 86660 241.950978489771 1430.72131448487
p
20 kg/cm2g T/P
1961.33 kpa y1
1.96133 mpa y
19.6133 bar y2

4
10

-0.04

10.12

Data CP Karbamat 9a
t1 182 y1
t2 182 y2
t 182 y

y 1.01192755941426

Data CP Karbamat 10
t1 182 y1
t2 182 y2
t 182 y

y 1.01049554737121
 4. PANAS REAKSI

ΔHf NH3

ΔHf CO2

ΔHf H2O
ΔHf Urea
ΔHf Carbamate
ΔHf Biuret

Outlet
11
Stripper Top Gas
Kg kmol
0 0
111566.1502 6549.61548667
102176.7532 2321.6712838
15582.77275 864.94076099
0 0
0 0
229325.67615 9736.22753146
kmol
16622.3544130435

%
°C
cal/gmol `C
KJ/kmol K 330.107020119
 NERACA PANAS
KOMPONEN
Panas Sensibel
Panas Steam
Panas Penguapan
Panas Reaksi
Panas Terakumulasi
Total
 H
20 x1 1.016
24 x 0
30 x2 1.006

x- 1.016 :
-0.01

: 30 x 10.16 min

: 30 x
x 0.33733333333
0.08062469067

1.011 23 x1
1.012 24 x2
23.93 x

1.01 22 x1
1.011 23 x2
22.50 x
4. PANAS REAKSI
gas -46.19 kj/mol
liquid -67.2 kj/mol
liquid -412.92 kj/mol
gas -393.51 kj/mol
liquid -285.84 kj/mol
gas -241.826 kj/mol
liquid -333.6 kj/mol
solid -645.05 kj/mol
liquid -626.4703 kj/mol
liquid -36.16 kj/mol

Reaksi Dekomposisi Carbamat

Reaksi NH4COONH2(l) ↔ CO2(g)

m 1241.74068 -
b 510.7713991 510.7713991
s 730.9692809 510.7713991

Panas Pembentukan (∆Hf 298)

∆H Rx.1 = produk - reaktan
= (∆Hf 2(ammonia) + ∆Hf(CO2)) - ∆Hf carbamat
= 140.58032
= 140580.32 kJ/kmol

Qf 298 = 71804406.7323257 kJ

PANAS REAKTAN
 Q reaktan RX.1 = 27044410.9284632

PANAS PRODUK

Q produk rx.1 = 9742711.20025641

PANAS REAKSI (Hrx)

Q rx.1 = 54502707.0041189

Q TOT = 95465671.0509176

NERACA PANAS
INPUT (KJ) OUTPUT (KJ)
307521105.88153 194676571.045265
189379031.98077 0
0 179521134.368233
0 95465671.0509176 Total output selain panas terakumulasi
0 27236761.3978849
496900137.8623 496900137.862301 ef 0.945186649544797
94.5186649544797
 2NH3(g) Reaksi
- m
1021.5427982 b
1021.5427982 s

Panas Pembentukan (∆Hf 298)

∆H Rx.2 =
=
=
=

Qf 298 =

PANAS REAKTAN
 Q reaktan RX.2 =

PANAS PRODUK

Q produk rx.2 =

PANAS REAKSI (Hrx)

Q rx.2 =

###
 Reaksi Hidrolisis

NH2CONH2(l) H2O(l) ↔ CO2(g) 2NH3(g)

2202.984959 4647.68137 - -
156.5544047 156.5544047 156.5544047 313.1088094
2046.4305543 4491.1269653 156.5544047 313.1088094

produk - reaktan
(∆Hf 2(ammonia) + ∆Hf(CO2)) - (∆Hf urea +∆Hf H2O)
133.55
133550 kJ/kmol

41815681.49537 kJ
 5233350.1308557

2986197.65086249

39568529.0153768
 Reaksi Pembentukan Biuret

Reaksi 2NH2CONH2(l) ↔ NH2CONHCONH2(l) NH3(g)

m 2046.430554 - -
b 2.4014584 1.2007292 1.200729
s 2044.0290956 1.2007292 1.200729

