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LAKSHYA JEE (2024)

Chemical Kinetics DPP-08

1. The rate constant, the activation energy and the 5. According to collision theory
Arrhenius parameter of a chemical reaction at 25°C (1) all collisions are sufficiently violent
are 3.0 × 10–4 s–1, 104.4 kJ mol–1 and 6.0 × 10–4 s–1, (2) all collisions are responsible for product
respectively. The value of rate constant at T →  is formation
(1) 2.0 × 1018 s–1 (3) all collisions are effective
(2) 6.0 × 10–4 s–1 (4) only a fraction of collisions are effective which
(3) infinity have enough energy to from products
(4) 3.6 × 1030 s–1
6. For a reaction Ea = 0 and k = 3.2 × 104 s–1 at 300 K.
2. In gaseous reactions, important for the understanding The value of k at 310 K would be
of the upper atmosphere H2O and O react (1) 6.4 × 104 s–1 (2) 3.2 × 104 s–1
bimolecularly to form two OH radicals. ΔH for this (3) 3.2 × 108 s–1 (4) 3.2 × 105 s–1
reaction is 72 kJ/mole at 500 K and Ea is 77 kJ mol–1;
then Ea for the bimolecular recombination o f two OH 7. For N2(g) + 3H2(g) → 2NH3(g), H = –22 kcal, Ea for
radicals to form H2O and O is the reaction is 70 kcal, Hence, the activation energy
(1) 3 kJ mol–1 (2) 4 kJ mol–1 for 2NH3(g) → N2(g) + 3H2(g) is
(3) 5 kJ mol –1
(4) 7 kJ mol–1 (1) 92 kcal (2) 70 kcal
(3) 48 kcal (4) 22 kcal
3. The hypothetical reaction, A2 + B2 → 2AB, follows
the following mechanism: 8. The activation energy for a chemical reaction
A2 ⇌ A + A (fast) depends upon
A + B2 → AB + B (slow) (1) Temperature
A + B → AB (fast) (2) Nature of reacting species
(3) Concentration of the reacting species
The order of the overall reaction is
(4) Collision frequency
(1) zero (2) 1
(3) 2 (4) 3/2 9. The rate of reaction increases to 2.3 times when the
temperature is raised from 300K to 310 K. If K is the
4. According to collision theory of reaction rates rate constant at 300 K then the rate constant at 310 K
will be equal to
(1) every collision between reactant molecules leads
(1) 2k (2) k
to a chemical reaction (3) 2.3k (4) 3k2
(2) rate of reaction is proportional to the velocity of
the molecules 10. The minimum energy for molecules to enter into
(3) rate of reaction is proportional to the average chemical reaction is called.
energy of the molecules (1) Kinetic energy
(2) Potential energy
(4) rate of reaction is proportional to the number of
(3) Threshold energy
collisions per second (4) Activation energy
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11. For a reaction, temperature coefficient = 2, if the 12. The activation energy of a reaction can be
temperature is increased from 25 oC to 35oC, then determined from the slope of which of the following
calculate the activation energy (in kJ) of the reaction. graphs?
(1) 52.8 kJ 1 T 1
(1) In k vs (2) vs
(2) 70 kJ T lnk T
(3) 100 kJ lnk
(3) lnkvsT (4) vs T
(4) 0 kJ T
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (2) 7. (1)
2. (3) 8. (2)
3. (4) 9. (3)
4. (4) 10. (3)
5. (4) 11. (1)
6. (2) 12. (1)

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