Panas Pembentukan (∆Hf 298)

∆H Rx.3 = produk - reaktan
= (∆Hf(biuret) + ∆Hf(ammonia)) - ∆Hf 2(Urea)
= 584.85
= 584850 kJ/kmol

Qf 298 = 1404492.94524 kJ

PANAS REAKTAN
 Q reaktan RX.3 = 50841.7377704432

PANAS PRODUK

Q produk rx.3 = 40783.8239522747

PANAS REAKSI (Hrx)

Q rx.3 = 1394435.03142183
1. PANAS SENSIBLE
Tabel Data Kapasitas Panas pada Gas dan Liquid
Komponen A
NH3(l) -182.157
NH3(g) 33.573
CO2(g) 27.437
CO2(l) -3981.02
H2O(l) 92.053
H2O(g) 33.933
O2(g) 29.526
Urea(l) 965.507
Urea(g) 24.856
(sumber:Yaws,Carl.1999.)

dik:
suhu inlet ke stripper (A9a)
suhu inlet ke stripper (A9b)
suhu inlet CO2 (A4)
suhu outlet ke HPD (A10)
suhu outlet ke CC (A11)
(sumber:material balance pusri)

Stream
Alir
Mol
KOMPONEN
NH2CONH2 0
NH3 0
CO2 1622.637
H2O 0
 NH2CONHCONH2 0
NH4COONH2 0
Total

2. PANAS PENGUAPAN
Komponen A T Tc
NH3 31.5230 239.75 405.6500
H2O 52.0530 457 647.1300

Hpenguapan NH3 ###

Hpenguapan H2O ###

###
input

p
Y1
Y
Y2

2948.564
125.906

output

p
Y1
Y
Y2

828.8599
623.027
 43.0615
238.846
238846
a Gas dan Liquid
B C D E
3.36E+00 -1.44E-02 2.04E-05
-1.26E-02 8.89E-05 -7.18E-08 1.86E-11
4.23E-02 -1.96E-05 4.00E-09 -2.99E-13
5.25E+01 -2.27E-01 3.29E-04
-4.00E-02 -2.11E-04 5.35E-07
-8.42E-03 2.99E-05 -1.78E-08 3.69E-12
-8.90E-03 3.81E-05 -3.26E-08 8.86E-12
-5.10E+00 1.00E-02 -6.38E-06
1.44E-01 3.81E-05 -1.10E-07 3.92E-11

°C K (+273)
= 184.9 457.9
= 184.9 457.9
= 114.86 387.86
= 180.03 453.03
= 187.85 460.85

INLET
Aliran 4 Aliran 9A (liquid)
CpdT(Kj/Kmol K) H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ)
0 0 2119.62752822 21138.6265118546 44806014.6633058
0 0 5584.85370318 23997.156614818 134020608.986102
3575.97125780573 5802501.72353328 0 0 0
0 0 4693.25276032 12235.2910853755 57423313.6598081
 0 0 2.80484073916 28757.04875628 80658.9418896233
0 0 1264.73710764 52879.4280654304 66878574.9049159
5802501.72353328 303209171.156021
311114453.691591

n ΔHv (kJ/kmol)
0.3640 22770
0.3210 35131.1802
 Double Interpolasi
p T H (m)
20 X1 320 m1,1 3068.8
21.2608172 X 324 m1,2 3080.2
50 X2 325 m2,1 2984.3
m2,2 2998.7

jadi 3074.4695636 734.816672516826 kcal/kg

kj/kg

Double Interpolasi
p T H (m)
10 X1 205 m1,1 2839.3
17.0831843 X 206 m1,2 2851.1
20 X2 210 m2,1 875.06
m2,2 897.69

jadi 1451.88682478 347.009662442455 kcal/kg

kj/kg
total 387.807010074
 0.18028981017057
10285.067029
0.00018028981017057
10285067.029

Berat Molekul
UREA 60.06200
NH3 17.03400
CO2 44.01000
H2O 18.01600
BIURET 103.0900
KARBAMAT 78.0780

DATA MENGGUNAKAN CARBAMAT

Inlet
Stream 4
Inlet CO2
KOMPONEN Kg kmol
NH2CONH2 0 0
NH3 0 0
CO2 71412.23529 1622.63656646
H2O 0 0
NH2CONHCONH2 0 0
NH4COONH2 0 0
71412.23529 1622.63656646
Total Kg
484485.1378445

Aliran 9B (gas) Aliran 10 (liquid)

Mol CpdT(Kj/Kmol K) H sensible (KJ) Mol
0 0 0 2017.66958143
280.98961400728 6087.61643047233 1710556.991023 412.504380709
42.7170009543286 6526.11479387389 278776.051878 0
20.7674858847691 5462.75893795273 113447.7691358 3762.0604657
0 0 0 3.45380987875
0 0 0 742.572206896
2102780.812037

3. PANAS STEAM
Komponen Tekanan (kg/cm2 G)
Steam (superhated) / input 21.6800
Condensat (saturatead) / output 17.4200

massa utk mencari Q steam 86090 (kg/h)

ΔH 517.8070100744 (kcal/kg)

Q steam 44578005.4973 kcal

186514375.0007 kj
 p
21.68 kg/cm2g
2126.08172 kpa
2.12608172 mpa
21.2608172 bar
764.816672516826

p
17.42 kg/cm2g
1708.31843 kpa
1.70831843 mpa
17.0831843 bar
247.009662442455

487.80701007437
 Cp Biuret
x1 33.06
cp
x2 33.27
y1 317.55
suhu
y2 320.52

Inlet Outlet
9A 9B 10
Reactor Out sol N Reactor Top Gas Stripper out Sol'N
Kg kmol Kg kmol Kg
127309.0686 2119.6275282208 0 0 121185.2704
95132.39798 5584.8537031819 4786.377085 280.98961400728 7026.599621
0 0 1879.975212 42.7170009543286 0
84553.64173 4693.2527603242 374.1470257 20.7674858847691 67777.28135
289.1510318 2.80484073916 0 0 356.0532604
98748.14389 1264.737107636 0 0 57978.55277
406032.4032318 13665.275940102 7040.4993227 344.474100846377 254323.7574014
Kg kmol Kg
485.1378445 15632.3866074105 484485.1378114

%wt karbamat 24.32 % %wt karbamat

T operasi 184.9 °C T operasi
cp karbamat 1.0123202619062 cal/gmol `C cp karbamat
4.2355479758155 KJ/kmol K 330.703114855725
OUTLET
Aliran 10 (liquid) Aliran 11 (gas)

CpdT(Kj/Kmol K) H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ)

20552.0774718065 41467301.550109 0 0 0
22599.594556394 9322431.7567637 6699.6377246 6206.86521518584 41583748.3468618
0 0 2288.1784753 6653.32760724669 15224001.0203306
11842.7651532233 44553198.587478 851.29977298 5565.45775972848 4737872.92738426
 27657.851847726 95524.96193659 0 0 0
51191.7656650485 38013582.404781 0 0 0
133452039.26107 61545622.2945767
194997661.555644

Temperatur (̊C) Flow(T/hr) Massa(kg/h) Enthalpy(kcal/kg) Enthalpy(kj/kg)

324 84.59 84590 764.816672516826 3074.469563596
206 86.09 86090 247.009662442455 1451.88682477618
p
20 kg/cm2g
1961.33 kpa
1.96133 mpa
19.6133 bar

Data CP Karbamat
t1 182
t2 182
t 182

Data CP Karbamat
t1 182
t2 182
t 182

y
 Outlet
10 11
Stripper out Sol'N Stripper Top Gas
kmol Kg kmol
2017.66958143252 0 0
412.50438070917 114121.629 6699.63772455
0 100702.7347 2288.17847535
3762.06046569716 15337.01671 851.29977298
3.45380987874673 0 0
742.572206895668 0 0
6938.26044461326 230161.38041 9839.11597288
Kg kmol
484485.1378114 16777.3764174902

22.80 %
180.03 °C
1.01079714383053 cal/gmol `C
4.22917524978693 KJ/kmol K 330.205545153
T/P H
y1 20 x1 1.016
y 24 x 0
y2 30 x2 1.006

4 x- 1.016 :
10 -0.01

-0.04 : 30 x 10.16 min

10.12 : 30 x
x 0.33733333333
0.08062469067

9a
y1 1.012 24 x1
y2 1.013 25 x2
y 24.32 x

1.0123202619062

10
y1 1.01 22 x1
y2 1.011 23 x2
y 22.80 x

1.01079714383053
 4. PANAS REAKSI
gas -46.19 kj/mol
ΔHf NH3
liquid -67.2 kj/mol
liquid -412.92 kj/mol
ΔHf CO2
gas -393.51 kj/mol
liquid -285.84 kj/mol
ΔHf H2O
gas -241.826 kj/mol
ΔHf Urea liquid -333.6 kj/mol
solid -645.05 kj/mol
ΔHf Carbamate
liquid -626.4703 kj/mol
ΔHf Biuret liquid -36.16 kj/mol

Reaksi Dekomposisi Carbamat

Reaksi NH4COONH2(l)
m 1264.737108
b 522.1649007
s 742.5722073

Panas Pembentukan (∆Hf 298)

∆H Rx.1 = produk - reaktan
= (∆Hf 2(ammonia) + ∆Hf(CO2)) - ∆Hf carbamat
= 140.58032
= 140580.32

Qf 298 = 73406108.8331742

PANAS REAKTAN
 Q reaktan RX.1 = 27611781.3048583

PANAS PRODUK

Q produk rx.1 = 9956148.46685413

PANAS REAKSI (Hrx)

Q rx.1 = 55750475.9951701

Q TOT = 82020308.5366838

NERACA PANAS
KOMPONEN INPUT (KJ) OUTPUT (KJ)
Panas Sensibel 311114453.691591 194997661.555644
Panas Steam 186514375.000714 0
Panas Penguapan 0 182457916.716788
Panas Reaksi 0 82020308.5366838 Total output selain panas ter
Panas Terakumulasi 0 38152941.8831887
Total 497628828.692305 497628828.692305
 Reaksi Dekomposisi Carbamat

↔ CO2(g) 2NH3(g)
- -
522.1649007 1044.3298014
522.1649007 1044.3298014

monia) + ∆Hf(CO2)) - ∆Hf carbamat

kJ/kmol

kJ
Total output selain panas terakumulasi ###
ef 0.92333052331
92.3330523307
 Reaksi Hidrolisis

Reaksi NH2CONH2(l) H2O(l) ↔ CO2(g)

m 2119.627527 4714.020246 -
b 100.6600077 100.6600077 100.6600077
s 2018.9675193 4613.3602383 100.6600077

Panas Pembentukan (∆Hf 298)

∆H Rx.2 = produk - reaktan
= (∆Hf 2(ammonia) + ∆Hf(CO2)) - (∆Hf urea +∆Hf H2O)
= 133.55
= 133550 kJ/kmol

Qf 298 = 26886288.05667 kJ

PANAS REAKTAN
 Q reaktan RX.2 = 3359418.80231635

PANAS PRODUK

Q produk rx.2 = 1919290.20888301

PANAS REAKSI (Hrx)

Q rx.2 = 25446159.4632367
 Reaksi Pembentukan Biuret

2NH3(g) Reaksi 2NH2CONH2(l) ↔

- m 2018.96752
201.3200154 b 1.29793828
201.3200154 s 2017.66958172

Panas Pembentukan (∆Hf 298)

∆H Rx.3 = produk - reaktan
= (∆Hf(biuret) + ∆Hf(ammonia)) - ∆Hf 2(Urea)
= 584.85
= 584850 kJ/kmol

Qf 298 = 759099.203058 kJ

PANAS REAKTAN
 Q reaktan RX.3 = 27436.632536359

PANAS PRODUK

Q produk rx.3 = 92010.5077553952

PANAS REAKSI (Hrx)

Q rx.3 = 823673.078277036
kan Biuret

NH2CONHCONH2(l) NH3(g)
- -
0.64896914 0.64896914
0.64896914 0.64896914

(ammonia)) - ∆Hf 2(Urea)

1. PANAS SENSIBLE
Tabel Data Kapasitas Panas pada Gas dan Liquid
Komponen A B
NH3(l) -182.157 3.3618
NH3(g) 33.573 -0.012581
CO2(g) 27.437 0.042315
CO2(l) -3981.02 5E+01
H2O(l) 92.053 -0.03995
H2O(g) 33.933 -0.0084186
O2(g) 29.526 -0.0089
Urea(l) 965.507 -5.0993
Urea(g) 24.856 0.144
(sumber:Yaws,Carl.1999.)

dik:
suhu inlet ke stripper (A9a) =
suhu inlet ke stripper (A9b) =
suhu inlet CO2 (A4) =
suhu outlet ke HPD (A10) =
suhu outlet ke CC (A11) =
(sumber:material balance pusri)

Stream
Aliran 4
Mol CpdT(Kj/Kmol K)
KOMPONEN
NH2CONH2 0 0
NH3 0 0
CO2 1627.9811725 3596.5418554209
H2O 0 0
 NH2CONHCONH2 0 0
NH4COONH2 0 0
Total

2. PANAS PENGUAPAN
Komponen A T Tc n
NH3 31.5230 239.75 405.6500 0.3640
H2O 52.0530 457 647.1300 0.3210

Hpenguapan NH3 ###

Hpenguapan H2O ###

###
input

p
Y1 20
Y 21.21178395
Y2 50

2953.5941982
121.0095531

output

p
Y1 10
Y 17.17144415
Y2 20

803.77940167
630.79018741
 43.0615 0.1802898101706
238.846 10285.067029
238846 0.0001802898102
10285067.029
C D E
-0.014398 0.000020371
9E-05 -7.1783E-08 1.86E-11
-2E-05 3.9968E-09 -2.99E-13
-2E-01 3E-04
-0.00021103 0.00000053469
3E-05 -1.7825E-08 3.69E-12
0.0000381 -0.0000000326 8.86E-12
0.010028 -0.0000063799
0.0000381 -0.00000011 3.92E-11

°C K (+273)
185.31 458.31
185.31 458.31
115.36 388.36
180.55 453.55
187.88 460.88

INLET
iran 4 Aliran 9A (liquid) Aliran 9B (ga
H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ) Mol
0 2182.492314608 21188.0804423307 46242822.7266879 0
0 5775.569005518 24118.0085445984 139295222.62501 288.6462725138
5855102.426592 0 0 0 43.230238832084
0 4224.507999001 12268.4473529066 51828153.9776752 18.693306055728
 0 3.204933611408 28850.229371779 92463.0698104306 0
0 1279.932719972 53030.9313063247 67876024.1495702 0
5855102.426592 305334686.548753
313337009.006061

ΔHv (kJ/kmol)
22770
35131.1802
 Double Interpolasi
T H (m)
X1 320 m1,1 3068.8
X 324 m1,2 3080.2
X2 325 m2,1 2984.3
m2,2 2998.7

jadi 3074.603751257 734.848744172891 kcal/kg 764.84874417289

kj/kg

Double Interpolasi
T H (m)
X1 205 m1,1 2839.3
X 206 m1,2 2851.1
X2 210 m2,1 875.06
m2,2 897.69

jadi 1434.569589083 342.870739208441 kcal/kg 242.87073920844

kj/kg
total 391.9780049645 491.97800496445
 Cp Biuret
Berat Molekul
cp
UREA 60.06200
NH3 17.03400
suhu
CO2 44.01000
H2O 18.01600
BIURET 103.0900
KARBAMAT 78.0780

DATA MENGGUNAKAN CARBAMAT

Inlet
Stream 4 9A
Inlet CO2 Reactor Out sol N
KOMPONEN Kg kmol Kg
NH2CONH2 0 0 131084.8534
NH3 0 0 98381.04244
CO2 71647.4514 1627.981172461 0
H2O 0 0 76108.73611
NH2CONHCONH2 0 0 330.396606
NH4COONH2 0 0 99934.58691
71647.4514 1627.981172461 405839.615466
Total Kg
484643.2088849

%wt karbamat
T operasi
cp karbamat
CpdT
OUTLET
Aliran 9B (gas) Aliran 10 (liquid)
CpdT(Kj/Kmol K) H sensible (KJ) Mol CpdT(Kj/Kmol K)

0 0 2007.978925111 20614.635342612
6104.17392785968 1761947.05105259 560.9791705413 22745.53311758
6543.78127780172 282889.227504286 0 0
5477.02754413659 102383.752158199 3678.085779862 11884.564566511
 0 0 3.699819481036 27774.55071411
0 0 736.0780629627 51353.55600407
2147220.03071508
196918599.2629

3. PANAS STEAM
Komponen Tekanan (kg/cm2 G) Temperatur (̊C)
Steam (superhated) / input 21.6300 324
Condensat (saturated) / output 17.5100 206

massa utk mencari Q steam 87920 (kg/h)

ΔH 521.97800496445 (kcal/kg)

Q steam 45892306.1964745 kcal

192013409.126049 kj
p
21.63 kg/cm2g
2121.178395 kpa
2.121178395 mpa
21.21178395 bar

p
17.51 kg/cm2g
1717.144415 kpa
1.717144415 mpa
17.17144415 bar
 Cp Biuret
x1 33.06
x2 33.27
y1 317.55
y2 320.52

Inlet Outlet
9A 9B 10
Reactor Out sol N Reactor Top Gas Stripper out Sol'N
kmol Kg kmol Kg kmol
2182.492314608 0 0 120603.2302 2007.97892511072
5775.569005518 4916.800606 288.646272513796 9555.719191 560.97917054127
0 1902.562811 43.2302388320836 0 0
4224.507999001 336.7786019 18.6933060557282 66264.39341 3678.08577986235
3.204933611408 0 0 381.4143903 3.69981948103599
1279.932719972 0 0 57471.503 736.078062962678
13465.70697271 7156.1420189 350.569817401608 254276.2601913 6986.82175795805
kmol Kg
15444.2579625737 484643.2088933

24.62 % %wt karbamat 22.60

185.31 °C T operasi 180.55
1.012624157697 cal/gmol `C cp karbamat 1.01060199318519
4.236819475805 KJ/kmol K 330.802391031905 CpdT 4.22835873948685
OUTLET
10 (liquid) Aliran 11 (gas)

H sensible (KJ) Mol CpdT(Kj/Kmol K) H sensible (KJ)

41393753.31681 0 0 0
12759770.30182 6938.4875425619 6208.07929462658 43074680.8490032
0 2388.5896864349 6654.62249254672 15895162.6528148
43712447.93194 391.59190730462 5566.50256644253 2179797.35700928
102760.823809 0 0 0
37800226.02972 0 0 0
135768958.4041 61149640.8588273
196918599.262925

Flow(T/hr) Massa(kg/h) Enthalpy(kcal/kg) Enthalpy(kj/kg)

85.76 85760 764.848744172891 3074.60375125683
87.92 87920 242.870739208441 1434.56958908329
p
20 kg/cm2g T/P
1961.33 kpa y1
1.96133 mpa y
19.6133 bar y2

4
10

-0.04

10.12

Data CP Karbamat 9a
t1 182 y1
t2 182 y2
t 182 y

y 1.01262415769719

Data CP Karbamat 10
t1 182 y1
t2 182 y2
t 182 y

y 1.01060199318519
 4. PANAS REAK

ΔHf NH3

ΔHf CO2

ΔHf H2O
ΔHf Urea
ΔHf Carbamate

ΔHf Biuret

Outlet
11
Stripper Top Gas
Kg kmol
0 0
118190.1968 6938.48754256194
105121.8321 2388.5896864349
7054.919802 391.591907304618
0 0
0 0
230366.948702 9718.66913630145
kmol
16705.4908942595

%
°C
cal/gmol `C
KJ/kmol K 330.141793661654
 NERACA PANA
KOMPONEN
Panas Sensibel
Panas Steam
Panas Penguapan
Panas Reaksi
Panas Terakumulasi
Total
 H
20 x1 1.016
24 x 0
30 x2 1.006

x- 1.016 :
-0.01

: 30 x 10.16 min

: 30 x
x 0.33733333333333
0.08062469066667

1.012 24 x1
1.013 25 x2
24.62 x

1.01 22 x1
1.011 23 x2
22.60 x
4. PANAS REAKSI
gas -46.19 kj/mol
liquid -67.2 kj/mol
liquid -412.92 kj/mol
gas -393.51 kj/mol
liquid -285.84 kj/mol
gas -241.826 kj/mol
liquid -333.6 kj/mol
solid -645.05 kj/mol
liquid -626.4703 kj/mol
liquid -36.16 kj/mol

Reaksi Dekomposisi Carbamat

Reaksi NH4COONH2(l) ↔ CO2(g)

m 1279.93272 -
b 543.8546571 543.8546571
s 736.0780629 543.8546571

Panas Pembentukan (∆Hf 298)

∆H Rx.1 = produk - reaktan
= (∆Hf 2(ammonia) + ∆Hf(CO2)) - ∆Hf carbamat
= 140.58032
= 140580.32 kJ/kmol

Qf 298 = 76455261.7286083 kJ

PANAS REAKTAN
 Q reaktan RX.1 = 28841118.9612949

PANAS PRODUK

Q produk rx.1 = 10371733.1058714

PANAS REAKSI (Hrx)

Q rx.1 = 57985875.8731849

Q TOT = 102412481.611218

NERACA PANAS
INPUT (KJ) OUTPUT (KJ)
313337009.006061 196918599.262925
192013409.126049 0
0 171746447.204516
0 102412481.611218 Total output selain panas terakumulasi
0 34272890.0534514
505350418.13211 505350418.13211 ef 0.932179951131471
93.2179951131471
 2NH3(g) Reaksi
- m
1087.7093142 b
1087.7093142 s

Panas Pembentukan (∆Hf 298)

∆H Rx.2 =
=
=
=

Qf 298 =

PANAS REAKTAN
 Q reaktan RX.2 =

PANAS PRODUK

Q produk rx.2 =

PANAS REAKSI (Hrx)

Q rx.2 =

###
 Reaksi Hidrolisis

NH2CONH2(l) H2O(l) ↔ CO2(g) 2NH3(g)

2182.492315 4243.201305 - -
173.5236181 173.5236181 173.5236181 347.0472362
2008.9686969 4069.6776869 173.5236181 347.0472362

produk - reaktan
(∆Hf 2(ammonia) + ∆Hf(CO2)) - (∆Hf urea +∆Hf H2O)
133.55
133550 kJ/kmol

46348158.39451 kJ
 5805497.7520928

3309230.93330695

43851891.5757242
 Reaksi Pembentukan Biuret

Reaksi 2NH2CONH2(l) ↔ NH2CONHCONH2(l) NH3(g)

m 2008.968697 - -
b 0.98977174 0.49488587 0.49488587
s 2007.97892526 0.49488587 0.49488587

Panas Pembentukan (∆Hf 298)

∆H Rx.3 = produk - reaktan
= (∆Hf(biuret) + ∆Hf(ammonia)) - ∆Hf 2(Urea)
= 584.85
= 584850 kJ/kmol

Qf 298 = 578868.002139 kJ

PANAS REAKTAN
 Q reaktan RX.3 = 20971.3632466656

PANAS PRODUK

Q produk rx.3 = 16817.5234167617

PANAS REAKSI (Hrx)

Q rx.3 = 574714.162309096